Startseite Naturwissenschaften Crystal structure of bis{μ2-2,4-dichloro-6-(8-(4-(diethylamino)-2-oxidophenyl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl)phenolato-κ5O:O,N,N′,O′}dicobalt(II) acetone solvate, C43H48Br4Co2N6O9
Artikel Open Access

Crystal structure of bis{μ2-2,4-dichloro-6-(8-(4-(diethylamino)-2-oxidophenyl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl)phenolato-κ5O:O,N,N′,O′}dicobalt(II) acetone solvate, C43H48Br4Co2N6O9

  • Shan-Shan Zheng , Jing Hao , Peng-Fei Lan , Xiu-Yan Dong und Wen-Kui Dong EMAIL logo
Veröffentlicht/Copyright: 12. Oktober 2017
Artikel downloaden (PDF)
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 232 Heft 6

Abstract

C43H48Br4Co2N6O9, triclinic, P1̅, a = 11.9298(7) Å, b = 12.8850(9) Å, c = 17.5241(11) Å, α = 84.854(6)°, β = 85.181(5)°, γ = 65.796(6)°, V = 2443.7(3) Å3, Z = 2, Rgt(F) = 0.0556, wRref(F2) = 0.1053, T = 293.51(10) K.

CCDC no.:: 1531179

The crystal structure is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.

Table 1

Data collection and handling.

Crystal:Clear light brown block
Size:0.24 × 0.25 × 0.23 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:4.01 mm−1
Diffractometer, scan mode:SuperNova ω
θmax, completeness:26.0°, 99.0%
N(hkl)measured, N(hkl)unique, Rint:17199, 9533, 0.043
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 5688
N(param)refined:583
Programs:CrysAlisPRO [18], OLEX2 [19], SHELX [20]
Table 2

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

xyzUiso*/Ueq
Br10.11660(5)0.53464(7)0.82380(4)0.0741(2)
Br20.14949(7)0.33564(8)0.54579(4)0.1003(3)
Br30.04000(6)1.35544(6)0.98651(4)0.0871(3)
Br40.06071(5)1.13914(6)0.71779(4)0.0797(3)
Co10.48537(5)0.60019(6)0.75071(3)0.03218(18)
Co20.45666(5)0.84565(6)0.77939(4)0.03416(19)
O10.3538(2)0.5482(3)0.75941(17)0.0377(9)
O20.6552(3)0.5051(3)0.60445(18)0.0451(10)
O30.7421(3)0.4144(3)0.75681(19)0.0443(10)
O40.3042(2)0.9781(3)0.77439(17)0.0406(9)
O50.6294(3)0.8767(3)0.8882(2)0.0581(12)
O60.6658(3)0.9084(4)0.7194(2)0.0579(11)
O120.4615(2)0.7046(3)0.84035(16)0.0334(8)
O150.4275(2)0.7545(3)0.69725(16)0.0313(8)
N20.4074(4)0.7756(4)1.1071(2)0.0503(13)
N90.5092(3)0.9196(4)0.8618(2)0.0407(11)
N120.6491(3)0.5053(3)0.7980(2)0.0369(11)
N180.2528(4)0.7718(4)0.4591(2)0.0480(12)
N270.5465(3)0.5128(3)0.6482(2)0.0356(10)
N450.5864(3)0.8577(4)0.6998(2)0.0407(11)
C10.3133(4)0.5021(4)0.7111(3)0.0325(12)
C20.2028(4)0.4874(5)0.7286(3)0.0457(15)
C30.1563(5)0.4378(5)0.6810(3)0.0569(17)
H30.08390.42870.69530.068*
C40.2176(5)0.4015(5)0.6117(3)0.0548(16)
C50.3246(4)0.4132(5)0.5908(3)0.0456(14)
H50.36510.38860.54390.055*
C60.3742(4)0.4621(4)0.6396(3)0.0322(12)
C70.4897(4)0.4680(4)0.6132(3)0.0363(13)
H70.52550.43640.56690.044*
C80.7256(4)0.5469(5)0.6441(3)0.0457(15)
H8A0.66990.61380.67010.055*
H8B0.77670.57070.60690.055*
C90.8064(4)0.4623(5)0.7018(3)0.0489(16)
H9A0.87030.40100.67490.059*
H9B0.84610.49930.72890.059*
C100.6736(4)0.4957(4)0.8699(3)0.0403(13)
H100.74530.43500.88500.048*
C110.6014(4)0.5690(4)0.9271(3)0.0352(13)
C120.6397(4)0.5416(5)1.0033(3)0.0491(15)
H120.70980.47591.01360.059*
C130.5774(4)0.6080(5)1.0618(3)0.0468(15)
H130.60530.58701.11120.056*
C140.4713(4)0.7082(5)1.0485(3)0.0420(14)
C150.4340(4)0.7387(4)0.9723(3)0.0362(13)
H150.36530.80560.96200.043*
C160.4977(4)0.6709(4)0.9125(3)0.0330(12)
C170.4323(5)0.7383(5)1.1874(3)0.0541(16)
H17A0.47120.65571.19210.065*
H17B0.35500.76231.21760.065*
C180.5145(5)0.7854(5)1.2196(3)0.0684(18)
H18A0.59180.76071.19050.103*
H18B0.52820.75821.27220.103*
H18C0.47550.86721.21640.103*
C190.2947(5)0.8772(5)1.0937(3)0.0596(18)
H19A0.30400.91471.04450.072*
H19B0.28220.92971.13310.072*
C200.1828(5)0.8499(6)1.0941(4)0.081(2)
H20A0.19420.79871.05470.122*
H20B0.11130.91891.08480.122*
H20C0.17190.81461.14320.122*
C210.2544(4)1.0614(4)0.8202(3)0.0390(13)
C220.1361(4)1.1458(5)0.8067(3)0.0478(15)
C230.0733(5)1.2325(5)0.8548(3)0.0534(16)
H23−0.00541.28580.84420.064*
C240.1289(5)1.2388(5)0.9187(3)0.0537(16)
C250.2469(5)1.1639(5)0.9325(3)0.0508(15)
H250.28461.17190.97470.061*
C260.3116(4)1.0752(4)0.8839(3)0.0386(13)
C270.4382(4)1.0072(5)0.8981(3)0.0432(14)
H270.47201.02820.93680.052*
C280.7113(4)0.7881(5)0.8421(3)0.0564(17)
H28A0.66940.74170.82970.068*
H28B0.78110.73970.87170.068*
C290.7581(5)0.8306(6)0.7684(3)0.0640(19)
H29A0.80960.86760.78120.077*
H29B0.80970.76520.73970.077*
C300.4984(4)0.8353(4)0.5857(3)0.0362(13)
C310.5784(4)0.8665(4)0.6260(3)0.0411(13)
H310.62880.89560.59680.049*
C320.4921(4)0.8593(5)0.5060(3)0.0472(15)
H320.54450.88980.48080.057*
C330.4125(4)0.8398(5)0.4643(3)0.0460(15)
H330.41060.85770.41170.055*
C340.3328(4)0.7925(5)0.5005(3)0.0398(14)
C350.3415(4)0.7632(4)0.5796(3)0.0349(12)
H350.29270.72810.60390.042*
C360.4213(4)0.7854(4)0.6224(3)0.0311(12)
C370.2414(5)0.8050(5)0.3772(3)0.0559(17)
H37A0.20240.76270.35500.067*
H37B0.32320.78330.35280.067*
C380.1686(5)0.9301(6)0.3594(4)0.082(2)
H38A0.16860.94590.30480.123*
H38B0.20520.97300.38210.123*
H38C0.08550.95130.37980.123*
C390.1673(5)0.7229(6)0.4956(3)0.070(2)
H39A0.14630.68450.45750.084*
H39B0.20870.66630.53570.084*
C400.0542(6)0.8081(7)0.5286(4)0.109(3)
H40A0.00570.85680.48820.164*
H40B0.07440.85300.56150.164*
H40C0.00830.77070.55780.164*
O7−0.0526(4)0.8951(5)0.8385(3)0.125(2)
C410.1093(5)0.8234(6)0.7462(4)0.091(2)
H41A0.04680.82490.71450.137*
H41B0.17540.74890.74730.137*
H41C0.14020.87880.72570.137*
C420.0567(5)0.8504(6)0.8244(4)0.074(2)
C430.1389(6)0.8254(8)0.8871(4)0.125(3)
H43A0.09140.83890.93510.188*
H43B0.18290.87360.88030.188*
H43C0.19630.74700.88720.188*

