Home Physical Sciences Crystal structure of poly[triaqua-bis(μ3-3,3′-((5-carboxylato-1,3-phenylene)bis(oxy))dibenzoato)-tris(1,10-phenanthroline)cobalt(II)], C78H46N6O20Co3
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Crystal structure of poly[triaqua-bis(μ3-3,3′-((5-carboxylato-1,3-phenylene)bis(oxy))dibenzoato)-tris(1,10-phenanthroline)cobalt(II)], C78H46N6O20Co3

  • Pei-xuan Li ORCID logo EMAIL logo and Wei Hui
Published/Copyright: September 28, 2020

Abstract

C78H46N6O20Co3, monoclinic, P21/c (no. 14), a = 10.789(4) Å, b = 48.885(18) Å, c = 15.205(4) Å, β = 124.604(19)°, V = 6601(4) Å3, Z = 4, Rgt(F) = 0.0539, wRref(F2) = 0.1205, T = 293(2) K.

CCDC no.: 2013872

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Pink block
Size:0.26 × 0.21 × 0.17 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:0.83 mm−1
Diffractometer, scan mode:Bruker APEX-II, φ and ω
θmax, completeness:25.0°, >99%
N(hkl)measured, N(hkl)unique, Rint:33479, 11606, 0.051
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 8450
N(param)refined:964
Programs:SHELX [1], Bruker [2]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Co10.29610(6)0.13132(2)0.51774(4)0.03142(14)
Co2−0.25365(6)0.00405(2)0.86193(4)0.03301(14)
Co3−0.09238(6)0.19125(2)1.16675(4)0.03625(15)
O1−0.1057(3)0.03522(5)0.9002(2)0.0355(6)
O1W0.3092(3)0.13568(6)0.3870(2)0.0396(7)
H1WB0.2720400.1511040.3580730.048*
H1WC0.2554000.1233640.3414730.048*
O20.0623(3)0.02581(5)1.07235(19)0.0356(6)
O2W−0.2046(3)0.00334(6)1.01586(19)0.0400(7)
H2WB−0.2678220.0137051.0158850.048*
H2WC−0.1183320.0105651.0572450.048*
O30.0519(3)0.06144(6)0.8301(2)0.0426(7)
O3W−0.1093(3)0.18379(6)1.2898(2)0.0439(7)
H3WB−0.0643080.1964111.3360280.053*
H3WC−0.0656280.1687511.3191170.053*
O40.0441(3)0.07409(6)0.5201(2)0.0398(7)
O4W0.8921(5)0.24621(9)0.4900(3)0.0962(14)
H4WC0.9292560.2616620.5186210.115*
H4WD0.9276470.2414320.4548010.115*
O50.1543(3)0.09004(6)0.3103(2)0.0435(7)
O60.2474(3)0.09151(5)0.48322(19)0.0348(6)
O70.5686(3)0.03645(7)0.9453(2)0.0571(9)
O80.5574(3)0.03054(6)0.7961(2)0.0440(7)
O90.0297(3)0.19677(6)1.0949(2)0.0418(7)
O100.1445(3)0.17952(6)1.2540(2)0.0425(7)
O110.2002(3)0.17607(6)1.0206(2)0.0467(8)
O120.0104(4)0.26928(6)0.8735(2)0.0606(9)
O13−0.0484(3)0.26812(6)0.7085(2)0.0485(8)
O140.0528(3)0.16991(6)0.6654(2)0.0483(8)
O150.1803(3)0.13622(6)0.5916(2)0.0419(7)
O160.0538(3)0.14296(6)0.4209(2)0.0406(7)
N1−0.2986(4)−0.00518(7)0.7117(2)0.0395(8)
N2−0.4116(4)−0.02759(7)0.8106(3)0.0423(9)
N3−0.1738(4)0.15118(7)1.1102(3)0.0410(8)
N4−0.3064(4)0.19901(7)1.0288(3)0.0396(8)
