Home Crystal structure of 3-(tert-butyldiphenylsilyl)-1-(2,6-dichlorophenyl)-2,2-diphenylpropan-1-ol, C37H36Cl2OSi
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Crystal structure of 3-(tert-butyldiphenylsilyl)-1-(2,6-dichlorophenyl)-2,2-diphenylpropan-1-ol, C37H36Cl2OSi

  • Shu-Liang Zhang , Zhao-Zhao Zhou and Xi Chen ORCID logo EMAIL logo
Published/Copyright: December 13, 2023
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 239 Issue 1

Abstract

C37H36Cl2OSi, monoclinic P21/n (no. 14), a = 10.4363(14) Å, b = 17.128(2) Å, c = 17.875(3) Å, β = 90.934(2)°, V = 3194.8(8) Å3, Z = 4, R gt (F) = 0.0491, wR ref (F2) = 0.1449, T = 296.15 K.

CCDC no.: 2294926

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colourless block
Size: 0.12 × 0.11 × 0.08 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 0.27 mm−1
Diffractometer, scan mode: Bruker APEX-II, φ and ω
θmax, completeness: 27.4°, >99 %
N(hkl)measured, N(hkl)unique, Rint: 18,849, 7173, 0.030
Criterion for Iobs, N(hkl)gt: Iobs > 2σ(Iobs), 4927
N(param)refined: 382
Programs: CrysAlisPro [1], SHELX [2, 3], Diamond [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z Uiso*/Ueq
C1 0.4110 (2) 0.38280 (13) 0.89461 (12) 0.0413 (5)
C2 0.4680 (3) 0.37858 (17) 0.97448 (13) 0.0568 (7)
C3 0.2924 (2) 0.32905 (17) 0.89086 (16) 0.0592 (7)
C4 0.3661 (3) 0.46710 (16) 0.87892 (17) 0.0610 (7)
C5 0.6962 (2) 0.39311 (13) 0.83799 (12) 0.0387 (5)
C6 0.7158 (3) 0.46516 (15) 0.87236 (15) 0.0544 (6)
C7 0.8369 (3) 0.49780 (19) 0.8807 (2) 0.0760 (9)
C8 0.9423 (3) 0.4586 (2) 0.85429 (19) 0.0818 (10)
C9 0.9268 (3) 0.3873 (2) 0.82068 (17) 0.0722 (9)
C10 0.8053 (2) 0.35490 (17) 0.81292 (14) 0.0529 (6)
C11 0.5509 (2) 0.23854 (12) 0.83889 (12) 0.0361 (5)
C12 0.6332 (2) 0.20960 (14) 0.89511 (14) 0.0482 (6)
C13 0.6387 (3) 0.13056 (16) 0.91247 (17) 0.0609 (7)
C14 0.5637 (3) 0.07835 (15) 0.87313 (18) 0.0643 (8)
C15 0.4824 (3) 0.10414 (15) 0.81750 (18) 0.0636 (8)
C16 0.4756 (3) 0.18340 (14) 0.80053 (15) 0.0518 (6)
C17 0.4507 (2) 0.36066 (13) 0.72768 (12) 0.0345 (5)
C18 0.49834 (19) 0.40564 (11) 0.65783 (11) 0.0315 (4)
C19 0.5053 (2) 0.49315 (12) 0.67961 (11) 0.0354 (5)
C20 0.3962 (2) 0.54074 (14) 0.67906 (15) 0.0514 (6)
C21 0.4019 (3) 0.61707 (15) 0.70533 (17) 0.0622 (7)
C22 0.5156 (3) 0.64795 (15) 0.73170 (16) 0.0615 (8)
C23 0.6237 (3) 0.60274 (14) 0.73229 (15) 0.0554 (7)
