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Advanced synthetic routes of metal organic frameworks and their diverse applications

  • Ghazala Iram

    Miss Ghazala Iram was born in Punjab-Pakistan in August 1996. She completed her schooling and college education at City Layyah-Pakistan and a bachelor’s degree in chemistry at Bahaudin Zakrya University Multan Pakistan in August 2017. She completed her master’s (M.Sc) in chemical sciences at the University of Agriculture Faisalabad in 2020. She then joined the University of Agriculture Faisalabad in September 2021 for an M.Phil. in chemistry in organometallics and coordination chemistry under the supervision of Dr. Muhammad Adnan Iqbal Associate Professor University of Agriculture Faisalabad. She completed her M.Phil. degree in August 2023. Her research work during M.Phil was on the synthesis of coordination complexes.

         , Ateeq-Ur-Rehman

    Dr. Ateeq-ur-Rehman is currently working as an Assistant Professor in the Department of Physics at the University of Agriculture, Faisalabad-Pakistan. After his M.Sc. in Physics, he undertook M.Phil. in solid state physics followed by a fully funded Ph.D. in Physics from Zhejiang University, China. During his Ph.D. studies, he concentrated on the structural and interfacial electronic properties of organic-inorganic interfaces. In addition to studying surface and interface physics, Dr. Rehman is also working on materials synthesis for next-generation energy storage devices. He is the reviewer of several high-impact factor journals; including PCCP and JAP just to mention.

     EMAIL logo     , Muhammad Adan Iqbal

    Dr. Muhammad Adan Iqbal was born in Punjab-Pakistan in April 1984. He completed his schooling and college education at city Faisalabad-Pakistan and bachelor’s degree in chemistry at university of the Punjab-Lahore-Pakistan in August 2007. He completed his masters (M.Phil) in environmental sciences at college of earth and environmental science, University of the Punjab, Lahore in 2010 and in parallel served as Lecturer of chemistry at Minhaj University Lahore till July 2010. He then joined Universiti Sains Malaysia, Penang-Malaysia in July 2010 for MS leading to PhD study in Dr. Rosenani A. Haque’s laboratory on a fellowship. He completed his PhD in organometallic chemistry in April 2014 and got an opportunity of postdoctoral fellowship at the same research laboratory. During his Ph.D studies Dr. Iqbal visited University of Western Australia, Perth, Australia on a research attachment at Professor Murray Baker’s research Laboratory. He finally joined University of Agriculture Faisalabad in September 2015 as assistant professor. Currently, he has established an organometallic and coordination chemistry laboratory at UAF community college, University of Agriculture Faisalabad-Pakistan with help of funding from Higher Education Commission of Pakistan through one SRGP and two NRPU research grants. His research interests include synthesis of metallodrugs. Dr. Iqbal has published more than 100 research and review articles in international journals, a book on organometallic chemistry and three book chapters. He is managing editor of a reputable research journal, Journal of Angiotherapy. He has produced 5 PhD and 32 M.Phil degree holders in the field of Chemistry. He has organized several workshops, Seminars and Symposiums. He has national (LUMS, University of the Punjab, Lahore, GC University Faisalabad, etc.) and international (University of Western Australia, Perth, Universiti Sains Malaysia, Malaysia, St John’s University, USA) research collaborations. He is working as coordinator for postgraduate classes in chemistry at PARS campus for 2 years and is currently serving additional duties of coordinator for postgraduate classes at PARS and as deputy director students affairs PARS.

     ORCID logo EMAIL logo     , Ayesha Zafar

    Miss Ayesha Zafar was born in Punjab-Pakistan in November 1997. She completed her schooling and college education at city Jaranwala-Pakistan and done her Graduation in BS Chemistry at Government Postgraduate College Jaranwala Pakistan in October 2020. She then joined University of Agriculture Faisalabad in September 2021 for M.Phil in chemistry in organometallics and coordination chemistry under the supervision of Dr. Muhammad Adnan Iqbal Associate Professor University of Agriculture Faisalabad and completed her M.Phil degree in August 2023. Her research work during M.Phil was on synthesis of metal complexes and their catalytic applications.

         , Adnan Majeed

    Mr. Adnan Majeed was born in Punjab-Pakistan in January 1998. He completed his schooling and college education at Sargodha-Pakistan and his bachelor’s degree in chemistry at The University of Lahore, Pakistan in October 2021. He then joined the University of Agriculture Faisalabad in September 2021 for an M.Phil. in chemistry in organometallics and coordination chemistry under the supervision of Dr. Muhammad Adnan Iqbal Associate Professor University of Agriculture Faisalabad. He completed his M.Phil. degree in August 2023. His research work during his M.Phil. was on the degradation of dyes by Organophotocatalysis using common organic acids.

