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Thermophysical characterization of mustard husk (MSH) and MSH char synthesized by the microwave pyrolysis of MSH

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Published/Copyright: May 15, 2023

Abstract

Thermophysical properties are calculated to determine performance parameters comprising specific heat capacity, thermal conductivity, thermal diffusivity and they are directly related to the dynamics of the material at atomic level and for thermal treatment of mustard husk (MSH) and MSH char, they play a vital role. Temperature dependence of thermophysical properties of MSH and MSH char have been investigated within the temperature range between 30 and 110 °C. MSH char is synthesized by the microwave pyrolysis of MSH. Thermogravimetric analysis of MSH and MSH char confirmed that MSH is more thermally stable as compared to MSH char. Moreover, it gave information about the degradation behaviour of MSH and MSH char. Thermophysical properties are measured by thermal analyser, based on the transient hot wire technique which is suitable to measure the thermal conductivity at elevated temperatures. At room temperature, thermal conductivity and thermal diffusivity of MSH are 0.187 W m−1 K−1 and 0.132 mm2 s−1, respectively. Specific heat capacity of MSH and MSH char are found to be almost same (1.349 kJ kg−1 K−1 for MSH and 1.310 kJ kg−1 K−1 for MSH char). Thermal conductivity and thermal diffusivity values are decreasing on increasing the temperature while specific heat capacity is increasing linearly on increasing the temperature. Low thermal conductivity and thermal diffusivity values of MSH imply that the conventional conductive heating is less effective and inefficient for the thermal treatment of MSH.


Corresponding author: Manoj Tripathi, Department of Physics and Materials Science and Engineering, Jaypee Institute of Information Technology, A-10, Sector 62, Noida, 201309, India, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Yao, X., Xu, K., Li, Y. Physicochemical properties and possible applications of waste corncob fly ash from biomass gasification industries of China. BioResources 2016, 11, 3783–3798. https://doi.org/10.15376/biores.11.2.3783-3798.Search in Google Scholar

2. Khoudja, D., Taallah, B., Izemmouren, O., Aggoun, S., Herihiri, O., Guettala, A. Mechanical and thermophysical properties of raw earth bricks incorporating date palm waste. Construct. Build. Mater. 2021, 270, 121824. https://doi.org/10.1016/j.conbuildmat.2020.121824.Search in Google Scholar

3. Balsora, H. K., Kartik, S., Rainey, T. J., Abbas, A., Joshi, J. B., Sharma, A., Chakinala, A. G. Kinetic modelling for thermal decomposition of agricultural residues at different heating rates. Biomass Convers. Biorefin. 2021, 13, 3281–3295. https://doi.org/10.1007/s13399-021-01382-4.Search in Google Scholar

4. Yang, X., Wang, H., Strong, P. J., Xu, S., Liu, S., Lu, K., Sheng, K., Guo, J., Che, L., He, L., Ok, Y. S., Yuan, G., Shen, Y., Chen, X. Thermal properties of biochars derived from waste biomass generated by. Agric. For. Sect. 2017, 10, 469. https://doi.org/10.3390/en10040469.Search in Google Scholar

5. Qian, X., Xue, J., Yang, Y., Lee, S. W. Thermal properties and combustion-related problems. Pred. Agric. Crop Residues 2021, 14, 4619. https://doi.org/10.3390/en14154619.Search in Google Scholar

6. Conti, J., Holtberg, P., Diefenderfer, J., LaRose, A., Turnure, J. T., Westfall, L. International Energy Outlook 2016 with Projections to 2040; U.S. Energy Information Administration: Washington, DC, United States, 2016.Search in Google Scholar

7. Kawale, H. D., Kishore, N. Comparative study on pyrolysis of Delonix Regia, Pinewood sawdust and their co-feed for plausible bio-fuels production. Energy 2020, 203, 117921. https://doi.org/10.1016/j.energy.2020.117921.Search in Google Scholar

8. Gupta, S., Gupta, G. K., Mondal, M. K. Thermal degradation characteristics, kinetics, thermodynamic, and reaction mechanism analysis of pistachio shell pyrolysis for its bioenergy potential. Biomass Convers. Biorefinery 2020, 12, 4847–4861. https://doi.org/10.1007/s13399-020-01104-2.Search in Google Scholar

9. Das, T. K., Nath, C. P., Das, S., Biswas, S., Bhattacharyya, R., Sudhishri, S., Raj, R., Singh, B., Kakralia, S. K., Rathi, N., Sharma, A. R., Dwivedi, B. S., Biswas, A. K., Chaudhari, S. K. Conservation Agriculture in rice-mustard cropping system for five years: impacts on crop productivity, profitability, water-use efficiency, and soil properties. Field Crop. Res. 2020, 250, 107781. https://doi.org/10.1016/j.fcr.2020.107781.Search in Google Scholar

10. Mikulčić, H., von Berg, E., Vujanović, M., Duić, N. Numerical study of co-firing pulverized coal and biomass inside a cement calciner. Waste Manag. Res. 2014, 32, 661–669. https://doi.org/10.1177/0734242x14538309.Search in Google Scholar

11. Gaurav, N., Sivasankari, S., Kiran, G. S., Ninawe, A., Selvin, J. Utilization of bioresources for sustainable biofuels: a review. Renew. Sustain. Energy Rev. 2017, 73, 205–214. https://doi.org/10.1016/j.rser.2017.01.070.Search in Google Scholar

12. Nawaz, A., Kumar, P. Pyrolysis of mustard straw: evaluation of optimum process parameters, kinetic and thermodynamic study. Bioresour. Technol. 2021, 340, 125722. https://doi.org/10.1016/j.biortech.2021.125722.Search in Google Scholar PubMed

