Home Physical Sciences The crystal structure of poly[bis(dimethylformamide-κ1N)-(μ4-2′,3,3″,5′-tetrakis(trifluoromethyl)-[1,1′:4′,1″-terphenyl]-4,4″-dicarboxylato-κ4 O,O′: O″,O‴)dicadmium(II)], C27H15CdF12NO5
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The crystal structure of poly[bis(dimethylformamide-κ1N)-(μ4-2′,3,3″,5′-tetrakis(trifluoromethyl)-[1,1′:4′,1″-terphenyl]-4,4″-dicarboxylato-κ4 O,O′: O″,O‴)dicadmium(II)], C27H15CdF12NO5

  • Yao-Hua Sun , Zhi-Jian Li , Ping Hao , Liang-Liang Zhang and Jing Hao ORCID logo EMAIL logo
Published/Copyright: June 27, 2025
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 240 Issue 5

Abstract

C27H15CdF12NO5, orthorhombic, Pnma (no. 62), a = 7.6643(3) Å, b = 31.5516(10) Å, c = 11.1830(4) Å, V = 2704.28(17) Å3, Z = 4, R gt(F) = 0.0359, wR ref(F 2) = 0.0906, T = 100 K.

CCDC no.: 2443859

The molecular structure is shown in the figure. Table 1 contains the crystallographic data and the list of the atoms including atomic coordinates and displacement parameters can be found in the cif-file attached to this article.

Table 1:

Data collection and handling.

Crystal: Clear whitish block
Size: 0.20 × 0.14 × 0.1 0mm
Wavelength: CuKα radiation (1.54184 Å)
μ: 7.63 mm−1
Diffractometer, scan mode: Rigaku synergy R, ω scans
θ max, completeness: 76.2°, 100 %
N(hkl)measured , N(hkl)unique, R int: 9169, 2754, 0.028
Criterion for I obs, N(hkl)gt: I obs > 2 σ(I obs), 2734
N(param)refined: 268
Programs: Rigaku, 1 Shelx, 2 Olex2 3

1 Source of material

The reagents were purchased from standard commercial sources and used without further purification. The 2′,3,3″,5′-tetrakis(trifluoromethyl)-[1,1′:4′,1″-terphenyl]-4,4″-dicarboxylic acid (H2TPDC-4CF3) was synthesized according to literature. 4 The preparation of the title crystal is similar to the previously reported literature procedure. 5 , 6 A mixture of H2TPDC-4CF3 (6.0 mg 0.01 mmol) and Cd(NO3)2·4H2O (6.0 mg 0.02 mmol) were dispersed in a mixed solution of N,N-dimethyl formamide (1.5 mL) and methyl alcohol (1.5 mL) and sealed in a caped glass bottle at 375 K for 72 h. The colourless block crystals suitable for X-ray single crystal diffraction analysis were prepared with the yield of 60 % based on H2TPDC-4CF3.

2 Experimental details

The initial crystal structure was solved and refined by Olex2 and SHELXS. 2 , 3 Anisotropic displacement parameters were assigned to all non-hydrogen atoms. Hydrogen atoms were located at geometrically calculated positions and refined with fixed thermal factors.

3 Comment

Metal-organic frameworks (MOFs) have attracted tremendous interest as a promising class of functional crystalline porous materials. 7 , 8 , 9 , 10 With the development of crystal engineering, the structures of MOFs can be predesigned and predicted according to several useful strategies such as reticular chemistry and soft/hard acid/base principle. In addition, the performance and structures of MOFs also could be significantly improved by introducing functional ligands containing F-carboxylic acids. 11 , 12 , 13 , 14 Recently, the LZPU-3 was obtained by using H2TPDC-4CF3 and Cd(NO3)2·4H2O under solvothermal conditions.