         , Sofia Hayat

    Miss Sofia Hayat was born in Punjab-Pakistan in July 1997. She completed her schooling and college education at city Toba Tek Singh-Pakistan and bachelor’s degree from Government College University Faisalabad Pakistan in August 2017. She completed her master’s (M.Sc) in chemical sciences at University of Agriculture Faisalabad in 2019. She then joined University of Agriculture Faisalabad in September 2021 for M.Phil in chemistry in organometallics and coordination chemistry under the supervision of Dr. Muhammad Adnan Iqbal Associate Professor University of Agriculture Faisalabad and completed her M.Phil degree in August 2023. Her research work during M.Phil was on the development of benzimidazolium salt based cubosome hydrogels for topical treatment of burns.

         and Maubashera Nawaz

    Miss Maubashera Nawaz was born in Punjab-Pakistan in October 1996. She completed her schooling and college education at city Jhang-Pakistan and bachelor’s degree in chemistry at Punjab University Lahore Pakistan in August 2017. She completed her master’s (M.Sc) in chemical sciences at University of Agriculture Faisalabad in 2020. She then joined University of Agriculture Faisalabad in September 2021 for M.Phil in chemistry in organometallics and coordination chemistry under the supervision of Dr. Muhammad Adnan Iqbal Associate Professor University of Agriculture Faisalabad and completed her M.Phil degree in August 2023. Her research work during M.Phil was on Development of N-alkylated benzimidazole based cubosome hydrogels for topical treatment of burns.
Published/Copyright: April 16, 2024
Reviews in Inorganic Chemistry
From the journal Reviews in Inorganic Chemistry Volume 44 Issue 4

Abstract

Metal-organic frameworks (MOFs) are crystalline materials characterized by their porous structures, formed through coordination bonding between metal ions/clusters and multidentate organic linkers. MOFs have emerged as a significant class of materials with applications in energy storage, CO2 adsorption, and catalysis. This study serves as a brief introduction to the currently available synthesis methods of MOFs, aimed at acquainting beginners in the field of chemical engineering with the ongoing developments in MOF research. The discussed synthesis methods encompass traditional solvothermal/hydrothermal approaches, microwave synthesis of MOFs, one-pot synthesis, MOF nanocomposites, isothermal synthesis, and fluid-fluid synthesis. Notably, the MOF/NH2/Fe3O4 combination exhibited enhanced adsorption capacity of 618 mg/g and retained an efficiency of over 90 %. This study displays a valuable technique for designing functional MOF hybrid composites. By combining MOFs with specific materials, numerous advantages can be achieved in the newly created compounds (MOF composites), including synergistic effects beneficial in catalytic applications, and overcoming the challenges associated with using bare MOFs.

Keywords: chemiresistive; microporous; tunable; fluorophores; MOFs; porous material
Corresponding authors: Ateeq-Ur-Rehman, Department of Physics, University of Agriculture, Faisalabad, Pakistan, E-mail: ; and Muhammad Adan Iqbal, Department of Chemistry, University of Agriculture, Faisalabad, Pakistan; and Organometallic and Coordination Chemistry Laboratory, University of Agriculture, Faisalabad, Pakistan, E-mail:

Funding source: Pakistan Science Foundation (PSF)

Award Identifier / Grant number: PSF/Cons/676

About the authors

Ghazala Iram

Miss Ghazala Iram was born in Punjab-Pakistan in August 1996. She completed her schooling and college education at City Layyah-Pakistan and a bachelor’s degree in chemistry at Bahaudin Zakrya University Multan Pakistan in August 2017. She completed her master’s (M.Sc) in chemical sciences at the University of Agriculture Faisalabad in 2020. She then joined the University of Agriculture Faisalabad in September 2021 for an M.Phil. in chemistry in organometallics and coordination chemistry under the supervision of Dr. Muhammad Adnan Iqbal Associate Professor University of Agriculture Faisalabad. She completed her M.Phil. degree in August 2023. Her research work during M.Phil was on the synthesis of coordination complexes.

