Home The crystal structure of dimethylammonium catena-[di(μ-aqua)-bis(μ9-benzene-1,3,5-tricarboxylato)pentalithium], C20H16Li5NO13
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The crystal structure of dimethylammonium catena-[di(μ-aqua)-bis(μ9-benzene-1,3,5-tricarboxylato)pentalithium], C20H16Li5NO13

  • Ying Li , Yu-Cai Qin and Bao-Kuan Chen ORCID logo EMAIL logo
Published/Copyright: September 9, 2020
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 235 Issue 6

Abstract

C20H16Li5NO13, orthorhombic, Pnma (no. 62), a = 9.9218(8) Å, b = 14.6941(11) Å, c = 13.5697(10) Å, V = 1978.4(3) Å3, Z = 4, Rgt(F) = 0.0439, wRref(F2) = 0.0960, T = 173(2) K.

CCDC no.: 1442769

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Colorless block
Size:0.21 × 0.17 × 0.14 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:0.14 mm−1
Diffractometer, scan mode:Bruker D8 quest, φ and ω
θmax, completeness:26.4°, >99%
N(hkl)measured, N(hkl)unique, Rint:9719, 2086, 0.085
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 1430
N(param)refined:190
Programs:Bruker [1], SHELX [2], Olex2 [3]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
C10.3316(2)0.61540(14)0.98985(15)0.0111(5)
C20.3527(2)0.58610(14)0.89394(15)0.0119(5)
H20.2775250.5758260.8520470.014*
C30.4824(2)0.57152(14)0.85810(15)0.0113(5)
C40.5925(2)0.58884(14)0.91913(15)0.0118(5)
H40.6811950.5775460.8957620.014*
C50.5737(2)0.62253(14)1.01400(15)0.0112(5)
C60.4426(2)0.63586(14)1.04877(16)0.0123(5)
H60.4290380.6591361.1133260.015*
C70.1928(2)0.61438(15)1.03547(15)0.0121(5)
C80.5016(2)0.52939(14)0.75820(15)0.0121(5)
C90.6919(2)0.63341(14)1.08296(15)0.0126(5)
C101.0615(4)0.7500000.8549(3)0.0276(9)
H10A1.1348570.7500000.9032120.041*
H10B1.0681370.8044600.8134820.041*
C110.8155(4)0.7500000.8361(3)0.0290(9)
H11A0.7304140.7500000.8727530.044*
H11B0.8202040.6955400.7945130.044*
Li10.2258(4)0.5644(3)1.2248(3)0.0177(8)
Li20.0494(4)0.4660(3)0.9122(3)0.0190(9)
Li30.1297(6)0.7500001.2191(4)0.0200(12)
N10.9301(3)0.7500000.9062(2)0.0294(8)
H10.925(3)0.7991(14)0.9455(16)0.035*
O10.18033(14)0.64744(10)1.12066(10)0.0152(4)
O20.09736(14)0.57719(10)0.98906(10)0.0160(4)
O30.40498(14)0.53272(10)0.69771(10)0.0153(4)
O40.61176(15)0.49114(10)0.73767(10)0.0167(4)
O50.80962(14)0.62671(11)1.04832(10)0.0175(4)
O60.66678(14)0.64572(10)1.17317(10)0.0156(4)
O7−0.0669(2)0.7500001.20898(17)0.0235(6)
H7−0.101(2)0.7056(14)1.1784(16)0.028*

Source of material

A mixture of 1,3,5-benzenetricarboxylic acid (H3BTC; 0.21 g, 1 mmol), LiOH ⋅ H2O (0.125 g, 3 mmol) and N,N′-dimethylacetamide (10 mL) was sealed in a 25 mL Teflon-lined stainless steel vessel and heated at 120 °C for 4320 mins. Yield: 50% based on Li.

Experimental details

The hydrogen atoms from O and N atoms were positioned based on difference electron peaks and refined freely with O7—H7 = 0.844 Å (Uiso(H) = 1.2Ueq(O)) and N1—H1 = 0.899 Å (Uiso(H) = 1.2Ueq(N)).