The asymmetric structural unit consists of one Cd atoms, one half of a deprotonated H2TPDC-4CF3 ligand, and one coordinated DMF molecule. The Cd(II) atom is coordinated with six oxygen atoms from four deprotonated H2TPDC-4CF3 ligands and one oxygen atom from coordinated DMF molecule, which form a seven-coordinated monocapped trigonal prism configuration. This deprotonated H2TPDC-4CF3 ligand adopts a tridentate bridging coordination mode. The Cd–O bond lengths fall in the range 2.267(3)–2.496(2) Å. In LZPU-3, the three benzene rings of the H2TPDC-4CF3 ligand are respectively located on two planes. Among them, R1 and R3 are on one plane while R2 is on the other plane. The angle between the two planes is 68.34° and this phenomenon is rare in previously reported MOFs materials. 15 , 16

Corresponding author: Jing Hao, School of Applied Chemical Engineering, Lanzhou Petrochemical University of Vocational Technology, Lanzhou, 730000, People’s Republic of China, E-mail:

Funding source: Education Department of Gansu Province

Award Identifier / Grant number: No. 2021CYZC-66

Funding source: Gansu Provincial Party Committee Organization Department

Award Identifier / Grant number: No. 2022LQTD-33

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by the Industry support project of Education Department of Gansu Province (No. 2021CYZC-66), and Gansu Provincial Party Committee Organization Department “Longyuan Youth Innovation and entrepreneurship talent (team)” project (No. 2022LQTD-33), and Gansu Provincial College Students’ Innovation Training Program Project.

  3. Conflict of interest: The authors declare no conflicts of interest regarding this article.

References

1. CrysAlisPRO. Rigaku Oxford Diffraction; Yarnton: England, 2015.Search in Google Scholar

2. Sheldrick, G. M. Crystal Structure Refinement with SHELXL. Acta Cryst. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Search in Google Scholar

3. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. OLEX2: A Complete Structure Solution, Refinement and Analysis Program. J. Appl. Cryst. 2009, 42, 339–341; https://doi.org/10.1107/s0021889808042726.Search in Google Scholar

4. Zhang, H.; Li, C.; Lang, F.; Li, M.; Liu, H.; Zhong, D. C.; Qin, J. S.; Di, Z.; Wang, D. H.; Zeng, L.; Pang, J.; Bu, X. H. Precisely Tuning Band Gaps of Hexabenzocoronene-Based MOFs Toward Enhanced Photocatalysis. Angew. Chem., Int. Ed. 2024, 63, e202418017; https://doi.org/10.1002/anie.202418017.Search in Google Scholar PubMed

5. Hao, J.; Lang, F.; Hao, L.; Yang, Y.; Zhang, L.; Zhang, H.; Li, Q. W.; Pang, J.; Bu, X.-H. Enhancing the Singlet Oxygen Capture and Release Rate of Metal-Organic Frameworks Through Interpenetration Tuning. Chin. Chem. Lett. 2023, 34, 108310; https://doi.org/10.1016/j.cclet.2023.108310.Search in Google Scholar

6. Yang, H.-Y.; Liu, H.-Y.; Zhao, Y.-M. Crystal Structure of the Dinuclear Mercury(II) Complex Bis(μ2-bromido)-dibromido-bis{1-[(benzotriazol-1-yl)methyl]-1-H-1,3-(2-ethyl-5-methyl-imidazol)-κ1 N} Dimercury(II), C26H30N10Hg2Br4. Z. Kristallogr. N. Cryst. Struct. 2025, 240 (1), 3–5; https://doi.org/10.1515/ncrs-2024-0273.Search in Google Scholar

7. He, J.; Li, N.; Li, Z. G.; Zhong, M.; Fu, Z. X.; Liu, M.; Bu, X.-H.; Shen, Z.; Li, W.; Zhang, J.; Chang, Z. Strategic Defect Engineering of Metal-Organic Frameworks for Optimizing the Fabrication of Single-Atom Catalysts. Adv. Funct. Mater. 2021, 31, 2103597; https://doi.org/10.1002/adfm.202103597.Search in Google Scholar