13. Jacob, G. A., Prabhakaran, S. P. S., Swaminathan, G., Joseyphus, R. J. Thermal kinetic analysis of mustard biomass with equiatomic iron–nickel catalyst and its predictive modeling. Chemosphere 2022, 286, 131901. https://doi.org/10.1016/j.chemosphere.2021.131901.Search in Google Scholar PubMed

14. Bensidhom, G., Ben Hassen Trabelsi, A., mahmood, M. A., Ceylan, S. Insights into pyrolytic feedstock potential of date palm industry wastes: kinetic study and product characterization. Fuel 2021, 285, 119096. https://doi.org/10.1016/j.fuel.2020.119096.Search in Google Scholar

15. Islam, M. A., Pal, A., Baran Saha, B., Yoon, S.-H., Miyawaki, J. Thermophysical characteristics of novel biomass-derived activated carbon as a function of synthesis parameters. Heat Transfer Eng. 2021, 43, 1–14. https://doi.org/10.1080/01457632.2021.2001743.Search in Google Scholar

16. Maiti, S., Purakayastha, S., Ghosh, B. Thermal characterization of mustard straw and stalk in nitrogen at different heating rates. Fuel 2007, 86, 1513–1518. https://doi.org/10.1016/j.fuel.2006.11.016.Search in Google Scholar

17. Asadi, I., Shafigh, P., Hashemi, M., Akhiani, A. R., Maghfouri, M., Sajadi, B., Metselaar, H. S. C., Esfandiari, M., Rezaei Talebi, H. Thermophysical properties of sustainable cement mortar containing oil palm boiler clinker (OPBC) as a fine aggregate. Construct. Build. Mater. 2021, 268, 121091. https://doi.org/10.1016/j.conbuildmat.2020.121091.Search in Google Scholar

18. Islam Md, A., Thu, K., Saha Bidyut, B. Specific heat capacity of mangrove and waste palm trunk in raw, carbonized and activated form. Proc. Inter. Exch. Innovat. Conf. Eng. Sci. 2018, 4, 151–152. https://doi.org/10.15017/1961328.Search in Google Scholar

19. Fontan, R. D. C. I., Santos, l. S., Bonomo, R. C. F., Lemos, A. R., Ribeiro, R. P., Veloso, C. M. Thermophysical properties of coconut water affected by temperature. J. Food Process Eng. 2009, 32, 382–397. https://doi.org/10.1111/j.1745-4530.2007.00222.x.Search in Google Scholar

20. Minim, L. A., Telis, V. R. N., Minim, V. P. R., Alcantara, L. A. P., Telis-Romero, J. Thermophysical properties of lemon juice as affected by temperature and water content. J. Chem. Eng. Data 2009, 54, 2269–2272. https://doi.org/10.1021/je900155c.Search in Google Scholar

21. Tripathi, M., Sahu, J., Ganesan, P., Laxmi, J. Thermophysical characterization of oil palm shell (OPS) and OPS char synthesized by the microwave pyrolysis of OPS. Appl. Therm. Eng. 2016, 105, 6.5–612. https://doi.org/10.1016/j.applthermaleng.2016.03.053.Search in Google Scholar

22. Salema, A. A., Ani, F. N. Microwave induced pyrolysis of oil palm biomass. Bioresour. Technol. 2011, 102, 3388–3395. https://doi.org/10.1016/j.biortech.2010.09.115.Search in Google Scholar PubMed

23. Undri, A., Abou-Zaid, M., Briens, C., Berruti, F., Rosi, L., Bartoli, M., Frediani, M., Frediani, P. Bio-oil from pyrolysis of wood pellets using a microwave multimode oven and different microwave absorbers. Fuel 2015, 153, 464–482. https://doi.org/10.1016/j.fuel.2015.02.081.Search in Google Scholar

24. Liu, G., Wright, M. M., Zhao, Q., Brown, R. C. Catalytic fast pyrolysis of duckweed: effects of pyrolysis parameters and optimization of aromatic production. J. Anal. Appl. Pyrolysis 2015, 112, 29–36. https://doi.org/10.1016/j.jaap.2015.02.026.Search in Google Scholar

25. Venkatesh, M. S., Raghavan, G. S. V. An overview of microwave processing and dielectric properties of agri-food materials. Biosyst. Eng. 2004, 88, 1–18. https://doi.org/10.1016/j.biosystemseng.2004.01.007.Search in Google Scholar

26. Mathis, N. Transient thermal conductivity measurements: comparison of destructive and nondestructive techniques. High. Temp. – High. Press. 2000, 32, 321–327. https://doi.org/10.1068/htwu289.Search in Google Scholar

27. Dey, T., Tripathi, M. Thermal properties of silicon powder filled high-density polyethylene composites. Thermochim. Acta 2010, 502, 35–42. https://doi.org/10.1016/j.tca.2010.02.002.10.1016/j.tca.2010.02.002Search in Google Scholar

28. El-Sayed, S. A., Mostafa, M. E. Pyrolysis characteristics and kinetic parameters determination of biomass fuel powders by differential thermal gravimetric analysis (TGA/DTG). Energy Convers. Manage. 2014, 85, 165–172. https://doi.org/10.1016/j.enconman.2014.05.068.Search in Google Scholar

29. Subramanian, S., Viswanathan, R. Thermal properties of minor millet grains and flours. Biosyst. Eng. 2003, 84, 289–296. https://doi.org/10.1016/S1537-5110(02)00222-2.Search in Google Scholar

Received: 2021-12-23
Accepted: 2023-01-23
Published Online: 2023-05-15
Published in Print: 2023-07-28

© 2023 Walter de Gruyter GmbH, Berlin/Boston

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