Comment

Metal-organic frameworks (MOFs) are porous materials composed of metal ions/clusters and organic units, which have the characteristics of porosity, high specific surface area and are easy to modify. MOFs and CPs are widely used in gas storage and separation [4], fluorescent responses [5], proton conductivity [6], membrane separation [7], [8], environmental pollution control [9], [10] and energy conversion [11], [12]. However, most of the MOFs are constructed from the transition metals or rare earth, and the alkali-metal-based MOFs are rare examples, particularly the lithium-based MOFs [13], [14]. Compared to other metals, the lithium-based MOFs can enhance gravimetric energy storage capacity more effectively, so we are interested in embarking on the synthesis of the lightest lithium-based MOFs.

Single crystal X-ray analysis reveals that the title compound crystallizes orthorhombically in the space group Pnma and contains three crystallographically independent Li ions (two in general positions one on a mirror plane). The Li1 center adopts four-coordinated geometry with four O atoms from different BTC ligands (Li1–O:1.887–1.920 Å). The Li2 center is five-coordinated with the square pyramidal geometry and the Li–O bond lengths are in the range of Li2–O: 1.996–2.289 Å. Although the Li3 center also adopts five-coordinated geometry, one coordinated O atom is from one water (Li3–O:1.954–2.149 Å). Note, the oxygen atoms offered by BTC anions connect different Li ions to form a complex 3D framework, which is completely different from other reported skeleton structures based on lithium and BTC [15], [16], [17].

Acknowledgements

This work was supported by the Natural Science Foundation of Liaoning Shihua University (2019XJJL-019).

References

1. Bruker. SAINTv8.37A. Bruker AXS Inc, Madison, WI, USA (2015).Search in Google Scholar

2. Sheldrick, G. M.: Crystal structure refinement with SHELXL. Acta Crystallogr. C71 (2015) 3–8.10.1107/S2053229614024218Search in Google Scholar PubMed PubMed Central

3. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H.: OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr. 42 (2009) 339–341.10.1107/S0021889808042726Search in Google Scholar

4. Du, X.; Fan, R. Q.; Qiang, L. S.; Song, Y.; Xing, K.; Chen, W.; Wang, P.; Yang, Y. L.: Unusually flexible indium(III) metal–organic polyhedra materials for detecting trace amounts of water in organic solvents and high proton conductivity. Inorg. Chem. 56 (2017) 3429–3439.10.1021/acs.inorgchem.6b02963Search in Google Scholar PubMed

5. Liu, G. C.; Li, Y.; Chi, J.; Xu, N.; Wang, X. L.; Lin, H. Y.; Chen, Y. Q.: Multi-functional fluorescent responses of cobalt complexes derived from functionalized amide-bridged ligand. Dyes Pigm. 174 (2020) 108064–108073.10.1016/j.dyepig.2019.108064Search in Google Scholar

6. Ma, X. J.; Chai, Y.; Li, P.; Wang, B.: Metal–organic framework films and their potential applications in environmental pollution control. Acc. Chem. Res. 52 (2019) 1461–1470.10.1021/acs.accounts.9b00113Search in Google Scholar PubMed

7. Li, S. W.; Dong, Y.; Zhou, J. W.; Liu, Y.; Wang, J. M.; Gao, X.; Han, Y. Z.; Qi, P. F.; Wang, B.: Carbon dioxide in the cage: manganese metal–organic frameworks for high performance CO2 electrodes in Li–CO2 batteries. Energy Environ. Sci. 11 (2018) 1318–1325.10.1039/C8EE00415CSearch in Google Scholar

8. Dong, Y. Y.; Zhang, J.; Yang, Y. L.; Qiu, L. L.; Xia, D. B.; Lin, K. F.; Wang, J. Q.; Fan, X.; Fan, R. Q.: Self-assembly of hybrid oxidant POM@Cu-BTC for enhanced efficiency and long–term stability of perovskite solar cells. Angew. Chem. Int. Ed. 58 (2019) 17610–17615.10.1002/anie.201909291Search in Google Scholar PubMed

9. Zheng, S. T.; Li, Y. F.; Wu, T.; Nieto, R. A.; Feng, P. Y.; Bu, X. H.: Porous lithium imidazolate frameworks constructed with charge-complementary ligands. Chem. Eur. J. 16 (2010) 13035–13040.10.1002/chem.201002316Search in Google Scholar PubMed PubMed Central

10. Yeung, H. H. M.; Kosa, M.; Parrinello, M.; Forster, P. M.; Cheetham, A. K.: Structural diversity and energetics in anhydrous lithium tartrates: experimental and computational studies of novel chiral polymorphs and their racemic and meso analogues. Cryst. Growth Des. 11 (2011) 221–230.10.1021/cg101170kSearch in Google Scholar

