Startseite Crystal structure of poly[[tris(μ2-cis-1,2-cyclohexanedicarboxylato)-κ2O, O′]-bis[μ3-1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene-κ3N, N′,N′′]-trizinc(II)] – water (1/20), C60H106N12O32Zn3
Artikel Open Access

Crystal structure of poly[[tris(μ2-cis-1,2-cyclohexanedicarboxylato)-κ2O, O′]-bis[μ3-1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene-κ3N, N′,N′′]-trizinc(II)] – water (1/20), C60H106N12O32Zn3

  • Bing-Feng Li ORCID logo EMAIL logo , Tong-Min Dong , Xi-Ting Xu , Yang Gu , Lei Gong , Wan-Ying Zhou und Kai-Long Zhong
Veröffentlicht/Copyright: 27. Februar 2020
Artikel downloaden (PDF)
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 235 Heft 3

Abstract

C60H106N12O32Zn3, monoclinic, P21/c (no. 14), a = 18.9877(14) Å, b = 19.7813(15) Å, c = 21.0699(14) Å, β = 103.345(2)°, V = 7700.2(10) Å3, Z = 4, Rgt(F) = 0.0626, wRref(F2) = 0.1752, T = 193 K.

CCDC no.: 1982978

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Colourless block
Size:0.32 × 0.20 × 0.20 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:0.98 mm−1
Diffractometer, scan mode:Bruker APEX-II, φ and ω
θmax, completeness:27.6°, >99%
N(hkl)measured, N(hkl)unique, Rint:47361, 17545, 0.097
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 8283
N(param)refined:857
Programs:PLATON [1], [2]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
C1−0.2046(3)0.6754(2)0.5746(2)0.0388(11)
H1A−0.21900.64660.60410.047*
C2−0.1396(3)0.7338(3)0.5256(2)0.0459(13)
H2A−0.09980.75350.51420.055*
C3−0.2095(3)0.7441(3)0.4948(2)0.0457(13)
H3A−0.22620.77200.45890.055*
C4−0.3295(3)0.7018(3)0.5101(2)0.0465(13)
H4A−0.34930.74060.52830.056*
H4B−0.34410.66140.52970.056*
C5−0.3590(2)0.6998(3)0.4379(2)0.0418(12)
C6−0.3683(2)0.6393(3)0.4042(2)0.0428(12)
H6A−0.35830.59880.42690.051*
C7−0.3927(2)0.6382(3)0.3359(2)0.0440(12)
C8−0.4070(3)0.6990(3)0.3030(3)0.0511(14)
H8A−0.42330.69920.25780.061*
C9−0.3974(2)0.7596(3)0.3368(3)0.0462(13)
C10−0.3746(2)0.7605(3)0.4041(2)0.0475(13)
H10A−0.36980.80140.42660.057*
C11−0.4150(3)0.8262(3)0.3004(3)0.0660(17)
H11A−0.38280.86110.32270.079*
H11B−0.40700.82150.25680.079*
C120.4569(3)0.6586(3)0.7443(2)0.0476(13)
H12A0.46230.67530.70450.057*
C13a0.4209(9)0.6037(8)0.8128(8)0.061(4)
H13Aa0.39190.57740.83300.074*
C13’b0.3993(7)0.6360(7)0.8216(6)0.057(3)
H13’b0.36170.63070.84270.068*
C14a0.4921(9)0.6130(8)0.8367(9)0.070(5)
H14Aa0.52130.59420.87420.084*
C14’b0.4709(8)0.6435(7)0.8487(7)0.064(4)
H14’b0.49180.64250.89320.077*
C150.1826(3)0.6978(3)0.7433(2)0.0471(13)
H15A0.15830.65680.74190.057*
C160.2598(4)0.7719(3)0.7342(3)0.0706(19)
H16A0.30020.79300.72520.085*
C170.2098(4)0.8023(3)0.7595(3)0.0741(19)
H17A0.20890.84760.77090.089*
C180.0773(2)0.7153(2)0.5924(2)0.0357(11)
H18A0.09400.67100.59310.043*
C190.0167(3)0.8027(2)0.6066(2)0.0429(13)
H19A−0.01700.83060.61930.052*
C200.0670(3)0.8232(2)0.5747(2)0.0468(13)
H20A0.07400.86700.56130.056*
C210.1666(3)0.7645(2)0.5338(2)0.0404(12)
H21A0.20910.74690.56410.049*
H21B0.17770.80990.52160.049*
C220.1490(2)0.7198(2)0.4731(2)0.0317(10)
C230.1529(2)0.6502(2)0.4803(2)0.0314(11)
H23A0.16830.63160.52170.038*
C240.1344(2)0.6079(2)0.4268(2)0.0329(10)
C250.1133(2)0.6367(3)0.3651(2)0.0411(12)
H25A0.09950.60900.32860.049*
C260.1127(2)0.7061(3)0.3575(2)0.0406(12)
C270.1295(2)0.7469(2)0.4115(2)0.0382(11)
H27A0.12760.79360.40630.046*
C280.1415(3)0.5324(2)0.4351(2)0.0401(12)
H28A0.13090.51950.47630.048*
H28B0.10660.51030.40040.048*
C290.2351(3)0.4882(2)0.3807(2)0.0379(11)
H29A0.20470.48420.33940.046*
C300.3288(3)0.4869(2)0.4604(2)0.0415(12)
H30A0.37620.48150.48440.050*
C310.2740(3)0.5095(2)0.4845(2)0.0408(12)
H31A0.27590.52230.52740.049*
C320.0946(3)0.7351(3)0.2890(2)0.0564(15)
H32A0.06970.77790.28900.068*
H32B0.06250.70440.26000.068*
C330.4954(3)0.4975(2)0.3213(2)0.0408(12)
H33A0.52420.47110.35360.049*
C340.4028(3)0.5387(3)0.2537(3)0.0760(19)
H34A0.35540.54610.23070.091*
C350.4617(3)0.5740(3)0.2468(3)0.078(2)
H35A0.46230.60930.21790.094*
C360.5951(3)0.5710(3)0.2997(3)0.0547(14)
H36A0.60680.57590.25750.066*
H36B0.62730.53720.32420.066*
C370.0397(2)0.5552(2)0.6696(2)0.0342(11)
C380.0731(2)0.4894(2)0.65478(18)0.0272(10)