N50.3873(4)0.17139(7)0.5671(3)0.0375(8)
N60.5107(3)0.12354(7)0.6556(2)0.0333(8)
C1−0.2440(5)0.00679(11)0.6637(4)0.0554(13)
H1A−0.1791680.0216080.6960640.066*
C2−0.2826(7)−0.00255(13)0.5628(4)0.0701(17)
H2A−0.2440550.0061230.5287800.084*
C3−0.3760(7)−0.02421(14)0.5168(4)0.0744(18)
H3A−0.401409−0.0304650.4507050.089*
C4−0.4338(6)−0.03706(11)0.5660(4)0.0596(14)
C5−0.3928(5)−0.02680(9)0.6641(3)0.0453(11)
C6−0.4552(5)−0.03843(9)0.7165(3)0.0433(11)
C7−0.5574(6)−0.06038(10)0.6699(4)0.0627(14)
C8−0.5934(7)−0.07000(13)0.5711(5)0.0855(19)
H8A−0.660795−0.0844840.5390740.103*
C9−0.5370(7)−0.05960(13)0.5214(5)0.0791(19)
H9A−0.564416−0.0669620.4562860.095*
C10−0.6159(6)−0.06989(12)0.7253(6)0.0812(19)
H10A−0.685125−0.0841560.6971030.097*
C11−0.5736(6)−0.05873(13)0.8188(5)0.0778(17)
H11A−0.612349−0.0651260.8561210.093*
C12−0.4719(5)−0.03768(10)0.8582(4)0.0580(13)
H12A−0.443585−0.0300070.9231190.070*
C130.0123(4)0.04023(8)0.9896(3)0.0294(9)
C140.0999(4)0.06513(8)1.0029(3)0.0299(9)
C150.1633(5)0.07982(9)1.0967(3)0.0408(10)
H15A0.1501310.0736741.1487830.049*
C160.2451(5)0.10317(9)1.1154(4)0.0529(12)
H16A0.2844910.1130411.1781820.063*
C170.2676(6)0.11164(9)1.0400(4)0.0536(12)
H17A0.3265180.1270151.0530050.064*
C180.2049(5)0.09789(9)0.9456(4)0.0445(11)
H18A0.2194970.1041120.8942680.053*
C190.1201(4)0.07483(8)0.9266(3)0.0335(9)
C200.1298(4)0.06067(8)0.7823(3)0.0349(9)
C210.2736(4)0.05104(8)0.8360(3)0.0348(9)
H21A0.3244990.0462460.9077330.042*
C220.3426(4)0.04845(8)0.7836(3)0.0317(9)
C230.2663(4)0.05527(8)0.6769(3)0.0330(9)
H23A0.3116220.0530060.6405550.040*
C240.1217(4)0.06552(8)0.6249(3)0.0326(9)
C250.0515(4)0.06827(9)0.6766(3)0.0374(10)
H25A−0.0460660.0750770.6412670.045*
C260.5022(5)0.03776(8)0.8463(3)0.0363(10)
C270.0134(4)0.05489(8)0.4435(3)0.0359(10)
C28−0.0683(5)0.03230(10)0.4326(3)0.0518(12)
H28A−0.0898760.0286240.4825970.062*
C29−0.1180(6)0.01517(10)0.3485(4)0.0619(14)
H29A−0.174455−0.0001310.3410350.074*
C30−0.0867(5)0.02004(9)0.2750(3)0.0533(13)
H30A−0.1231110.0084780.2166220.064*
C31−0.0008(5)0.04221(8)0.2886(3)0.0411(10)
H31A0.0213230.0455420.2387480.049*
C320.0546(4)0.05994(8)0.3741(3)0.0306(9)
C330.1585(4)0.08231(8)0.3896(3)0.0314(9)
C340.0606(4)0.14196(8)0.5064(3)0.0327(9)
C35−0.0800(4)0.14716(8)0.5009(3)0.0355(9)
C36−0.2150(5)0.13846(9)0.4119(4)0.0472(11)
H36A−0.2173210.1306730.3551810.057*
C37−0.3469(5)0.14116(10)0.4058(4)0.0549(13)
H37A−0.4374540.1351300.3454690.066*
C38−0.3439(5)0.15257(11)0.4876(4)0.0570(13)
H38A−0.4325200.1537610.4843520.068*
C39−0.2124(5)0.16246(10)0.5758(4)0.0472(11)
