Home The crystal structure of bis(N-(amino(pyridin-2-yl)methylene)-5-chloro-2-hydroxybenzohydrazonato-κ3N,N′,O)zinc(II) – methanol (2/5), C57H60Cl2N16O13Zn2
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The crystal structure of bis(N-(amino(pyridin-2-yl)methylene)-5-chloro-2-hydroxybenzohydrazonato-κ3N,N′,O)zinc(II) – methanol (2/5), C57H60Cl2N16O13Zn2

  • Zhang Cuihong , Wang Dengwu , Ge Yuan , Yang Liguo ORCID logo and Miao Zongcheng EMAIL logo
Published/Copyright: March 25, 2020
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 235 Issue 3

Abstract

C57H60Cl2N16O13Zn2, monoclinic, P21 (no. 4), a = 11.0273(2) Å, b = 22.1495(3) Å, c = 13.3766(2) Å, β = 107.000(1)°, V = 3124.46(9) Å3, Z = 2, Rgt(F) = 0.0316, wRref(F2) = 0.0806, T = 296(2) K [1–3].

CCDC no.: 1980321

The asymmetric unit of the title crystal structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Yellow block
Size:0.10 × 0.08 × 0.06 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:1.02 mm−1
Diffractometer, scan mode:Bruker APEX-II, φ and ω
θmax, completeness:25.0°, >99%
N(hkl)measured, N(hkl)unique, Rint:32370, 10823, 0.026
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 10292
N(param)refined:854
Programs:Bruker [1], SHELX [2], [3]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Zn10.09813(4)0.65761(2)0.63387(4)0.01910(12)
Zn20.87077(4)0.39141(2)0.72220(4)0.01934(12)
Cl1a0.508(5)0.470(2)0.189(3)0.0344(6)
Cl1′b0.5290(3)0.46194(13)0.1739(2)0.0344(6)
Cl2a0.314(9)0.387(6)0.954(8)0.0474(7)
Cl2′b0.3282(5)0.3889(4)0.9434(5)0.0474(7)
Cl3a−0.239(5)0.588(3)0.061(4)0.0397(6)
Cl3′b−0.2544(3)0.59732(16)0.0742(3)0.0397(6)
Cl4a−0.439(3)0.660(2)0.840(3)0.0399(7)
Cl4′b−0.43415(16)0.68425(19)0.8664(2)0.0399(7)
N10.2700(4)0.69532(17)0.5879(3)0.0224(8)
N2−0.0286(3)0.77312(16)0.6450(3)0.0182(8)
N30.0762(3)0.74821(16)0.6210(3)0.0173(8)
N40.1285(4)0.84394(17)0.5698(3)0.0222(8)
H4A0.06510.86130.58300.027*
H4B0.18010.86470.54630.027*
N50.2255(3)0.63474(17)0.7920(3)0.0211(8)
N60.3118(3)0.50130(16)0.6748(3)0.0272(9)
H6A0.28790.48190.61660.033*
H6B0.37880.49020.72270.033*
N70.1428(3)0.56937(16)0.6243(3)0.0200(8)
N80.0993(3)0.53925(16)0.5299(3)0.0205(8)
N90.9798(4)0.56733(17)0.8333(3)0.0274(9)
H9A0.95170.59210.78230.033*
H9B1.01940.58070.89450.033*
N100.9052(3)0.48154(16)0.7309(3)0.0195(8)
N110.8488(3)0.51726(16)0.6433(3)0.0205(8)
N120.9751(4)0.40760(16)0.8862(3)0.0245(9)
N130.8887(3)0.20346(17)0.6723(3)0.0236(8)
H13A0.82550.18680.68700.028*
H13B0.93990.18180.64970.028*
N140.8384(3)0.30043(17)0.7173(3)0.0193(8)
N150.7335(3)0.27877(16)0.7441(3)0.0203(8)
N161.0324(4)0.35029(17)0.6815(3)0.0218(8)
O1−0.1940(3)0.85313(15)0.6467(3)0.0346(8)
H1−0.13580.83770.62910.052*
O2−0.0540(3)0.67549(13)0.6967(2)0.0208(7)
O30.0418(3)0.44516(14)0.4179(2)0.0276(7)
H30.07020.46450.47200.041*
O40.0079(3)0.63109(13)0.4695(2)0.0217(7)
O50.5759(3)0.20093(15)0.7662(3)0.0345(8)
H50.63830.21430.75210.052*
O60.6969(3)0.37993(14)0.7658(3)0.0269(8)
O70.7430(3)0.61375(14)0.5428(2)0.0289(7)
H70.79940.59680.58780.043*
O80.7845(3)0.42419(13)0.5665(2)0.0209(7)
O90.1502(7)0.8075(3)0.8738(6)0.119(3)
H9D0.11630.80290.80850.143*
O100.6667(4)0.9457(2)0.5152(4)0.0529(11)
H10A0.70980.92560.56420.079*
O110.5733(4)0.48377(17)0.7844(4)0.0500(11)
H11A0.61170.45550.76830.075*
O120.7476(5)0.1067(3)0.7601(5)0.0864(18)
H12A0.68090.09980.77790.104*
O130.9409(5)0.1308(2)0.9591(4)0.0676(14)
H13D0.91550.11980.89800.101*
C1−0.4032(5)0.7911(2)0.7845(4)0.0296(11)
H1A−0.46970.80390.80890.036*