H38A0.04850.45360.67350.033*
C390.0585(2)0.4751(2)0.58145(19)0.0340(11)
H39A0.07790.51180.56010.041*
H39B0.00670.47320.56350.041*
C400.0926(3)0.4088(2)0.5673(2)0.0436(12)
H40A0.08630.40370.52050.052*
H40B0.06800.37140.58280.052*
C410.1729(3)0.4061(2)0.5999(2)0.0460(13)
H41A0.19250.36250.59160.055*
H41B0.19840.44090.58170.055*
C420.1841(3)0.4167(2)0.6726(2)0.0400(12)
H42A0.16120.38010.69110.048*
H42B0.23550.41570.69270.048*
C430.1524(2)0.4842(2)0.6881(2)0.0331(11)
H43A0.15560.48490.73520.040*
C440.1993(3)0.5417(2)0.6737(2)0.0387(11)
C45−0.1171(2)0.6728(3)0.7378(2)0.0375(11)
C46−0.1585(3)0.6990(2)0.7864(2)0.0384(11)
H46A−0.19460.73150.76370.046*
C47−0.1992(3)0.6415(3)0.8132(2)0.0453(13)
H47A−0.22830.66370.84000.054*
C48−0.1465(3)0.5953(3)0.8594(2)0.0555(15)
H48A−0.17370.56210.87790.067*
H48B−0.11700.57120.83500.067*
C49−0.0978(3)0.6342(3)0.9141(2)0.0524(14)
H49A−0.06320.60360.94050.063*
H49B−0.12670.65400.94180.063*
C50−0.0576(3)0.6898(3)0.8876(2)0.0497(14)
H50A−0.02890.71550.92360.060*
H50B−0.02500.66980.86370.060*
C51−0.1087(3)0.7360(2)0.8438(2)0.0422(12)
H51A−0.08110.77000.82680.051*
H51B−0.13820.75910.86900.051*
C520.2526(3)0.3958(3)0.2398(3)0.0568(15)
C530.3630(4)0.6563(4)0.5850(3)0.0650(17)
C54′b0.4072(5)0.7088(5)0.5420(4)0.039(2)
H54Ab0.42200.74860.56950.047*
C54a0.3726(6)0.6631(7)0.5247(5)0.046(3)
H54Ba0.33440.63450.49890.055*
C550.3607(4)0.7307(3)0.4885(4)0.084(2)
H55A0.38140.76570.51940.101*
H55B0.30890.73870.47630.101*
C56′b0.3403(5)0.6718(6)0.4283(5)0.064(3)
H56Ab0.31400.63450.44180.076*
H56Bb0.31050.69160.38910.076*
C56a0.3859(7)0.7401(8)0.4356(6)0.078(5)
H56Ca0.34950.72470.39820.093*
H56Da0.39210.78830.43030.093*
C57′b0.4106(6)0.6471(5)0.4154(4)0.050(3)
H57Ab0.40020.60890.38580.060*
H57Eb0.43040.68270.39310.060*
C57a0.4572(7)0.7052(6)0.4342(6)0.064(4)
H57Ba0.49720.73250.45780.077*
H57Ca0.46160.70140.38940.077*
C580.4620(3)0.6281(3)0.4678(3)0.0727(19)
H58A0.43240.59750.43680.087*
H58B0.51170.61240.47530.087*
C59′0.4759(4)0.6795(4)0.5276(4)0.032(2)
H59A0.50160.71790.51430.038*
C590.4416(5)0.6246(6)0.5221(5)0.041(3)
H59B0.43400.57690.53100.050*
C1040.5209(4)0.6547(4)0.5838(3)0.077(2)
N1−0.1366(2)0.69008(17)0.57610(16)0.0320(9)
N2−0.2505(2)0.70636(18)0.52570(17)0.0353(9)
N30.3050(2)0.47298(18)0.39505(17)0.0378(9)
N40.2145(2)0.50990(17)0.43359(17)0.0320(9)
N50.4254(2)0.4899(2)0.30058(19)0.0446(10)
N60.5203(2)0.5480(2)0.29043(19)0.0470(10)
N70.02274(19)0.73479(18)0.61726(16)0.0317(9)
N80.1056(2)0.76719(18)0.56619(16)0.0341(9)
N90.2430(2)0.7063(2)0.72367(17)0.0439(10)
N100.1607(2)0.7548(2)0.76532(17)0.0450(10)
N110.3952(2)0.6381(2)0.75412(19)0.0484(11)
N120.5108(2)0.6537(2)0.7961(2)0.0564(12)
O1−0.07099(17)0.71374(15)0.72234(13)0.0385(8)
O2−0.12977(17)0.61678(16)0.71211(15)0.0447(8)
O3−0.00975(18)0.58108(15)0.62506(15)0.0416(8)
O40.05900(19)0.58174(19)0.72451(17)0.0647(11)
O50.26248(18)0.54719(17)0.71045(17)0.0524(9)
O60.17671(18)0.58255(15)0.62889(15)0.0440(8)
O70.32399(19)0.6921(2)0.61224(16)0.0609(11)
O80.3900(4)0.6010(4)0.5941(4)0.0326(19)
O8′0.3555(6)0.5933(5)0.6110(4)0.075(3)
O90.43496(18)0.39237(18)0.41265(17)0.0532(9)
O10′0.5069(6)0.6899(6)0.6146(6)0.070(3)
O100.5411(5)0.7042(5)0.6369(5)0.061(3)
O110.29557(19)0.3616(2)0.28403(18)0.0594(10)
O120.2570(2)0.4592(2)0.23806(17)0.0693(12)
Zn1−0.04634(3)0.66849(3)0.64543(2)0.03150(14)
Zn20.30049(3)0.63607(3)0.68745(3)0.04090(16)
Zn30.36221(3)0.42863(3)0.33805(3)0.04353(17)

  1. aOccupancy: 0.472(6), bOccupancy: 0.528(6).

Source of material

The ligand, 1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene (timb), was synthesized according to the method reported previously [3]. All other reagents used were of commercially available quality and were used as received without further purification. 0.1 mmol timb, 0.15 mmol 1,2-cyclohexanedicarboxylic acid, 0.15 mmol ZnSO4⋅7H2O, 0.3 mmol tetrabutylammonium hydroxide and 15.0 mL water were mixed and placed in a thick Pyrex tube, which was sealed and heated to 413 K for 48 h. The tube was cooled to ambient temperature spontaneously and colourless block-shaped crystals of the title compound were obtained.

