Home Physical Sciences Crystal structure of tetrakis(methanol-κO)-bis{μ2-3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olate-κ4O,N;O′:O′}dizinc(II), C38H38Zn2N2O14
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Crystal structure of tetrakis(methanol-κO)-bis{μ2-3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olate-κ4O,N;O′:O′}dizinc(II), C38H38Zn2N2O14

  • Jing Li , Hao-Ran Jia and Yin-Xia Sun EMAIL logo
Published/Copyright: September 29, 2017
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 232 Issue 6

Abstract

C38H38Zn2N2O14, monoclinic, P21/n (no. 14), a = 9.6906(6) Å, b = 7.9055(5) Å, c = 24.0501(18) Å, β = 99.878(7)°, Z = 2, V = 1815.1(2) Å3, Rgt(F) = 0.0474, wRref(F2) = 0.1143, T = 293 K.

CCDC no.:: 1543586

The crystal structure is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.

Table 1

Data collection and handling.

Crystal:Clear light Yellow, block
Size:0.33 × 0.21 × 0.20 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:9.5 cm−1
Diffractometer, scan mode:Bruker SMART, φ and ω-scans
2θmax, completeness:26°, >99%
N(hkl)measured, N(hkl)unique, Rint:7013, 3565, 0.038
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 2853
N(param)refined:262
Programs:Bruker programs [1], SHELX [2]
Table 2

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Zn10.39341(4)0.10872(6)0.525675(17)0.04040(17)
O1−0.0488(2)0.4116(3)0.57414(10)0.0378(6)
O2−0.1022(2)0.2989(3)0.49031(10)0.0405(6)
O30.3550(2)0.2433(3)0.59301(10)0.0421(6)
O40.4016(2)−0.0388(3)0.45665(9)0.0302(5)
O50.2802(3)−0.2579(3)0.27440(10)0.0464(7)
O60.3326(3)−0.1402(4)0.56647(11)0.0509(7)
H60.271(3)−0.209(3)0.5491(8)0.076*
O70.4601(3)0.3285(4)0.47869(13)0.0607(8)
H70.538(2)0.382(4)0.4863(15)0.091*
N10.1833(3)0.1571(3)0.49796(11)0.0272(6)
C10.2271(3)0.2917(4)0.58657(13)0.0295(7)
C20.1795(4)0.3873(4)0.63125(13)0.0309(7)
C30.2653(4)0.4235(4)0.68308(14)0.0391(9)
H30.35760.38580.68980.047*
C40.2142(5)0.5141(5)0.72391(16)0.0492(10)
H40.27160.53660.75820.059*
C50.0773(5)0.5718(5)0.71400(17)0.0514(11)
H50.04330.63390.74160.062*
C6−0.0084(4)0.5381(5)0.66372(17)0.0480(10)
H6A−0.10030.57720.65700.058*
C70.0430(4)0.4453(4)0.62303(14)0.0334(8)
C8−0.0102(3)0.3162(4)0.53107(14)0.0290(7)
C90.1292(3)0.2544(4)0.53833(13)0.0275(7)
C100.1128(3)0.1064(4)0.45094(14)0.0312(7)
H100.01850.13570.44340.037*
C110.1655(3)0.0081(4)0.40855(13)0.0275(7)
C120.3024(3)−0.0600(4)0.41142(12)0.0250(7)
C130.3320(3)−0.1492(4)0.36523(13)0.0284(7)
H130.4211−0.19450.36680.034*
C140.2340(4)−0.1729(4)0.31713(13)0.0316(7)
C150.0992(4)−0.1103(4)0.31372(14)0.0373(8)
H150.0319−0.12730.28170.045*
C160.0688(4)−0.0227(5)0.35922(14)0.0364(8)
H16−0.02160.01900.35730.044*
C170.1883(4)−0.2626(5)0.22137(15)0.0507(11)
H17A0.2359−0.31250.19360.076*
H17B0.1600−0.14960.21010.076*
H17C0.1072−0.32890.22480.076*
C180.3295(6)−0.1604(7)0.62426(18)0.0738(15)
H18A0.2415−0.12060.63230.111*
H18B0.4044−0.09650.64590.111*
H18C0.3407−0.27790.63410.111*
C190.3768(6)0.4115(6)0.4331(2)0.0863(18)
H19A0.32440.32940.40870.129*
H19B0.43590.47440.41230.129*
H19C0.31340.48740.44710.129*

