Home Physical Sciences Crystal structure of tricyclohexyl[4-(4H-1,2,4-triazol-4-yl)-benzoato-κO]tin(IV), C27H39N3O2Sn
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Crystal structure of tricyclohexyl[4-(4H-1,2,4-triazol-4-yl)-benzoato-κO]tin(IV), C27H39N3O2Sn

  • Jingjing Qing , Jie Tian , Xin Deng and Fuxing Zhang ORCID logo EMAIL logo
Published/Copyright: November 7, 2023
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 239 Issue 1

Abstract

C27H39N3O2Sn, monoclinic, P21/c (no. 14), a = 10.3317(6) Å, b = 15.8067(9) Å, c = 16.5497(9) Å, β = 90.5380(10)°, V = 2702.6(3) Å3, Z = 4, Rgt(F) = 0.0370, wRref(F2) = 0.0954, T = 296(2) K.

CCDC no.: 2278991

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colorless lump
Size: 0.20 × 0.19 × 0.18 mm
Wavelength: MoKα radiation (0.71073 Å)
μ: 0.97 mm−1
Diffractometer, scan mode: Bruker APEX-II, φ and ω
θmax, completeness: 26.4°, >99 %
N(hkl)measured, N(hkl)unique, Rint: 30,612, 5552, 0.016
Criterion for Iobs, N(hkl)gt: Iobs > 2σ(Iobs), 5311
N(param)refined: 299
Programs: Bruker [1], Shelx [2, 3], WinGX/Ortep [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