Elemental analysis

Calcd. for C60H106N12O32Zn3: C, 42.26%; H, 6.22%; N, 9.86%; Found: C, 42.19%; H,6.25%; N, 9.90%.

Experimental details

H atoms bound to C atoms were positioned geometrically and allowed to ride on their parent atoms, with C—H = 0.93 (phenyl & imidazolyl), 0.97 (methylene) or 0.96 methyl Å and Uiso(H) = 1.2Ueq(C). One imidazolyl ring of the timb ligand (atoms C13 and C14) and one cyclohexanedicarboxylate group (atoms O8, C54, C56, C57, C59 and O10) are disordered over two positions and were refined as having two orientations with site occupancies of 0.528(5) and 0.471(5). The guest water molecules were disordered and could not be modelled acceptably. The SQUEEZE routine [1] in PLATON [2] was used to remove the unassigned electron density. The residual electron density was assigned to twenty molecules present in the crystal [207e per asymmetric unit; one water molecule give 10e]. This suggestion was verified by a TGA (ThermoGravimetric Analysis) experiment.

Comment

It is well known that the self-assembly of metal-organic frameworks (MOFs) can be influenced by organic ligands, metal centers, temperature, solvent, counter ions, pH value, molar ratio of ligand-to-metal and so on [4]. Thus, it is still challenging to predict and control the structures and compositions of MOFs. Employing multidentate organic ligands and suitable metal ions via metal–ligand coordination, hydrogen-bonding and π − π interactions, which is a major approach for the construction of novel MOFs with fascinating structures and interesting properties. Recently imidazole-containing tripodal ligands, such as 1,3-bis(1-imidazolyl)-5-(imidazol-1-yl-methyl)benezene [5], 1-(1-imidazolyl)3,5-bis(imidazol-1-ylmethyl)benzene [6], 2,4,6-tris[4-(imidazol-1-ylmethyl)phenyl]-1,3,5-trazine [7], 1,3,5-tris(imidazol-1-yl)-2,4,6-trimethyl-benzene [8], 1,3,5-tris(1-imidazolyl)benzene [9] and 1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene [4], etc, have been applied in constructing MOFs due to the presence of three possible coordinating arms. On the other hand, polycarboxylic acids have also been widely employed as an ligand in coordination reactions and in the assembly of metal-organic frameworks because of its variable coordination modes after being deprotonated.

We focus our attention on the construction of novel MOFs with imidazole-containing and carboxylate-containing mixed ligands. In the present work, we successfully obtained a new ZnII three-dimensional coordination polymer with 1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene (timb) and 1,2-cyclohexanedicarboxylate via a solvothermal reaction.

Single-crystal X-ray diffraction structural analysis shows that the title complex crystallizes in the monoclinic space group P21/c and the asymmetric unit consists of three crystallographically independent ZnII centres (Zn1, Zn2 and Zn3), two timb ligands and three 1,2-cyclohexanedicarboxylate dianions and twenty uncoordinated water molecules. Zn1 is coordinated by N3 and N7 from two individual tripodal timb ligands and by O1 and O3 from two different bridging 1,2-cyclohexanedicarboxylate anions, forming a distorted tetrahedral ZnN2O2 coordination geometry. The coordination environment of each Zn2 and Zn3 centre is very similar to that of Zn1. The Zn–N bond lengths range from 1.992(4) to 2.038(4) Å and the Zn–O bond length range from 1.948(3) to 2.065(3) Å, respectively. The timb ligand adopts cis, trans and trans substituent conformations and coordinates to three ZnII centres (Zn1, Zn2 and Zn3), generating a Zn–timb–Zn chain (chain A) along the [1 0 0] direction. The 1,2-cyclohexanedicarboxylate anion acts as a bridging link between two ZnII cations, giving rise to the formation of linear Zn–1,2-cyclohexanedicarboxylate–Zn chains (chain B) running parallel to the a axis. The adjacent A and B chains interlacing connect to each other via ZnII centres, leading to a three-dimensional structure. There are disordered solvent water molecules in the crystal.

Acknowledgements

This work was financially supported by the Qinglan Project of colleges and universities in Jiangsu Province; Jiangsu College Students Training Program for Innovation and Entrepreneurship (grant No. 201912920016Y).

References

1. Spek, A. L.: PLATON SQUEEZE: a tool for the calculation of the disordered solvent contribution to the calculated structure factors. Acta Crystallogr. C71 (2015) 9–18.10.1107/S2053229614024929Suche in Google Scholar

2. Spek, A. L.: Structure validation in chemical crystallography. Acta Crystallogr. D65 (2009) 148–155.10.1107/S090744490804362XSuche in Google Scholar PubMed PubMed Central

3. Liu, H.-K.; Sun, W.-Y.; Ma, D.-J.; Yu, K.-B.; Tang, W.-X.: The first X-ray structurally characterized M3L2 cage-like complex with tetrahedral metal centres and its encapsulation of a neutral guest molecule. Chem. Commun. 7 (2000) 591–592.10.1039/b000259nSuche in Google Scholar

4. Luo, L.; Chen, K.; Liu, Q.; Lu, Y.; Okamura, T.; Lv, G. C.; Zhao, Y.; Sun, W.-Y.: Zinc(II) and cadmium(II) complexes with 1,3,5-benzenetricarboxylate and imidazole-containing ligands: structural variation via reaction temperature and solvent. Cryst. Growth Des. 13 (2013) 2312–2321.10.1021/cg301815wSuche in Google Scholar

5. Deng, Y.; Zhao, Y.; Wang, P.; Yao, Z.-Y.; Zhang, X.-D.; Sun, W.-Y.: Coordination polymers with 1,3-bis(1-imidazolyl)-5-(imidazol-1-ylmethyl)benzene and biphenyl-4,4′-dicarboxylate ligands: selective adsorption of gas and dye molecules. Microporous Mesoporous Mater. 241 (2017) 192–201.10.1016/j.micromeso.2016.11.027Suche in Google Scholar

6. Zhao, W.; Fan, J.; Okamura, T.; Sun, W. Y.; Ueyama, N.: Syntheses, crystal structures and anion-exchange properties of novel coordination polymers with imidazole-containing tripodal ligands. Microporous Mesoporous Mater. 78 (2005) 265–279.10.1016/j.micromeso.2004.10.030Suche in Google Scholar