8. He, J.; Xu, J.; Yin, J.; Li, N.; Bu, X.-H. Recent Advances in Luminescent Metal-Organic Frameworks for Chemical Sensors. Sci. China Mater. 2019, 62, 1655–1678; https://doi.org/10.1007/s40843-019-1169-9.Search in Google Scholar

9. Han, S.-D.; Hu, J.-X.; Li, J.-H.; Wang, G.-M. Anchoring Polydentate N/O-ligands in Metal Phosphite/Phosphate/Phosphonate (MPO) for Functional Hybrid Materials. Coord. Chem. Rev. 2023, 475, 214892; https://doi.org/10.1016/j.ccr.2022.214892.Search in Google Scholar

10. Li, H.-Y.; Kong, X.-J.; Han, S.-D.; Pang, J.; He, T.; Wang, G. M.; Bu, X. H. Metalation of Metal-Organic Frameworks: Fundamentals and Applications. Chem. Soc. Rev. 2024, 53, 5626–5676; https://doi.org/10.1039/d3cs00873h.Search in Google Scholar PubMed

11. Wei, X.; Jiang, C.; Xu, H.; Ouyang, Y.; Wang, Z.; Lu, C.; Lu, X.; Pang, J.; Dai, F.; Bu, X. H. Synergistic Effect of Organic Ligands on Metal Site Spin States in 2D Metal-Organic Frameworks for Enhanced ORR Performance. ACS Catal. 2023, 13, 15663–15672; https://doi.org/10.1021/acscatal.3c04100.Search in Google Scholar

12. Bi, W. J.; Chen, H.; Yang, S. W.; Wang, X. H. The Crystal Structure of poly[(Tripyridine-κ3 N,N′,N″) μ3-(pyridine-3,4-dicarboxylate-κ3 N:O:O′) Manganese(II)], C22H22N4O8Mn. Z. Kristallogr. N. Cryst. Struct. 2024, 239, 99–101; https://doi.org/10.1515/ncrs-2023-0457.Search in Google Scholar

13. Yao, X. T.; Cai, J.; Liu, Y.; Chen, M. S. Crystal Structure of poly[(μ3-5-bromoisophthalato-κ4 O,O ′: O″,O‴)-(μ2-1,2-bis(1,2,4-triazole-1-ylmethyl)benzene-κ2 N:N′) cobalt(II)], C20H15BrCoN6O4. Z. Kristallogr. –N. Cryst. Struct. 2024, 239, 653–655; https://doi.org/10.1515/ncrs-2024-0126.Search in Google Scholar

14. He, L.; Xiao, L.; Fu, W. The Crystal Structure of poly[(μ3-1,3-Phenylenedioxydiacetate-κ5 O,O,O′,O″,O″’)- bis(4′-(4-(1H-imidazole-1-yl)phenyl)-4,2′:6′,4″-terpyridine-κN) cadmium(II)], C58H42CdN10O6. Z. Kristallogr. N. Cryst. Struct. 2023, 238, 1047–1050; https://doi.org/10.1515/ncrs-2023-0280.Search in Google Scholar

15. Yao, X. T.; Chen, X. Y.; Liu, Y.; Chen, M. S. Crystal Structure of poly[(μ2-5-bromoisophthalato-κ4 O,O′: O″,O‴)-(μ2-1,4-bis(2-methylimidazol-1-ylmethyl)benzene-N:N′) cadmium(II)], C24H21BrCdN4O4. Z. Kristallogr. N. Cryst. Struct. 2024, 239, 665–667; https://doi.org/10.1515/ncrs-2024-0129.Search in Google Scholar

16. Li, N.; Pang, J.; Lang, F.; Bu, X. H. Flexible Metal-Organic Frameworks: From Local Structural Design to Functional Realization. Acc. Chem. Res. 2024, 57, 2279–2292; https://doi.org/10.1021/acs.accounts.4c00253.Search in Google Scholar PubMed

Received: 2025-04-14
Accepted: 2025-06-19
Published Online: 2025-06-27
Published in Print: 2025-10-27