11. Osta, R. E.; Frigoli, M.; Marrot, J.; Guillou, N.; Chevreau, H.; Walton, R. I.; Millange, F. A.: Lithium–organic framework with coordinatively unsaturated metal sites that reversibly binds water. Chem. Commun. 48 (2012) 10639–10641.10.1039/c2cc35861aSearch in Google Scholar PubMed

12. Ong, T. T.; Kavuru, P.; Nguyen, T.; Cantwell, R.; Wojtas, Ł.; Zaworotko, M. J.: 2:1 Cocrystals of homochiral and achiral amino acid zwitterions with Li+ salts: water-stable zeolitic and diamondoid metal-organic materials. J. Am. Chem. Soc. 133 (2011) 9224–9227.10.1021/ja203002wSearch in Google Scholar PubMed

13. Kim, T. K.; Lee, J. H.; Moon, D.; Moon, H. R.: Luminescent Li-based metal-organic framework tailored for the selective detection of explosive nitroaromatic compounds: direct observation of interaction sites. Inorg. Chem. 52 (2013) 589–595.10.1021/ic3011458Search in Google Scholar PubMed

14. Abrahams, B. F.; Grannas, M. J.; Hudson, T. A.; Robson, R.: A simple lithium(I) salt with a microporous structure and its gas sorption properties. Angew. Chem. Int. Ed. 49 (2010) 1087–108910.1002/anie.200906322Search in Google Scholar PubMed

15. Koltunova, T. K.; Samsonenko, D. G.; Rakhmanova, M. I.; Dybtsev, D. N.; Fedin, V. P.: Synthesis, crystal structure, thermal stability, and luminescent properties of lithium trimesate coordination polymer. Russ. Chem. Bull. 64 (2015) 2903–2907.10.1007/s11172-015-1245-3Search in Google Scholar

16. Clough, A.; Zheng, S. T.; Zhao, X.; Lin, Q. P.; Feng, P. Y.; Bu, X. H.: New lithium ion clusters for construction of porous MOFs. Cryst. Growth Des. 14 (2014) 897–900.10.1021/cg4016756Search in Google Scholar

17. Jiang, Z.-Q.; Du, Y.; Zhu, X.-J.; Lu, J.; Huang, Z.-C.; Li, Y.-F.; Kang, Y.: Versatile solvothermal synthetic method and structural characterization of lithium coordination networks. J. Inorg. Organomet. Polym. Mat. 29 (2019) 1447–1456.10.1007/s10904-019-01108-0Search in Google Scholar

Received: 2020-06-02
Accepted: 2020-06-22
Published Online: 2020-09-09
Published in Print: 2020-10-27

©2020 Ying Li et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  72. Crystal structure of 4-[(3-methoxyphenyl)carbamoyl]butanoic acid, C12H15NO4
  73. Crystal structure of dichlorido-bis(tri-4-tolylphosphane oxide-κO)-di(4-chlorophenyl-κC)tin(IV), C54H50Cl4O2P2Sn
  74. Crystal structure of dichloridodimethylbis(tri-4-tolylphosphane oxide-κO)-tin(IV), C44H48Cl2O2P2Sn
  75. Crystal structure of chlorido(2-methylquinolin-8-olato-κ2N,O)-bis(4-tolyl-κC)tin(IV), C24H22ClNOSn
  76. Crystal structure of (E)-dichloro(1-chloro-3-methoxyprop-1-en-2-yl)(4-methoxyphenyl)-λ4-tellane, C11H13Cl3O2Te
  77. Crystal structure of bis{N-methyl-N′-[3-(4-methoxyphenyl)-1-methylpropane-1-ylidene]carbamohydrazonothioato}zinc(II), C26H36N6O2S2Zn
  78. Crystal structure of (2-carboxy-4-(3-carboxy-5-carboxylatophenoxy)benzoato-κ2O,O′)bis(1,10-phenantroline-κ2N,N′)cobalt(II), C40H24N4O9Co
  79. The crystal structure of (3S,8R,10R,14R)-17-((2S,5S)-5-(2-hydroxypropan-2-yl)-2-methyltetrahydrofuran-2-yl)-4,4,8,10,14-pentamethyl-12-oxohexadecahydro-1H-cyclopenta[a]phenanthren-3-yl acetate, C32H52O5
  80. Crystal structure of (μ2-1,1′-bis(diphenylphosphino)ferrocene-κ2P,P′)-bis[(Z)N-(3-fluorophenyl)-O-methylthiocarbamato-S]digold(I) chloroform solvate, C50H42Au2F2FeN2O2P2S2, CHCl3
  81. Crystal structure of poly[bis(μ2-1,4-di(1H-imidazol-1-yl)benzene-κ2N:N′)-(μ2-tetraoxidomolybdato(VI)-κ2O:O′)cobalt(II)], C24H20N8O4MoCo
https://doi.org/10.1515/ncrs-2020-0270
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Articles in the same Issue