Source of material

A methanol solution (3.0 mL) of cobalt acetate tetrahydrate (373.5 mg, 0.015 mmol) was added to a acetone solution (2.0 mL) of H2L: 4-(diethylamino)-2-hydroxybenzaldehyde O-(2-(((3,5-dichloro-2-hydroxybenzylidene)amino)oxy)ethyl) oxime (3.96 mg, 0.010 mmol) at room temperature. The color of the solution turned brown immediately. After the mixture was stirred for 1 h, the mixture was filtered. The resulting filtrate was left undisturbed for about two weeks to form clear light brown block crystals. Yield: 58%. Elemental analysis-Anal. Calcd. for C43H48Br4Co2N6O9: C, 41.98%; H, 3.93%; N, 6.83%. Found: C, 42.18%; H, 3.91%; N, 6.80%.

Experimental details

Hydrogen atoms were placed in their geometrically idealized positions and constrained to ride on their parent atoms.

Discussion

Salen-type ligands and their derivatives have a significant position in the field of modern coordination chemistry as a kind of N2O2 tetradentate ligands [1], [2], [3], [4], [5]. They are capable of forming stable metal complexes [6], [7], [8], [9], which may have unique properties and various structures, for example, they can show biological activity [10], form supramolecular architectures [11], [12], [13], or may construct optical and magnetic materials [14], [15], [16], and so on.

The crystal structure of the title compound is only built up by the C43H48Br4Co2N6O9 complex and one acetone molecule. The complex consists of two Co(II) atoms and two completely deprotonated L2− units resulting in an asymmetrical binuclear Co(II) complex. The penta-coordinated Co(II) atom (Co1 or Co2) lies in the N2O2 coordination sphere (O1, O12, N12 and N27 or O4, O15, N9 and N45), and coordinates to another penolato oxygen atom (O12 or O15). The Co(II) atoms of the title compound can be described as trigonal bipyramidally coordinated with axial donor atoms (O12 and N27 or O15 and N5). The title compound has a “stepped” conformation as observed in the dimers of [{Cu(Brsalamo)}2] [17]. The dimer is bridged through phenolato oxygen atoms (O12 and O15) across the crystallographic center of asymmetry (Co1—O15 = 1.989(3) Å, Co1—O12 = 2.085(3) Å, Co2—O12 = 2.006(3) Å, Co2—O15 = 2.073(3) Å, Co2—Co1 = 3.121(4) Å, Co2—O12—Co1 = 99.41(13)°, Co2—O15—Co1 =100.41(13)°, O12—Co1—O15 = 77.70(12)° and O12—Co2—O15 = 77.59(12)°).