C24 0.6182 (2) 0.52604 (13) 0.70675 (13) 0.0440 (5)
C25 0.62576 (19) 0.37517 (12) 0.62846 (11) 0.0330 (4)
C26 0.6687 (2) 0.29965 (13) 0.64399 (13) 0.0440 (5)
C27 0.7802 (3) 0.27077 (17) 0.61177 (15) 0.0595 (7)
C28 0.8491 (3) 0.31643 (19) 0.56355 (17) 0.0644 (8)
C29 0.8086 (2) 0.39063 (17) 0.54715 (15) 0.0554 (7)
C30 0.6988 (2) 0.42010 (13) 0.57962 (13) 0.0416 (5)
C31 0.3906 (2) 0.39440 (13) 0.59428 (11) 0.0373 (5)
C32 0.3595 (2) 0.30944 (14) 0.57629 (12) 0.0404 (5)
C33 0.2567 (3) 0.27159 (18) 0.61096 (14) 0.0606 (8)
C34 0.2315 (4) 0.1923 (2) 0.60193 (19) 0.0885 (13)
C35 0.3063 (5) 0.1491 (2) 0.5555 (2) 0.0947 (13)
C36 0.4003 (4) 0.18283 (17) 0.51649 (18) 0.0711 (9)
C37 0.4253 (2) 0.26193 (15) 0.52568 (13) 0.0481 (6)
Cl1 0.14991 (7) 0.32299 (7) 0.66617 (5) 0.0914 (3)
Cl2 0.54013 (7) 0.29926 (5) 0.46575 (4) 0.0664 (2)
H00A 0.312120 0.415468 0.615897 0.045*
H00D 0.673162 0.470878 0.568640 0.050*
H00F 0.622512 0.268122 0.676217 0.053*
H00G 0.692384 0.495976 0.707931 0.053*
H00H 0.685547 0.244241 0.921510 0.058*
H00I 0.796519 0.306244 0.790320 0.063*
H00K 0.419719 0.200133 0.762789 0.062*
H00L 0.645447 0.492285 0.890302 0.065*
H00M 0.318714 0.520987 0.660866 0.062*
H00N 0.701018 0.623307 0.749786 0.067*
H00O 0.854773 0.421340 0.514199 0.067*
H00P 0.518915 0.699135 0.748991 0.074*
H00Q 0.328167 0.647547 0.705064 0.075*
H00E 0.256822 0.329467 0.840988 0.089*
H00J 0.229378 0.347467 0.925211 0.089*
H00R 0.317086 0.276790 0.904061 0.089*
H00T 0.807922 0.220452 0.622975 0.071*
H00U 0.923164 0.296936 0.542108 0.077*
H00S 0.498778 0.326670 0.984133 0.085*
H00V 0.403085 0.391529 1.009837 0.085*
H00W 0.537709 0.414899 0.979276 0.085*
H00X 0.693080 0.113025 0.950636 0.073*
H 0.308469 0.483325 0.917241 0.092*
HA 0.322897 0.469177 0.831140 0.092*
H00Y 0.439017 0.501258 0.878629 0.092*
H00Z 0.568105 0.025385 0.884314 0.077*
H00 0.431712 0.068681 0.791019 0.076*
H00B 0.366 (2) 0.3832 (13) 0.7388 (12) 0.040 (6)*
H00C 0.433 (2) 0.3072 (14) 0.7114 (13) 0.045 (7)*
H004 0.479602 0.427307 0.511119 0.077*
H010 0.997759 0.360589 0.803019 0.087*
H011 0.846969 0.545990 0.904040 0.091*
H012 0.448356 0.153344 0.483470 0.085*
H013 0.164485 0.168925 0.627263 0.106*
H014 1.023538 0.480501 0.859271 0.098*
H015 0.291980 0.095749 0.550824 0.114*
O1 0.41224 (17) 0.44062 (10) 0.53036 (9) 0.0514 (4)
Si1 0.53266 (5) 0.34733 (3) 0.82295 (3) 0.03081 (14)