  1. Frontmatter
  2. Crystal structure of poly[tetraaqua-bis(μ4-5-(4-carboxy-benzylamino)-isophthalato-κ4O,O′:O′′:O′′′)-(μ2-4,4′-di(1H-imidazol-1-yl)-1,1′-biphenyl-κ2N:N′)dicadmium(II)], C25H22N3O8Cd
  3. The crystal structure of 2-(2-(2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indol-2-ium-1-yl)phenoxy)acetate, C19H18N2O3
  4. Crystal structure of poly[aqua-μ2-4,4′-bipyridine-κ2N:N′)-μ2-bis(2-(2-((2,6-dichlorophenyl)amino)phenyl)acetato-κ2O,O′)zinc(II)], C38H28Cl4N4O4Zn
  5. Crystal structure of 1-(2-(1H-indol-3-yl)ethyl)-4-benzyl-3-hydroxy-3,6-diphenylpiperazine-2,5-dione, C33H29N3O3
  6. The crystal structure 2,2′-bipyridine-κ2N,N′-(2-(3-amino-4-chlorobenzoyl)benzoato-κ1O)-(2-(3-amino-4-chlorobenzoyl)benzoato-κ2O,O′)zinc(II) — ethanol (1/1), C40H32Cl2N4O7Zn
  7. Crystal structure of catena-poly[(μ3-2-carboxy-4-(3-carboxy-5-carboxylatophenoxy)benzoato-κ3O:O′:O′′)-bis(μ2-4,4′-bis(pyrid-4-yl)biphenyl-k1N)copper(II)], C60H40N4O9Cu
  8. The crystal structure of dimethylammonium catena-[di(μ-aqua)-bis(μ9-benzene-1,3,5-tricarboxylato)pentalithium], C20H16Li5NO13
  9. Crystal structure of tetraaqua-bis(3,5-di(pyridin-4-yl)-1,2,4-triazol-1-ido-κ1N)nickel(II) dihydrate, C24H28O6N10Ni
  10. The crystal structure of tetrakis(1-methylimidazole-κ1N)-oxido-(sulfato-κ1O)vanadium(IV), C16H24N8O5SV
  11. Crystal structure of methyl 2-(6,11-dioxo-2,3,6,11-tetrahydro-1H-benzo[f]pyrrolo[2,1-a]isoindole-5-carbonyl)benzoate, C24H17NO5
  12. Crystal structure of (E)-N′-(2-hydroxy-4-(2-(piperidin-1-yl)ethoxy)benzylidene) nicotinohydrazide monohydrate, C20H24N4O3 ⋅ H2O
  13. Crystal structure of poly[bis(μ3-(1-(3,5-di(1H-imidazol-1-yl)phenyl)-1H-imidazole-κ3N:N′:N′′)cobalt(II)] dinitrate — N,N-dimethylformamide (1/4), C42H52N18O10Co
  14. The crystal structure bis{hexakis(1-methyl-1H-imidazole-κ1N)cobalt(II)} tetrakis(μ3-oxido)-octakis(μ2-oxido)-tetradecaoxido-octamolybdate(VI), C24H36CoMo4N12O13
  15. Crystal structure of di-μ-nicotinato-κ2N:O; κ2O:N-bis-[aqua-bis(benzyl)(nicotinato-κ2O,O′)tin(IV)], C52H48N4O10Sn2
  16. Crystal structure of dichlorido-bis[2-(2-(3-(pyridin-2-yl)-1H-1,2,4-triazol-5-yl)phenoxy)benzoic acidmanganese(II) monohydrate, C40H30N8O7MnCl2
  17. The crystal structure of benzyl 3β-acetylglycyrrhetate, C39H54O5
  18. Synthesis and crystal structure of (E)-1-benzyl-3-(4-methoxystyryl)quinoxalin-2(1H)-one, C24H20N2O2
  19. Crystal structure of trans-dichloridobis(4-chlorophenyl-κC1)(1,10-phenanthroline-κ2N,N′)tin(IV) dimethylsulphoxide solvate, C26H22Cl4N2OSSn
  20. Crystal structure of phenyl(1,3,4a-triphenyl-4a,5,6,10b-tetrahydro-1H-[1,4]oxazino[2,3-c]quinolin-5-yl)methanone, C36H28N2O2