H39A−0.2124040.1707860.6307910.057*
C40−0.0808(4)0.15997(8)0.5820(3)0.0351(9)
C410.0574(4)0.18532(9)0.7441(3)0.0372(10)
C420.0181(4)0.21233(9)0.7265(3)0.0393(10)
H42A−0.0249300.2200380.6591940.047*
C430.0440(4)0.22802(8)0.8118(3)0.0343(9)
C440.1094(4)0.21643(8)0.9107(3)0.0373(10)
H44A0.1293800.2270040.9682420.045*
C450.1454(5)0.18915(8)0.9244(3)0.0366(10)
C460.1191(4)0.17322(9)0.8414(3)0.0381(10)
H46A0.1426020.1546840.8510350.046*
C470.3137(5)0.18880(8)1.1135(3)0.0393(10)
C480.4480(6)0.19495(11)1.1267(4)0.0598(14)
H48A0.4588470.1925471.0707730.072*
C490.5629(6)0.20447(12)1.2217(5)0.0661(15)
H49A0.6538500.2084681.2308660.079*
C500.5503(5)0.20845(11)1.3054(4)0.0610(14)
H50A0.6307350.2152381.3703120.073*
C510.4162(5)0.20217(10)1.2910(3)0.0526(12)
H51A0.4063390.2043841.3475650.063*
C520.2944(4)0.19256(8)1.1934(3)0.0346(9)
C530.1475(5)0.18911(8)1.1786(3)0.0340(9)
C540.3250(5)0.19484(10)0.5228(4)0.0529(12)
H54A0.2300790.1948760.4587330.063*
C550.3941(6)0.21948(10)0.5670(5)0.0669(15)
H55A0.3466220.2357350.5323990.080*
C560.5300(6)0.22005(11)0.6602(4)0.0647(14)
H56A0.5762540.2367400.6903980.078*
C570.6013(5)0.19605(9)0.7113(4)0.0461(11)
C580.5236(5)0.17167(9)0.6595(3)0.0375(10)
C590.5908(4)0.14617(8)0.7072(3)0.0318(9)
C600.7333(4)0.14525(10)0.8040(3)0.0413(11)
C610.8060(5)0.16988(12)0.8551(4)0.0537(13)
H61A0.8988160.1693550.9207920.064*
C620.7439(5)0.19402(11)0.8109(4)0.0538(13)
H62A0.7952410.2099600.8461590.065*
C630.7924(5)0.11932(11)0.8443(4)0.0539(13)
H63A0.8879730.1176040.9071310.065*
C640.7116(5)0.09665(10)0.7925(4)0.0518(12)
H64A0.7506640.0793350.8192700.062*
C650.5697(5)0.09966(9)0.6988(3)0.0418(10)
H65A0.5133920.0840070.6648810.050*
C66−0.3828(4)0.17628(9)0.9740(3)0.0364(10)
C67−0.5237(5)0.17724(10)0.8771(3)0.0453(11)
C68−0.5840(5)0.20280(13)0.8371(4)0.0615(15)
H68A−0.6768830.2043990.7719270.074*
C69−0.5086(6)0.22540(13)0.8921(4)0.0685(15)
H69A−0.5502890.2426020.8657770.082*
C70−0.3686(5)0.22300(10)0.9884(4)0.0515(12)
H70A−0.3171840.2387841.0253530.062*
C71−0.5960(5)0.15238(11)0.8260(3)0.0507(13)
H71A−0.6889710.1528940.7604590.061*
C72−0.5342(5)0.12823(11)0.8697(4)0.0508(12)
H72A−0.5853640.1122200.8349480.061*
C73−0.3902(5)0.12670(9)0.9692(3)0.0418(11)
C74−0.3140(4)0.15090(9)1.0185(3)0.0360(10)
C75−0.3184(6)0.10230(10)1.0168(4)0.0561(13)
H75A−0.3657330.0857070.9861900.067*
C76−0.1778(6)0.10281(10)1.1088(4)0.0627(14)
H76A−0.1279440.0865581.1417270.075*
C77−0.1097(5)0.12768(10)1.1531(4)0.0581(13)
H77A−0.0137820.1277171.2163740.070*
C78−0.0026(5)0.25731(9)0.7965(3)0.0384(10)