© 2025 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of (S)-N-(10-((2,2-dimethoxyethyl)amino)-1,2,3-trimethoxy-9-oxo-5,6,7,9-tetrahydrobenzo[a]heptalen-7-yl)acetamide, C25H32N2O7
  4. The crystal structure of 6,6′-difluoro-3,3′-dimethyl-5,5′-di(10H-phenoxazin-10-yl)- [1,1′-biphenyl]-2,2′-dicarbonitrile, C40H24F2N4O2
  5. Crystal structure of poly[(di-ethylenediamine-κ2N,N′)cadmium(II) tetradedocyloxidohexavanadate] (V4+/V5+ = 2/1), C4H16CdN4O14V6
  6. The crystal structure of poly[bis(dimethylformamide-κ1N)-(μ4-2′,3,3″,5′-tetrakis(trifluoromethyl)-[1,1′:4′,1″-terphenyl]-4,4″-dicarboxylato-κ4 O,O′: O″,O‴)dicadmium(II)], C27H15CdF12NO5
  7. Crystal structure of bis(μ2-ferrocenylcarboxylato-O,O′)-(μ3-oxido-κ3O:O:O)-bis(μ2-salicyladoximato-κ2N,O,O′)-(μ2-isopropoxo)-tris(isopropoxy-κ1O trititanium(IV)), C48H55N2O13Fe2Ti3
  8. Crystal structure of 3-(diethylamino)-7,9,11-trimethyl-8-phenyl-6H,13H-12λ4,13λ4-chromeno[3′,4′:4,5]pyrrolo[1,2-c]pyrrolo[2,1-f][1,3,2]diazaborinin-6-one, C28H26BF2N3O2
  9. The crystal structure of catena-poly[aqua-μ2-2-nitro-benzene-1,3-dicarboxylato-κ2O,O′)-(1,10-phenanthroline-κ2N,N′)-zinc(II)], C20H13N3O7Zn
  10. Crystal structure of poly[diaqua-{μ3-1-(3-carboxylatophenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ4O,O′:O′′:O′′′′}manganese(II)] hydrate
  11. Crystal structure of N′-((1-hydroxycyclohexyl)(phenyl)methyl)-2-methoxybenzohydrazide methanol solvate, C22H28N2O4
  12. The cocrystal of caffeic acid — progesterone — water (1/2/1), C51H70O9
  13. Crystal structure of (((oxido(quinolin-6-yl)methoxy)triphenyl-λ5-stibanyl)oxy)(quinolin-7-yl)methanolate
  14. Crystal structure of [(E)-6′-(diethylamino)-2-(2-(((E)-pyren-1-ylmethylene)amino)ethyl)-4′-(2-((E)-1,3,3-trimethylindolin-2-ylidene)ethylidene)-1′,2′,3′,4′-tetrahydrospiro[isoindoline-1,9′-xanthen]-3-one]-methanol, solvate C57H56N4O3
  15. The crystal structure of 1-(acridin-9-yl)pyrrolidine-2,5-dione, C17H22N2O2
  16. Crystal structure of N-(4-acetylphenyl)-2-(6-methoxynaphthalen-2-yl)propanamide, C22H21NO3
  17. The crystal structure of 5,10,15,20-tetrakis(4-(1H-1,2,4-triazol-1-yl)phenyl)porphyrin, C52H34N16
  18. Crystal structure of hexacarbonyl-μ2-[phenylmethanedithiolato-κ4S:S,S′:S′]diiron (Fe–Fe) C13H6Fe2O6S2
  19. Crystal structure of diiodo-bis(1-((2-propyl-1H-benzo[d]imidazol-1-yl)methyl)-1H-benzo[d][1,2,3]triazole-κ1N)cadmium(II), C34H34CdI2N10
  20. Crystal structure of (E)-(3-(3-bromophenyl)acryloyl)ferrocene, C19H15BrFeO
  21. Crystal structure of catena-poly(μ2-6-chloropyridine-2-carboxylato-κ3N,O:O′)(6-chloropyridine-2-carboxylato-κ2O,N)copper(II), C12H6Cl2N2O4Cu