Atom x y z Uiso*/Ueq
Sn1 0.25939 (2) 0.21054 (2) 0.02219 (2) 0.03203 (9)
C1 0.2663 (3) 0.3468 (2) 0.0329 (2) 0.0447 (8)
H1 0.339761 0.358251 0.069176 0.054*
O1 0.4246 (2) 0.19177 (16) 0.10000 (14) 0.0420 (5)
O2 0.5619 (2) 0.2620 (2) 0.02118 (15) 0.0533 (6)
C2 0.1505 (5) 0.3859 (3) 0.0740 (3) 0.0649 (11)
H2A 0.138742 0.359771 0.126453 0.078*
H2B 0.073205 0.375544 0.041784 0.078*
C6 0.2990 (5) 0.3912 (3) −0.0452 (3) 0.0669 (12)
H6A 0.232310 0.379055 −0.085154 0.080*
H6B 0.380261 0.369186 −0.065302 0.080*
N1 1.0393 (3) 0.2688 (2) 0.43958 (18) 0.0454 (7)
C7 0.3145 (3) 0.1415 (2) −0.0837 (2) 0.0432 (7)
H7 0.236560 0.110620 −0.100554 0.052*
C12 0.4159 (5) 0.0737 (3) −0.0674 (3) 0.0668 (12)
H12A 0.387663 0.037809 −0.023373 0.080*
H12B 0.496730 0.100248 −0.051165 0.080*
C11 0.4378 (7) 0.0198 (3) −0.1425 (3) 0.0919 (18)
H11A 0.507753 −0.019686 −0.131855 0.110*
H11B 0.360212 −0.012769 −0.153939 0.110*
C10 0.4703 (6) 0.0720 (4) −0.2148 (3) 0.0951 (19)
H10A 0.554286 0.098135 −0.206533 0.114*
H10B 0.475849 0.035455 −0.261781 0.114*
C9 0.3717 (5) 0.1392 (3) −0.2306 (3) 0.0723 (13)
H9A 0.290456 0.113014 −0.246415 0.087*
H9B 0.400171 0.174551 −0.274874 0.087*
C8 0.3506 (4) 0.1943 (3) −0.1553 (2) 0.0535 (9)
H8A 0.429229 0.225517 −0.143122 0.064*
H8B 0.282320 0.234978 −0.166386 0.064*
C13 0.1399 (4) 0.1365 (3) 0.1016 (2) 0.0549 (9)
H13 0.053142 0.160816 0.095097 0.066*
C14 0.1259 (10) 0.0496 (4) 0.0742 (4) 0.160 (3)
H14A 0.211128 0.024270 0.070552 0.192*
H14B 0.087983 0.049820 0.020316 0.192*
C15 0.0424 (10) −0.0048 (5) 0.1290 (4) 0.177 (3)
H15A −0.047564 0.010579 0.120265 0.212*
H15B 0.052024 −0.063498 0.112890 0.212*
C16 0.0718 (9) 0.0018 (4) 0.2159 (4) 0.134 (2)
H16A 0.005966 −0.027511 0.246482 0.161*
H16B 0.154610 −0.024623 0.227489 0.161*
C17 0.0760 (7) 0.0899 (4) 0.2398 (3) 0.1064 (19)
H17A 0.103583 0.093434 0.295890 0.128*
H17B −0.010508 0.113445 0.235798 0.128*
C18 0.1671 (7) 0.1426 (4) 0.1884 (3) 0.1012 (18)
H18A 0.160640 0.201317 0.204736 0.121*
H18B 0.255302 0.124204 0.198629 0.121*
C3 0.1700 (6) 0.4820 (3) 0.0846 (4) 0.0852 (16)
H3A 0.091993 0.506405 0.106965 0.102*
H3B 0.240168 0.491776 0.122827 0.102*
C4 0.1999 (7) 0.5249 (3) 0.0077 (4) 0.0973 (19)
H4A 0.124308 0.522668 −0.027436 0.117*
H4B 0.218802 0.583958 0.018530 0.117*
C5 0.3105 (6) 0.4869 (3) −0.0345 (4) 0.0921 (18)
H5A 0.389130 0.499251 −0.004276 0.111*
H5B 0.318083 0.512940 −0.087288 0.111*
C19 0.5337 (3) 0.2290 (2) 0.0854 (2) 0.0378 (7)
C20 0.6258 (3) 0.2314 (2) 0.15666 (19) 0.0354 (6)
C21 0.5963 (3) 0.1905 (2) 0.2283 (2) 0.0405 (7)
H21 0.520875 0.158523 0.231513 0.049*
C22 0.6777 (3) 0.1965 (2) 0.2952 (2) 0.0426 (8)
H22 0.657773 0.168502 0.342951 0.051*
C23 0.7891 (3) 0.2450 (2) 0.28989 (19) 0.0349 (6)
C24 0.8206 (3) 0.2858 (2) 0.2187 (2) 0.0437 (8)
H24 0.895536 0.318204 0.215589 0.052*
C25 0.7393 (3) 0.2778 (2) 0.1520 (2) 0.0430 (8)
H25 0.761216 0.303799 0.103596 0.052*
N2 0.8698 (2) 0.25446 (18) 0.36022 (16) 0.0359 (6)
C27 0.8318 (3) 0.2574 (3) 0.4385 (2) 0.0470 (8)
H27 0.746327 0.253900 0.455224 0.056*
N3 0.9303 (3) 0.2658 (3) 0.48687 (19) 0.0550 (8)
C26 1.0007 (3) 0.2624 (2) 0.3645 (2) 0.0423 (7)
H26 1.055193 0.263108 0.320125 0.051*

1 Source of material

All chemicals were purchased from commercial sources and used as received without further purification. An amount of 1 mmol tricyclohexyltin hydroxide and 1 mmol 4-(4H-1,2,4-triazol-4-yl)benzoic acid were added in CH3OH (25 mL) and refluxed with agitating for 12 h. The reaction solution was filtered. Finally, the title crystal was precipitated by controlling solvent volatilization.

2 Experimental details

All H-atoms bonded to C atoms were placed geometrically and refined using a riding model with common isotropic displacement factors Uiso(H) = 1.2 or 1.5 Ueq(parent C-atom).