Source of material

The 3,5-bis(3-carboxyphennoxy)benzoic acid 39.4 mg, (0.1 mmol), 1,10-phenanthroline hydrate 19.8 mg (0.1 mmol) and cobalt (II) acetate 17.7 mg (0.1 mmol) were dissolved in 5 mL methanol and acetonitrile and stirred for 15 minutes. The mixture was transferred to the autoclave lined with PTFE and heated at 200 °C for 12 hours. Then it was reduced to 120 °C and heated for 4 hours, and finally slowly reduced to room temperature.

Experimental details

The structure was solved by direct methods and refined with the SHELX crystallographic software package [1]. The hydrogen atoms were placed at calculated positions and refined as riding atoms.

Comment

Functional complexes are widely used in gas storage and separation, catalysis, drug delivery, chemical sensing and so on. Three benzene rings can support the space well and form functional complexes more powerfully, and the existence of oxygen ion give them amount of space to rotate and twist, to provide different coordinations. In this project we used 1,10-phenanthroline as auxiliary ligands [3], [4] to sythesize the title complexes.

The asymmetric unit of the title structure contains three Co metal atoms, three phenanthroline molecules, two anionic 3,3′-((5-carboxylato-1,3-phenylene)bis(oxy))dibenzoates and four water molecules (three of them are Co-coordinated). The anionic ligands connect three Co(II) nodes to a 3D network, whereas the 1,10-phenanthroline and water ligands are not in a bridging mode. Geometric parameters are all in the expected ranges [5].

Acknowledgements

We gratefully acknowledge support: Innovation Capability Support Program of Shaanxi (Program No. 2020TD-021).

References

1. Sheldrick, G. M.: SHELXTL, Version 5.1, Software Reference Manual, Madison, WI, USA (1997).Search in Google Scholar

2. BRUKER. SAINT, APEX2 and SADABS. Bruker AXS Inc., Madison, WI, USA (2009).Search in Google Scholar

3. Ramadan, A. M.; Shaban, S. Y.; Ibrahim, M. M.; El-Shami, F. I.; Al-Harbi, S. A.: Ternary complexes containing copper(II), L-valinate and α,α′-bipyridyl or 1,10-phenanthroline: synthesis, characterization, ligand substitution and oxidase biomimetic catalytic activity studies. J. Mol. Struct. 1189 (2019) 360–376.10.1016/j.molstruc.2019.04.003Search in Google Scholar

4. Lu, J. F.; Jin, L. X.; Song, J.; Zhao, C. B.; Yue, S. Y.; Li, L.; Yang, H. T.; Cao, X. Y.; Ge, H. G.: A novel 3D metal coordination polymer based on tetranuclear cobalt cluster building blocks: synthesis, crystal structure and photocatalytic property. Chin. J. Struct. Chem. 37 (2018) 1814–1820.Search in Google Scholar

5. Fan, L.; Gao, L.; Wang, X.; Wang, J.; Zhao, L.; Fang, K.; Hu, T.: Structural diversity and magnetic properties of four Cu(II)/Co(II) coordination complexes based on 3,5-bis(2-carboxylphenoxy)benzoic acid. Polyhedron 141 (2018) 133–139.10.1016/j.poly.2017.11.038Search in Google Scholar

Received: 2020-07-08
Accepted: 2020-08-20
Published Online: 2020-09-28
Published in Print: 2020-10-27