Source of materials

The ligand was synthesized according to a method reported previously [3], [4], [5]. To an ethanol solution (5 mL) of 2-hydroxy-4-methoxybenzaldehyde (152.2 mg, 1 mmol) was added an ethanol solution (5 mL) of 3-amino-4-hydroxy-2H-chromen-2-one (177.2 mg, 1 mmol). The solution was stirred under reflux conditions at 434 K for 6 h. After cooling to room temperature, the precipitate was filtered and washed with ethanol and hexane. The product was dried under vacuum (yield 71.8%, m.p. 460–461 K). Anal. Calcd. for C17H13NO5 (%): C, 65.59; H, 4.21; N, 4.50. Found (%): C, 66.47; H, 4.13; N, 4.85.

A solution of zinc(II) acetate dihydrate (3.00 mg, 0.014 mmol) in methanol (5 mL) was added dropwise to a mixed solution composed by triethylamine (0.5 mL) and dichloromethane (5 mL) of 4-hydroxy-3-[(2-hydroxy-4-methoxy-benzylidene)-amino]-benzopyran-2-one (4.40 mg, 0.014 mmol) at room temperature. The color of the mixing solution turns to yellow immediately, and the mixture was filtered and the filtrate was allowed to stand at room temperature for about 2 weeks and we obtained yellow block crystals. Elemental analysis-Anal. calcd. for C38H38Zn2N2O14 (%): C, 52.01; H, 4.36; N, 3.19. Found (%): C, 52.53; H, 4.22; N, 3.46.

Experimental details

Hydrogen atoms were placed in their geometrically idealized positions and constrained to ride on their parent atoms.

Comment

Coumarin derivatives have been found to exhibit antibiotic, antibacterial, antifungal, anticoagulating and plant regulating activities. Schiff base (contain –C = N– group) as a class of ligands are known to coordinate with metal ions through the azomethine nitrogen atom [6, 7] . And they can form all kinds of stable metal complexes [8, 9] , which have interesting structures and wide use in biochemistry [10, 11] . Furthermore, they may have magnetic properties [12, 13] , photophysical properties [14, 15] , and used in the fields of molecular recognition [16, 17] , and supramolecular architectures [18].

The X-ray structural study reveals that the title complex is dinuclear (cf. the figure). Thus the title complex Zn(II) consists of two tridentate deprotonated ligands, and four coordinated methanol molecules. Each Zn(II) is hexa-coordinated by one nitrogen atoms and three oxygen atoms of deprotonated ligands defining the N2O2 basal plane, plus two oxygen atoms from the methanol molecules occupying the apical positions. Thus, the coordination geometry of the Zn(II) center can be described as a slightly distorted octahedron.

In the crystal structure there are two intermolecular (O6—H6⋯O2 and O7—H7⋯O7) hydrogen bonds, which link the title complex molecules into an infinite chain-like supramolecular structure. This linkage is further stabilized by two C—H⋯π and π⋯π stacking interactions with the centroid-centroid distances of 3.916(2)–4.003(2) Å to form a 3D network.

Acknowledgement

The supports by the Graduate Student Experimental Innovation and Technology Project of Lanzhou Jiaotong University are gratefully acknowledged.