  21. Crystal structure of (4aS,5S,6aS,6a1S, 10aS)-4a,5,6a,6a1,9,10-hexahydro-7H-4,5-methanocyclobuta[4,5]naphtho[8a,1-b]pyran-6(2H)-one, C15H16O2
  22. Crystal structure of [(Z)-O-isopropyl N-(4-chlorophenyl)thiocarbamato-κS]-(triphenylphosphine-κP)-gold(I), C28H26AuClNOPS
  23. Crystal structure of (μ2-1,1′-bis(diphenylphosphino)ferrocene-P,P′)-bis[(Z)-O-isopropyl N-(4-chlorophenyl)thiocarbamato-S]-di-gold(I) acetonitrile di-solvate, C54H50Au2Cl2FeN2O2P2S2⋅2(C2H3N)
  24. Crystal structure of (6aR,6a1S,10aS)-2,4a,6a,6a1,9,10-hexahydro-7H-4,5-methanocyclobuta[4,5]naphtho[8a,1-b]pyran, C15H16O
  25. Crystal structure of 5,17-diformyl-25,26,27,28-tetrahydroxycalix[4]arene- dichloromethane, C31H26Cl2O6
  26. Crystal structure of 2-tert-butyl 1-methyl 5-{4-[(methoxycarbonyl)amino]phenyl}-2,5-dihydro-1H-pyrrole-1,2-dicarboxylate, C19H24N2O6
  27. Crystal structure of [2-carboxybenzene-1-thiolato-S]-(triethylphosphane-P)-gold(I), C13H20AuO2PS
  28. Synthesis and crystal structure of bis(5-methyl-2-aldehyde-phenolato-κ2O1,O2)copper(II), C16H14CuO4
  29. Crystal structure of poly[triaqua-(di(2,2′-bipyridine-κ2N,N′)-μ4-silanetetrayltetrakis(benzene-4,1-diyl)tetrakis (hydrogen phosphonato)-κ4O:O′:O′′:O′′′) dicadmium(II)], C44H42N4O15P4Cd2Si
  30. Crystal structure of bis[μ2-(N,N-diethylcarbamodithioato-κS:κS,κS′)]-bis(triethylphosphine-P)-di-silver(I), C22H50Ag2N2P2S4
  31. Crystal structure of bis[μ2-(pyrrolidine-1-carbodithioato-κS:κS,κS′)]-bis(triethylphosphine-κP)disilver(I), C22H46Ag2N2P2S4
  32. Crystal structure of bis[μ2-(N-(2-hydroxyethyl)-N-methylcarbamodithioato-κS:κS,κS′)]-bis(triethylphosphine-P)-di-silver(I), C20H46Ag2N2O2P2S4
  33. The crystal structure of (2E,2′E)-,2,2′-bis[1-(2-pyrazinyl)ethylidene]carbonimidic dihydrazide, C13H15N9
  34. The crystal structure of (E)-1-(quinolin-2-ylmethyl)-2-((1-(quinolin-2-ylmethyl)pyridin-2(1H)-ylidene)amino)pyridin-1-ium, C30H25BrN5
  35. Crystal structure of catena-poly[(μ2-1-((benzotriazol-1-yl)methyl)-1H-1,3-imdazole-κ2N:N′)-(1-((benzotriazol-1-yl)methyl)-1H-1,3-imdazole-κ1N)-(methanol-κ1O)mercury(II)] dinitrate, C21H22N12O7Hg
  36. Crystal structure of 1-(6-hydroxy-2-phenylbenzofuran-5-yl)ethan-1-one, C16H12O3
  37. The crystal structure of oxonium hexaquaaluminium disulfate hexahydrate
  38. Crystal structure of catena{(μ2-1,10-phenanthroline-κ4N,N,N′,N′)-(μ2-1,10-phenanthroline-κ3N,N,N′)potassium(I) {[bis(2-hydroxyethyl)iminiumyl](sulfanidyl)methyl}sulfanide hemi(1,10-phenanthroline)}, {C24H16KN4, 0.5(C12H8N2), C5H10NO2S2}
  39. Crystal structure of chlorido-[(N,N-di-isobutyl)dithiocarbamato-κ2S,S′]-di(4-methylbenzyl-κC)tin(IV), C25H36ClNS2Sn