References

Chai, L. Q.; Zhang, Y. L.; Ding, X. Q.: Crystal structure of 2,2′-dinitro-2,2′-[(1,4-butylene)dioxybis(nitrilomethylidyne)]dibenzene, C18H18N4O6. Z. Kristallogr. NCS 225 (2010) 685–686.10.1524/ncrs.2010.0300Suche in Google Scholar

Sun, Y. X.; Liu, G. H.; Wang, J.; Liu, S. H.; Wang, H.: Crystal structure of bis(3-ethoxy-4-hydroxybenzaldehyde)O,O′-(butane-1,4-diyl)dioxime, C22H28N2O6. Z. Kristallogr. NCS 227 (2012) 123–124.10.1524/ncrs.2012.0056Suche in Google Scholar

Xu, L.; Li, N.; Zhao, L.: Crystal structure of 4-chloro-4′,6′-dichloro-2,2′-[propane-1,3-diyldioxybis(nitrilomethylidyne)] diphenol, C17H14Cl3N2O4. Z. Kristallogr. NCS 231 (2016) 967–968.10.1515/ncrs-2016-0025Suche in Google Scholar

Zhang, Y. J.; Zhang, X. Y.; Zhao, M. M.; Li, G.; Yang, Y. H.; Dong, X. Y.: Synthesis and crystal structure of five-coordinated cobalt(II) dimer with asymmetrical N2O2 coordination sphere. Asian J. Chem. 26 (2014) 2643–2645.10.14233/ajchem.2014.15775Suche in Google Scholar

Wang, P.; Zhao, L.: Synthesis, structure and spectroscopic properties of the trinuclear cobalt(II) and nickel(II) complexes based on 2-hydroxynaphthaldehyde and bis(aminooxy)alkane. Spectrochim. Acta, Part A 135 (2015) 342–350.10.1016/j.saa.2014.06.129Suche in Google Scholar PubMed

Sun, Y. X.; Gao, X. H.: Synthesis, characterization, and crystal structure of a new CuII complex with Salen-type ligand. Synth. React. Inorg. Met. Org. Nano Met. Chem. 41 (2011) 973–978.10.1080/15533174.2011.591329Suche in Google Scholar

Dong, W. K.; Zhu, L. C.; Dong, Y. J.; Ma, J. C.; Zhang, Y.: Mono, di and heptanuclear metal(II) complexes based on symmetric and asymmetric tetradentate Salamo-type ligands: syntheses, structures and spectroscopic properties. Polyhedron 117 (2016) 148–154.10.1016/j.poly.2016.05.055Suche in Google Scholar

Dong, W. K.; Duan, J. G.; Guan, Y. H.; Shi, J. Y.; Zhao, C. Y.: Synthesis, crystal structure and spectroscopic behaviors of Co(II) and Cu(II) complexes with Salen-type bisoxime ligands. Inorg. Chim. Acta 362 (2009) 1129–1134.10.1016/j.ica.2008.05.028Suche in Google Scholar

Sun, Y. X.; Zhao, Y. Y.; Li, C. Y.; Yu, B.; Guo, J. Q.; Li, J.: Supramolecular cobalt(II) and copper(II) complexes with Schiff base ligand: syntheses, characterizations and crystal structures. Chinese J. Inorg. Chem. 32 (2016) 913–920.Suche in Google Scholar

Wu, H. L.; Bai, Y. C.; Zhang, Y. H.; Li, Z.; Wu, M. C.; Chen, C. Y.; Zhang, J. W.: Synthesis, crystal structure, antioxidation and DNA-binding properties of a dinuclear copper(II) complex with bis(N-salicylidene)-3-oxapentane-1,5-diamine. J. Coord. Chem. 67 (2014) 3054–3066.10.1080/00958972.2014.959507Suche in Google Scholar

Dong, W. K.; Sun, Y. X.; Zhao, C. Y.; Dong, X. Y.; Xu, L.: Synthesis, structure and properties of supramolecular Mn(II), Co(II), Ni(II) and Zn(II) complexes containing Salen-type bisoxime ligands. Polyhedron 29 (2010) 2087–2097.10.1016/j.poly.2010.04.006Suche in Google Scholar

Sun, Y. X.; Wang, L.; Dong, X. Y.; Ren, Z. L.; Meng, W. S.: Synthesis, characterization and crystal structure of a supramolecular CoII complex containing Salen-type bisoxime: Synth. React. Inorg. Met.-Org. Nano-Met. Chem. 43 (2013) 599–603.10.1080/15533174.2012.751424Suche in Google Scholar

Dong, X. Y.; Sun, Y. X.; Wang, L.; Li, L.: Synthesis and structure of a penta- and hexa-coordinated tri-nuclear cobalt(II) complex. J. Chem. Res. 36 (2012) 387–390.10.3184/174751912X13366711594575Suche in Google Scholar

Wang, P.; Zhao, L.: An infinite 2D supramolecular cobalt(II) complex based on an asymmetric Salamo-type ligand: synthesis, crystal structure, and spectral properties. Synth. React. Inorg. Met. Org. Nano Met. Chem. 46 (2016) 1095–1101.10.1080/15533174.2015.1004416Suche in Google Scholar

Anbu, S.; Kandaswamy, M.; Suthaharan, P.; Murugan, V.; Varghese, B.: Structural, magnetic, electrochemical, catalytic, DNA binding and cleavage studies of new macrocyclic binuclear copper(II) complexes. J. Inorg. Biochem. 103 (2009) 401–410.10.1016/j.jinorgbio.2008.12.013Suche in Google Scholar PubMed

Song, X. Q.; Liu, P. P.; Liu, Y. A.; Zhou, J. J.; Wang, X. L.: Two dodecanuclear heterometallic [Zn6Ln6] clusters constructed by a multidentate salicylamide salen-like ligand: Synthesis, structure, luminescence and magnetic properties. Dalton Trans. 45 (2016) 8154–8163.10.1039/C6DT00212ASuche in Google Scholar

Dong, W. K.; Feng, J. H.; Yang, X. Q.: Synthesis and crystal structure of a five-coordinated Cu(II) dimer with 4,4′-dibromo-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol. Synth. React. Inorg. Metal-Org. Nano-Met. Chem. 37 (2007) 189–192.10.1080/15533170701301587Suche in Google Scholar