  22. Crystal structure of poly[diaqua-μ 3-(5-(3,5-dicarboxy-2,4,6-trimethylbenzyl)-2,4,6-trimethylisophthalato)-κ 6O,O′:O″,O‴:O‴′,O‴″) terbium(III)-monohydrate], C23H28TbO12
  23. Crystal structure of (E)-2-(((5-chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)methylene)amino)-3′,6′-dihydroxyspiro[isoindoline-1,9′-xanthen]-3-one – ethanol (1/2), C35H33ClN4O6
  24. The crystal structure of 3-(5-amino-3-phenylisoxazol-4-yl)-4-chloro-3-hydroxyindolin-2-one, C17H12ClN3O3
  25. The crystal structure of dimethylammonium 4-[2-(4-fluorophenyl)-4, 5-diphenyl-1H-imidazol-1-yl]benzenesulfonate, C29H26FN3O3S
  26. Crystal structure of (R)-2-ammonio-3-((5-carboxypentyl)thio)propanoate
  27. Crystal structure of 4-cyclohexyl-5-(thiophen-2-yl)-2,4-dihydro-3H-1,2,4-triazole-3-thione, C12H15N3S2
  28. The crystal structure of 4,6-bis(dimethylamino)-2-fluoroisophthalonitrile, C12H13FN4
  29. Hydrogen bonding in the crystal structure of nicotin-1,1′-dium tetrabromidomanganate(II)
  30. The crystal structure of bis(2-bromobenzyl)(2-((2-oxybenzylidene)amino)-4-methylpentanoato-κ3N, O,O′)tin(IV), C27H27Br2NO3Sn
  31. Crystal structure of (E)-(3-(p-tolyl)acryloyl)ferrocene, C20H18FeO
  32. Crystal structure of (E)-7-fluoro-2-((5-(4-methylpiperazin-1-yl)pyridin-2-yl)methylene)-3,4-dihydronaphthalen-1(2H)-one, C21H22FN3O
  33. Crystal structure of (E)-7-methoxy-2-((5-(4-methylpiperazin-1-yl)pyridin-2-yl)methylene)-3,4-dihydronaphthalen-1(2H)-one, C22H25N3O2
  34. The crystal structure of poly(bis(μ2-1,3,5-tri(1H-imidazol-1-yl)benzene-κ2N:N′)-(μ2-2,3,5,6-tetrafluoroterephthalato-κ2O:O′)-manganese(II), C38H24F4N12O4Mn
  35. Crystal structure of (3,4-dimethoxybenzyl)triphenylphosphonium bromide ethanol solvate, C29H32BrO3P
  36. Crystal structure of tetraethylammonium hydrogencarbonate – (diaminomethylene)thiourea – water (2/1/3)
  37. Crystal structure of N, N-Dimethyl-N′-tosylformimidamide, C10H14N2O2S
  38. The crystal structure of ethyl 2-methyl-5-oxo-4-(2-methoxyphenyl)-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate, C20H23N2O4
  39. Crystal structure of bis(μ2-1,5-bis[(E)-1-(2-hydroxyphenyl)ethylidene] thiocarbonohydrazide)-bis(dimethylformamide)-dizinc(II) dimethylformamide solvate, C40H46N10O6S2Zn2⋅C3H7NO
  40. Crystal structure of azido-κ1N{hydridotris(3-tert-butyl-5-methylpyrazol-1-yl)borato-κ3N,N′,N″}copper(II), C24H40BCuN9
  41. The crystal structure of fac-tricarbonyl(1,10-phenanthroline-κ2N,N′)-(azido-κ1N)rhenium(I), C15H8N5O3Re
  42. Crystal structure of 4-((triphenylphosphonio)methyl)pyridin-1-ium tetrachloridozincate(II), C24H22Cl4NPZn
https://doi.org/10.1515/ncrs-2025-0187