3 Comment

Organotin carboxylates, a class of organometallic compounds, have drawn considerable interest due to their diverse structures and significant biological activities [5, 6]. As these have shown higher apoptosis inducing character compared to the platinum complexes, both in vivo and in vitro, organotin carboxylates are found be the most promising alternatives [7, 8]. It is found that the activity and structure of organotin carboxylates are related. Therefore, the investigation on the crystal structures of organotin carboxylates has received wide attention [9, 10]. In this context, we have crystallized the title compound.

In the molecular structure (Figure), the Sn(IV) ion is four-coordinated by one oxygen atom of one carboxyl group and three carbon atoms of three cyclohexyl groups. Bond lengths and angles are all in the expected ranges [11–13]. The C–Sn–C angles and C–Sn–O angles are ranging from 112.29(15)° to 124.37(14)° and 90.93(12)° to 101.76(11)°, respectively. The bond lengths of Sn–C are ranging from 2.146(3) to 2.162(4) Å, and Sn1–O1 is 2.149(2) Å.

Corresponding author: Fuxing Zhang, Key Laboratory of Organometallic New Materials (Hengyang Normal University), College of Hunan Province, Hunan Provincial Key Laboratory of Functional Metal–Organic Compounds, School of Chemistry and Materials Science Hengyang Normal University Hengyang, Hunan 421008, China, E-mail:

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by College Students Innovation and Entrepreneurship Training Program of Hunan Province General Project, College Students Innovation and Entrepreneurship Training Program of National General Project.

  3. Competing interests: The authors declare no conflicts of interest regarding this article.

References

1. Bruker. SAINT, APEX2 and SADABS; Bruker AXS Inc.: Madison, WI, USA, 2012.Search in Google Scholar

2. Sheldrick, G. M. SHELXTL – integrated space-group and crystal-structure determination. Acta Crystallogr. 2015, A71, 3–8; https://doi.org/10.1107/s2053273314026370.Search in Google Scholar PubMed PubMed Central

3. Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Search in Google Scholar

4. Farrugia, L. J. WINGX and ORTEP for Windows: an update. J. Appl. Crystallogr. 2012, 45, 849–854; https://doi.org/10.1107/s0021889812029111.Search in Google Scholar

5. Du, X.-M., Ma, J.-W., Li, Q.-L., Cheng, S., Cui, Y., Ma, C.-L. Syntheses, structures, and the in vitro anticancer mechanism of triorganotin(IV) complexes based on 4,4′-stilbenedicarboxylic acid. Appl. Organomet. Chem. 2023, 37, e7016; https://doi.org/10.1002/aoc.7016.Search in Google Scholar

6. Amir, M. K., Khan, S., Rehman, Z., Shah, A., Butler, I. S. Anticancer activity of organotin(IV) carboxylates. Inorg. Chim. Acta 2014, 423, 14–25; https://doi.org/10.1016/j.ica.2014.07.053.Search in Google Scholar

7. Muhammad, N., Ahmad, M., Sirajuddin, M., Ali, Z., Tumanov, N., Wouters, J., Chafik, A., Solak, K., Mavi, A., Muhammad, S., Shujah, S., Ali, S., Al-Sehemi, A. G. Synthesis, characterization, biological activity and molecular docking studies of novel organotin(IV) carboxylates. Front. Pharmacol 2022, 13, 864336–864352; https://doi.org/10.3389/fphar.2022.864336.Search in Google Scholar PubMed PubMed Central

8. Butt, A. F., Ahmed, M. N., Bhatti, M. H., Choudhary, M. A., Ayub, K., Tahir, M. N., Mahmood, T. Synthesis, structural properties, DFT studies, antimicrobial activities and DNA binding interactions of two newly synthesized organotin(IV) carboxylates. J. Mol. Struct. 2019, 1191, 291–300; https://doi.org/10.1016/j.molstruc.2019.04.066.Search in Google Scholar

9. Sun, J. The crystal structure of the cocrystal di-μ2-chlorido-octamethyl-di-μ3-oxido-bis(2,3,4,5-tetrafluorobenzoato-κ2O,O′)tetratin(IV) – octamethyl-di-μ3-oxido-bis(μ2-2,3,4,5-tetrafluorobenzoato-κ2O:O′)-bis(μ2-2,3,4,5-tetrafluorobenzoato-κ2O:O; O′)tetratin(IV) C58H54Cl2F24O16Sn8. Z. Kristallogr. – New Cryst. Struct. 2021, 236, 1231–1233; https://doi.org/10.1515/ncrs-2021-0288.Search in Google Scholar