Agilent. CrysAlisPRO: Agilent Technologies. Yarnton, UK, 2009.Suche in Google Scholar

Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H.: OLEX2: a complete structure solution, refinement and analysis programm. J. Appl. Cryst. allogr. 42 (2009) 339–341.10.1107/S0021889808042726Suche in Google Scholar

Sheldrick, G. M.: A short history of SHELX. Acta Crystallogr. A. 64 (2008) 112–122.10.1107/S0108767307043930Suche in Google Scholar PubMed

Received: 2017-3-26
Accepted: 2017-8-29
Published Online: 2017-10-12
Published in Print: 2017-11-27

©2017 Shan-Shan Zheng et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Artikel in diesem Heft

  1. Cover and Frontmatter
  2. Crystal structure of potassium 1-methyl-1H-1,2,3,4-tetrazole-5-thiolate, C2H3N4SK
  3. Crystal structure of bis(3-(3-ethylureido)-N,N-dimethylpropan-1-aminium) bis (μ3-2-(hydroxymethyl)-2-(oxidomethyl)propane-1,3-bis(olato))-(μ6-oxo)-hexakis(μ2-oxo)-hexaoxo-hexavanadium(V) – dichloromethane (1/1), C27H60Cl2N6O23V6
  4. Crystal structure of bis(μ3-methanolato-κ3O:O:O)-bis(μ2-methanolato-κ2O:O)-dimethanol-bis{6,6′-(1,3-dihydroxyl-2-acetylpropane-1,3-diyl)bis(2-chloro-4-bromophenolato)}tetramanganese(III) C40H40Br4Cl4Mn4O16
  5. Synthesis and crystal structure of tetrakis(μ2-methanolato)-dimethanol-bis(μ2-2-acetyl-1,3-bis(3,5-dibromo-2-oxidophenyl)propane-1,3-bis(olato)-κ5O1,O2,O3:O3,O4,O5)tetramanganese(III), C40H40Br8Mn4O16
  6. Synthesis and crystal structure tetrakis(μ2-methanolato)-dimethanol-bis(μ2-2-acetyl-1,3-bis(3,5-dichloro-2-oxidophenyl)propane-1,3-bis(olato)-κ5O1,O2,O3:O3,O4,O5), tetramanganese(III), C40H40Cl8Mn4O16
  7. Crystal structure of bis{5-methoxy-2-((E)-((4-((E)-1-(methoxyimino)ethyl)phenyl)imino)methyl)phenolato-κ2N,O)}copper(II), C34H34CuN4O6
  8. Crystal structure of (E)-1-(2-hydroxy-3-{[2-hydroxybenzylidene]amino}phenyl)ethan-1-one, C15H13NO3
  9. Crystal structure of bis(μ2-acetato-κ2O:O′)-bis{μ2-4-chloro-2-(8-(4-(diethylamino)-2-oxidophenyl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl)phenolato-κ6O:O,N,N′,O′′:O′′}tricobalt(II), C44H49Cl2Co3N6O12
  10. Crystal structure of bis{μ2-2,4-dichloro-6-(8-(4-(diethylamino)-2-oxidophenyl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl)phenolato-κ5O:O,N,N′,O′}dicobalt(II) acetone solvate, C43H48Br4Co2N6O9
  11. Synthesis and crystal structure of bis(μ2-acetato-κ2O:O′)-bis{μ2-4-chloro-2-(8-(4-(diethylamino)-2-oxidophenyl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl)phenolato-κ6O:O,N,N′,O′:O′}trizinc(II), C44H49Cl2N6O12Zn3
  12. Crystal structure of bis{5-(N,N′-diethylamine)-5′-methoxy -2,2′-[ethylenediyldioxybis(nitrilomethylidyne)]diphenolato}-bis(μ2-acetato-κ2O:O′)trizinc(II), C46H56Zn3N6O14
  13. Crystal structure of tris(cyano-(hydrogen tris(3,5-dimethylpyrazolyl)borate))-iron(III) 4-methoxypyridinium monohydrate, C24H32BN10O2Fe
  14. Synthesis and crystal structure of bis{1-(((4-(1-(hydroxyimino)ethyl)phenyl)imino)methyl)naphthalen-2-olato-κ2O,N}copper(II), C38H30CuN4O4
  15. Crystal structure of (E)-1-(4-{[(E)-2-Hydroxy-1-naphthalenylmethylene] amino}phenyl)ethanone oxime, C19H16N2O2
  16. The pseudosymmetric crystal structure of 2-(2-naphthalenyl)-3-nitro-2H-1-benzopyran, C38H26N2O6
  17. Crystal structure of 2-benzoyl-3-(4-methoxyphenyl)cyclopropane-1,1-dicarbonitrile, C19H14N2O2
  18. N′-(5-ethoxycarbonyl-3,4-dimethyl-pyrrol-2-yl-methylidene)-4-hydroxybenzohydrazide monohydrate, C17H21N3O5
