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Organometallic complexes and reaction methods for synthesis: a review

  • Kwestan Namiq Aziz , Karzan Mahmood Ahmed ORCID logo , Rebaz Anwar Omer ORCID logo , Aryan Fathulla Qader ORCID logo EMAIL logo und Eman Ibraheem Abdulkareem ORCID logo
Veröffentlicht/Copyright: 13. August 2024
Reviews in Inorganic Chemistry
Aus der Zeitschrift Reviews in Inorganic Chemistry Band 44 Heft 4

Abstract

Organometallics are chemical compounds that consist of carbon-metal linkages. They have emerged as a result of the combination of organic and inorganic chemistry and exhibit a stable metal-carbon bond in solution. These compounds possess properties that lie between those of ionic and covalent bonds, making them highly significant in various industries. The fact that organometallics are present in all living organisms further emphasises their importance. In this overview, we will explore general reactions, such as substitution and insertion reactions, as well as different techniques for creating organometallic complexes. Additionally, we will provide a brief synthesis review of various types of organometallic complexes, including carbonyls, hydrides, alkyls, carbenes, and carbines. Organometallic compounds find extensive applications in stoichiometric chemical processes in both research and industry. Moreover, they serve as catalysts to enhance these reactions, making them more than just theoretical compounds. For example, organotin compounds are widely used as fire retardants, polymers, medications, insecticides, and stabilizers for polyvinyl chloride.

Keywords: organometallic; carbon-metal; substitution reactions; synthesis; industrial applications
Corresponding author: Aryan Fathulla Qader, Department of Chemistry, Faculty of Science and Health, Koya University, Danielle Mitterrand Boulevard, Koya KOY45, Kurdistan Region – F.R., Iraq, E-mail:

Acknowledgments

We want to express our gratitude to the heads of the chemistry departments at Koya University.

  1. Research ethics: Not applicable.

  2. Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: The authors state no conflict of interest.

  4. Research funding: None declared.

  5. Data availability: Not applicable.

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Received: 2024-06-07
Accepted: 2024-07-22
Published Online: 2024-08-13
Published in Print: 2024-11-26

© 2024 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/revic-2024-0037
Schlagwörter für diesen Artikel
organometallic; carbon-metal; substitution reactions; synthesis; industrial applications

Artikel in diesem Heft

  1. Frontmatter
  2. Unveiling the multifaceted roles of protonated 1,2-bis(4-pyridyl)ethylene (HBpe+) ligand in metal-driven supramolecular assembly: a comprehensive structural review
  3. Advanced synthetic routes of metal organic frameworks and their diverse applications
  4. Carbon materials derived by crystalline porous materials for capacitive energy storage
  5. BiVO4-based heterojunction nanophotocatalysts for water splitting and organic pollutant degradation: a comprehensive review of photocatalytic innovation
  6. Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base
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Heruntergeladen am 7.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/revic-2024-0037/html?srsltid=AfmBOoqEXWe_Xk2kbP54uxIRSaIKdvvlxGIzKCCnzCfwBHudML8EeWpn
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