Ateeq-Ur-Rehman

Dr. Ateeq-ur-Rehman is currently working as an Assistant Professor in the Department of Physics at the University of Agriculture, Faisalabad-Pakistan. After his M.Sc. in Physics, he undertook M.Phil. in solid state physics followed by a fully funded Ph.D. in Physics from Zhejiang University, China. During his Ph.D. studies, he concentrated on the structural and interfacial electronic properties of organic-inorganic interfaces. In addition to studying surface and interface physics, Dr. Rehman is also working on materials synthesis for next-generation energy storage devices. He is the reviewer of several high-impact factor journals; including PCCP and JAP just to mention.

Muhammad Adan Iqbal

Dr. Muhammad Adan Iqbal was born in Punjab-Pakistan in April 1984. He completed his schooling and college education at city Faisalabad-Pakistan and bachelor’s degree in chemistry at university of the Punjab-Lahore-Pakistan in August 2007. He completed his masters (M.Phil) in environmental sciences at college of earth and environmental science, University of the Punjab, Lahore in 2010 and in parallel served as Lecturer of chemistry at Minhaj University Lahore till July 2010. He then joined Universiti Sains Malaysia, Penang-Malaysia in July 2010 for MS leading to PhD study in Dr. Rosenani A. Haque’s laboratory on a fellowship. He completed his PhD in organometallic chemistry in April 2014 and got an opportunity of postdoctoral fellowship at the same research laboratory. During his Ph.D studies Dr. Iqbal visited University of Western Australia, Perth, Australia on a research attachment at Professor Murray Baker’s research Laboratory. He finally joined University of Agriculture Faisalabad in September 2015 as assistant professor. Currently, he has established an organometallic and coordination chemistry laboratory at UAF community college, University of Agriculture Faisalabad-Pakistan with help of funding from Higher Education Commission of Pakistan through one SRGP and two NRPU research grants. His research interests include synthesis of metallodrugs. Dr. Iqbal has published more than 100 research and review articles in international journals, a book on organometallic chemistry and three book chapters. He is managing editor of a reputable research journal, Journal of Angiotherapy. He has produced 5 PhD and 32 M.Phil degree holders in the field of Chemistry. He has organized several workshops, Seminars and Symposiums. He has national (LUMS, University of the Punjab, Lahore, GC University Faisalabad, etc.) and international (University of Western Australia, Perth, Universiti Sains Malaysia, Malaysia, St John’s University, USA) research collaborations. He is working as coordinator for postgraduate classes in chemistry at PARS campus for 2 years and is currently serving additional duties of coordinator for postgraduate classes at PARS and as deputy director students affairs PARS.

Ayesha Zafar

Miss Ayesha Zafar was born in Punjab-Pakistan in November 1997. She completed her schooling and college education at city Jaranwala-Pakistan and done her Graduation in BS Chemistry at Government Postgraduate College Jaranwala Pakistan in October 2020. She then joined University of Agriculture Faisalabad in September 2021 for M.Phil in chemistry in organometallics and coordination chemistry under the supervision of Dr. Muhammad Adnan Iqbal Associate Professor University of Agriculture Faisalabad and completed her M.Phil degree in August 2023. Her research work during M.Phil was on synthesis of metal complexes and their catalytic applications.

Adnan Majeed

Mr. Adnan Majeed was born in Punjab-Pakistan in January 1998. He completed his schooling and college education at Sargodha-Pakistan and his bachelor’s degree in chemistry at The University of Lahore, Pakistan in October 2021. He then joined the University of Agriculture Faisalabad in September 2021 for an M.Phil. in chemistry in organometallics and coordination chemistry under the supervision of Dr. Muhammad Adnan Iqbal Associate Professor University of Agriculture Faisalabad. He completed his M.Phil. degree in August 2023. His research work during his M.Phil. was on the degradation of dyes by Organophotocatalysis using common organic acids.

Sofia Hayat

Miss Sofia Hayat was born in Punjab-Pakistan in July 1997. She completed her schooling and college education at city Toba Tek Singh-Pakistan and bachelor’s degree from Government College University Faisalabad Pakistan in August 2017. She completed her master’s (M.Sc) in chemical sciences at University of Agriculture Faisalabad in 2019. She then joined University of Agriculture Faisalabad in September 2021 for M.Phil in chemistry in organometallics and coordination chemistry under the supervision of Dr. Muhammad Adnan Iqbal Associate Professor University of Agriculture Faisalabad and completed her M.Phil degree in August 2023. Her research work during M.Phil was on the development of benzimidazolium salt based cubosome hydrogels for topical treatment of burns.