  19. The crystal structure of carbonyl-[4-(2,4-dichlorophenylamino)pent-3-en-2-onato-κ2N,O]-(triphenylphosphine-κP)rhodium(I), RhC30H25Cl2NO2P
  20. Crystal structure of (E)-5-(diethylamino)-2-(((1,1,2-trihydroxyethyl)iminio)methyl)phenolate, C15H24N2O4
  21. Crystal structure of poly[(μ2-1,4-bis((2-ethyl-1H-benzo[d]imidazol-1-yl)methyl)benzene-κ2N:N′)(μ2-isophthalato-κ4O,O′:O′′,O′′′)cadmium(II)], C34H30N4O4Cd
  22. Crystal structure of 5,6-Dihydro-9,10-dimethoxybenzo[g]-1,3-benzodioxolo[5,6-a]chinolizinium 3-(4-hydroxyphenyl)-4-oxo-4H-chromen-7-olate - methanol - water (1/1/1), C36H33NO10
  23. A single crystal study on 2-(methylcarbamoyl)benzoic acid, C9H9NO3
  24. Crystal structure of the salt 1,1′-(ethane-1,2-diyl)bis(1,4-diazabicyclo[2.2.2]octan-1-ium) diperchlorate, C14H28N4(ClO4)2
  25. Crystal structure of 2,5-bis((E)-2-(trifluoromethyl)benzylidene)cyclopentan-1-one, C21H14F6O
  26. Crystal structure of catena-poly[(μ2-benzene-1,4-dicarboxylato-κ2O:O′)-(1-ethyl-6-fluoro-7-(4-methylpiperazin-1-ium-1-yl)-4-oxo-1,4-dihydroquinoline-3-carboxylato-κ2O,O′)zinc(II)] 1.25 hydrate, C25H26.5N3O8.25FZn
  27. Crystal structure of 1-methyl-1,4-diazabicyclo[2.2.2]octan-1-ium poly[aqua-bis(μ2-perchlorato-κ3O,O′:O′′)sodium], C7H17Cl2N2NaO9
  28. Crystal structure of trimethyammonium 2,6-dicarboxyisonicotinate monohydrate, C11H16N2O7
  29. Crystal structure of dodecaguanidinium bis(tetrapropylammonium) heptacarbonate, C43H128N38O21
  30. Crystal structure of poly[tetraaqua-bis(μ6-benzene-1,2,4,5-tetracarboxylato)nickel(II)diyttrium(III)]dihydrate, C20H16NiO22Y2
  31. Halogen bonds and π–π interactions in the crystal structure of 1,3,5-trifluoro-2,4,6-triiodobenzene–N,N-dimethylformamide (1/1), C9H7F3I3NO
  32. Crystal structure of guanidinium tetraethylammonium carbonate dihydrate, C10H30N4O5
  33. The crystal structure of oxonium chlorido-ethylenediaminetetraactetotin(IV) hydrate, C10H17ClN2O10Sn
  34. Crystal structure of 8-((E)-((4-((E)-1-((benzyloxy)imino)ethyl)phenyl)imino)methyl)-7-hydroxy-4-methyl-2H-chromen-2-one, C26H22N2O4
  35. Crystal structure of bis{5-(diethylamino)-2-(((2-oxo-2H-chromen-6-yl)imino)methyl)phenolato-κ2O,N}copper(II), C40H38CuN4O6
  36. Crystal structure of fac-(acetylacetonato-κ2O,O′)tricarbonyl(tri(p-tolyl)phosphine-κP)rhenium(I), C29H28O5PRe
  37. Crystal structure of fac-(acetylacetonato-κ2O,O′)tricarbonyl(benzyldiphenylphosphine-κP)rhenium(I), C27H24O5PRe
  38. Crystal structure of triethylammonium bis{3-(((3-oxidonaphthalen-1-yl)methylene)amino)-2-oxo-2H-chromen-4-olato-κ3O,N,O′}manganese(III), C46H38MnN3O8
  39. Crystal structure of bis(N,N,N-ethyldimethylethanaminium) bis(heptaselenido-κ2Se1,Se7)palladate(II), C12H32N2PdSe14
  40. Crystal structure of bis(4-(1H-pyrazol-5-yl)pyridine-κ2N:N′)-bis(2-(2-((2,6-difluorophenyl)amino)phenyl)acetate-κO)cadmium(II), C44H34N8CdCl4O4
  41. Crystal structure of 4,4′-(1,4-phenylene)bis(pyridin-1-ium) catena-poly[diaqua-bis(μ2-3′,5′-dicarboxy-[1,1′-biphenyl]-2,5-dicarboxylato-κ2O:O′] dihydrate, C48H42O22N2Ca
  42. The crystal structure of (S)-2-benzylsuccinic acid, C11H12O4
  43. Crystal structure of poly[aqua-(μ3-4-(pyridin-4-yl)isophthalato-κ4O,O′:O′′:O′′′)-(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:O′)yttrium(III)], C26H17N2O9Y
  44. Crystal structure of ethyl 1-(3,4-dimethylphenyl)-5-methyl-1H-1,2,3-triazole-4-carboxylate, C14H17N3O2