C2−0.3601(4)0.7325(2)0.8005(4)0.0291(11)
C3−0.2608(4)0.7127(2)0.7661(3)0.0232(10)
H3A−0.23400.67290.77730.028*
C4−0.2001(4)0.7519(2)0.7147(3)0.0191(9)
C5−0.2461(4)0.8113(2)0.6958(4)0.0232(10)
C6−0.3470(4)0.8304(2)0.7321(4)0.0295(11)
H6−0.37600.86990.72070.035*
C7−0.0879(4)0.7308(2)0.6833(3)0.0170(9)
C80.1471(4)0.7838(2)0.5862(3)0.0171(9)
C90.2602(4)0.7543(2)0.5660(3)0.0184(9)
C100.3461(4)0.7856(2)0.5286(4)0.0238(10)
H100.33500.82650.51290.029*
C110.4488(5)0.7547(2)0.5151(4)0.0315(12)
H110.50870.77470.49070.038*
C120.4618(5)0.6936(2)0.5383(4)0.0333(12)
H120.53030.67180.52990.040*
C130.3695(4)0.6660(2)0.5745(4)0.0307(11)
H130.37760.62500.59000.037*
C140.3605(5)0.2742(3)0.8864(4)0.0342(12)
H140.29350.26410.91220.041*
C15−0.1624(4)0.5528(2)0.1764(4)0.0281(11)
C16−0.1485(5)0.4918(2)0.1602(4)0.0327(12)
H16−0.18530.47470.09490.039*
C17−0.0790(4)0.4566(2)0.2429(4)0.0296(11)
H17−0.06960.41550.23330.036*
C18−0.0230(4)0.4828(2)0.3403(3)0.0222(10)
C19−0.0345(4)0.5444(2)0.3551(3)0.0196(9)
C20−0.1065(4)0.5790(2)0.2714(3)0.0229(10)
H20−0.11650.62020.28030.027*
C210.0268(4)0.5747(2)0.4575(3)0.0188(9)
C220.2453(4)0.54844(19)0.6907(3)0.0201(9)
C230.2815(4)0.5801(2)0.7932(3)0.0207(9)
C240.3604(4)0.5555(2)0.8831(4)0.0290(11)
H240.39880.51830.88140.035*
C250.3818(5)0.5868(3)0.9761(4)0.0384(13)
H250.43440.57081.03790.046*
C260.3241(5)0.6419(2)0.9759(4)0.0330(12)
H260.33670.66371.03740.040*
C270.2468(4)0.6641(2)0.8818(4)0.0295(11)
H270.20810.70140.88180.035*
C280.4005(4)0.3329(2)0.8894(4)0.0290(11)
C290.4997(4)0.3497(2)0.8511(4)0.0264(11)
H290.52550.38980.85410.032*
C300.5603(4)0.3060(2)0.8080(4)0.0213(10)
C310.5199(4)0.2456(2)0.8052(4)0.0268(11)
C320.4200(5)0.2304(2)0.8451(4)0.0328(12)
H320.39360.19040.84360.039*
C330.6698(4)0.3243(2)0.7706(3)0.0197(9)
C340.9071(4)0.2627(2)0.6844(3)0.0181(9)
C351.0206(4)0.29032(19)0.6626(3)0.0173(9)
C361.1068(4)0.2581(2)0.6265(3)0.0233(10)
H361.09670.21690.61340.028*
C371.2089(4)0.2891(2)0.6106(4)0.0282(11)
H371.26780.26890.58520.034*
C381.2224(4)0.3498(2)0.6326(4)0.0301(11)
H381.29260.37030.62490.036*
C391.1341(4)0.3799(2)0.6656(4)0.0266(10)
H391.14270.42120.67750.032*
C401.0087(5)0.3672(2)0.9626(4)0.0336(12)
H400.98200.32750.94770.040*
C411.0812(5)0.3809(3)1.0630(4)0.0382(13)
H411.10190.35161.11500.046*
C421.1214(5)0.4393(3)1.0831(4)0.0418(14)
H421.17290.44991.14910.050*
C431.0858(5)0.4825(2)1.0057(4)0.0322(12)
H431.11160.52241.01930.039*
C441.0110(4)0.4654(2)0.9072(3)0.0226(9)
C450.9621(4)0.50770(19)0.8174(3)0.0207(9)
C460.7890(4)0.4819(2)0.5633(3)0.0186(9)
C470.7201(4)0.5135(2)0.4659(3)0.0188(9)
C480.6997(4)0.5767(2)0.4604(3)0.0208(9)
C490.6297(4)0.6031(2)0.3679(4)0.0264(10)
H490.61710.64470.36510.032*
C500.5778(4)0.5684(2)0.2790(4)0.0282(11)
H500.53050.58650.21710.034*
C510.5976(4)0.5068(2)0.2840(3)0.0235(10)
C520.6673(4)0.4793(2)0.3760(3)0.0220(10)
H520.67900.43770.37780.026*
C530.2816(9)0.8238(5)0.8738(9)0.118(4)
H53A0.32030.84850.93360.177*
H53B0.27830.84570.81120.177*
H53C0.33050.78770.87670.177*
C540.5393(6)0.9227(3)0.4834(6)0.065(2)
H54A0.50760.92060.54290.097*
H54B0.53870.88310.45400.097*
H54C0.48640.94920.43190.097*
C550.6429(8)0.5339(4)0.7935(10)0.123(5)
H55A0.59320.56810.80230.185*
H55B0.66900.53930.73170.185*
H55C0.71640.53050.85320.185*
C560.7207(7)0.0555(3)0.6861(7)0.091(3)
H56A0.79120.04960.65890.137*
H56B0.64590.06400.62970.137*
H56C0.70740.01960.72180.137*
C570.9820(8)0.1905(3)0.9629(6)0.069(2)
H57A0.91150.21610.92980.103*
H57B1.04550.19390.92710.103*
H57C1.01740.20251.03450.103*