References

Bruker: APEX2, SAINT and SADABS. Brucker AXS Inc., Madison, Wisconsin, USA (2009).Search in Google Scholar

Sheldrick, G. M.: A short history of SHELX. Acta Crystallogr. A64 (2008) 112–122.10.1107/S0108767307043930Search in Google Scholar PubMed

Xu, L.; Li, N.; Zhao, L.: Crystal structure of 4-chloro-4′,6′-dichloro-2,2′-[propane-1,3-diyldioxybis(nitrilomethylidyne)]diphenol, C17H14Cl3N2O4. Z. Kristallogr. NCS 231 (2016) 967–968.10.1515/ncrs-2016-0025Search in Google Scholar

Zhao, L.; Wang, F.; An, Q. Q.; Zhao, J. X.: Crystal structure of (E)-1-(4-(((E)-3,5-dichloro-2-hydroxybenzylidene)amino)phenyl)ethan-1-one O-ethyl oxime, C17H16Cl2N2O2. Z. Kristallogr. NCS 231 (2016) 1045–1046.10.1515/ncrs-2016-0044Search in Google Scholar

Sun, Y. X.; Liu, G. H.; Wang, J.; Liu, S. H.; Wang, H.: Crystal structure of bis(3-ethoxy-4-hydroxybenzaldehyde)O,O′-(butane-1,4-diyl)dioxime, C22H28N2O6. Z. Kristallogr. NCS 227 (2012) 123–124.10.1524/ncrs.2012.0056Search in Google Scholar

Dong, W. K.; Zhu, L. C.; Dong, Y. J.; Ma, J. C.; Zhang, Y.: Mono, di and heptanuclear metal(II) complexes based on symmetric and asymmetric tetradentate Salamo-type ligands: syntheses, structures and spectroscopic properties. Polyhedron 117 (2016) 148–154.10.1016/j.poly.2016.05.055Search in Google Scholar

Sun, Y. X.; Zhao, Y. Y.; Li, C. Y.; Yu, B.; Guo, J. Q.; Li, J.: Supramolecular cobalt(II) and copper(II) complexes with Schiff base ligand: syntheses, characterizations and crystal structures. Chin. J. Inorg. Chem. 32 (2016) 913–920.Search in Google Scholar

Wang, P.; Zhao, L.: Synthesis, structure and spectroscopic properties of the trinuclear cobalt(II) and nickel(II) complexes based on 2-hydroxynaphthaldehyde and bis(aminooxy)alkane. Spectrochim. Acta A 135 (2015) 342–350.10.1016/j.saa.2014.06.129Search in Google Scholar PubMed

Dong, W. K.; Duan, J. G.; Guan, Y. H.; Shi, J. Y.; Zhao, C. Y.: Synthesis, crystal structure and spectroscopic behaviors of Co(II) and Cu(II) complexes with Salen-type bisoxime ligands. Inorg. Chim. Acta 362 (2009) 1129–1134.10.1016/j.ica.2008.05.028Search in Google Scholar

Wu, H. L.; Yuan, J. K.; Bai, Y.; Jia, F.; Liu, B.; Kou, F.; Kong, J.: Synthesis, structure, DNA-binding properties, and antioxidant activity of copper(II) and cobalt(II) complexes with bis(N-allylbenzimidazol-2-ylmethyl)benzylamine. Trans. Met. Chem. 36 (2011) 819–827.10.1007/s11243-011-9536-5Search in Google Scholar

Wu, H. L.; Bai, Y. C.; Zhang, Y. H.; Li, Z.; Wu, M. C.; Chen, C. Y.; Zhang, J. W.: Synthesis, crystal structure, antioxidation and DNA-binding properties of a dinuclear copper(II) complex with bis(N-salicylidene)-3-oxapentane-1,5-diamine. J. Coord. Chem. 67 (2014) 3054–3066.10.1080/00958972.2014.959507Search in Google Scholar

Song, X. Q.; Liu, P. P.; Liu, Y. A.; Zhou, J. J.; Wang, X. L.: Two dodecanuclear heterometallic [Zn6Ln6] clusters constructed by a multidentate salicylamide salen-like ligand: Synthesis, structure, luminescence and magnetic properties. Dalton Trans. 45 (2016) 8154–8163.10.1039/C6DT00212ASearch in Google Scholar