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of (S)-N-(10-((2,2-dimethoxyethyl)amino)-1,2,3-trimethoxy-9-oxo-5,6,7,9-tetrahydrobenzo[a]heptalen-7-yl)acetamide, C25H32N2O7
  4. The crystal structure of 6,6′-difluoro-3,3′-dimethyl-5,5′-di(10H-phenoxazin-10-yl)- [1,1′-biphenyl]-2,2′-dicarbonitrile, C40H24F2N4O2
  5. Crystal structure of poly[(di-ethylenediamine-κ2N,N′)cadmium(II) tetradedocyloxidohexavanadate] (V4+/V5+ = 2/1), C4H16CdN4O14V6
  6. The crystal structure of poly[bis(dimethylformamide-κ1N)-(μ4-2′,3,3″,5′-tetrakis(trifluoromethyl)-[1,1′:4′,1″-terphenyl]-4,4″-dicarboxylato-κ4 O,O′: O″,O‴)dicadmium(II)], C27H15CdF12NO5
  7. Crystal structure of bis(μ2-ferrocenylcarboxylato-O,O′)-(μ3-oxido-κ3O:O:O)-bis(μ2-salicyladoximato-κ2N,O,O′)-(μ2-isopropoxo)-tris(isopropoxy-κ1O trititanium(IV)), C48H55N2O13Fe2Ti3
  8. Crystal structure of 3-(diethylamino)-7,9,11-trimethyl-8-phenyl-6H,13H-12λ4,13λ4-chromeno[3′,4′:4,5]pyrrolo[1,2-c]pyrrolo[2,1-f][1,3,2]diazaborinin-6-one, C28H26BF2N3O2
  9. The crystal structure of catena-poly[aqua-μ2-2-nitro-benzene-1,3-dicarboxylato-κ2O,O′)-(1,10-phenanthroline-κ2N,N′)-zinc(II)], C20H13N3O7Zn
  10. Crystal structure of poly[diaqua-{μ3-1-(3-carboxylatophenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ4O,O′:O′′:O′′′′}manganese(II)] hydrate
  11. Crystal structure of N′-((1-hydroxycyclohexyl)(phenyl)methyl)-2-methoxybenzohydrazide methanol solvate, C22H28N2O4
  12. The cocrystal of caffeic acid — progesterone — water (1/2/1), C51H70O9
  13. Crystal structure of (((oxido(quinolin-6-yl)methoxy)triphenyl-λ5-stibanyl)oxy)(quinolin-7-yl)methanolate
  14. Crystal structure of [(E)-6′-(diethylamino)-2-(2-(((E)-pyren-1-ylmethylene)amino)ethyl)-4′-(2-((E)-1,3,3-trimethylindolin-2-ylidene)ethylidene)-1′,2′,3′,4′-tetrahydrospiro[isoindoline-1,9′-xanthen]-3-one]-methanol, solvate C57H56N4O3
  15. The crystal structure of 1-(acridin-9-yl)pyrrolidine-2,5-dione, C17H22N2O2
  16. Crystal structure of N-(4-acetylphenyl)-2-(6-methoxynaphthalen-2-yl)propanamide, C22H21NO3
  17. The crystal structure of 5,10,15,20-tetrakis(4-(1H-1,2,4-triazol-1-yl)phenyl)porphyrin, C52H34N16
  18. Crystal structure of hexacarbonyl-μ2-[phenylmethanedithiolato-κ4S:S,S′:S′]diiron (Fe–Fe) C13H6Fe2O6S2
  19. Crystal structure of diiodo-bis(1-((2-propyl-1H-benzo[d]imidazol-1-yl)methyl)-1H-benzo[d][1,2,3]triazole-κ1N)cadmium(II), C34H34CdI2N10
  20. Crystal structure of (E)-(3-(3-bromophenyl)acryloyl)ferrocene, C19H15BrFeO
  21. Crystal structure of catena-poly(μ2-6-chloropyridine-2-carboxylato-κ3N,O:O′)(6-chloropyridine-2-carboxylato-κ2O,N)copper(II), C12H6Cl2N2O4Cu