  45. Crystal structure of tetrakis(methanol-κO)-bis{μ2-3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olate-κ4O,N;O′:O′}dizinc(II), C38H38Zn2N2O14
  46. Crystal structure of bromido(4,4′-dimethoxy-2,2′-bipyridine-κ2N,N′)(isopropyl(diphenyl)phosphane-κP)copper(I), C27H29BrCuN2O2P
  47. Crystal structure of bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)-9,9-dioctylfluorene, C41H64B2O4
  48. Crystal structure of 11-oxo-2,3,6,7-tetrahydro-1H,5H,11H-pyrano[2,3-f]pyrido[3,2,1-ij]quinoline-10-carbaldehyde - a julolidine derivative, C16H15NO3
  49. Crystal structure of 1,3-dimethyl-5,5-dibenzylbarbituric acid, C20H20N2O3
  50. Crystal structure of bis(N,N,N-trimethylethanaminium) poly[bis(μ2-heptaselenido-κ2Se1,Se7)palladate(II)], C10H28N2PdSe14
  51. Crystal structure of 1-{4-[(5-Chloro-2-hydroxy-benzylidene)amino]phenyl} ethanone O-ethyl-oxime, C17H17ClN2O2
  52. The crystal structure of methyl N-(4-bromophenyl)carbamate, C8H8BrNO2
  53. Synthesis and crystal structure of 1-{4-[(2-hydroxy-benzylidene)amino]phenyl}ethanone oxime, C15H14N2O2
  54. Crystal structure of 1,1′-butanebis(3-methyl-1H-imidazol-3-ium)bis(hexafluorophosphate), C12H20F12N4P2
  55. (E)-N-benzylidene-3-(benzylthio)-5-p-tolyl-4H-1,2,4-triazol-4-amine, C23H20N4S
  56. Crystal structure of ethyl 5-methyl-1-(pyridin-3-yl)-1H-1,2,3-triazole-4-carboxylate, C11H12N4O2
  57. Crystal structure of 5,5-difluoro-10-(4-fluorophenyl)-1,3,7,9-tetramethyl-5H-4l4,5l4-dipyrrolo[1,2-c:2′,1′-f][1,3,2]diazaborinine - a Z′ = 3 structure, C19H18B2F3N2
  58. The crystal structure of the Matrine derivative: 12-(1H-indol-1-yl)dodecahydro-1H,5H,10H-dipyrido[2,1-f:3′,2′,1′-ij][1,6]naphthyridin-10-one hydrate, C23H29N3O
  59. The crystal structure of tris(μ2-1,3-bis(4,4,4-trifluoro-3-oxido-1-(oxo)but-2-en-1-yl)phenyl-κ4O,O′:O′′,O′′′)-bis(1,2-dimethoxyethane-κ2O,O′)dilutetium(III), C50H38F18Lu2O16
  60. The crystal structure of (Z)-2-(3-(2-(4-chlorobenzoyl)hydrazono)-2-oxoindolin-1-yl) acetic acid, C17H12ClN3O4
  61. Synthesis and crystal structure of trans-tetraqua-bis(2-(((7-hydroxy-3-(4-hydroxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)ammonio)acetato-κO)cobalt(II) hexahydrate, C36H48CoN2O28S2
  62. The crystal structure of N,N-dimethyl-2,6-di-p-tolylpyrimidin-4-amine, C20H21N3
  63. The crystal structure (E)-4-methyl-N′-(2-nitrobenzylidene)benzenesulfonohydrazide, C14H13N3O4S
  64. Crystal structure of catena-poly[(μ2-1,3-bis(benzimidazol-1-yl)propane κ2N:N′)-(μ2-5-methoxyisophthalato-κ2O:O′)zinc(II)] hydrate, C26H24ZnN4O6
  65. The crystal structure of (E)-N′-(quinolin-2-ylmethylene)furan-2-carbohydrazide monohydrate, C15H13N3O3
  66. Crystal structure of 2,8-diphenyl-3,7,9-trioxa-1-azaspiro[4.5]dec-1-ene, C18H17N1O3
  67. Crystal structure of diethyl 2-(4-chlorophenyl)-1,3-dioxane-5,5-dicarboxylate, C16H19ClO6
  68. Crystal structure of 1-(carboxymethyl)-1H-benzo[d][1,2,3]triazole 3-oxide, C8H7N3O3
  69. Crystal structure of (acetylacetonato-κ2O,O′)-(2-amino-6-chlorobenzoato-κO)-oxido(1,10-phenanthroline-κ2N,N′)vanadium(IV) – trichloromethane (1/1)
  70. Crystal structure of (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one, C17H12Cl2O
  71. The crystal structure of trans-dibromido-bis(pyridine-κN)platinum(II), C10H10Br2N2Pt
https://doi.org/10.1515/ncrs-2017-0035
Creative Commons
BY-NC-ND 4.0