Dong, W. K.; Ma, J. C.; Dong, Y. J.; Zhu, L. C.; Zhang, Y.: Di- and tetranuclear heterometallic 3d-4f cobalt(II)-lanthanide(III) complexes derived from a hexadentate bisoxime: syntheses, structures and magnetic properties. Polyhedron 115 (2016) 228–235.10.1016/j.poly.2016.05.017Search in Google Scholar

Wang, L.; Ma, J. C.; Dong, W. K.; Zhu, L. C.; Zhang, Y.: A novel self-assembled nickel(II)-cerium(III) heterotetranuclear dimer constructed from N2O2-type bisoxime and terephthalic acid: synthesis, structure, and photophysical properties. Z. Anorg. Allg. Chem. 642 (2016) 834–839.10.1002/zaac.201600125Search in Google Scholar

Dong, W. K.; Ma, J. C.; Zhu, L. C.; Sun, Y. X.; Sunday, F. A.; Zhang, Y.: A series of heteromultinuclear zinc(II)-lanthanide(III) complexes based on 3-MeOsalamo:syntheses, structural characterizations, and luminescent properties. Cryst. Growth Des. 14 (2016) 6903–6914.10.1021/acs.cgd.6b01067Search in Google Scholar

Dong, W. K.; Li, X. L.; Wang, L.; Zhang, Y.; Ding, Y. J.: A new application of Salamo-type bisoximes: As a relay-sensor for Zn2+/Cu2+ and its novel complexes for successive sensing of H+/OH−. Sens. Actuators B 229 (2016) 370–378.10.1016/j.snb.2016.01.139Search in Google Scholar

Dong, W. K.; Sunday, F. A.; Zhang, Y.; Sun, Y. X.; Dong, X. Y.: A reversible “turn-on” fluorescent sensor for selective detection of Zn2+. Sens. Actuators B 238 (2017) 723–734.10.1016/j.snb.2016.07.047Search in Google Scholar

Dong, W. K.; Sun, Y. X.; Zhao, C. Y.; Dong, X. Y.; Xu, L.: Synthesis, structure and properties of supramolecular Mn(II), Co(II), Ni(II) and Zn(II) complexes containing Salen-type bisoxime ligands. Polyhedron 29 (2010) 2087–2097.10.1016/j.poly.2010.04.006Search in Google Scholar

Received: 2017-4-13
Accepted: 2017-9-13
Published Online: 2017-9-29
Published in Print: 2017-11-27