1 Source of materials

An improved synthesis was performed which was similar to the previously report [5], [6], [7], [8]. To the solution of 2,6-dichlorobenzaldehyde (1.75 g, 10.0 mmol) in anhydrous 1,4-dioxane (100 mL) was added tert-butyldiphenylsilanecarboxylic acid (4.26 g, 15.0 mmol), 1,1-diphenylethylene (2.70 g, 15.0 mmol), NaHCO3 (0.84 g, 10.0 mmol) and organic photo catalyst 4CzIPN (394 mg, 0.5 mmol) under argon atmosphere. After addition, the reaction mixture was irradiated under 440 nm Kessil light for 12 h. TLC detection showed the reaction was finished. After simple filtration by silicon gel, the solvent was removed in vacuo. The obtained residue was dissolved in dichloromethane (100 mL), washed with water (50 mL × 2), brine (50 mL × 2), and dried over anhydrous MgSO4. After filtration, the solvent was evaporated in vacuo. The obtained residue was purified by column chromatography to afford white solid of 3-(tert-butyldiphenylsilyl)-1-(2,6-dichlorophenyl)-2,2-diphenylpropan-1-ol (4.38 g, 72 %), which was further purified by recrystallization from hexane and ethyl acetate. Crystals were obtained by slow evaporation from the solution at 268–270 K.

2 Experimental details

Carbon bound hydrogen atoms were included using riding models. For the OH group additionally a rotation about the C–O bond was allowed.

3 Comment

The 3-(tert-butyldiphenylsilyl)-1-(2,6-dichlorophenyl)-2,2-diphenylpropan-1-ol is a product formed by the reductive radical polar crossover (RPC)-type reaction [9], in which the anion is generated from single-electron reduction. RPC reactions have been proven useful in the formation of multiple bonds in a single transformation, including a multicomponent reaction (MCR) manifold [10]. In this paper, a silane radical was produced through single electron oxidation and decarboxylation of tert-butyldiphenylsilanecarboxylic acid anion, which then was added to the olefin to form carbon-centered radical. Next, carbon anion was achieved after single-electron reduction with low-valence organic photo catalyst 4CzIPN. Finally, carbon anion can then be added to aldehyde to provide the 3-silyl-propan-1-ol derivative. Different from Nozaki–Hiyama-Kishi type reaction [11], multicomponent strategy of reductive RPC reactions without alkyl metal species was rarely reported [8], especially with silane radical. Crystals of 3-(tert-butyl diphenylsilyl)-1-(2,6-dichlorophenyl)-2,2-diphenylpropan-1-ol were obtained by continuous adjustment of crystallization conditions, which revealed the specific structure of the multicomponent RPC reaction product with silanecarboxylic acid for the first time. In the meantime, this result also provides direct structural proof for the structure of the previous report [8], which is very significant for further understanding 3-silyl-propan-1-ol derivative and multicomponent RPC reaction. The title structure (see the Figure) was reported for the first time in this paper. This crystal structure is a racemic alcohol with a chiral carbon atom (C31). The propyl alcohol was linked to a 2,6-dichlorophenyl at C31, two phenyl at C18, and a silyl group at C17. The bond lengths and angles are in the expected ranges [12, 13].

Corresponding author: Xi Chen, Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, P.R. China, E-mail:

Funding source: Nanchang Normal University

Award Identifier / Grant number: NSBSJJ2020009

Funding source: Ph.D. Programs Foundation of Jiangxi Science and Technology Normal University

Funding source: Science and Technology project of Jiangxi Provincial Education Office

Award Identifier / Grant number: GJJ2201329

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by from the Nanchang Normal University (NSBSJJ2020009), the Ph.D. Programs Foundation of Jiangxi Science and Technology Normal University，the Science and Technology project of Jiangxi Provincial Education Office (GJJ2201329).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Oxford Diffraction Ltd. CrysAlisPRO: Abingdon, Oxfordshire, England, 2006.Search in Google Scholar

2. Sheldrick, G. M. Shelxtl – integrated space-group and crystal-structure determination. Acta Crystallogr. 2015, A71, 3–8.10.1107/S2053273314026370Search in Google Scholar PubMed PubMed Central

3. Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Search in Google Scholar

4. Brandenburg, K. DIAMOND. Visual Crystal Structure Information System. Ver. 4.0; Crystal Impact: Bonn, Germany, 2015.Search in Google Scholar