7. Wan, S. Y.; Fan, J.; Okamura, T.; Zhu, H. F.; Ouyang, X. M.; Sun, W. Y.; Ueyama, N.: 2D 4.82 Network with threefold parallel interpenetration from nanometer-sized tripodal ligand and lead(ii) nitrate. Chem. Commun. 21 (2002) 2520–2521.10.1039/b207568gSuche in Google Scholar

8. Yan, W.-Y.; He, R.-T.; Dai, M.; Ren, Z.-G.; Li, H.-X.; Lang, J.-P.: Assembly of 1D and 2D zinc(II) coordination polymers from flexible polyimidazolyl-based ligands. Inorg. Chem. Commun. 36 (2013) 51–55.10.1016/j.inoche.2013.08.002Suche in Google Scholar

9. Su, Z.; Fan, J.; Okamura, T.; Chen, M.-S.; Chen, S.-S.; Sun, W.-Y.; Ueyama, N.: Interpenetrating and self-penetrating zinc(II) complexes with rigid tripodal imidazole-containing ligand and benzenedicarboxylate. Cryst. Growth Des. 10 (2010) 1911–1922.10.1021/cg100020tSuche in Google Scholar

Received: 2019-12-06
Accepted: 2020-02-10
Published Online: 2020-02-27
Published in Print: 2020-04-28

©2020 Bing-Feng Li et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 Public License.