  1. Occupancy: a0.067(12), b0.933(12).

Source of material

The ligand was synthesized by the reaction of 5-chlorosalicylhydrazide and 2-cyanopyridine. The ligand N-(amino(pyridin-2-yl)methylene)-5-chloro-2-hydroxybenzohydrazonic acid; (0.010 mol) and zinc acetate (0.01 mol) was added to methanol (30 mL). This mixture was refluxed for 24 h with the formation of a yellow powder. The solid was filtered off, washed with water, methanol and ether and dried under vacuum. Yield (3.5 g, 34%).

Experimental details

The C-bound H atoms were geometrically placed (C—H = 0.95–0.98 Å) and refined as riding with Uiso(H) = 1.2–1.5 Ueq(C). The N-bound H atoms were located in a difference Fourier map but were refined with a distance restraint of N—H = 0.88 ± 0.01 Å, and with Uiso(H) set to 1.2 Ueq(N) [1], [2], [3].

Comment

Many picolinic hydrazone ligands have been studied due to the four coordination sites in the ligands. A lot of complexes with the picolinic hydrazone ligands have been synthesized and characterized [4], [5], [6]. Now, a new ligand, N′-(5-chloro-2-hydroxybenzoyl)pyridine-2-carbohydrazonamide, was synthesized by our group. Then a new zinc complex with this ligand has been sythesized, which is similar with related complexes [7], [8], [9]. As shown in the figure, the title compound crystallizes in the monoclinic space group P21 with two formula units in the asymmetric unit. The bond lengths of Zn1-N1, Zn1-N3 and Zn1-O2 are 2.313, 2.023 and 2.122 Å, respectively, which are similar with the zinc complex in the reference [8].

Acknowledgements

This work was supported by Scientific Research Program Funded by Shaanxi Provincial Education Department (No. 18JK1206, No. 19JK0909). The Science Research Foundation of Xijing University (No. XJ18B06).

References

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Received: 2019-11-29
Accepted: 2020-01-28
Published Online: 2020-03-25
Published in Print: 2020-04-28

©2020 Zhang Cuihong et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 Public License.