©2020 Pei-xuan Li et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  32. Crystal structure of bis[μ2-(N-(2-hydroxyethyl)-N-methylcarbamodithioato-κSSS′)]-bis(triethylphosphine-P)-di-silver(I), C20H46Ag2N2O2P2S4
  33. The crystal structure of (2E,2′E)-,2,2′-bis[1-(2-pyrazinyl)ethylidene]carbonimidic dihydrazide, C13H15N9
  34. The crystal structure of (E)-1-(quinolin-2-ylmethyl)-2-((1-(quinolin-2-ylmethyl)pyridin-2(1H)-ylidene)amino)pyridin-1-ium, C30H25BrN5
  35. Crystal structure of catena-poly[(μ2-1-((benzotriazol-1-yl)methyl)-1H-1,3-imdazole-κ2N:N′)-(1-((benzotriazol-1-yl)methyl)-1H-1,3-imdazole-κ1N)-(methanol-κ1O)mercury(II)] dinitrate, C21H22N12O7Hg
  36. Crystal structure of 1-(6-hydroxy-2-phenylbenzofuran-5-yl)ethan-1-one, C16H12O3
  37. The crystal structure of oxonium hexaquaaluminium disulfate hexahydrate
  38. Crystal structure of catena{(μ2-1,10-phenanthroline-κ4N,N,N′,N′)-(μ2-1,10-phenanthroline-κ3N,N,N′)potassium(I) {[bis(2-hydroxyethyl)iminiumyl](sulfanidyl)methyl}sulfanide hemi(1,10-phenanthroline)}, {C24H16KN4, 0.5(C12H8N2), C5H10NO2S2}
  39. Crystal structure of chlorido-[(N,N-di-isobutyl)dithiocarbamato-κ2S,S′]-di(4-methylbenzyl-κC)tin(IV), C25H36ClNS2Sn
  40. Crystal structure of chlorido-(η5-pentamethylcyclopentadienyl)-(4-chloro-4-pyridyl-2,2′:6′,2′′-terpyridine-κ2N,N′) rhodium(III) hexaflourophosphate, C31H29Cl2F6N3PRh
  41. The crystal structure of catena-poly[bis-(3,5-dinitro-1,2,4-triazolato-κ2N:O)-(μ2-1,4-bis(1-imidazolyl)benzene-κ2N:N′)copper(II)], C16H10CuN14O8
  42. Crystal structure of poly[triaqua-bis(μ3-3,3′-((5-carboxylato-1,3-phenylene)bis(oxy))dibenzoato)-tris(1,10-phenanthroline)cobalt(II)], C78H46N6O20Co3
  43. The crystal structure of 2,4-dihydroxybenzoic acid–nicotinamide–methanol (1/1/1), C15H18N2O6
  44. The crystal structure of aqua{N,N,N′,N′-tetrakis[(1H-benzimidazol-κN3) methyl]cyclohexane-1,2-diamine}lead(II) diacetate–methanol (1/2), C44H54N10O7Pb
  45. Crystal structure of (2-amino-5-bromo-3-iodophenyl)(3-(4-chlorophenyl)oxiran-2-yl)methanone, C15H10BrClINO2
  46. Synthesis and crystal structure of 3-octyl-5,5-diphenylimidazolidine-2,4-dione, C23H28N2O2
  47. Synthesis and crystal structure of 2-azido-N-(4-nitrophenyl)acetamide, C8H7N5O3
  48. Crystal structure of tert-butyl (1S,2R,5R)-2-(hydroxymethyl)-4-(4-methoxyphenyl)-6-oxa-3-azabicyclo[3.1.0]hexane-3-carboxylate, C17H23NO5
  49. Crystal structure of 4-[(4-methoxy-2-nitrophenyl)carbamoyl]butanoic acid, C12H14N2O6
  50. Crystal structure of 3-ethyl-1-[(E)-[(2E)-3-phenylprop-2-en-1-ylidene]amino]thiourea, C12H15N3S
  51. Crystal structure of 4,4′-bipyridin-1,1′-dium poly[bis(μ4-benzene-1,3,5-triyltris(hydrogen phosphonato-κ4O:O′:O′′:O′′′))zinc(II)], C11H11NO9P3Zn
  52. Crystal structure of (μ2-1,1′-bis(diphenylphosphino)butane-κ2P,P′)-bis[(Z)-N-(3-fluorophenyl)-O-methylthiocarbamato-κS]-di-gold(I), C44H42Au2F2N2O2P2S2
  53. Crystal structure of (μ2-1,1′-bis(diphenylphosphino)hexane-κ2P,P′)-bis[(Z)-N-(3-fluorophenyl)-O-methylthiocarbamato-κS]digold(I), C46H46Au2F2N2O2P2S2
  54. Crystal structure of tetrakis (N-(2-hydroxyethyl)-N-isopropylcarbamodithioato-κS,S′)-(μ2(2-(pyridin-4-yl)vinyl)pyridine-κN,N′)dicadmium(II), C36H58Cd2N6O4S8
  55. Crystal structure of 4-(2-(benzo[b]thiophen-2-yl)-3,3,4,4,5,5-hexafluorocyclopent-1-en-1-yl)-1,5-dimethyl-1H-pyrrole-2-carbonitrile, C20H12F6N2S