Artikel in diesem Heft

  1. Frontmatter
  2. Crystal structure of catena-poly[(μ2-3-(benzo[d]thiazol-2-yl)-5-carboxybenzoato-κ2N:O)silver(I)], C15H8AgNO4S
  3. Crystal structure of bis(4-phenylpiperazin-1-ium) bis(2-(4-phenylpiperazin-1-yl)succinato-κ2O,O′)copper(II) tetrahydrate, C48H70CuN8O12, [C10H14N2]2[Cu(C14H17N2O4)2] ⋅ 4 H2O
  4. Crystal structure of triaqua-bis(2-(6-hydroxy-5-(hydroxymethyl)-5,8a-dimethyl-2-methylenedecahydronaphthalen-1-yl)-1-(2-oxo-2,5-dihydrofuran-3-yl)ethane-1-sulfonato-κ2O,O′)calcium(II) – ethanol (1/2), C44H76CaO19S2
  5. The crystal structure of ethyl 5-(4-(diphenylamino)phenyl)thiophene-2-carboxylate, C25H21NO2S
  6. The crystal structure of 5-bromo-2-(2-methyl-2H-tetrazol-5-yl)pyridine, C7H6BrN5
  7. The crystal structure of (E)-5-chloro-2-hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)benzohydrazide, C15H13ClN2O4
  8. The crystal structure of (2Z,2′Z)-N′,N′′′′-(pyridine-2,6-dicarbonyl)dipicolinohydrazonamide, C19H17N9O2
  9. Photochromic properties and crystal structure of 3,3′-(perfluorocyclopent-1-ene-1,2-diyl)bis(5-(4-(azidomethyl)phenyl)-2-methylthiophene), C29H20F6N6S2
  10. Crystal structure of aqua-dichlorido-(4-(((3-ethoxy-2-oxidobenzylidene)hydrazono)(oxido)methyl)pyridin-1-ium-κ3N,O,O′)iron(III), C15H16Cl2N3O4Fe
  11. Crystal structure of catena-poly[diaqua-(μ2-4,4′-bipyridine-κ2N:N′)-bis(2,3,4,5-tetrabromo-6-carboxybenzoato-κ1O)-nickel(II)], C26H14Br8NiN2O10
  12. Crystal structure of diethanol-κ1O-bis(μ2-N-((2-oxidonaphthalen-1-yl)methylene)pyrazine-2-carbohydrazonato-κ5N,O,O′:O′:N′)-bis(nitrato-κ2O,O′)dieuropium(III), C36H32N10O12Eu2
  13. The crystal structure of 2-aminoisophthalic acid, C8H7NO4
  14. Crystal structure of (E)-2-(4-((3,4-difluorobenzyl)oxy)styryl)-4,6-dimethoxybenzaldehyde, C24H20F2O4
  15. Crystal structure of 2-benzoylpyrene, C23H14O
  16. Crystal structure of chlorido-(η6-p-cymene)-(N-(2-fluorophenyl)-1-(pyridin-2-yl)methanimine-κ2N,N′)ruthenium(II) – acetone (1/1), C22H23ClN2F7OPRu
  17. The crystal structure of 2-bromoisonicotinic acid, C6H4BrNO2
  18. Crystal structure of 1,3,5,7-tetraphenyl-8-(N-phenylformamido)-2-oxa-5-azabicyclo[4.2.0]oct -3-en-7-yl benzoate, C44H34N2O4
  19. Synthesis and crystal structure of 4-(3-acetyl-5-(thiophen-2-yl)-2,3-dihydro-1,3,4-oxadiazol-2-yl)-7-(diethylamino)-2H-chromen-2-one, C21H21N3O4S
  20. Crystal structure of poly[diaqua-(μ2-4,4′-bipyridine-κ2N:N′)-(μ2-3,4,5,6-tetrafluorophthalato-κ2O:O′)nickel(II)], C18H12F4NiN2O6
  21. Crystal structure of 4-hydroxynaphtho[2,3-b]benzofuran-6,11-dione, C16H8O4
  22. The crystal structure of 3,10-bis(4-methoxyphenyl)-6,12-dibenzyl-2,9-acetyl-6,12-diazapentacyclo[6.3.1.02,7.04,11.05,9]dodecane – acetone (1/1), C45H48N2O5
  23. The crystal structure of (E)-2-(((2-(1H-indol-3-yl)ethyl)iminio)methyl)-6-bromophenolate, C17H15N2BrO
  24. Crystal structure of catena-poly[diaqua-(μ2-oxalyl dihydrazide-κ4N,O:N′,O′)-bis(μ2-pyridine-2,3-dicarboxylato-κ3N,O,O′)dicadmium(II)] hexahydrate, C16H28O18N6Cd2
  25. Crystal structure of poly[tetra-(μ4-naphthalene-1,8-dicarboxylato-κ4O:O,O′: O′′:O′′,O′′′)-(μ4-oxo-κ4O:O:O:O) penta-lead(II)], C48H24O17Pb5
  26. Crystal structure of 5H-dibenzo[c,f][1,5]oxabismocin-12 (7H)-yl acetate, C16H15O3Bi
  27. The crystal structure of 2-(4-chloro-6-nitrophenyl)-1-(4-chloro-3-nitrophenyl)diazene 1-oxide, C12H6Cl2N4O5
  28. Crystal structure of bis(3-methyl-N-(1-(pyrazin-2-yl)ethylidene)benzohydrazonato-κ3O,N,N′)nickel(II), C28H26N8O2Ni
  29. Crystal structure of 3,10-bis(4-chlorophenyl)-6,12-dibenzyl-2,9-acetyl-6,12-diazapentacyclo[6.3.1.02,7.04,11.05,9]-dodecane, C40H36Cl2N2O2
  30. Crystal structure of bis[(μ2-4⋯O,O′:O′)-(4-hydroxybenzoato-κ2O,O′)-(1,10-phenanthroline-κ2N,N′)]-di-lead(II)μ-4-hydroxybenzoato-κ3O,O′:O′;κ3O,O′:O′-bis-[(4-hydroxybenzoato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)di-lead(II)] monohydrate, C52H36N4O12Pb2 ⋅ H2O
  31. Crystal structure of poly[diaqua-(μ3-3,4,5,6-tetrafluoro-phthalato-κ3O:O′:O′′)-(μ2-1,2-bis(4-pyridyl)ethene-κ2N:N′)cobalt(II)], C14H9CoF4NO6
  32. Crystal structure of 7-hydroxy-4-phenyl-2H-chromen-2-one, C15H10O3
  33. Crystal structure of 3,7-dimethyl-1-(5-oxohexyl)-3,7-dihydro-1H-purine-2,6-dione 4-hydroxybenzoic acid, C20H24N4O6
  34. Crystal structure of catena-poly[(μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4-ylmethylene)amino)-1,2-dihydro-3H-pyrazol-3-one-κ2N:O)-bis(nitrato-κ1O)zinc(II)], C17H16N6O7Zn
  35. The crystal structure of diaqua-bis(6-aminopicolinato-κ2N,O)magnesium(II), C12H14O6N4Mg
  36. Crystal structure of (pyridine-2-carboxamide-κ2N,O)-[tris((1H-benzo[d]imidazol-2-yl)methyl)amine-κ4N,N′,N′′,N′′′]nickel(II) diperchlorate — methanol (1/3), C33H39Cl2N9NiO12
  37. Crystal structure of catena-poly[diaqua-bis(3-(4-trifluoromethyl-phenyl)-acrylato-κO1)-(μ2-1,4-bis(1-imidazolyl)benzene-κ2N3:N3′)cobalt(II)], C32H26CoF6N4O6
  38. Crystal structure of (E)-3-(2-(2-hydroxy-4-methoxystyryl)-3,3-dimethyl-3H-indol-1-ium-1-yl)propane-1-sulfonate monohydrate, C22H25NO5S⋅H2O
  39. The crystal structure of bis(N-oxy-2-(1H-tetrazol-1-yl) acetamide κ2O,O′)-diaqua-zinc(II), C6H12ZnN10O6