5. Venditto, N. J., Boerth, J. A. Photoredox-catalyzed multi-component synthesis of functionalized γ-amino butyric acids via reductive radical polar crossover. Org. Lett. 2023, 25, 3429–3434; https://doi.org/10.1021/acs.orglett.3c00991.Search in Google Scholar PubMed

6. Cheng, Y.-Y., Hou, H.-Y., Liu, Y., Yu, J.-X., Chen, B., Tung, C.-H., Wu, L. α–Acylation of alkenes by a single photocatalyst. Angew. Chem. Int. Ed. 2022, 61, e202208831; https://doi.org/10.1002/anie.202208831.Search in Google Scholar PubMed

7. Bao, Q.-F., Li, M., Xia, Y., Wang, Y.-Z., Zhou, Z.-Z., Liang, Y.-M. Visible-light-mediated decarboxylative radical addition bifunctionalization cascade for the production of 1,4-amino alcohols. Org. Lett. 2021, 23, 1107–1112; https://doi.org/10.1021/acs.orglett.1c00034.Search in Google Scholar PubMed

8. Hou, J., Ee, A., Cao, H., Ong, H.-W., Xu, J.-H., Wu, J. Visible-light-mediated metal-free difunctionalization of alkenes with CO2 and silanes or C(sp3)–H alkanes. Angew. Chem. Int. Ed. 2018, 57, 17220–17224; https://doi.org/10.1002/anie.201811266.Search in Google Scholar PubMed

9. Pitzer, L., Schwarz, J. L., Glorius, F. Reductive radical-polar crossover: traditional electrophiles in modern radical reactions. Chem. Sci. 2019, 10, 8285–8291; https://doi.org/10.1039/c9sc03359a.Search in Google Scholar PubMed PubMed Central

10. Sharma, S., Singh, J., Sharma, A. Visible light assisted radical-polar/polar-radical crossover reactions in organic synthesis. Adv. Synth. Catal. 2021, 363, 3146–3169; https://doi.org/10.1002/adsc.202100205.Search in Google Scholar

11. Schwarz, J. L., Schäfers, F., Tlahuext-Aca, A., Lückemeier, L., Glorius, F. Diastereoselective allylation of aldehydes by dual photoredox and chromium catalysis. J. Am. Chem. Soc. 2018, 140, 12705–12709; https://doi.org/10.1021/jacs.8b08052.Search in Google Scholar PubMed

12. Bauer, J. O., The crystal structure of adamantylmethoxydiphenylsilane, C23H28OSi. Z. Krist. - New Cryst. Struct. 2021, 236, 1117–1120; https://doi.org/10.1039/c8sc05677c.Search in Google Scholar PubMed PubMed Central

13. Lei, Z., Xue, F., Wang, B., Wang, S., Xia, Y., Zhang, Y., Jin, W., Liu, C., CSD Communication, 2023.Search in Google Scholar
Received: 2023-10-12
Accepted: 2023-11-13
Published Online: 2023-12-13
Published in Print: 2024-02-26