©2017 Jing Li et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

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  1. Cover and Frontmatter
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  57. Crystal structure of 5,5-difluoro-10-(4-fluorophenyl)-1,3,7,9-tetramethyl-5H-4l4,5l4-dipyrrolo[1,2-c:2′,1′-f][1,3,2]diazaborinine - a Z′ = 3 structure, C19H18B2F3N2
  58. The crystal structure of the Matrine derivative: 12-(1H-indol-1-yl)dodecahydro-1H,5H,10H-dipyrido[2,1-f:3′,2′,1′-ij][1,6]naphthyridin-10-one hydrate, C23H29N3O
  59. The crystal structure of tris(μ2-1,3-bis(4,4,4-trifluoro-3-oxido-1-(oxo)but-2-en-1-yl)phenyl-κ4O,O′:O′′,O′′′)-bis(1,2-dimethoxyethane-κ2O,O′)dilutetium(III), C50H38F18Lu2O16
  60. The crystal structure of (Z)-2-(3-(2-(4-chlorobenzoyl)hydrazono)-2-oxoindolin-1-yl) acetic acid, C17H12ClN3O4
  61. Synthesis and crystal structure of trans-tetraqua-bis(2-(((7-hydroxy-3-(4-hydroxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)ammonio)acetato-κO)cobalt(II) hexahydrate, C36H48CoN2O28S2
  62. The crystal structure of N,N-dimethyl-2,6-di-p-tolylpyrimidin-4-amine, C20H21N3
  63. The crystal structure (E)-4-methyl-N′-(2-nitrobenzylidene)benzenesulfonohydrazide, C14H13N3O4S
  64. Crystal structure of catena-poly[(μ2-1,3-bis(benzimidazol-1-yl)propane κ2N:N′)-(μ2-5-methoxyisophthalato-κ2O:O′)zinc(II)] hydrate, C26H24ZnN4O6
  65. The crystal structure of (E)-N′-(quinolin-2-ylmethylene)furan-2-carbohydrazide monohydrate, C15H13N3O3
  66. Crystal structure of 2,8-diphenyl-3,7,9-trioxa-1-azaspiro[4.5]dec-1-ene, C18H17N1O3
  67. Crystal structure of diethyl 2-(4-chlorophenyl)-1,3-dioxane-5,5-dicarboxylate, C16H19ClO6
  68. Crystal structure of 1-(carboxymethyl)-1H-benzo[d][1,2,3]triazole 3-oxide, C8H7N3O3
  69. Crystal structure of (acetylacetonato-κ2O,O′)-(2-amino-6-chlorobenzoato-κO)-oxido(1,10-phenanthroline-κ2N,N′)vanadium(IV) – trichloromethane (1/1)
  70. Crystal structure of (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one, C17H12Cl2O
  71. The crystal structure of trans-dibromido-bis(pyridine-κN)platinum(II), C10H10Br2N2Pt
https://doi.org/10.1515/ncrs-2017-0113
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Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of potassium 1-methyl-1H-1,2,3,4-tetrazole-5-thiolate, C2H3N4SK
  3. Crystal structure of bis(3-(3-ethylureido)-N,N-dimethylpropan-1-aminium) bis (μ3-2-(hydroxymethyl)-2-(oxidomethyl)propane-1,3-bis(olato))-(μ6-oxo)-hexakis(μ2-oxo)-hexaoxo-hexavanadium(V) – dichloromethane (1/1), C27H60Cl2N6O23V6
  4. Crystal structure of bis(μ3-methanolato-κ3O:O:O)-bis(μ2-methanolato-κ2O:O)-dimethanol-bis{6,6′-(1,3-dihydroxyl-2-acetylpropane-1,3-diyl)bis(2-chloro-4-bromophenolato)}tetramanganese(III) C40H40Br4Cl4Mn4O16
  5. Synthesis and crystal structure of tetrakis(μ2-methanolato)-dimethanol-bis(μ2-2-acetyl-1,3-bis(3,5-dibromo-2-oxidophenyl)propane-1,3-bis(olato)-κ5O1,O2,O3:O3,O4,O5)tetramanganese(III), C40H40Br8Mn4O16