  40. Crystal structure of (E)-4-((4-chlorophenylimino)methyl)pyridinium 3,5-dinitrobenzoate, C19H13ClN4O6
  41. Crystal structure of dichlorido-bis((E)-2-((pyridin-4-ylmethylene)amino)phenol)zinc(II), C24H20Cl2N4O2Zn
  42. Crystal structure of cyclo-[tetrachlorido-bis(μ2-p-xylylenediamine-κ2N:N′)dipalladium(II)] dimethyl sulfoxide solvate, C20H36Cl4N4O2Pd2S2
  43. Crystal structure of 4-(3-fluorophenyl)-7-hydroxy-2H-chromen-2-one, C15H9FO3
  44. Crystal structure of (E)-2-((2-(pyrimidin-2-yl)hydrazono)methyl)quinolin-1-ium perchlorate – methanol (1/1), C15H16N5O5Cl
  45. The crystal structure of bis(N-(amino(pyridin-2-yl)methylene)-5-chloro-2-hydroxybenzohydrazonato-κ3N,N′,O)zinc(II) – methanol (2/5), C57H60Cl2N16O13Zn2
  46. Synthesis and crystal structure of 4,4′-di(4-pyridyl)-6,6′-di(tert-butyl)-2,2′-[propylenedioxybis(nitrilomethylidyne)]diphenol, C35H40N4O4
  47. Crystal structure of (3E,3′E)-3,3′-((1,3,4-thiadiazole-2,5-diyl)bis(sulfanediyl))bis(4-hydroxy-4-phenylbut-3-en-2-one), C22H18N2O4S3
  48. Crystal structure of (N-benzyl-N-methyl-dithiocarbamato-κ2S,S′)di(4-chlorobenzyl)chloridotin(IV), C23H22Cl3NS2Sn
  49. Crystal structure of (1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O6) sodium bromide hydrate, [Na(18-crown-6)]Br ⋅ H2O, C12H26BrNaO7
  50. Crystal structure of 7-ethoxyl-6,8-difluoro-4-oxo-1-phenyl-1,4-dihydro-quinoline-3-carboxylic acid, C18H13F2N1O4
  51. Crystal structure of chlorido (2-(4-ethylphenyl)pyrimidine-k2C,N)(triphenylphosphane-kP) palladium(II), C30H26ClN2PPd
  52. Crystal structure of 18-crown-6 – 1,4-diiodotetrafluorobenzene – acetonitrile (1/1/2), C22H30F4I2N2O6
  53. Crystal structure of diisobutyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate, C16H24O6
  54. Crystal structure of poly[[tris(μ2-cis-1,2-cyclohexanedicarboxylato)-κ2O, O′]-bis[μ3-1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene-κ3N, N′,N′′]-trizinc(II)] – water (1/20), C60H106N12O32Zn3
  55. The synthesis and crystal structure of 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-((trifluoromethyl)sulfinyl)-1H-pyrazole-3-carboxamide–tetrahydrofuran (1/1), C16H14N4Cl2F6O3S
  56. Crystal structure of dimethylbis(diisopropyldithiocarbamato-κ2S,S′)tin(IV), C16H34N2S4Sn
  57. Crystal structure of diisopropyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate, C14H20O6
  58. The synthesis and crystal structure of ethyl (E)-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-5-((2-methoxybenzylidene)amino)-4-((trifluoromethyl)sulfinyl)-1H-pyrazole-3-carboxylate, C22H15N3Cl2F6O4S
  59. The crystal structure of a matrine derivative, 13-(methylamine-1-yl) carbodithioate matrine, C17H27N3OS2
  60. Crystal structure of bis(2-hydroxy-6-((phenylimino)methyl)phenolato-κ2N,O)copper(II), C26H20CuN2O4
  61. The crystal structure of 2-p-fluorophenyl-5-dihydroxymethyl-1,3,4-oxadiazole, C9H7FN2O3
  62. Crystal structure of dichloridobis(4-chlorophenyl-κC1)(1,10-phenanthroline-κ2N,N′)tin(IV), C24H16Cl4N2Sn
  63. Crystal structure of bis{bromido-triphenyltin(IV)}(μ2-[4,4′-bipyridine]1,1′-dioxide-κ2O:O′), C46H38Br2N2O2Sn2
  64. Crystal structure of 2-(5-chloro-quinolin-8-yloxy)-N-quinolin-8-yl-acetamide, C20H14N3O2Cl
  65. Crystal structure of bis(N-(1-(3-ethylpyrazin-2-yl)ethylidene)-3-hydroxy-2-naphthohydrazonato-κ3N,N′,O)cobalt(II) — dimethylformamide (1/1), C41H41N9O5Co
  66. Crystal structure of bis[2-(1-(3-ethylpyrazin-2-yl)ethylidene)-1-tosylhydrazin-1-ido-κ3-N,N′,O]copper(II), C30H34N8O4S2Cu
  67. Crystal structure of (2-p-tolylpyrimidine-κ2C,N)(triphenylphosphane-κP) palladium(II), C29H24ClN2PPd
  68. Halogen bonding in crystal structure of bis(1,4,7,10-tetraoxacyclododecane-κ4O,O′,O′′,O′′′)cesium triiodide, C16H32CsI3O8
  69. The synthesis and crystal structure of N-(3-cyano-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylsulfinyl)-1H-pyrazol-5-yl)-2-phenylacetamide, C20H10N4Cl2F6O2S
  70. The crystal structure of 4-(trifluoromethyl)nicotinic acid, C7H4F3NO2
  71. Crystal structure of 3-(2-methylbenzyl)thiazolidin-2-one, C11H13ONS
  72. The crystal structure of 2,2,2-trifluoro-1-(isoquinolin-1-yl)ethane-1,1-diol, C11H8F3NO2
  73. The crystal structure of 3-bromoisonicotinic acid, C6H4BrNO2
  74. The crystal structure of 5-nitropicolinic acid monohydrate, C6H6N2O5
  75. The crystal structure of 3-(4-hydroxybenzyl)-1,5-dioxaspiro[5.5]undecane-2,4-dione, C16H18O5
  76. Crystal structure of [[Mo3Se7(S2CNEt2)3]2(μ-Se)] ⋅ 2(C6H4Cl2), C42H68Cl4Mo6N6S12Se15
  77. Crystal structure of (E)-4-hydroxy-3-((5-phenyl-1,3,4-oxadiazol-2-yl)thio)pent-3-en-2-one, C13H12N2O3S
  78. The crystal structure of (2,3-dioxo-5,6:13,14-dibenzo-9,10-benzo-1,4,8,11-7, 11-diene-κ4N,N′,N′′,N′′′)-nickel(II), Ni(C22H14N4O2)
  79. Crystal structure of 3-(1-benzyl-2-ethyl-4-nitro-1H-imidazol-5-ylthio)-propanoic acid, C15H17N3O4S
  80. The crystal structure of dichlorobis(2-(dicyclohexylphosphino)-2′,4′,6′-tri-i-propyl-1,1′-biphenyl) palladium(II)-dichloroform, C68H100Cl8P2Pd
  81. Crystal structure and antimicrobial properties of (1,4,7,10-tetraoxacyclododecane-κ4O,O′,O′′,O′′′)cesium(I) pentaiodide, C16H32CsI5O8
https://doi.org/10.1515/ncrs-2019-0892
Creative Commons
BY 4.0