  56. Crystal structure of bis(octahydrocyclopenta[c]pyrrolium)pentachlorobismuthate(III), (C7NH14)2BiCl5
  57. The crystal structure of diaqua-tris(nitrato-κ2O,O′)-bis(4,4,5,5-tetramethyl-2-(p-pyridyl)imidazoline-1-oxyl 3-oxide-κN)samarium(III), C24H36N9O15Sm
  58. Synthesis and crystal structure of methyl 2-(2-((tert-butoxycarbonyl)amino)phenyl)-2-(4-oxo-4H-chromen-3-yl)acetate, C23H23NO6
  59. Crystal structure of O-hexyl benzoylcarbamothioate, C14H19NO2S
  60. Crystal structure of chlorido-(O-methyl phenylcarbamothioamide-κS)-bis(triphenylphosphane-κP)silver(I), C44H39AgClNOP2S
  61. Crystal structure of chlorido-(O-ethyl phenylcarbamothioamide-κS)-bis(triphenylphosphane-κP)-silver(I), C45H41AgClNOP2S
  62. Crystal structure of 4-[(2-methoxyphenyl)carbamoyl]butanoic acid, C12H15NO4
  63. Crystal structure of ethyl 4-methyl-2-oxo-5-phenyl-1,3,4-oxadiazinane-3-carboxylate, C13H16N2O4
  64. Crystal structure of catena-poly[diaqua(μ2-2-(hydroxymethyl)-1H-imidazole-4,5-dicarboxylato)cadmium(II)], C6H8CdN2O7
  65. Crystal structure of (1S)-N-(chloromethyl)-1-((4S,6aR,8aS, 8bR,9aR)-4-methoxy-6a,8a-dimethyl-1,3,4, 5,6,6a,6b,7,8,8a,9a,10,10a,10b-tetradecahydro-8bH-naphtho[2′,1′:4,5] indeno[1,2-b]oxiren-8b-yl)-N-methylethan-1-amine, C24H46ClNO5
  66. Crystal structure of 4-[(3,5-dichlorophenyl)carbamoyl]butanoic acid, C11H11Cl2NO3
  67. Crystal structure of (2Z)-2-amino-3-[(E)-[(2,4-dihydroxyphenyl)methylidene]-amino]but-2-enedinitrile, C11H8N4O2
  68. Crystal structure of 3-methyl-1-[(E)-(4-phenylbutan-2-ylidene)amino]thiourea, C12H17N3S
  69. Crystal structure of carbonyl{hydridotris[3-phenyl-5-methylpyrazol-1-yl]borato-κ3N,N′N′′}copper(I), C31H28BCuN6O
  70. Crystal structure of ethane-1,2-diylbis(diphenylphosphine oxide) – dihydrogenperoxide (1/2), C26H28O6P2
  71. Crystal structure of 2-(pyridin-2-ylamino)pyridinium chloride dibenzyldichlorostannane, [C10H10N3]Cl, C14H14Cl2Sn
  72. Crystal structure of 4-[(3-methoxyphenyl)carbamoyl]butanoic acid, C12H15NO4
  73. Crystal structure of dichlorido-bis(tri-4-tolylphosphane oxide-κO)-di(4-chlorophenyl-κC)tin(IV), C54H50Cl4O2P2Sn
  74. Crystal structure of dichloridodimethylbis(tri-4-tolylphosphane oxide-κO)-tin(IV), C44H48Cl2O2P2Sn
  75. Crystal structure of chlorido(2-methylquinolin-8-olato-κ2N,O)-bis(4-tolyl-κC)tin(IV), C24H22ClNOSn
  76. Crystal structure of (E)-dichloro(1-chloro-3-methoxyprop-1-en-2-yl)(4-methoxyphenyl)-λ4-tellane, C11H13Cl3O2Te
  77. Crystal structure of bis{N-methyl-N′-[3-(4-methoxyphenyl)-1-methylpropane-1-ylidene]carbamohydrazonothioato}zinc(II), C26H36N6O2S2Zn
  78. Crystal structure of (2-carboxy-4-(3-carboxy-5-carboxylatophenoxy)benzoato-κ2O,O′)bis(1,10-phenantroline-κ2N,N′)cobalt(II), C40H24N4O9Co
  79. The crystal structure of (3S,8R,10R,14R)-17-((2S,5S)-5-(2-hydroxypropan-2-yl)-2-methyltetrahydrofuran-2-yl)-4,4,8,10,14-pentamethyl-12-oxohexadecahydro-1H-cyclopenta[a]phenanthren-3-yl acetate, C32H52O5
  80. Crystal structure of (μ2-1,1′-bis(diphenylphosphino)ferrocene-κ2P,P′)-bis[(Z)N-(3-fluorophenyl)-O-methylthiocarbamato-S]digold(I) chloroform solvate, C50H42Au2F2FeN2O2P2S2, CHCl3
  81. Crystal structure of poly[bis(μ2-1,4-di(1H-imidazol-1-yl)benzene-κ2N:N′)-(μ2-tetraoxidomolybdato(VI)-κ2O:O′)cobalt(II)], C24H20N8O4MoCo
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