© 2023 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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https://doi.org/10.1515/ncrs-2023-0450
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of poly[diaqua-(μ4-3,3′-di(1H-1,2,4-triazol-1-yl)-[1,1′-biphenyl]-4,4′-dicarboxylate-N:N′:O:O′)cadmium(II)], C18H14N6O6Cd
  4. Crystal structure of (8R,8′S,13S,13′R)-8,8′-bis(hydroxymethyl)-9,9′,10,10′-tetramethoxy-5,5′,6,6′,8,8′,13,13′-octahydro-[13,13′-bi[1,3]dioxolo[4,5-g]isoquinolino[3,2-a]isoquinoline]-7,7′-diium chloride-methanol (1/2), C46H58N2O14Cl2
  5. The crystal structure of 8-methoxy-2,2-diphenyl-tosyl-1,2-dihydro-2λ4,3λ4-[1,3,2]diazaborolo[4,5,1-ig]quinoline, C29H25BN2O3S
  6. Crystal structure of aqua-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N″,N‴)copper(II) 5-carboxyisophthalate tetrahydrate, C25H50N4CuO11
  7. The crystal structure of 1-(naphthalen-2-ylsulfonyl)-2,2-diphenyl-1,2-dihydro-2λ4,3λ4-[1,3,2]diazaborolo[4,5,1-ij]quinoline, C31H23BN2O2S
  8. Crystal structure of iodido-(η6-benzene) (1-(pyridin-2-yl)-N-(p-fluoro-methanamine)-κ2N,Nʹ)ruthenium(II) hexaflourophosphate, (C18H15F7IN2RuP)
  9. The crystal structure of 1-(3-oxo-1-phenyl-3-(p-tolyl) propylidene)-1,3-dihydro-2H-inden-2-one, C25H20O2
  10. Crystal structure of tricyclohexyl[4-(4H-1,2,4-triazol-4-yl)-benzoato-κO]tin(IV), C27H39N3O2Sn
  11. Crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylate-κ4N,O,O,O)cadmium(II)]monohydrate, C12H15NO9Cd
  12. Crystal structure of ethyl 2-((4-(3,5-dimethylisoxazol-4-yl)-2,6-difluorophenyl)amino)benzoate, C20H18F2N2O3
  13. The crystal structure of 2-(hydroxymethyl)-2-(4H-1,2,4-triazol-4-yl)propane-1,3-diol, C6H11N3O3
  14. The crystal structure of 1,2-bis(2,4-dinitrophenyl) hydrazine, C12H8N6O8
  15. Crystal structure of 1-(2,6-dichloro-4-(3,5-dimethylisoxazol-4-yl)phenyl)-1,2-dihydro-4H-benzo[d][1,3]oxazin-4-one, C19H14Cl2N2O3
  16. The crystal structure of 5-amino-5-oxo-4-(1-oxo-4-(2-oxopyrrolidin-1-yl)isoindolin-2-yl)pentanoic acid, C17H19N3O5
  17. Crystal structure of N2,N6-bis(2-(((Z)-5-bromo-2-hydroxybenzylidene)amino) phenyl)pyridine-2,6-dicarboxamide, C33H23Br2N5O4
  18. The crystal structure of (E)-2-methoxy-6-(((5-methyl-1,3,4-thiadiazol-2-yl)imino)methyl)phenol, C11H11N3O2S
  19. The crystal structure of 3-((tert-butyldiphenylsilyl)methyl)-5,5-diphenyl-6-(p-tolyl) tetrahydro-2H-pyran-2-one, C41H42O2Si
  20. Crystal structure of 9-fluoro-4-(6-methoxypyridin-3-yl)-5,6-dihydrobenzo[h]quinazolin-2-amine, C18H15FN4O
  21. The crystal structure of 2-bromo-5-(4-cyanophenoxy)benzyl 1-methyl-1,2,5,6-tetrahydropyridine-3-carboxylate, C21H19BrN2O3
  22. Crystal structure of 3,3′-(1,4-phenylenebis(methylene))bis(1-isopropyl-1H-imidazol-3-ium) bis(hexafluorophosphate(V)), C10H14F6N2P
  23. The crystal structure of 2,2-di(thiophen-3-yl)-1-tosyl-1,2-dihydro-2λ4,3λ4-[1,3,2]diazaborolo[4,5,1-ig]quinoline, C24H19BN2O2S3
  24. Crystal structure of 5-bromo-1-(2-iodobenzoyl)-1H-indole-3-carbaldehyde, C16H9BrINO2