  6. Synthesis and crystal structure tetrakis(μ2-methanolato)-dimethanol-bis(μ2-2-acetyl-1,3-bis(3,5-dichloro-2-oxidophenyl)propane-1,3-bis(olato)-κ5O1,O2,O3:O3,O4,O5), tetramanganese(III), C40H40Cl8Mn4O16
  7. Crystal structure of bis{5-methoxy-2-((E)-((4-((E)-1-(methoxyimino)ethyl)phenyl)imino)methyl)phenolato-κ2N,O)}copper(II), C34H34CuN4O6
  8. Crystal structure of (E)-1-(2-hydroxy-3-{[2-hydroxybenzylidene]amino}phenyl)ethan-1-one, C15H13NO3
  9. Crystal structure of bis(μ2-acetato-κ2O:O′)-bis{μ2-4-chloro-2-(8-(4-(diethylamino)-2-oxidophenyl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl)phenolato-κ6O:O,N,N′,O′′:O′′}tricobalt(II), C44H49Cl2Co3N6O12
  10. Crystal structure of bis{μ2-2,4-dichloro-6-(8-(4-(diethylamino)-2-oxidophenyl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl)phenolato-κ5O:O,N,N′,O′}dicobalt(II) acetone solvate, C43H48Br4Co2N6O9
  11. Synthesis and crystal structure of bis(μ2-acetato-κ2O:O′)-bis{μ2-4-chloro-2-(8-(4-(diethylamino)-2-oxidophenyl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl)phenolato-κ6O:O,N,N′,O′:O′}trizinc(II), C44H49Cl2N6O12Zn3
  12. Crystal structure of bis{5-(N,N′-diethylamine)-5′-methoxy -2,2′-[ethylenediyldioxybis(nitrilomethylidyne)]diphenolato}-bis(μ2-acetato-κ2O:O′)trizinc(II), C46H56Zn3N6O14
  13. Crystal structure of tris(cyano-(hydrogen tris(3,5-dimethylpyrazolyl)borate))-iron(III) 4-methoxypyridinium monohydrate, C24H32BN10O2Fe
  14. Synthesis and crystal structure of bis{1-(((4-(1-(hydroxyimino)ethyl)phenyl)imino)methyl)naphthalen-2-olato-κ2O,N}copper(II), C38H30CuN4O4
  15. Crystal structure of (E)-1-(4-{[(E)-2-Hydroxy-1-naphthalenylmethylene] amino}phenyl)ethanone oxime, C19H16N2O2
  16. The pseudosymmetric crystal structure of 2-(2-naphthalenyl)-3-nitro-2H-1-benzopyran, C38H26N2O6
  17. Crystal structure of 2-benzoyl-3-(4-methoxyphenyl)cyclopropane-1,1-dicarbonitrile, C19H14N2O2
  18. N′-(5-ethoxycarbonyl-3,4-dimethyl-pyrrol-2-yl-methylidene)-4-hydroxybenzohydrazide monohydrate, C17H21N3O5
  19. The crystal structure of carbonyl-[4-(2,4-dichlorophenylamino)pent-3-en-2-onato-κ2N,O]-(triphenylphosphine-κP)rhodium(I), RhC30H25Cl2NO2P
  20. Crystal structure of (E)-5-(diethylamino)-2-(((1,1,2-trihydroxyethyl)iminio)methyl)phenolate, C15H24N2O4
  21. Crystal structure of poly[(μ2-1,4-bis((2-ethyl-1H-benzo[d]imidazol-1-yl)methyl)benzene-κ2N:N′)(μ2-isophthalato-κ4O,O′:O′′,O′′′)cadmium(II)], C34H30N4O4Cd
  22. Crystal structure of 5,6-Dihydro-9,10-dimethoxybenzo[g]-1,3-benzodioxolo[5,6-a]chinolizinium 3-(4-hydroxyphenyl)-4-oxo-4H-chromen-7-olate - methanol - water (1/1/1), C36H33NO10
  23. A single crystal study on 2-(methylcarbamoyl)benzoic acid, C9H9NO3
  24. Crystal structure of the salt 1,1′-(ethane-1,2-diyl)bis(1,4-diazabicyclo[2.2.2]octan-1-ium) diperchlorate, C14H28N4(ClO4)2
  25. Crystal structure of 2,5-bis((E)-2-(trifluoromethyl)benzylidene)cyclopentan-1-one, C21H14F6O