10. Ding, R.-F., Wang, Q.-B., Wen, X.-M. Crystal structure of bis(μ3-oxo)-bis[μ2-2-(2-formylphenoxy)acetato-O, O′]-bis[μ2-2-(2-formylphenoxy)acetato-O,O′]-octakis(n-butyl)tetratin(IV), Sn4O2(C9H7O4)4(C4H9)8. Z. Kristallogr. – New Cryst. Struct. 2011, 226, 31–32; https://doi.org/10.1524/ncrs.2011.0016.Search in Google Scholar

11. Liu, X., Zhang, F.-X., He, L.-F., Li, D.-W., Zeng, W.-H., Jiang, S.-Y., He, X., Sheng, L.-B., Zhu, X.-M. Synthesis, structure and antitumor activity of two tris(o-bromobenzyl)tin carboxylates. Chin. J. Inorg. Chem. 2022, 38, 46–52.Search in Google Scholar

12. Song, X., Cahill, C., Eng, G. Crystal structure of tricyclohexyltin 4-hydroxybenzoate. Main Group Met. Chem. 2002, 25, 703–704; https://doi.org/10.1515/mgmc.2002.25.11.703.Search in Google Scholar

13. Danish, M., Tahir, M. N., Ahmad, N., Ali, S., Badshah, A. Tricyclohexyl[2-(2,3-dimethylanilino)benzoato-κO]tin(IV). Acta Crystallogr. 2009, E65, m1614; https://doi.org/10.1107/s1600536809048314.Search in Google Scholar
Received: 2023-09-22
Accepted: 2023-10-25
Published Online: 2023-11-07
Published in Print: 2024-02-26