  40. Crystal structure of chlorido-(η5-pentamethylcyclopentadienyl)-(4-chloro-4-pyridyl-2,2′:6′,2′′-terpyridine-κ2N,N′) rhodium(III) hexaflourophosphate, C31H29Cl2F6N3PRh
  41. The crystal structure of catena-poly[bis-(3,5-dinitro-1,2,4-triazolato-κ2N:O)-(μ2-1,4-bis(1-imidazolyl)benzene-κ2N:N′)copper(II)], C16H10CuN14O8
  42. Crystal structure of poly[triaqua-bis(μ3-3,3′-((5-carboxylato-1,3-phenylene)bis(oxy))dibenzoato)-tris(1,10-phenanthroline)cobalt(II)], C78H46N6O20Co3
  43. The crystal structure of 2,4-dihydroxybenzoic acid–nicotinamide–methanol (1/1/1), C15H18N2O6
  44. The crystal structure of aqua{N,N,N′,N′-tetrakis[(1H-benzimidazol-κN3) methyl]cyclohexane-1,2-diamine}lead(II) diacetate–methanol (1/2), C44H54N10O7Pb
  45. Crystal structure of (2-amino-5-bromo-3-iodophenyl)(3-(4-chlorophenyl)oxiran-2-yl)methanone, C15H10BrClINO2
  46. Synthesis and crystal structure of 3-octyl-5,5-diphenylimidazolidine-2,4-dione, C23H28N2O2
  47. Synthesis and crystal structure of 2-azido-N-(4-nitrophenyl)acetamide, C8H7N5O3
  48. Crystal structure of tert-butyl (1S,2R,5R)-2-(hydroxymethyl)-4-(4-methoxyphenyl)-6-oxa-3-azabicyclo[3.1.0]hexane-3-carboxylate, C17H23NO5
  49. Crystal structure of 4-[(4-methoxy-2-nitrophenyl)carbamoyl]butanoic acid, C12H14N2O6
  50. Crystal structure of 3-ethyl-1-[(E)-[(2E)-3-phenylprop-2-en-1-ylidene]amino]thiourea, C12H15N3S
  51. Crystal structure of 4,4′-bipyridin-1,1′-dium poly[bis(μ4-benzene-1,3,5-triyltris(hydrogen phosphonato-κ4O:O′:O′′:O′′′))zinc(II)], C11H11NO9P3Zn
  52. Crystal structure of (μ2-1,1′-bis(diphenylphosphino)butane-κ2P,P′)-bis[(Z)-N-(3-fluorophenyl)-O-methylthiocarbamato-κS]-di-gold(I), C44H42Au2F2N2O2P2S2
  53. Crystal structure of (μ2-1,1′-bis(diphenylphosphino)hexane-κ2P,P′)-bis[(Z)-N-(3-fluorophenyl)-O-methylthiocarbamato-κS]digold(I), C46H46Au2F2N2O2P2S2
  54. Crystal structure of tetrakis (N-(2-hydroxyethyl)-N-isopropylcarbamodithioato-κS,S′)-(μ2(2-(pyridin-4-yl)vinyl)pyridine-κN,N′)dicadmium(II), C36H58Cd2N6O4S8
  55. Crystal structure of 4-(2-(benzo[b]thiophen-2-yl)-3,3,4,4,5,5-hexafluorocyclopent-1-en-1-yl)-1,5-dimethyl-1H-pyrrole-2-carbonitrile, C20H12F6N2S
  56. Crystal structure of bis(octahydrocyclopenta[c]pyrrolium)pentachlorobismuthate(III), (C7NH14)2BiCl5
  57. The crystal structure of diaqua-tris(nitrato-κ2O,O′)-bis(4,4,5,5-tetramethyl-2-(p-pyridyl)imidazoline-1-oxyl 3-oxide-κN)samarium(III), C24H36N9O15Sm
  58. Synthesis and crystal structure of methyl 2-(2-((tert-butoxycarbonyl)amino)phenyl)-2-(4-oxo-4H-chromen-3-yl)acetate, C23H23NO6
  59. Crystal structure of O-hexyl benzoylcarbamothioate, C14H19NO2S
  60. Crystal structure of chlorido-(O-methyl phenylcarbamothioamide-κS)-bis(triphenylphosphane-κP)silver(I), C44H39AgClNOP2S