Artikel in diesem Heft

  1. Frontmatter
  2. Crystal structure of catena-poly[(μ2-3-(benzo[d]thiazol-2-yl)-5-carboxybenzoato-κ2N:O)silver(I)], C15H8AgNO4S
  3. Crystal structure of bis(4-phenylpiperazin-1-ium) bis(2-(4-phenylpiperazin-1-yl)succinato-κ2O,O′)copper(II) tetrahydrate, C48H70CuN8O12, [C10H14N2]2[Cu(C14H17N2O4)2] ⋅ 4 H2O
  4. Crystal structure of triaqua-bis(2-(6-hydroxy-5-(hydroxymethyl)-5,8a-dimethyl-2-methylenedecahydronaphthalen-1-yl)-1-(2-oxo-2,5-dihydrofuran-3-yl)ethane-1-sulfonato-κ2O,O′)calcium(II) – ethanol (1/2), C44H76CaO19S2
  5. The crystal structure of ethyl 5-(4-(diphenylamino)phenyl)thiophene-2-carboxylate, C25H21NO2S
  6. The crystal structure of 5-bromo-2-(2-methyl-2H-tetrazol-5-yl)pyridine, C7H6BrN5
  7. The crystal structure of (E)-5-chloro-2-hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)benzohydrazide, C15H13ClN2O4
  8. The crystal structure of (2Z,2′Z)-N′,N′′′′-(pyridine-2,6-dicarbonyl)dipicolinohydrazonamide, C19H17N9O2
  9. Photochromic properties and crystal structure of 3,3′-(perfluorocyclopent-1-ene-1,2-diyl)bis(5-(4-(azidomethyl)phenyl)-2-methylthiophene), C29H20F6N6S2
  10. Crystal structure of aqua-dichlorido-(4-(((3-ethoxy-2-oxidobenzylidene)hydrazono)(oxido)methyl)pyridin-1-ium-κ3N,O,O′)iron(III), C15H16Cl2N3O4Fe
  11. Crystal structure of catena-poly[diaqua-(μ2-4,4′-bipyridine-κ2N:N′)-bis(2,3,4,5-tetrabromo-6-carboxybenzoato-κ1O)-nickel(II)], C26H14Br8NiN2O10
  12. Crystal structure of diethanol-κ1O-bis(μ2-N-((2-oxidonaphthalen-1-yl)methylene)pyrazine-2-carbohydrazonato-κ5N,O,O′:O′:N′)-bis(nitrato-κ2O,O′)dieuropium(III), C36H32N10O12Eu2
  13. The crystal structure of 2-aminoisophthalic acid, C8H7NO4
  14. Crystal structure of (E)-2-(4-((3,4-difluorobenzyl)oxy)styryl)-4,6-dimethoxybenzaldehyde, C24H20F2O4
  15. Crystal structure of 2-benzoylpyrene, C23H14O
  16. Crystal structure of chlorido-(η6-p-cymene)-(N-(2-fluorophenyl)-1-(pyridin-2-yl)methanimine-κ2N,N′)ruthenium(II) – acetone (1/1), C22H23ClN2F7OPRu
  17. The crystal structure of 2-bromoisonicotinic acid, C6H4BrNO2
  18. Crystal structure of 1,3,5,7-tetraphenyl-8-(N-phenylformamido)-2-oxa-5-azabicyclo[4.2.0]oct -3-en-7-yl benzoate, C44H34N2O4
  19. Synthesis and crystal structure of 4-(3-acetyl-5-(thiophen-2-yl)-2,3-dihydro-1,3,4-oxadiazol-2-yl)-7-(diethylamino)-2H-chromen-2-one, C21H21N3O4S
  20. Crystal structure of poly[diaqua-(μ2-4,4′-bipyridine-κ2N:N′)-(μ2-3,4,5,6-tetrafluorophthalato-κ2O:O′)nickel(II)], C18H12F4NiN2O6
  21. Crystal structure of 4-hydroxynaphtho[2,3-b]benzofuran-6,11-dione, C16H8O4
  22. The crystal structure of 3,10-bis(4-methoxyphenyl)-6,12-dibenzyl-2,9-acetyl-6,12-diazapentacyclo[6.3.1.02,7.04,11.05,9]dodecane – acetone (1/1), C45H48N2O5
  23. The crystal structure of (E)-2-(((2-(1H-indol-3-yl)ethyl)iminio)methyl)-6-bromophenolate, C17H15N2BrO
  24. Crystal structure of catena-poly[diaqua-(μ2-oxalyl dihydrazide-κ4N,O:N′,O′)-bis(μ2-pyridine-2,3-dicarboxylato-κ3N,O,O′)dicadmium(II)] hexahydrate, C16H28O18N6Cd2
  25. Crystal structure of poly[tetra-(μ4-naphthalene-1,8-dicarboxylato-κ4O:O,O′: O′′:O′′,O′′′)-(μ4-oxo-κ4O:O:O:O) penta-lead(II)], C48H24O17Pb5
  26. Crystal structure of 5H-dibenzo[c,f][1,5]oxabismocin-12 (7H)-yl acetate, C16H15O3Bi
  27. The crystal structure of 2-(4-chloro-6-nitrophenyl)-1-(4-chloro-3-nitrophenyl)diazene 1-oxide, C12H6Cl2N4O5
  28. Crystal structure of bis(3-methyl-N-(1-(pyrazin-2-yl)ethylidene)benzohydrazonato-κ3O,N,N′)nickel(II), C28H26N8O2Ni
  29. Crystal structure of 3,10-bis(4-chlorophenyl)-6,12-dibenzyl-2,9-acetyl-6,12-diazapentacyclo[6.3.1.02,7.04,11.05,9]-dodecane, C40H36Cl2N2O2
  30. Crystal structure of bis[(μ2-4⋯O,O′:O′)-(4-hydroxybenzoato-κ2O,O′)-(1,10-phenanthroline-κ2N,N′)]-di-lead(II)μ-4-hydroxybenzoato-κ3O,O′:O′;κ3O,O′:O′-bis-[(4-hydroxybenzoato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)di-lead(II)] monohydrate, C52H36N4O12Pb2 ⋅ H2O
  31. Crystal structure of poly[diaqua-(μ3-3,4,5,6-tetrafluoro-phthalato-κ3O:O′:O′′)-(μ2-1,2-bis(4-pyridyl)ethene-κ2N:N′)cobalt(II)], C14H9CoF4NO6
  32. Crystal structure of 7-hydroxy-4-phenyl-2H-chromen-2-one, C15H10O3
  33. Crystal structure of 3,7-dimethyl-1-(5-oxohexyl)-3,7-dihydro-1H-purine-2,6-dione 4-hydroxybenzoic acid, C20H24N4O6
  34. Crystal structure of catena-poly[(μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4-ylmethylene)amino)-1,2-dihydro-3H-pyrazol-3-one-κ2N:O)-bis(nitrato-κ1O)zinc(II)], C17H16N6O7Zn
  35. The crystal structure of diaqua-bis(6-aminopicolinato-κ2N,O)magnesium(II), C12H14O6N4Mg
  36. Crystal structure of (pyridine-2-carboxamide-κ2N,O)-[tris((1H-benzo[d]imidazol-2-yl)methyl)amine-κ4N,N′,N′′,N′′′]nickel(II) diperchlorate — methanol (1/3), C33H39Cl2N9NiO12
  37. Crystal structure of catena-poly[diaqua-bis(3-(4-trifluoromethyl-phenyl)-acrylato-κO1)-(μ2-1,4-bis(1-imidazolyl)benzene-κ2N3:N3′)cobalt(II)], C32H26CoF6N4O6
  38. Crystal structure of (E)-3-(2-(2-hydroxy-4-methoxystyryl)-3,3-dimethyl-3H-indol-1-ium-1-yl)propane-1-sulfonate monohydrate, C22H25NO5S⋅H2O
  39. The crystal structure of bis(N-oxy-2-(1H-tetrazol-1-yl) acetamide κ2O,O′)-diaqua-zinc(II), C6H12ZnN10O6
  40. Crystal structure of (E)-4-((4-chlorophenylimino)methyl)pyridinium 3,5-dinitrobenzoate, C19H13ClN4O6