  22. Crystal structure of poly[diaqua-μ 3-(5-(3,5-dicarboxy-2,4,6-trimethylbenzyl)-2,4,6-trimethylisophthalato)-κ 6O,O′:O″,O‴:O‴′,O‴″) terbium(III)-monohydrate], C23H28TbO12
  23. Crystal structure of (E)-2-(((5-chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)methylene)amino)-3′,6′-dihydroxyspiro[isoindoline-1,9′-xanthen]-3-one – ethanol (1/2), C35H33ClN4O6
  24. The crystal structure of 3-(5-amino-3-phenylisoxazol-4-yl)-4-chloro-3-hydroxyindolin-2-one, C17H12ClN3O3
  25. The crystal structure of dimethylammonium 4-[2-(4-fluorophenyl)-4, 5-diphenyl-1H-imidazol-1-yl]benzenesulfonate, C29H26FN3O3S
  26. Crystal structure of (R)-2-ammonio-3-((5-carboxypentyl)thio)propanoate
  27. Crystal structure of 4-cyclohexyl-5-(thiophen-2-yl)-2,4-dihydro-3H-1,2,4-triazole-3-thione, C12H15N3S2
  28. The crystal structure of 4,6-bis(dimethylamino)-2-fluoroisophthalonitrile, C12H13FN4
  29. Hydrogen bonding in the crystal structure of nicotin-1,1′-dium tetrabromidomanganate(II)
  30. The crystal structure of bis(2-bromobenzyl)(2-((2-oxybenzylidene)amino)-4-methylpentanoato-κ3N, O,O′)tin(IV), C27H27Br2NO3Sn
  31. Crystal structure of (E)-(3-(p-tolyl)acryloyl)ferrocene, C20H18FeO
  32. Crystal structure of (E)-7-fluoro-2-((5-(4-methylpiperazin-1-yl)pyridin-2-yl)methylene)-3,4-dihydronaphthalen-1(2H)-one, C21H22FN3O
  33. Crystal structure of (E)-7-methoxy-2-((5-(4-methylpiperazin-1-yl)pyridin-2-yl)methylene)-3,4-dihydronaphthalen-1(2H)-one, C22H25N3O2
  34. The crystal structure of poly(bis(μ2-1,3,5-tri(1H-imidazol-1-yl)benzene-κ2N:N′)-(μ2-2,3,5,6-tetrafluoroterephthalato-κ2O:O′)-manganese(II), C38H24F4N12O4Mn
  35. Crystal structure of (3,4-dimethoxybenzyl)triphenylphosphonium bromide ethanol solvate, C29H32BrO3P
  36. Crystal structure of tetraethylammonium hydrogencarbonate – (diaminomethylene)thiourea – water (2/1/3)
  37. Crystal structure of N, N-Dimethyl-N′-tosylformimidamide, C10H14N2O2S
  38. The crystal structure of ethyl 2-methyl-5-oxo-4-(2-methoxyphenyl)-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate, C20H23N2O4
  39. Crystal structure of bis(μ2-1,5-bis[(E)-1-(2-hydroxyphenyl)ethylidene] thiocarbonohydrazide)-bis(dimethylformamide)-dizinc(II) dimethylformamide solvate, C40H46N10O6S2Zn2⋅C3H7NO
  40. Crystal structure of azido-κ1N{hydridotris(3-tert-butyl-5-methylpyrazol-1-yl)borato-κ3N,N′,N″}copper(II), C24H40BCuN9
  41. The crystal structure of fac-tricarbonyl(1,10-phenanthroline-κ2N,N′)-(azido-κ1N)rhenium(I), C15H8N5O3Re
  42. Crystal structure of 4-((triphenylphosphonio)methyl)pyridin-1-ium tetrachloridozincate(II), C24H22Cl4NPZn
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