  26. Crystal structure of catena-poly[(μ2-benzene-1,4-dicarboxylato-κ2O:O′)-(1-ethyl-6-fluoro-7-(4-methylpiperazin-1-ium-1-yl)-4-oxo-1,4-dihydroquinoline-3-carboxylato-κ2O,O′)zinc(II)] 1.25 hydrate, C25H26.5N3O8.25FZn
  27. Crystal structure of 1-methyl-1,4-diazabicyclo[2.2.2]octan-1-ium poly[aqua-bis(μ2-perchlorato-κ3O,O′:O′′)sodium], C7H17Cl2N2NaO9
  28. Crystal structure of trimethyammonium 2,6-dicarboxyisonicotinate monohydrate, C11H16N2O7
  29. Crystal structure of dodecaguanidinium bis(tetrapropylammonium) heptacarbonate, C43H128N38O21
  30. Crystal structure of poly[tetraaqua-bis(μ6-benzene-1,2,4,5-tetracarboxylato)nickel(II)diyttrium(III)]dihydrate, C20H16NiO22Y2
  31. Halogen bonds and π–π interactions in the crystal structure of 1,3,5-trifluoro-2,4,6-triiodobenzene–N,N-dimethylformamide (1/1), C9H7F3I3NO
  32. Crystal structure of guanidinium tetraethylammonium carbonate dihydrate, C10H30N4O5
  33. The crystal structure of oxonium chlorido-ethylenediaminetetraactetotin(IV) hydrate, C10H17ClN2O10Sn
  34. Crystal structure of 8-((E)-((4-((E)-1-((benzyloxy)imino)ethyl)phenyl)imino)methyl)-7-hydroxy-4-methyl-2H-chromen-2-one, C26H22N2O4
  35. Crystal structure of bis{5-(diethylamino)-2-(((2-oxo-2H-chromen-6-yl)imino)methyl)phenolato-κ2O,N}copper(II), C40H38CuN4O6
  36. Crystal structure of fac-(acetylacetonato-κ2O,O′)tricarbonyl(tri(p-tolyl)phosphine-κP)rhenium(I), C29H28O5PRe
  37. Crystal structure of fac-(acetylacetonato-κ2O,O′)tricarbonyl(benzyldiphenylphosphine-κP)rhenium(I), C27H24O5PRe
  38. Crystal structure of triethylammonium bis{3-(((3-oxidonaphthalen-1-yl)methylene)amino)-2-oxo-2H-chromen-4-olato-κ3O,N,O′}manganese(III), C46H38MnN3O8
  39. Crystal structure of bis(N,N,N-ethyldimethylethanaminium) bis(heptaselenido-κ2Se1,Se7)palladate(II), C12H32N2PdSe14
  40. Crystal structure of bis(4-(1H-pyrazol-5-yl)pyridine-κ2N:N′)-bis(2-(2-((2,6-difluorophenyl)amino)phenyl)acetate-κO)cadmium(II), C44H34N8CdCl4O4
  41. Crystal structure of 4,4′-(1,4-phenylene)bis(pyridin-1-ium) catena-poly[diaqua-bis(μ2-3′,5′-dicarboxy-[1,1′-biphenyl]-2,5-dicarboxylato-κ2O:O′] dihydrate, C48H42O22N2Ca
  42. The crystal structure of (S)-2-benzylsuccinic acid, C11H12O4
  43. Crystal structure of poly[aqua-(μ3-4-(pyridin-4-yl)isophthalato-κ4O,O′:O′′:O′′′)-(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:O′)yttrium(III)], C26H17N2O9Y
  44. Crystal structure of ethyl 1-(3,4-dimethylphenyl)-5-methyl-1H-1,2,3-triazole-4-carboxylate, C14H17N3O2
  45. Crystal structure of tetrakis(methanol-κO)-bis{μ2-3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olate-κ4O,N;O′:O′}dizinc(II), C38H38Zn2N2O14
  46. Crystal structure of bromido(4,4′-dimethoxy-2,2′-bipyridine-κ2N,N′)(isopropyl(diphenyl)phosphane-κP)copper(I), C27H29BrCuN2O2P
  47. Crystal structure of bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)-9,9-dioctylfluorene, C41H64B2O4