  41. Crystal structure of dichlorido-bis((E)-2-((pyridin-4-ylmethylene)amino)phenol)zinc(II), C24H20Cl2N4O2Zn
  42. Crystal structure of cyclo-[tetrachlorido-bis(μ2-p-xylylenediamine-κ2N:N′)dipalladium(II)] dimethyl sulfoxide solvate, C20H36Cl4N4O2Pd2S2
  43. Crystal structure of 4-(3-fluorophenyl)-7-hydroxy-2H-chromen-2-one, C15H9FO3
  44. Crystal structure of (E)-2-((2-(pyrimidin-2-yl)hydrazono)methyl)quinolin-1-ium perchlorate – methanol (1/1), C15H16N5O5Cl
  45. The crystal structure of bis(N-(amino(pyridin-2-yl)methylene)-5-chloro-2-hydroxybenzohydrazonato-κ3N,N′,O)zinc(II) – methanol (2/5), C57H60Cl2N16O13Zn2
  46. Synthesis and crystal structure of 4,4′-di(4-pyridyl)-6,6′-di(tert-butyl)-2,2′-[propylenedioxybis(nitrilomethylidyne)]diphenol, C35H40N4O4
  47. Crystal structure of (3E,3′E)-3,3′-((1,3,4-thiadiazole-2,5-diyl)bis(sulfanediyl))bis(4-hydroxy-4-phenylbut-3-en-2-one), C22H18N2O4S3
  48. Crystal structure of (N-benzyl-N-methyl-dithiocarbamato-κ2S,S′)di(4-chlorobenzyl)chloridotin(IV), C23H22Cl3NS2Sn
  49. Crystal structure of (1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O6) sodium bromide hydrate, [Na(18-crown-6)]Br ⋅ H2O, C12H26BrNaO7
  50. Crystal structure of 7-ethoxyl-6,8-difluoro-4-oxo-1-phenyl-1,4-dihydro-quinoline-3-carboxylic acid, C18H13F2N1O4
  51. Crystal structure of chlorido (2-(4-ethylphenyl)pyrimidine-k2C,N)(triphenylphosphane-kP) palladium(II), C30H26ClN2PPd
  52. Crystal structure of 18-crown-6 – 1,4-diiodotetrafluorobenzene – acetonitrile (1/1/2), C22H30F4I2N2O6
  53. Crystal structure of diisobutyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate, C16H24O6
  54. Crystal structure of poly[[tris(μ2-cis-1,2-cyclohexanedicarboxylato)-κ2O, O′]-bis[μ3-1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene-κ3N, N′,N′′]-trizinc(II)] – water (1/20), C60H106N12O32Zn3
  55. The synthesis and crystal structure of 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-((trifluoromethyl)sulfinyl)-1H-pyrazole-3-carboxamide–tetrahydrofuran (1/1), C16H14N4Cl2F6O3S
  56. Crystal structure of dimethylbis(diisopropyldithiocarbamato-κ2S,S′)tin(IV), C16H34N2S4Sn
  57. Crystal structure of diisopropyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate, C14H20O6
  58. The synthesis and crystal structure of ethyl (E)-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-5-((2-methoxybenzylidene)amino)-4-((trifluoromethyl)sulfinyl)-1H-pyrazole-3-carboxylate, C22H15N3Cl2F6O4S
  59. The crystal structure of a matrine derivative, 13-(methylamine-1-yl) carbodithioate matrine, C17H27N3OS2
  60. Crystal structure of bis(2-hydroxy-6-((phenylimino)methyl)phenolato-κ2N,O)copper(II), C26H20CuN2O4
  61. The crystal structure of 2-p-fluorophenyl-5-dihydroxymethyl-1,3,4-oxadiazole, C9H7FN2O3
  62. Crystal structure of dichloridobis(4-chlorophenyl-κC1)(1,10-phenanthroline-κ2N,N′)tin(IV), C24H16Cl4N2Sn
  63. Crystal structure of bis{bromido-triphenyltin(IV)}(μ2-[4,4′-bipyridine]1,1′-dioxide-κ2O:O′), C46H38Br2N2O2Sn2
  64. Crystal structure of 2-(5-chloro-quinolin-8-yloxy)-N-quinolin-8-yl-acetamide, C20H14N3O2Cl
  65. Crystal structure of bis(N-(1-(3-ethylpyrazin-2-yl)ethylidene)-3-hydroxy-2-naphthohydrazonato-κ3N,N′,O)cobalt(II) — dimethylformamide (1/1), C41H41N9O5Co
  66. Crystal structure of bis[2-(1-(3-ethylpyrazin-2-yl)ethylidene)-1-tosylhydrazin-1-ido-κ3-N,N′,O]copper(II), C30H34N8O4S2Cu
  67. Crystal structure of (2-p-tolylpyrimidine-κ2C,N)(triphenylphosphane-κP) palladium(II), C29H24ClN2PPd
  68. Halogen bonding in crystal structure of bis(1,4,7,10-tetraoxacyclododecane-κ4O,O′,O′′,O′′′)cesium triiodide, C16H32CsI3O8
  69. The synthesis and crystal structure of N-(3-cyano-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-4-(trifluoromethylsulfinyl)-1H-pyrazol-5-yl)-2-phenylacetamide, C20H10N4Cl2F6O2S
  70. The crystal structure of 4-(trifluoromethyl)nicotinic acid, C7H4F3NO2
  71. Crystal structure of 3-(2-methylbenzyl)thiazolidin-2-one, C11H13ONS
  72. The crystal structure of 2,2,2-trifluoro-1-(isoquinolin-1-yl)ethane-1,1-diol, C11H8F3NO2
  73. The crystal structure of 3-bromoisonicotinic acid, C6H4BrNO2
  74. The crystal structure of 5-nitropicolinic acid monohydrate, C6H6N2O5
  75. The crystal structure of 3-(4-hydroxybenzyl)-1,5-dioxaspiro[5.5]undecane-2,4-dione, C16H18O5
  76. Crystal structure of [[Mo3Se7(S2CNEt2)3]2(μ-Se)] ⋅ 2(C6H4Cl2), C42H68Cl4Mo6N6S12Se15
  77. Crystal structure of (E)-4-hydroxy-3-((5-phenyl-1,3,4-oxadiazol-2-yl)thio)pent-3-en-2-one, C13H12N2O3S
  78. The crystal structure of (2,3-dioxo-5,6:13,14-dibenzo-9,10-benzo-1,4,8,11-7, 11-diene-κ4N,N′,N′′,N′′′)-nickel(II), Ni(C22H14N4O2)
  79. Crystal structure of 3-(1-benzyl-2-ethyl-4-nitro-1H-imidazol-5-ylthio)-propanoic acid, C15H17N3O4S
  80. The crystal structure of dichlorobis(2-(dicyclohexylphosphino)-2′,4′,6′-tri-i-propyl-1,1′-biphenyl) palladium(II)-dichloroform, C68H100Cl8P2Pd
  81. Crystal structure and antimicrobial properties of (1,4,7,10-tetraoxacyclododecane-κ4O,O′,O′′,O′′′)cesium(I) pentaiodide, C16H32CsI5O8
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 30.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2019-0892/html
Button zum nach oben scrollen