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Unveiling the multifaceted roles of protonated 1,2-bis(4-pyridyl)ethylene (HBpe+) ligand in metal-driven supramolecular assembly: a comprehensive structural review

  • Debabrata Singha ORCID logo , Pritha Datta , Sasthi Charan Halder , Atish Dipankar Jana ORCID logo EMAIL logo and Nilasish Pal ORCID logo EMAIL logo
Published/Copyright: February 16, 2024
Reviews in Inorganic Chemistry
From the journal Reviews in Inorganic Chemistry Volume 44 Issue 4

Abstract

A protonated form of 1,2-bis(4-pyridyl)ethylene (HBpe+), produced through proton transfer or pH adjustments, plays a significant role in forming unique supramolecular structures. In contrast, non-protonated forms of the molecule (Bpe) are extensively studied in metal-organic complexes. In this review, we examine the fascinating world of HBpe+ as a monodentate ligand in the realm of coordination chemistry. It discusses how protonated ligands influence the assembly of supramolecular structures, as well as their properties and functions. Structures such as 1:1 adduct, coordination polymers, and metal clusters are often formed as a result. In these assemblies, HBpe+ engages in a variety of interactions that influence its supramolecular behavior. The interactions include coordination complexes with metal ions, hydrogen bonds, aromatic ring stacking, and double bond stacking (π⋯π stacking). The flexibility and conformation of the ligand have a significant impact on the overall structure and stability of complexes. It opens the door to developing functional materials by unraveling the unique attributes and role of HBpe+ in supramolecular assembly. With these insights, it is possible to explore the functional properties of HBpe+ through controlled assembly processes in order to create innovative and functional materials.

Keywords: 1,2-bis(4-pyridyl)ethylene (Bpe); supramolecular structure; coordination polymer; π⋯π stacking
Corresponding authors: Atish Dipankar Jana, Centre for Research in Nano Science and Crystal Engineering, Sibani Mandal Mahavidyalaya, Namkhana 743357, West Bengal, India; and Institute of Astronomy, Space and Earth Science, P 177, CIT Road, Scheme 7m, Kolkata 700054, West Bengal, India, E-mail: ; and Nilasish Pal, Department of Chemistry, Seth Anandram Jaipuria College, 10, Raja Nabakrishna Street, Kolkata 700005, West Bengal, India, E-mail:

Funding source: WBDST

Award Identifier / Grant number: 203(Sanc.)/ST/P/S&T/15G-32/2017

  1. Research ethics: Not applicable.

  2. Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: The authors state no conflict of interest.

  4. Research funding: This work is financially supported by WBDST, Project Sanction No. 203(Sanc.)/ST/P/S&T/15G-32/2017.

  5. Data availability: Cif files are downloaded from CCDC search (CSD version 5.39) by using CCDC software.

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Received: 2023-09-18
Accepted: 2024-01-22
Published Online: 2024-02-16
Published in Print: 2024-11-26

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Unveiling the multifaceted roles of protonated 1,2-bis(4-pyridyl)ethylene (HBpe+) ligand in metal-driven supramolecular assembly: a comprehensive structural review
  3. Advanced synthetic routes of metal organic frameworks and their diverse applications
  4. Carbon materials derived by crystalline porous materials for capacitive energy storage
  5. BiVO4-based heterojunction nanophotocatalysts for water splitting and organic pollutant degradation: a comprehensive review of photocatalytic innovation
  6. Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base
  7. Solid-phase extraction of organophosphates from polluted waters on a matrix-imprinted sorbent
  8. Reduction mechanism and energy transfer between Eu3+ and Eu2+ in Eu-doped materials synthesized in air atmosphere
  9. Green synthesis and applications of mono/bimetallic nanoparticles on mesoporous clay: a review
  10. Hydroxyapatite biomaterials: a comprehensive review of their properties, structures, clinical applications, and producing techniques
  11. Water desalination, and energy consumption applications of 2D nano materials: hexagonal boron nitride, graphenes, and quantum dots
  12. Transformative applications of “click” chemistry in the development of MOF architectures − a mini review
  13. A review of carbon-based adsorbents for the removal of organic and inorganic components
  14. Mercury removal from water: insights from MOFs and their composites
  15. Organometallic complexes and reaction methods for synthesis: a review
  16. Comprehensive review of metal-based coordination compounds in cancer therapy: from design to biochemical reactivity
https://doi.org/10.1515/revic-2023-0025
Keywords for this article
1,2-bis(4-pyridyl)ethylene (Bpe); supramolecular structure; coordination polymer; π⋯π stacking

Articles in the same Issue

  1. Frontmatter
  2. Unveiling the multifaceted roles of protonated 1,2-bis(4-pyridyl)ethylene (HBpe+) ligand in metal-driven supramolecular assembly: a comprehensive structural review
  3. Advanced synthetic routes of metal organic frameworks and their diverse applications
  4. Carbon materials derived by crystalline porous materials for capacitive energy storage
  5. BiVO4-based heterojunction nanophotocatalysts for water splitting and organic pollutant degradation: a comprehensive review of photocatalytic innovation
  6. Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base
  7. Solid-phase extraction of organophosphates from polluted waters on a matrix-imprinted sorbent
  8. Reduction mechanism and energy transfer between Eu3+ and Eu2+ in Eu-doped materials synthesized in air atmosphere
  9. Green synthesis and applications of mono/bimetallic nanoparticles on mesoporous clay: a review
  10. Hydroxyapatite biomaterials: a comprehensive review of their properties, structures, clinical applications, and producing techniques
  11. Water desalination, and energy consumption applications of 2D nano materials: hexagonal boron nitride, graphenes, and quantum dots
  12. Transformative applications of “click” chemistry in the development of MOF architectures − a mini review
  13. A review of carbon-based adsorbents for the removal of organic and inorganic components
  14. Mercury removal from water: insights from MOFs and their composites
  15. Organometallic complexes and reaction methods for synthesis: a review
  16. Comprehensive review of metal-based coordination compounds in cancer therapy: from design to biochemical reactivity
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