  25. The crystal structure of monocarbonyl-2-carboxypyridinato-κ2N,O-triphenylphosphine-rhodium(I) acetonitrile solvate, C26H20.50N1.50O3PRh
  26. Crystal structure of dichlorido-tetrakis(1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pent-1-en-3-ol-κ1N)manganese(II), C60H68O4N12Cl10Mn
  27. Crystal structure of 3-(tert-butyldiphenylsilyl)-1-(2,6-dichlorophenyl)-2,2-diphenylpropan-1-ol, C37H36Cl2OSi
  28. Crystal structure of langite from Mine du Pradet (France)
  29. The crystal structure of 5′-(furan-2-yl)-3′-((4-methylphenyl)sulfonamido)-3′,4′,5′,6′-tetrahydro-[1,1′:3′,1″-terphenyl]-4′-carboxylic acid, C30H27NO5S
  30. Synthesis and crystal structure of bis{2-(((4-acetophenone)imino)methyl)-4-fluorophenolato-κ2N,O}zinc(II), C30H22F2N2O4Zn
  31. The crystal structure of poly[(tripyridine-κ3N,N′,N″) μ3-(pyridine-3,4-dicarboxylate-κ3N:O:O′) manganese(II)], C22H22N4O8Mn
  32. The crystal structure of (E)-4-chloro-N′-(1-(4-hydroxyphenyl)propylidene)benzohydrazide, C16H15ClN2O2
  33. Synthesis and crystal structure of bis{2-(tert-butyl)-6-((E)-((4-((E)-1-(methoxyimino) ethyl)phenyl)imino)methyl)phenolato-κ2N,O}cobalt(II), C40H46CoN4O4
  34. Crystal structure of tetraaqua-[(1-(carboxymethyl)-1H-pyrazole-3-carboxylato-κ2N,O)cobalt(II)], C6H12CoN2O8
  35. (6R,7S)-2,3,13-trimethoxy-6,7-dimethyl-5,6,7,8-tetrahydrobenzo[3′,4′]cycloocta [1′,2′:4,5]benzo[1,2-d][1,3]dioxol-1-ol, C22H26O6
  36. Crystal structure of 2-((2,6-dichloro-4-(3,5-dimethylisoxazol-4-yl)phenyl)amino)benzoic acid, C18H14Cl2N2O3
  37. Crystal structure of (5aS,6aS,8aR,9R,11aS, 11bS,13R,13aS)-1,1,8a,11a-tetramethyl-9-((S)-1-((S)-5-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)ethyl)-3-oxo-1,7,8,8a,9,10,11,11a,11b,12,13,13a-dodecahydro-3H,6H-cyclopenta[5,6]cyclopropa[1,8a]naphtho[2,1-c]oxepin-13-yl acetate, C32H44O6
  38. Crystal structure of catena-poly[triaqua-(μ2-1-(4-carboxylatophenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylato-O,O′:O″)cobalt(II)], C12H12N2O8Co
  39. Crystal structure of 3-[(furan-2-ylmethyl)-amino]-2-(2,3,4,5-tetrafluoro-benzoyl)-acrylic acid ethyl ester, C17H13F4NO4
  40. Crystal structure of methyl 4-(2-ethoxy-2-oxoethoxy)-3-methoxybenzoate, C13H16O6
  41. Crystal structure of 4-bromo-2-(4-chlorophenyl)-1-methyl-5-(trifluoromethyl)-1H-pyrrole-3-carbonitrile, C13H7BrClF3N2
  42. The crystal structure of triaqua-(8-carboxymethoxy-quinoline-2-carboxylate-κ3N,O,O)nickel(II) monohydrate, C12H15NO9Ni
  43. Crystal structure of dihydroxy(2,4,6-triisopro-pylphenyl)telluronium trifluoromethanesulfonate, C16H25F3O5STe
  44. The crystal structure of 1-(carboxymethyl)-1H-imidazole 3-oxide
  45. The crystal structure of 1,3,5-tris(dibromomethyl)benzene, C9H6Br6
  46. Crystal structure of (Z)-3-(4-methoxyphenyl)-4-(5-methyl-1-phenyl-1H-1,2,3-triazol-4-yl)-N-phenylthiazol-2(3H)-imine, C25H21N5OS
  47. Crystal structure of (Z)-3-(3-(4-hydroxyphenyl)-2-(phenylimino)-2,3-dihydrothiazol-4-yl)-2H-chromen-2-one, C24H16N2O3S
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