  61. Crystal structure of chlorido-(O-ethyl phenylcarbamothioamide-κS)-bis(triphenylphosphane-κP)-silver(I), C45H41AgClNOP2S
  62. Crystal structure of 4-[(2-methoxyphenyl)carbamoyl]butanoic acid, C12H15NO4
  63. Crystal structure of ethyl 4-methyl-2-oxo-5-phenyl-1,3,4-oxadiazinane-3-carboxylate, C13H16N2O4
  64. Crystal structure of catena-poly[diaqua(μ2-2-(hydroxymethyl)-1H-imidazole-4,5-dicarboxylato)cadmium(II)], C6H8CdN2O7
  65. Crystal structure of (1S)-N-(chloromethyl)-1-((4S,6aR,8aS, 8bR,9aR)-4-methoxy-6a,8a-dimethyl-1,3,4, 5,6,6a,6b,7,8,8a,9a,10,10a,10b-tetradecahydro-8bH-naphtho[2′,1′:4,5] indeno[1,2-b]oxiren-8b-yl)-N-methylethan-1-amine, C24H46ClNO5
  66. Crystal structure of 4-[(3,5-dichlorophenyl)carbamoyl]butanoic acid, C11H11Cl2NO3
  67. Crystal structure of (2Z)-2-amino-3-[(E)-[(2,4-dihydroxyphenyl)methylidene]-amino]but-2-enedinitrile, C11H8N4O2
  68. Crystal structure of 3-methyl-1-[(E)-(4-phenylbutan-2-ylidene)amino]thiourea, C12H17N3S
  69. Crystal structure of carbonyl{hydridotris[3-phenyl-5-methylpyrazol-1-yl]borato-κ3N,N′N′′}copper(I), C31H28BCuN6O
  70. Crystal structure of ethane-1,2-diylbis(diphenylphosphine oxide) – dihydrogenperoxide (1/2), C26H28O6P2
  71. Crystal structure of 2-(pyridin-2-ylamino)pyridinium chloride dibenzyldichlorostannane, [C10H10N3]Cl, C14H14Cl2Sn
  72. Crystal structure of 4-[(3-methoxyphenyl)carbamoyl]butanoic acid, C12H15NO4
  73. Crystal structure of dichlorido-bis(tri-4-tolylphosphane oxide-κO)-di(4-chlorophenyl-κC)tin(IV), C54H50Cl4O2P2Sn
  74. Crystal structure of dichloridodimethylbis(tri-4-tolylphosphane oxide-κO)-tin(IV), C44H48Cl2O2P2Sn
  75. Crystal structure of chlorido(2-methylquinolin-8-olato-κ2N,O)-bis(4-tolyl-κC)tin(IV), C24H22ClNOSn
  76. Crystal structure of (E)-dichloro(1-chloro-3-methoxyprop-1-en-2-yl)(4-methoxyphenyl)-λ4-tellane, C11H13Cl3O2Te
  77. Crystal structure of bis{N-methyl-N′-[3-(4-methoxyphenyl)-1-methylpropane-1-ylidene]carbamohydrazonothioato}zinc(II), C26H36N6O2S2Zn
  78. Crystal structure of (2-carboxy-4-(3-carboxy-5-carboxylatophenoxy)benzoato-κ2O,O′)bis(1,10-phenantroline-κ2N,N′)cobalt(II), C40H24N4O9Co
  79. The crystal structure of (3S,8R,10R,14R)-17-((2S,5S)-5-(2-hydroxypropan-2-yl)-2-methyltetrahydrofuran-2-yl)-4,4,8,10,14-pentamethyl-12-oxohexadecahydro-1H-cyclopenta[a]phenanthren-3-yl acetate, C32H52O5
  80. Crystal structure of (μ2-1,1′-bis(diphenylphosphino)ferrocene-κ2P,P′)-bis[(Z)N-(3-fluorophenyl)-O-methylthiocarbamato-S]digold(I) chloroform solvate, C50H42Au2F2FeN2O2P2S2, CHCl3
  81. Crystal structure of poly[bis(μ2-1,4-di(1H-imidazol-1-yl)benzene-κ2N:N′)-(μ2-tetraoxidomolybdato(VI)-κ2O:O′)cobalt(II)], C24H20N8O4MoCo
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