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  32. Crystal structure of 7-hydroxy-4-phenyl-2H-chromen-2-one, C15H10O3
  33. Crystal structure of 3,7-dimethyl-1-(5-oxohexyl)-3,7-dihydro-1H-purine-2,6-dione 4-hydroxybenzoic acid, C20H24N4O6
  34. Crystal structure of catena-poly[(μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4-ylmethylene)amino)-1,2-dihydro-3H-pyrazol-3-one-κ2N:O)-bis(nitrato-κ1O)zinc(II)], C17H16N6O7Zn
  35. The crystal structure of diaqua-bis(6-aminopicolinato-κ2N,O)magnesium(II), C12H14O6N4Mg
  36. Crystal structure of (pyridine-2-carboxamide-κ2N,O)-[tris((1H-benzo[d]imidazol-2-yl)methyl)amine-κ4N,N′,N′′,N′′′]nickel(II) diperchlorate — methanol (1/3), C33H39Cl2N9NiO12
  37. Crystal structure of catena-poly[diaqua-bis(3-(4-trifluoromethyl-phenyl)-acrylato-κO1)-(μ2-1,4-bis(1-imidazolyl)benzene-κ2N3:N3′)cobalt(II)], C32H26CoF6N4O6
  38. Crystal structure of (E)-3-(2-(2-hydroxy-4-methoxystyryl)-3,3-dimethyl-3H-indol-1-ium-1-yl)propane-1-sulfonate monohydrate, C22H25NO5S⋅H2O
  39. The crystal structure of bis(N-oxy-2-(1H-tetrazol-1-yl) acetamide κ2O,O′)-diaqua-zinc(II), C6H12ZnN10O6
  40. Crystal structure of (E)-4-((4-chlorophenylimino)methyl)pyridinium 3,5-dinitrobenzoate, C19H13ClN4O6
  41. Crystal structure of dichlorido-bis((E)-2-((pyridin-4-ylmethylene)amino)phenol)zinc(II), C24H20Cl2N4O2Zn
  42. Crystal structure of cyclo-[tetrachlorido-bis(μ2-p-xylylenediamine-κ2N:N′)dipalladium(II)] dimethyl sulfoxide solvate, C20H36Cl4N4O2Pd2S2
  43. Crystal structure of 4-(3-fluorophenyl)-7-hydroxy-2H-chromen-2-one, C15H9FO3
  44. Crystal structure of (E)-2-((2-(pyrimidin-2-yl)hydrazono)methyl)quinolin-1-ium perchlorate – methanol (1/1), C15H16N5O5Cl
  45. The crystal structure of bis(N-(amino(pyridin-2-yl)methylene)-5-chloro-2-hydroxybenzohydrazonato-κ3N,N′,O)zinc(II) – methanol (2/5), C57H60Cl2N16O13Zn2
  46. Synthesis and crystal structure of 4,4′-di(4-pyridyl)-6,6′-di(tert-butyl)-2,2′-[propylenedioxybis(nitrilomethylidyne)]diphenol, C35H40N4O4
  47. Crystal structure of (3E,3′E)-3,3′-((1,3,4-thiadiazole-2,5-diyl)bis(sulfanediyl))bis(4-hydroxy-4-phenylbut-3-en-2-one), C22H18N2O4S3
  48. Crystal structure of (N-benzyl-N-methyl-dithiocarbamato-κ2S,S′)di(4-chlorobenzyl)chloridotin(IV), C23H22Cl3NS2Sn
  49. Crystal structure of (1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O6) sodium bromide hydrate, [Na(18-crown-6)]Br ⋅ H2O, C12H26BrNaO7
  50. Crystal structure of 7-ethoxyl-6,8-difluoro-4-oxo-1-phenyl-1,4-dihydro-quinoline-3-carboxylic acid, C18H13F2N1O4
  51. Crystal structure of chlorido (2-(4-ethylphenyl)pyrimidine-k2C,N)(triphenylphosphane-kP) palladium(II), C30H26ClN2PPd
  52. Crystal structure of 18-crown-6 – 1,4-diiodotetrafluorobenzene – acetonitrile (1/1/2), C22H30F4I2N2O6
  53. Crystal structure of diisobutyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate, C16H24O6
  54. Crystal structure of poly[[tris(μ2-cis-1,2-cyclohexanedicarboxylato)-κ2O, O′]-bis[μ3-1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene-κ3N, N′,N′′]-trizinc(II)] – water (1/20), C60H106N12O32Zn3
  55. The synthesis and crystal structure of 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-((trifluoromethyl)sulfinyl)-1H-pyrazole-3-carboxamide–tetrahydrofuran (1/1), C16H14N4Cl2F6O3S