Artikel in diesem Heft

  1. Cover and Frontmatter
  2. Crystal structure of potassium 1-methyl-1H-1,2,3,4-tetrazole-5-thiolate, C2H3N4SK
  3. Crystal structure of bis(3-(3-ethylureido)-N,N-dimethylpropan-1-aminium) bis (μ3-2-(hydroxymethyl)-2-(oxidomethyl)propane-1,3-bis(olato))-(μ6-oxo)-hexakis(μ2-oxo)-hexaoxo-hexavanadium(V) – dichloromethane (1/1), C27H60Cl2N6O23V6
  4. Crystal structure of bis(μ3-methanolato-κ3O:O:O)-bis(μ2-methanolato-κ2O:O)-dimethanol-bis{6,6′-(1,3-dihydroxyl-2-acetylpropane-1,3-diyl)bis(2-chloro-4-bromophenolato)}tetramanganese(III) C40H40Br4Cl4Mn4O16
  5. Synthesis and crystal structure of tetrakis(μ2-methanolato)-dimethanol-bis(μ2-2-acetyl-1,3-bis(3,5-dibromo-2-oxidophenyl)propane-1,3-bis(olato)-κ5O1,O2,O3:O3,O4,O5)tetramanganese(III), C40H40Br8Mn4O16
  6. Synthesis and crystal structure tetrakis(μ2-methanolato)-dimethanol-bis(μ2-2-acetyl-1,3-bis(3,5-dichloro-2-oxidophenyl)propane-1,3-bis(olato)-κ5O1,O2,O3:O3,O4,O5), tetramanganese(III), C40H40Cl8Mn4O16
  7. Crystal structure of bis{5-methoxy-2-((E)-((4-((E)-1-(methoxyimino)ethyl)phenyl)imino)methyl)phenolato-κ2N,O)}copper(II), C34H34CuN4O6
  8. Crystal structure of (E)-1-(2-hydroxy-3-{[2-hydroxybenzylidene]amino}phenyl)ethan-1-one, C15H13NO3
  9. Crystal structure of bis(μ2-acetato-κ2O:O′)-bis{μ2-4-chloro-2-(8-(4-(diethylamino)-2-oxidophenyl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl)phenolato-κ6O:O,N,N′,O′′:O′′}tricobalt(II), C44H49Cl2Co3N6O12
  10. Crystal structure of bis{μ2-2,4-dichloro-6-(8-(4-(diethylamino)-2-oxidophenyl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl)phenolato-κ5O:O,N,N′,O′}dicobalt(II) acetone solvate, C43H48Br4Co2N6O9
  11. Synthesis and crystal structure of bis(μ2-acetato-κ2O:O′)-bis{μ2-4-chloro-2-(8-(4-(diethylamino)-2-oxidophenyl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl)phenolato-κ6O:O,N,N′,O′:O′}trizinc(II), C44H49Cl2N6O12Zn3
  12. Crystal structure of bis{5-(N,N′-diethylamine)-5′-methoxy -2,2′-[ethylenediyldioxybis(nitrilomethylidyne)]diphenolato}-bis(μ2-acetato-κ2O:O′)trizinc(II), C46H56Zn3N6O14
  13. Crystal structure of tris(cyano-(hydrogen tris(3,5-dimethylpyrazolyl)borate))-iron(III) 4-methoxypyridinium monohydrate, C24H32BN10O2Fe
  14. Synthesis and crystal structure of bis{1-(((4-(1-(hydroxyimino)ethyl)phenyl)imino)methyl)naphthalen-2-olato-κ2O,N}copper(II), C38H30CuN4O4
  15. Crystal structure of (E)-1-(4-{[(E)-2-Hydroxy-1-naphthalenylmethylene] amino}phenyl)ethanone oxime, C19H16N2O2
  16. The pseudosymmetric crystal structure of 2-(2-naphthalenyl)-3-nitro-2H-1-benzopyran, C38H26N2O6
  17. Crystal structure of 2-benzoyl-3-(4-methoxyphenyl)cyclopropane-1,1-dicarbonitrile, C19H14N2O2
  18. N′-(5-ethoxycarbonyl-3,4-dimethyl-pyrrol-2-yl-methylidene)-4-hydroxybenzohydrazide monohydrate, C17H21N3O5
  19. The crystal structure of carbonyl-[4-(2,4-dichlorophenylamino)pent-3-en-2-onato-κ2N,O]-(triphenylphosphine-κP)rhodium(I), RhC30H25Cl2NO2P
  20. Crystal structure of (E)-5-(diethylamino)-2-(((1,1,2-trihydroxyethyl)iminio)methyl)phenolate, C15H24N2O4
  21. Crystal structure of poly[(μ2-1,4-bis((2-ethyl-1H-benzo[d]imidazol-1-yl)methyl)benzene-κ2N:N′)(μ2-isophthalato-κ4O,O′:O′′,O′′′)cadmium(II)], C34H30N4O4Cd
  22. Crystal structure of 5,6-Dihydro-9,10-dimethoxybenzo[g]-1,3-benzodioxolo[5,6-a]chinolizinium 3-(4-hydroxyphenyl)-4-oxo-4H-chromen-7-olate - methanol - water (1/1/1), C36H33NO10
  23. A single crystal study on 2-(methylcarbamoyl)benzoic acid, C9H9NO3
  24. Crystal structure of the salt 1,1′-(ethane-1,2-diyl)bis(1,4-diazabicyclo[2.2.2]octan-1-ium) diperchlorate, C14H28N4(ClO4)2
  25. Crystal structure of 2,5-bis((E)-2-(trifluoromethyl)benzylidene)cyclopentan-1-one, C21H14F6O
  26. Crystal structure of catena-poly[(μ2-benzene-1,4-dicarboxylato-κ2O:O′)-(1-ethyl-6-fluoro-7-(4-methylpiperazin-1-ium-1-yl)-4-oxo-1,4-dihydroquinoline-3-carboxylato-κ2O,O′)zinc(II)] 1.25 hydrate, C25H26.5N3O8.25FZn
  27. Crystal structure of 1-methyl-1,4-diazabicyclo[2.2.2]octan-1-ium poly[aqua-bis(μ2-perchlorato-κ3O,O′:O′′)sodium], C7H17Cl2N2NaO9
  28. Crystal structure of trimethyammonium 2,6-dicarboxyisonicotinate monohydrate, C11H16N2O7
  29. Crystal structure of dodecaguanidinium bis(tetrapropylammonium) heptacarbonate, C43H128N38O21
  30. Crystal structure of poly[tetraaqua-bis(μ6-benzene-1,2,4,5-tetracarboxylato)nickel(II)diyttrium(III)]dihydrate, C20H16NiO22Y2
  31. Halogen bonds and π–π interactions in the crystal structure of 1,3,5-trifluoro-2,4,6-triiodobenzene–N,N-dimethylformamide (1/1), C9H7F3I3NO
  32. Crystal structure of guanidinium tetraethylammonium carbonate dihydrate, C10H30N4O5
  33. The crystal structure of oxonium chlorido-ethylenediaminetetraactetotin(IV) hydrate, C10H17ClN2O10Sn
  34. Crystal structure of 8-((E)-((4-((E)-1-((benzyloxy)imino)ethyl)phenyl)imino)methyl)-7-hydroxy-4-methyl-2H-chromen-2-one, C26H22N2O4