Maubashera Nawaz

Miss Maubashera Nawaz was born in Punjab-Pakistan in October 1996. She completed her schooling and college education at city Jhang-Pakistan and bachelor’s degree in chemistry at Punjab University Lahore Pakistan in August 2017. She completed her master’s (M.Sc) in chemical sciences at University of Agriculture Faisalabad in 2020. She then joined University of Agriculture Faisalabad in September 2021 for M.Phil in chemistry in organometallics and coordination chemistry under the supervision of Dr. Muhammad Adnan Iqbal Associate Professor University of Agriculture Faisalabad and completed her M.Phil degree in August 2023. Her research work during M.Phil was on Development of N-alkylated benzimidazole based cubosome hydrogels for topical treatment of burns.

  1. Research ethics: Not applicable.

  2. Author contributions: Ghazala Iram: Writing-original draft, Software; Ateeq-Ur-Rehman: Resources and Validation; Muhammad Adnan Iqbal: Conceptualization, Resources, Supervision, Overall guidance; Ayesha Zafar: Data curation, Visualization. Adnan Majeed: Review and editing, Software. Sofia Hayat: Formal analysis; Mubashera Nawaz: Validation.

  3. Competing interests: The authors declare no conflict of interest.

  4. Research funding: The authors are thankful to the Pakistan Science Foundation (PSF) for awarding the research grant PSF/Cons/676.

  5. Data availability: Data will be provided on demand.

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Received: 2023-09-01
Accepted: 2024-03-20
Published Online: 2024-04-16
Published in Print: 2024-11-26

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Unveiling the multifaceted roles of protonated 1,2-bis(4-pyridyl)ethylene (HBpe+) ligand in metal-driven supramolecular assembly: a comprehensive structural review
  3. Advanced synthetic routes of metal organic frameworks and their diverse applications
  4. Carbon materials derived by crystalline porous materials for capacitive energy storage
  5. BiVO4-based heterojunction nanophotocatalysts for water splitting and organic pollutant degradation: a comprehensive review of photocatalytic innovation
  6. Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base
  7. Solid-phase extraction of organophosphates from polluted waters on a matrix-imprinted sorbent
  8. Reduction mechanism and energy transfer between Eu3+ and Eu2+ in Eu-doped materials synthesized in air atmosphere
  9. Green synthesis and applications of mono/bimetallic nanoparticles on mesoporous clay: a review
  10. Hydroxyapatite biomaterials: a comprehensive review of their properties, structures, clinical applications, and producing techniques
  11. Water desalination, and energy consumption applications of 2D nano materials: hexagonal boron nitride, graphenes, and quantum dots
  12. Transformative applications of “click” chemistry in the development of MOF architectures − a mini review
  13. A review of carbon-based adsorbents for the removal of organic and inorganic components
  14. Mercury removal from water: insights from MOFs and their composites
  15. Organometallic complexes and reaction methods for synthesis: a review
  16. Comprehensive review of metal-based coordination compounds in cancer therapy: from design to biochemical reactivity
https://doi.org/10.1515/revic-2023-0024
Keywords for this article
chemiresistive; microporous; tunable; fluorophores; MOFs; porous material

Articles in the same Issue

  1. Frontmatter
  2. Unveiling the multifaceted roles of protonated 1,2-bis(4-pyridyl)ethylene (HBpe+) ligand in metal-driven supramolecular assembly: a comprehensive structural review
  3. Advanced synthetic routes of metal organic frameworks and their diverse applications
  4. Carbon materials derived by crystalline porous materials for capacitive energy storage
  5. BiVO4-based heterojunction nanophotocatalysts for water splitting and organic pollutant degradation: a comprehensive review of photocatalytic innovation
  6. Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base
  7. Solid-phase extraction of organophosphates from polluted waters on a matrix-imprinted sorbent
  8. Reduction mechanism and energy transfer between Eu3+ and Eu2+ in Eu-doped materials synthesized in air atmosphere
  9. Green synthesis and applications of mono/bimetallic nanoparticles on mesoporous clay: a review
  10. Hydroxyapatite biomaterials: a comprehensive review of their properties, structures, clinical applications, and producing techniques
  11. Water desalination, and energy consumption applications of 2D nano materials: hexagonal boron nitride, graphenes, and quantum dots
  12. Transformative applications of “click” chemistry in the development of MOF architectures − a mini review
  13. A review of carbon-based adsorbents for the removal of organic and inorganic components
  14. Mercury removal from water: insights from MOFs and their composites
  15. Organometallic complexes and reaction methods for synthesis: a review
  16. Comprehensive review of metal-based coordination compounds in cancer therapy: from design to biochemical reactivity
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