  56. Crystal structure of dimethylbis(diisopropyldithiocarbamato-κ2S,S′)tin(IV), C16H34N2S4Sn
  57. Crystal structure of diisopropyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate, C14H20O6
  58. The synthesis and crystal structure of ethyl (E)-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-5-((2-methoxybenzylidene)amino)-4-((trifluoromethyl)sulfinyl)-1H-pyrazole-3-carboxylate, C22H15N3Cl2F6O4S
  59. The crystal structure of a matrine derivative, 13-(methylamine-1-yl) carbodithioate matrine, C17H27N3OS2
  60. Crystal structure of bis(2-hydroxy-6-((phenylimino)methyl)phenolato-κ2N,O)copper(II), C26H20CuN2O4
  61. The crystal structure of 2-p-fluorophenyl-5-dihydroxymethyl-1,3,4-oxadiazole, C9H7FN2O3
  62. Crystal structure of dichloridobis(4-chlorophenyl-κC1)(1,10-phenanthroline-κ2N,N′)tin(IV), C24H16Cl4N2Sn
  63. Crystal structure of bis{bromido-triphenyltin(IV)}(μ2-[4,4′-bipyridine]1,1′-dioxide-κ2O:O′), C46H38Br2N2O2Sn2
  64. Crystal structure of 2-(5-chloro-quinolin-8-yloxy)-N-quinolin-8-yl-acetamide, C20H14N3O2Cl
  65. Crystal structure of bis(N-(1-(3-ethylpyrazin-2-yl)ethylidene)-3-hydroxy-2-naphthohydrazonato-κ3N,N′,O)cobalt(II) — dimethylformamide (1/1), C41H41N9O5Co
  66. Crystal structure of bis[2-(1-(3-ethylpyrazin-2-yl)ethylidene)-1-tosylhydrazin-1-ido-κ3-N,N′,O]copper(II), C30H34N8O4S2Cu
  67. Crystal structure of (2-p-tolylpyrimidine-κ2C,N)(triphenylphosphane-κP) palladium(II), C29H24ClN2PPd
  68. Halogen bonding in crystal structure of bis(1,4,7,10-tetraoxacyclododecane-κ4O,O′,O′′,O′′′)cesium triiodide, C16H32CsI3O8
  69. The synthesis and crystal structure of N-(3-cyano-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylsulfinyl)-1H-pyrazol-5-yl)-2-phenylacetamide, C20H10N4Cl2F6O2S
  70. The crystal structure of 4-(trifluoromethyl)nicotinic acid, C7H4F3NO2
  71. Crystal structure of 3-(2-methylbenzyl)thiazolidin-2-one, C11H13ONS
  72. The crystal structure of 2,2,2-trifluoro-1-(isoquinolin-1-yl)ethane-1,1-diol, C11H8F3NO2
  73. The crystal structure of 3-bromoisonicotinic acid, C6H4BrNO2
  74. The crystal structure of 5-nitropicolinic acid monohydrate, C6H6N2O5
  75. The crystal structure of 3-(4-hydroxybenzyl)-1,5-dioxaspiro[5.5]undecane-2,4-dione, C16H18O5
  76. Crystal structure of [[Mo3Se7(S2CNEt2)3]2(μ-Se)] ⋅ 2(C6H4Cl2), C42H68Cl4Mo6N6S12Se15
  77. Crystal structure of (E)-4-hydroxy-3-((5-phenyl-1,3,4-oxadiazol-2-yl)thio)pent-3-en-2-one, C13H12N2O3S
  78. The crystal structure of (2,3-dioxo-5,6:13,14-dibenzo-9,10-benzo-1,4,8,11-7, 11-diene-κ4N,N′,N′′,N′′′)-nickel(II), Ni(C22H14N4O2)
  79. Crystal structure of 3-(1-benzyl-2-ethyl-4-nitro-1H-imidazol-5-ylthio)-propanoic acid, C15H17N3O4S
  80. The crystal structure of dichlorobis(2-(dicyclohexylphosphino)-2′,4′,6′-tri-i-propyl-1,1′-biphenyl) palladium(II)-dichloroform, C68H100Cl8P2Pd
  81. Crystal structure and antimicrobial properties of (1,4,7,10-tetraoxacyclododecane-κ4O,O′,O′′,O′′′)cesium(I) pentaiodide, C16H32CsI5O8
https://doi.org/10.1515/ncrs-2019-0874
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Articles in the same Issue