© 2023 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  2. New Crystal Structures
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  4. Crystal structure of (8R,8′S,13S,13′R)-8,8′-bis(hydroxymethyl)-9,9′,10,10′-tetramethoxy-5,5′,6,6′,8,8′,13,13′-octahydro-[13,13′-bi[1,3]dioxolo[4,5-g]isoquinolino[3,2-a]isoquinoline]-7,7′-diium chloride-methanol (1/2), C46H58N2O14Cl2
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  12. Crystal structure of ethyl 2-((4-(3,5-dimethylisoxazol-4-yl)-2,6-difluorophenyl)amino)benzoate, C20H18F2N2O3
  13. The crystal structure of 2-(hydroxymethyl)-2-(4H-1,2,4-triazol-4-yl)propane-1,3-diol, C6H11N3O3
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  23. The crystal structure of 2,2-di(thiophen-3-yl)-1-tosyl-1,2-dihydro-2λ4,3λ4-[1,3,2]diazaborolo[4,5,1-ig]quinoline, C24H19BN2O2S3
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https://doi.org/10.1515/ncrs-2023-0419
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of poly[diaqua-(μ4-3,3′-di(1H-1,2,4-triazol-1-yl)-[1,1′-biphenyl]-4,4′-dicarboxylate-N:N′:O:O′)cadmium(II)], C18H14N6O6Cd
  4. Crystal structure of (8R,8′S,13S,13′R)-8,8′-bis(hydroxymethyl)-9,9′,10,10′-tetramethoxy-5,5′,6,6′,8,8′,13,13′-octahydro-[13,13′-bi[1,3]dioxolo[4,5-g]isoquinolino[3,2-a]isoquinoline]-7,7′-diium chloride-methanol (1/2), C46H58N2O14Cl2
  5. The crystal structure of 8-methoxy-2,2-diphenyl-tosyl-1,2-dihydro-2λ4,3λ4-[1,3,2]diazaborolo[4,5,1-ig]quinoline, C29H25BN2O3S
  6. Crystal structure of aqua-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N″,N‴)copper(II) 5-carboxyisophthalate tetrahydrate, C25H50N4CuO11
  7. The crystal structure of 1-(naphthalen-2-ylsulfonyl)-2,2-diphenyl-1,2-dihydro-2λ4,3λ4-[1,3,2]diazaborolo[4,5,1-ij]quinoline, C31H23BN2O2S
  8. Crystal structure of iodido-(η6-benzene) (1-(pyridin-2-yl)-N-(p-fluoro-methanamine)-κ2N,Nʹ)ruthenium(II) hexaflourophosphate, (C18H15F7IN2RuP)
  9. The crystal structure of 1-(3-oxo-1-phenyl-3-(p-tolyl) propylidene)-1,3-dihydro-2H-inden-2-one, C25H20O2
  10. Crystal structure of tricyclohexyl[4-(4H-1,2,4-triazol-4-yl)-benzoato-κO]tin(IV), C27H39N3O2Sn
  11. Crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylate-κ4N,O,O,O)cadmium(II)]monohydrate, C12H15NO9Cd
  12. Crystal structure of ethyl 2-((4-(3,5-dimethylisoxazol-4-yl)-2,6-difluorophenyl)amino)benzoate, C20H18F2N2O3
  13. The crystal structure of 2-(hydroxymethyl)-2-(4H-1,2,4-triazol-4-yl)propane-1,3-diol, C6H11N3O3
  14. The crystal structure of 1,2-bis(2,4-dinitrophenyl) hydrazine, C12H8N6O8
  15. Crystal structure of 1-(2,6-dichloro-4-(3,5-dimethylisoxazol-4-yl)phenyl)-1,2-dihydro-4H-benzo[d][1,3]oxazin-4-one, C19H14Cl2N2O3
  16. The crystal structure of 5-amino-5-oxo-4-(1-oxo-4-(2-oxopyrrolidin-1-yl)isoindolin-2-yl)pentanoic acid, C17H19N3O5
  17. Crystal structure of N2,N6-bis(2-(((Z)-5-bromo-2-hydroxybenzylidene)amino) phenyl)pyridine-2,6-dicarboxamide, C33H23Br2N5O4
  18. The crystal structure of (E)-2-methoxy-6-(((5-methyl-1,3,4-thiadiazol-2-yl)imino)methyl)phenol, C11H11N3O2S
  19. The crystal structure of 3-((tert-butyldiphenylsilyl)methyl)-5,5-diphenyl-6-(p-tolyl) tetrahydro-2H-pyran-2-one, C41H42O2Si
  20. Crystal structure of 9-fluoro-4-(6-methoxypyridin-3-yl)-5,6-dihydrobenzo[h]quinazolin-2-amine, C18H15FN4O
  21. The crystal structure of 2-bromo-5-(4-cyanophenoxy)benzyl 1-methyl-1,2,5,6-tetrahydropyridine-3-carboxylate, C21H19BrN2O3