  48. Crystal structure of 11-oxo-2,3,6,7-tetrahydro-1H,5H,11H-pyrano[2,3-f]pyrido[3,2,1-ij]quinoline-10-carbaldehyde - a julolidine derivative, C16H15NO3
  49. Crystal structure of 1,3-dimethyl-5,5-dibenzylbarbituric acid, C20H20N2O3
  50. Crystal structure of bis(N,N,N-trimethylethanaminium) poly[bis(μ2-heptaselenido-κ2Se1,Se7)palladate(II)], C10H28N2PdSe14
  51. Crystal structure of 1-{4-[(5-Chloro-2-hydroxy-benzylidene)amino]phenyl} ethanone O-ethyl-oxime, C17H17ClN2O2
  52. The crystal structure of methyl N-(4-bromophenyl)carbamate, C8H8BrNO2
  53. Synthesis and crystal structure of 1-{4-[(2-hydroxy-benzylidene)amino]phenyl}ethanone oxime, C15H14N2O2
  54. Crystal structure of 1,1′-butanebis(3-methyl-1H-imidazol-3-ium)bis(hexafluorophosphate), C12H20F12N4P2
  55. (E)-N-benzylidene-3-(benzylthio)-5-p-tolyl-4H-1,2,4-triazol-4-amine, C23H20N4S
  56. Crystal structure of ethyl 5-methyl-1-(pyridin-3-yl)-1H-1,2,3-triazole-4-carboxylate, C11H12N4O2
  57. Crystal structure of 5,5-difluoro-10-(4-fluorophenyl)-1,3,7,9-tetramethyl-5H-4l4,5l4-dipyrrolo[1,2-c:2′,1′-f][1,3,2]diazaborinine - a Z′ = 3 structure, C19H18B2F3N2
  58. The crystal structure of the Matrine derivative: 12-(1H-indol-1-yl)dodecahydro-1H,5H,10H-dipyrido[2,1-f:3′,2′,1′-ij][1,6]naphthyridin-10-one hydrate, C23H29N3O
  59. The crystal structure of tris(μ2-1,3-bis(4,4,4-trifluoro-3-oxido-1-(oxo)but-2-en-1-yl)phenyl-κ4O,O′:O′′,O′′′)-bis(1,2-dimethoxyethane-κ2O,O′)dilutetium(III), C50H38F18Lu2O16
  60. The crystal structure of (Z)-2-(3-(2-(4-chlorobenzoyl)hydrazono)-2-oxoindolin-1-yl) acetic acid, C17H12ClN3O4
  61. Synthesis and crystal structure of trans-tetraqua-bis(2-(((7-hydroxy-3-(4-hydroxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)ammonio)acetato-κO)cobalt(II) hexahydrate, C36H48CoN2O28S2
  62. The crystal structure of N,N-dimethyl-2,6-di-p-tolylpyrimidin-4-amine, C20H21N3
  63. The crystal structure (E)-4-methyl-N′-(2-nitrobenzylidene)benzenesulfonohydrazide, C14H13N3O4S
  64. Crystal structure of catena-poly[(μ2-1,3-bis(benzimidazol-1-yl)propane κ2N:N′)-(μ2-5-methoxyisophthalato-κ2O:O′)zinc(II)] hydrate, C26H24ZnN4O6
  65. The crystal structure of (E)-N′-(quinolin-2-ylmethylene)furan-2-carbohydrazide monohydrate, C15H13N3O3
  66. Crystal structure of 2,8-diphenyl-3,7,9-trioxa-1-azaspiro[4.5]dec-1-ene, C18H17N1O3
  67. Crystal structure of diethyl 2-(4-chlorophenyl)-1,3-dioxane-5,5-dicarboxylate, C16H19ClO6
  68. Crystal structure of 1-(carboxymethyl)-1H-benzo[d][1,2,3]triazole 3-oxide, C8H7N3O3
  69. Crystal structure of (acetylacetonato-κ2O,O′)-(2-amino-6-chlorobenzoato-κO)-oxido(1,10-phenanthroline-κ2N,N′)vanadium(IV) – trichloromethane (1/1)
  70. Crystal structure of (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one, C17H12Cl2O
  71. The crystal structure of trans-dibromido-bis(pyridine-κN)platinum(II), C10H10Br2N2Pt
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