Startseite Naturwissenschaften Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base
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Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base

  • Saleh Bufarwa ORCID logo EMAIL logo , Reem El-Seifat , Hana Binhamad und Rehab Hesien
Veröffentlicht/Copyright: 1. Mai 2024
Reviews in Inorganic Chemistry
Aus der Zeitschrift Reviews in Inorganic Chemistry Band 44 Heft 4

Abstract

Scientists are searching for reactive oxygen species, which have been associated with various health issues like heart problems, neurological disorders, inflammation, and aging. Salen complexes have proven to be effective in multiple oxidative stress situations and have been used as catalase and superoxide mimetics. To explore this further, three mixed complexes were synthesized using a Schiff base (salen) and a sugar (d-glucose) with Co(II), Ni(II), and Cu(II) ions. These complexes were then diagnosed by different analytical and spectral techniques. Stoichiometry, stereochemistry, some physical properties, and the method of bonding complexes were measured. Comparisons of the IR and 1HNMR spectra of the ligands with the complexes demonstrated the involvement of the azomethine group of the ligand in the chelation process. The mass spectra and TGA agree with the proposed formula of the complexes, and the conductivity and UV–Vis data supported the octahedral geometry of the complexes, and information was obtained from partial parameter calculations by molecular modeling. The metal complexes exhibited strong antimicrobial and antioxidant properties when compared to standard drugs. The like-superoxide and catalyst mimetic complexes were screened using DPPH ABTS, revealing their effectiveness.

Keywords: Schiff base; salen; d-glucose; spectroscopic methods; superoxide mimetics; antibacterial activity
Corresponding author: Saleh Bufarwa, Department of Chemistry, Omar Al-Mukhtar University, El-Beida City, Libya, E-mail:

Acknowledgments

Mr. Saleh Bufarwa expresses his gratitude to Mr. Omran Muftah, Faculty of Pharmacy at Omar Al-Mukhtar University, for his assistance in conducting some analyses. The author also extend their sincere thanks to Mr. Abdul-Jalil Hamad for providing some of the requirements for this research., as well as the Department of Chemistry, Omar Al-Mukhtar University, for providing research facilities.

  1. Research ethics: Not applicable.

  2. Author contributions: H.B. and S.B—Conceptualization, Validation, Writing an original draft, Investigation, Methodology, Data curation. R.E. and R.H—Data curation, Supervision, Writing—review and editing, Validation. R.E.—Sofware, Visualization, Writing—original draft, Methodology, and Validation. S.B—Sofware, Visualization, Writing—original draft, Validation. H.B.—Writing-review and editing, Validation “The authors have accepted responsibility for the entire content of this manuscript and approved its submission.”

  3. Competing interests: The authors state no conflict of interest.

  4. Research funding: None declared.

  5. Data availability: The raw data can be obtained on request from the corresponding author.

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Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/revic-2023-0028).

Received: 2023-10-15
Accepted: 2024-04-08
Published Online: 2024-05-01
Published in Print: 2024-11-26

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

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  3. Advanced synthetic routes of metal organic frameworks and their diverse applications
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  5. BiVO4-based heterojunction nanophotocatalysts for water splitting and organic pollutant degradation: a comprehensive review of photocatalytic innovation
  6. Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base
  7. Solid-phase extraction of organophosphates from polluted waters on a matrix-imprinted sorbent
  8. Reduction mechanism and energy transfer between Eu3+ and Eu2+ in Eu-doped materials synthesized in air atmosphere
  9. Green synthesis and applications of mono/bimetallic nanoparticles on mesoporous clay: a review
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  12. Transformative applications of “click” chemistry in the development of MOF architectures − a mini review
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https://doi.org/10.1515/revic-2023-0028
Schlagwörter für diesen Artikel
Schiff base; salen; d-glucose; spectroscopic methods; superoxide mimetics; antibacterial activity

Artikel in diesem Heft

  1. Frontmatter
  2. Unveiling the multifaceted roles of protonated 1,2-bis(4-pyridyl)ethylene (HBpe+) ligand in metal-driven supramolecular assembly: a comprehensive structural review
  3. Advanced synthetic routes of metal organic frameworks and their diverse applications
  4. Carbon materials derived by crystalline porous materials for capacitive energy storage
  5. BiVO4-based heterojunction nanophotocatalysts for water splitting and organic pollutant degradation: a comprehensive review of photocatalytic innovation
  6. Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base
  7. Solid-phase extraction of organophosphates from polluted waters on a matrix-imprinted sorbent
  8. Reduction mechanism and energy transfer between Eu3+ and Eu2+ in Eu-doped materials synthesized in air atmosphere
  9. Green synthesis and applications of mono/bimetallic nanoparticles on mesoporous clay: a review
  10. Hydroxyapatite biomaterials: a comprehensive review of their properties, structures, clinical applications, and producing techniques
  11. Water desalination, and energy consumption applications of 2D nano materials: hexagonal boron nitride, graphenes, and quantum dots
  12. Transformative applications of “click” chemistry in the development of MOF architectures − a mini review
  13. A review of carbon-based adsorbents for the removal of organic and inorganic components
  14. Mercury removal from water: insights from MOFs and their composites
  15. Organometallic complexes and reaction methods for synthesis: a review
  16. Comprehensive review of metal-based coordination compounds in cancer therapy: from design to biochemical reactivity
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