  35. Crystal structure of bis{5-(diethylamino)-2-(((2-oxo-2H-chromen-6-yl)imino)methyl)phenolato-κ2O,N}copper(II), C40H38CuN4O6
  36. Crystal structure of fac-(acetylacetonato-κ2O,O′)tricarbonyl(tri(p-tolyl)phosphine-κP)rhenium(I), C29H28O5PRe
  37. Crystal structure of fac-(acetylacetonato-κ2O,O′)tricarbonyl(benzyldiphenylphosphine-κP)rhenium(I), C27H24O5PRe
  38. Crystal structure of triethylammonium bis{3-(((3-oxidonaphthalen-1-yl)methylene)amino)-2-oxo-2H-chromen-4-olato-κ3O,N,O′}manganese(III), C46H38MnN3O8
  39. Crystal structure of bis(N,N,N-ethyldimethylethanaminium) bis(heptaselenido-κ2Se1,Se7)palladate(II), C12H32N2PdSe14
  40. Crystal structure of bis(4-(1H-pyrazol-5-yl)pyridine-κ2N:N′)-bis(2-(2-((2,6-difluorophenyl)amino)phenyl)acetate-κO)cadmium(II), C44H34N8CdCl4O4
  41. Crystal structure of 4,4′-(1,4-phenylene)bis(pyridin-1-ium) catena-poly[diaqua-bis(μ2-3′,5′-dicarboxy-[1,1′-biphenyl]-2,5-dicarboxylato-κ2O:O′] dihydrate, C48H42O22N2Ca
  42. The crystal structure of (S)-2-benzylsuccinic acid, C11H12O4
  43. Crystal structure of poly[aqua-(μ3-4-(pyridin-4-yl)isophthalato-κ4O,O′:O′′:O′′′)-(μ2-5-carboxy-2-(pyridin-4-yl)benzoato-κ2O:O′)yttrium(III)], C26H17N2O9Y
  44. Crystal structure of ethyl 1-(3,4-dimethylphenyl)-5-methyl-1H-1,2,3-triazole-4-carboxylate, C14H17N3O2
  45. Crystal structure of tetrakis(methanol-κO)-bis{μ2-3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olate-κ4O,N;O′:O′}dizinc(II), C38H38Zn2N2O14
  46. Crystal structure of bromido(4,4′-dimethoxy-2,2′-bipyridine-κ2N,N′)(isopropyl(diphenyl)phosphane-κP)copper(I), C27H29BrCuN2O2P
  47. Crystal structure of bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)-9,9-dioctylfluorene, C41H64B2O4
  48. Crystal structure of 11-oxo-2,3,6,7-tetrahydro-1H,5H,11H-pyrano[2,3-f]pyrido[3,2,1-ij]quinoline-10-carbaldehyde - a julolidine derivative, C16H15NO3
  49. Crystal structure of 1,3-dimethyl-5,5-dibenzylbarbituric acid, C20H20N2O3
  50. Crystal structure of bis(N,N,N-trimethylethanaminium) poly[bis(μ2-heptaselenido-κ2Se1,Se7)palladate(II)], C10H28N2PdSe14
  51. Crystal structure of 1-{4-[(5-Chloro-2-hydroxy-benzylidene)amino]phenyl} ethanone O-ethyl-oxime, C17H17ClN2O2
  52. The crystal structure of methyl N-(4-bromophenyl)carbamate, C8H8BrNO2
  53. Synthesis and crystal structure of 1-{4-[(2-hydroxy-benzylidene)amino]phenyl}ethanone oxime, C15H14N2O2
  54. Crystal structure of 1,1′-butanebis(3-methyl-1H-imidazol-3-ium)bis(hexafluorophosphate), C12H20F12N4P2
  55. (E)-N-benzylidene-3-(benzylthio)-5-p-tolyl-4H-1,2,4-triazol-4-amine, C23H20N4S
  56. Crystal structure of ethyl 5-methyl-1-(pyridin-3-yl)-1H-1,2,3-triazole-4-carboxylate, C11H12N4O2
  57. Crystal structure of 5,5-difluoro-10-(4-fluorophenyl)-1,3,7,9-tetramethyl-5H-4l4,5l4-dipyrrolo[1,2-c:2′,1′-f][1,3,2]diazaborinine - a Z′ = 3 structure, C19H18B2F3N2
  58. The crystal structure of the Matrine derivative: 12-(1H-indol-1-yl)dodecahydro-1H,5H,10H-dipyrido[2,1-f:3′,2′,1′-ij][1,6]naphthyridin-10-one hydrate, C23H29N3O
  59. The crystal structure of tris(μ2-1,3-bis(4,4,4-trifluoro-3-oxido-1-(oxo)but-2-en-1-yl)phenyl-κ4O,O′:O′′,O′′′)-bis(1,2-dimethoxyethane-κ2O,O′)dilutetium(III), C50H38F18Lu2O16
  60. The crystal structure of (Z)-2-(3-(2-(4-chlorobenzoyl)hydrazono)-2-oxoindolin-1-yl) acetic acid, C17H12ClN3O4
  61. Synthesis and crystal structure of trans-tetraqua-bis(2-(((7-hydroxy-3-(4-hydroxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)ammonio)acetato-κO)cobalt(II) hexahydrate, C36H48CoN2O28S2
  62. The crystal structure of N,N-dimethyl-2,6-di-p-tolylpyrimidin-4-amine, C20H21N3
  63. The crystal structure (E)-4-methyl-N′-(2-nitrobenzylidene)benzenesulfonohydrazide, C14H13N3O4S
  64. Crystal structure of catena-poly[(μ2-1,3-bis(benzimidazol-1-yl)propane κ2N:N′)-(μ2-5-methoxyisophthalato-κ2O:O′)zinc(II)] hydrate, C26H24ZnN4O6
  65. The crystal structure of (E)-N′-(quinolin-2-ylmethylene)furan-2-carbohydrazide monohydrate, C15H13N3O3
  66. Crystal structure of 2,8-diphenyl-3,7,9-trioxa-1-azaspiro[4.5]dec-1-ene, C18H17N1O3
  67. Crystal structure of diethyl 2-(4-chlorophenyl)-1,3-dioxane-5,5-dicarboxylate, C16H19ClO6
  68. Crystal structure of 1-(carboxymethyl)-1H-benzo[d][1,2,3]triazole 3-oxide, C8H7N3O3
  69. Crystal structure of (acetylacetonato-κ2O,O′)-(2-amino-6-chlorobenzoato-κO)-oxido(1,10-phenanthroline-κ2N,N′)vanadium(IV) – trichloromethane (1/1)
  70. Crystal structure of (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one, C17H12Cl2O
  71. The crystal structure of trans-dibromido-bis(pyridine-κN)platinum(II), C10H10Br2N2Pt
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2026 De Gruyter Brill
Heruntergeladen am 25.1.2026 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2017-0035/html
Button zum nach oben scrollen