  1. Frontmatter
  2. Crystal structure of catena-poly[(μ2-3-(benzo[d]thiazol-2-yl)-5-carboxybenzoato-κ2N:O)silver(I)], C15H8AgNO4S
  3. Crystal structure of bis(4-phenylpiperazin-1-ium) bis(2-(4-phenylpiperazin-1-yl)succinato-κ2O,O′)copper(II) tetrahydrate, C48H70CuN8O12, [C10H14N2]2[Cu(C14H17N2O4)2] ⋅ 4 H2O
  4. Crystal structure of triaqua-bis(2-(6-hydroxy-5-(hydroxymethyl)-5,8a-dimethyl-2-methylenedecahydronaphthalen-1-yl)-1-(2-oxo-2,5-dihydrofuran-3-yl)ethane-1-sulfonato-κ2O,O′)calcium(II) – ethanol (1/2), C44H76CaO19S2
  5. The crystal structure of ethyl 5-(4-(diphenylamino)phenyl)thiophene-2-carboxylate, C25H21NO2S
  6. The crystal structure of 5-bromo-2-(2-methyl-2H-tetrazol-5-yl)pyridine, C7H6BrN5
  7. The crystal structure of (E)-5-chloro-2-hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)benzohydrazide, C15H13ClN2O4
  8. The crystal structure of (2Z,2′Z)-N′,N′′′′-(pyridine-2,6-dicarbonyl)dipicolinohydrazonamide, C19H17N9O2
  9. Photochromic properties and crystal structure of 3,3′-(perfluorocyclopent-1-ene-1,2-diyl)bis(5-(4-(azidomethyl)phenyl)-2-methylthiophene), C29H20F6N6S2
  10. Crystal structure of aqua-dichlorido-(4-(((3-ethoxy-2-oxidobenzylidene)hydrazono)(oxido)methyl)pyridin-1-ium-κ3N,O,O′)iron(III), C15H16Cl2N3O4Fe
  11. Crystal structure of catena-poly[diaqua-(μ2-4,4′-bipyridine-κ2N:N′)-bis(2,3,4,5-tetrabromo-6-carboxybenzoato-κ1O)-nickel(II)], C26H14Br8NiN2O10
  12. Crystal structure of diethanol-κ1O-bis(μ2-N-((2-oxidonaphthalen-1-yl)methylene)pyrazine-2-carbohydrazonato-κ5N,O,O′:O′:N′)-bis(nitrato-κ2O,O′)dieuropium(III), C36H32N10O12Eu2
  13. The crystal structure of 2-aminoisophthalic acid, C8H7NO4
  14. Crystal structure of (E)-2-(4-((3,4-difluorobenzyl)oxy)styryl)-4,6-dimethoxybenzaldehyde, C24H20F2O4
  15. Crystal structure of 2-benzoylpyrene, C23H14O
  16. Crystal structure of chlorido-(η6-p-cymene)-(N-(2-fluorophenyl)-1-(pyridin-2-yl)methanimine-κ2N,N′)ruthenium(II) – acetone (1/1), C22H23ClN2F7OPRu
  17. The crystal structure of 2-bromoisonicotinic acid, C6H4BrNO2
  18. Crystal structure of 1,3,5,7-tetraphenyl-8-(N-phenylformamido)-2-oxa-5-azabicyclo[4.2.0]oct -3-en-7-yl benzoate, C44H34N2O4
  19. Synthesis and crystal structure of 4-(3-acetyl-5-(thiophen-2-yl)-2,3-dihydro-1,3,4-oxadiazol-2-yl)-7-(diethylamino)-2H-chromen-2-one, C21H21N3O4S
  20. Crystal structure of poly[diaqua-(μ2-4,4′-bipyridine-κ2N:N′)-(μ2-3,4,5,6-tetrafluorophthalato-κ2O:O′)nickel(II)], C18H12F4NiN2O6
  21. Crystal structure of 4-hydroxynaphtho[2,3-b]benzofuran-6,11-dione, C16H8O4
  22. The crystal structure of 3,10-bis(4-methoxyphenyl)-6,12-dibenzyl-2,9-acetyl-6,12-diazapentacyclo[6.3.1.02,7.04,11.05,9]dodecane – acetone (1/1), C45H48N2O5
  23. The crystal structure of (E)-2-(((2-(1H-indol-3-yl)ethyl)iminio)methyl)-6-bromophenolate, C17H15N2BrO
  24. Crystal structure of catena-poly[diaqua-(μ2-oxalyl dihydrazide-κ4N,O:N′,O′)-bis(μ2-pyridine-2,3-dicarboxylato-κ3N,O,O′)dicadmium(II)] hexahydrate, C16H28O18N6Cd2
  25. Crystal structure of poly[tetra-(μ4-naphthalene-1,8-dicarboxylato-κ4O:O,O′: O′′:O′′,O′′′)-(μ4-oxo-κ4O:O:O:O) penta-lead(II)], C48H24O17Pb5
  26. Crystal structure of 5H-dibenzo[c,f][1,5]oxabismocin-12 (7H)-yl acetate, C16H15O3Bi
  27. The crystal structure of 2-(4-chloro-6-nitrophenyl)-1-(4-chloro-3-nitrophenyl)diazene 1-oxide, C12H6Cl2N4O5
  28. Crystal structure of bis(3-methyl-N-(1-(pyrazin-2-yl)ethylidene)benzohydrazonato-κ3O,N,N′)nickel(II), C28H26N8O2Ni