  22. Crystal structure of 3,3′-(1,4-phenylenebis(methylene))bis(1-isopropyl-1H-imidazol-3-ium) bis(hexafluorophosphate(V)), C10H14F6N2P
  23. The crystal structure of 2,2-di(thiophen-3-yl)-1-tosyl-1,2-dihydro-2λ4,3λ4-[1,3,2]diazaborolo[4,5,1-ig]quinoline, C24H19BN2O2S3
  24. Crystal structure of 5-bromo-1-(2-iodobenzoyl)-1H-indole-3-carbaldehyde, C16H9BrINO2
  25. The crystal structure of monocarbonyl-2-carboxypyridinato-κ2N,O-triphenylphosphine-rhodium(I) acetonitrile solvate, C26H20.50N1.50O3PRh
  26. Crystal structure of dichlorido-tetrakis(1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pent-1-en-3-ol-κ1N)manganese(II), C60H68O4N12Cl10Mn
  27. Crystal structure of 3-(tert-butyldiphenylsilyl)-1-(2,6-dichlorophenyl)-2,2-diphenylpropan-1-ol, C37H36Cl2OSi
  28. Crystal structure of langite from Mine du Pradet (France)
  29. The crystal structure of 5′-(furan-2-yl)-3′-((4-methylphenyl)sulfonamido)-3′,4′,5′,6′-tetrahydro-[1,1′:3′,1″-terphenyl]-4′-carboxylic acid, C30H27NO5S
  30. Synthesis and crystal structure of bis{2-(((4-acetophenone)imino)methyl)-4-fluorophenolato-κ2N,O}zinc(II), C30H22F2N2O4Zn
  31. The crystal structure of poly[(tripyridine-κ3N,N′,N″) μ3-(pyridine-3,4-dicarboxylate-κ3N:O:O′) manganese(II)], C22H22N4O8Mn
  32. The crystal structure of (E)-4-chloro-N′-(1-(4-hydroxyphenyl)propylidene)benzohydrazide, C16H15ClN2O2
  33. Synthesis and crystal structure of bis{2-(tert-butyl)-6-((E)-((4-((E)-1-(methoxyimino) ethyl)phenyl)imino)methyl)phenolato-κ2N,O}cobalt(II), C40H46CoN4O4
  34. Crystal structure of tetraaqua-[(1-(carboxymethyl)-1H-pyrazole-3-carboxylato-κ2N,O)cobalt(II)], C6H12CoN2O8
  35. (6R,7S)-2,3,13-trimethoxy-6,7-dimethyl-5,6,7,8-tetrahydrobenzo[3′,4′]cycloocta [1′,2′:4,5]benzo[1,2-d][1,3]dioxol-1-ol, C22H26O6
  36. Crystal structure of 2-((2,6-dichloro-4-(3,5-dimethylisoxazol-4-yl)phenyl)amino)benzoic acid, C18H14Cl2N2O3
  37. Crystal structure of (5aS,6aS,8aR,9R,11aS, 11bS,13R,13aS)-1,1,8a,11a-tetramethyl-9-((S)-1-((S)-5-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)ethyl)-3-oxo-1,7,8,8a,9,10,11,11a,11b,12,13,13a-dodecahydro-3H,6H-cyclopenta[5,6]cyclopropa[1,8a]naphtho[2,1-c]oxepin-13-yl acetate, C32H44O6
  38. Crystal structure of catena-poly[triaqua-(μ2-1-(4-carboxylatophenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylato-O,O′:O″)cobalt(II)], C12H12N2O8Co
  39. Crystal structure of 3-[(furan-2-ylmethyl)-amino]-2-(2,3,4,5-tetrafluoro-benzoyl)-acrylic acid ethyl ester, C17H13F4NO4
  40. Crystal structure of methyl 4-(2-ethoxy-2-oxoethoxy)-3-methoxybenzoate, C13H16O6
  41. Crystal structure of 4-bromo-2-(4-chlorophenyl)-1-methyl-5-(trifluoromethyl)-1H-pyrrole-3-carbonitrile, C13H7BrClF3N2
  42. The crystal structure of triaqua-(8-carboxymethoxy-quinoline-2-carboxylate-κ3N,O,O)nickel(II) monohydrate, C12H15NO9Ni
  43. Crystal structure of dihydroxy(2,4,6-triisopro-pylphenyl)telluronium trifluoromethanesulfonate, C16H25F3O5STe
  44. The crystal structure of 1-(carboxymethyl)-1H-imidazole 3-oxide
  45. The crystal structure of 1,3,5-tris(dibromomethyl)benzene, C9H6Br6
  46. Crystal structure of (Z)-3-(4-methoxyphenyl)-4-(5-methyl-1-phenyl-1H-1,2,3-triazol-4-yl)-N-phenylthiazol-2(3H)-imine, C25H21N5OS
  47. Crystal structure of (Z)-3-(3-(4-hydroxyphenyl)-2-(phenylimino)-2,3-dihydrothiazol-4-yl)-2H-chromen-2-one, C24H16N2O3S
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