  29. Crystal structure of 3,10-bis(4-chlorophenyl)-6,12-dibenzyl-2,9-acetyl-6,12-diazapentacyclo[6.3.1.02,7.04,11.05,9]-dodecane, C40H36Cl2N2O2
  30. Crystal structure of bis[(μ2-4⋯O,O′:O′)-(4-hydroxybenzoato-κ2O,O′)-(1,10-phenanthroline-κ2N,N′)]-di-lead(II)μ-4-hydroxybenzoato-κ3O,O′:O′;κ3O,O′:O′-bis-[(4-hydroxybenzoato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)di-lead(II)] monohydrate, C52H36N4O12Pb2 ⋅ H2O
  31. Crystal structure of poly[diaqua-(μ3-3,4,5,6-tetrafluoro-phthalato-κ3O:O′:O′′)-(μ2-1,2-bis(4-pyridyl)ethene-κ2N:N′)cobalt(II)], C14H9CoF4NO6
  32. Crystal structure of 7-hydroxy-4-phenyl-2H-chromen-2-one, C15H10O3
  33. Crystal structure of 3,7-dimethyl-1-(5-oxohexyl)-3,7-dihydro-1H-purine-2,6-dione 4-hydroxybenzoic acid, C20H24N4O6
  34. Crystal structure of catena-poly[(μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4-ylmethylene)amino)-1,2-dihydro-3H-pyrazol-3-one-κ2N:O)-bis(nitrato-κ1O)zinc(II)], C17H16N6O7Zn
  35. The crystal structure of diaqua-bis(6-aminopicolinato-κ2N,O)magnesium(II), C12H14O6N4Mg
  36. Crystal structure of (pyridine-2-carboxamide-κ2N,O)-[tris((1H-benzo[d]imidazol-2-yl)methyl)amine-κ4N,N′,N′′,N′′′]nickel(II) diperchlorate — methanol (1/3), C33H39Cl2N9NiO12
  37. Crystal structure of catena-poly[diaqua-bis(3-(4-trifluoromethyl-phenyl)-acrylato-κO1)-(μ2-1,4-bis(1-imidazolyl)benzene-κ2N3:N3′)cobalt(II)], C32H26CoF6N4O6
  38. Crystal structure of (E)-3-(2-(2-hydroxy-4-methoxystyryl)-3,3-dimethyl-3H-indol-1-ium-1-yl)propane-1-sulfonate monohydrate, C22H25NO5S⋅H2O
  39. The crystal structure of bis(N-oxy-2-(1H-tetrazol-1-yl) acetamide κ2O,O′)-diaqua-zinc(II), C6H12ZnN10O6
  40. Crystal structure of (E)-4-((4-chlorophenylimino)methyl)pyridinium 3,5-dinitrobenzoate, C19H13ClN4O6
  41. Crystal structure of dichlorido-bis((E)-2-((pyridin-4-ylmethylene)amino)phenol)zinc(II), C24H20Cl2N4O2Zn
  42. Crystal structure of cyclo-[tetrachlorido-bis(μ2-p-xylylenediamine-κ2N:N′)dipalladium(II)] dimethyl sulfoxide solvate, C20H36Cl4N4O2Pd2S2
  43. Crystal structure of 4-(3-fluorophenyl)-7-hydroxy-2H-chromen-2-one, C15H9FO3
  44. Crystal structure of (E)-2-((2-(pyrimidin-2-yl)hydrazono)methyl)quinolin-1-ium perchlorate – methanol (1/1), C15H16N5O5Cl
  45. The crystal structure of bis(N-(amino(pyridin-2-yl)methylene)-5-chloro-2-hydroxybenzohydrazonato-κ3N,N′,O)zinc(II) – methanol (2/5), C57H60Cl2N16O13Zn2
  46. Synthesis and crystal structure of 4,4′-di(4-pyridyl)-6,6′-di(tert-butyl)-2,2′-[propylenedioxybis(nitrilomethylidyne)]diphenol, C35H40N4O4
  47. Crystal structure of (3E,3′E)-3,3′-((1,3,4-thiadiazole-2,5-diyl)bis(sulfanediyl))bis(4-hydroxy-4-phenylbut-3-en-2-one), C22H18N2O4S3
  48. Crystal structure of (N-benzyl-N-methyl-dithiocarbamato-κ2S,S′)di(4-chlorobenzyl)chloridotin(IV), C23H22Cl3NS2Sn
  49. Crystal structure of (1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O6) sodium bromide hydrate, [Na(18-crown-6)]Br ⋅ H2O, C12H26BrNaO7
  50. Crystal structure of 7-ethoxyl-6,8-difluoro-4-oxo-1-phenyl-1,4-dihydro-quinoline-3-carboxylic acid, C18H13F2N1O4
  51. Crystal structure of chlorido (2-(4-ethylphenyl)pyrimidine-k2C,N)(triphenylphosphane-kP) palladium(II), C30H26ClN2PPd
  52. Crystal structure of 18-crown-6 – 1,4-diiodotetrafluorobenzene – acetonitrile (1/1/2), C22H30F4I2N2O6
  53. Crystal structure of diisobutyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate, C16H24O6
  54. Crystal structure of poly[[tris(μ2-cis-1,2-cyclohexanedicarboxylato)-κ2O, O′]-bis[μ3-1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene-κ3N, N′,N′′]-trizinc(II)] – water (1/20), C60H106N12O32Zn3
  55. The synthesis and crystal structure of 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-((trifluoromethyl)sulfinyl)-1H-pyrazole-3-carboxamide–tetrahydrofuran (1/1), C16H14N4Cl2F6O3S
  56. Crystal structure of dimethylbis(diisopropyldithiocarbamato-κ2S,S′)tin(IV), C16H34N2S4Sn
  57. Crystal structure of diisopropyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate, C14H20O6
  58. The synthesis and crystal structure of ethyl (E)-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-5-((2-methoxybenzylidene)amino)-4-((trifluoromethyl)sulfinyl)-1H-pyrazole-3-carboxylate, C22H15N3Cl2F6O4S
  59. The crystal structure of a matrine derivative, 13-(methylamine-1-yl) carbodithioate matrine, C17H27N3OS2
  60. Crystal structure of bis(2-hydroxy-6-((phenylimino)methyl)phenolato-κ2N,O)copper(II), C26H20CuN2O4
  61. The crystal structure of 2-p-fluorophenyl-5-dihydroxymethyl-1,3,4-oxadiazole, C9H7FN2O3
  62. Crystal structure of dichloridobis(4-chlorophenyl-κC1)(1,10-phenanthroline-κ2N,N′)tin(IV), C24H16Cl4N2Sn
  63. Crystal structure of bis{bromido-triphenyltin(IV)}(μ2-[4,4′-bipyridine]1,1′-dioxide-κ2O:O′), C46H38Br2N2O2Sn2
  64. Crystal structure of 2-(5-chloro-quinolin-8-yloxy)-N-quinolin-8-yl-acetamide, C20H14N3O2Cl
  65. Crystal structure of bis(N-(1-(3-ethylpyrazin-2-yl)ethylidene)-3-hydroxy-2-naphthohydrazonato-κ3N,N′,O)cobalt(II) — dimethylformamide (1/1), C41H41N9O5Co
  66. Crystal structure of bis[2-(1-(3-ethylpyrazin-2-yl)ethylidene)-1-tosylhydrazin-1-ido-κ3-N,N′,O]copper(II), C30H34N8O4S2Cu
  67. Crystal structure of (2-p-tolylpyrimidine-κ2C,N)(triphenylphosphane-κP) palladium(II), C29H24ClN2PPd
  68. Halogen bonding in crystal structure of bis(1,4,7,10-tetraoxacyclododecane-κ4O,O′,O′′,O′′′)cesium triiodide, C16H32CsI3O8
  69. The synthesis and crystal structure of N-(3-cyano-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylsulfinyl)-1H-pyrazol-5-yl)-2-phenylacetamide, C20H10N4Cl2F6O2S
  70. The crystal structure of 4-(trifluoromethyl)nicotinic acid, C7H4F3NO2
  71. Crystal structure of 3-(2-methylbenzyl)thiazolidin-2-one, C11H13ONS
  72. The crystal structure of 2,2,2-trifluoro-1-(isoquinolin-1-yl)ethane-1,1-diol, C11H8F3NO2
  73. The crystal structure of 3-bromoisonicotinic acid, C6H4BrNO2
  74. The crystal structure of 5-nitropicolinic acid monohydrate, C6H6N2O5
  75. The crystal structure of 3-(4-hydroxybenzyl)-1,5-dioxaspiro[5.5]undecane-2,4-dione, C16H18O5
  76. Crystal structure of [[Mo3Se7(S2CNEt2)3]2(μ-Se)] ⋅ 2(C6H4Cl2), C42H68Cl4Mo6N6S12Se15
  77. Crystal structure of (E)-4-hydroxy-3-((5-phenyl-1,3,4-oxadiazol-2-yl)thio)pent-3-en-2-one, C13H12N2O3S
  78. The crystal structure of (2,3-dioxo-5,6:13,14-dibenzo-9,10-benzo-1,4,8,11-7, 11-diene-κ4N,N′,N′′,N′′′)-nickel(II), Ni(C22H14N4O2)
  79. Crystal structure of 3-(1-benzyl-2-ethyl-4-nitro-1H-imidazol-5-ylthio)-propanoic acid, C15H17N3O4S
  80. The crystal structure of dichlorobis(2-(dicyclohexylphosphino)-2′,4′,6′-tri-i-propyl-1,1′-biphenyl) palladium(II)-dichloroform, C68H100Cl8P2Pd
  81. Crystal structure and antimicrobial properties of (1,4,7,10-tetraoxacyclododecane-κ4O,O′,O′′,O′′′)cesium(I) pentaiodide, C16H32CsI5O8
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