Startseite Crystal structure of 1,1′-((1E,1′E)-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(naphthalen-2-olato)nickel(II), C72H52N4O8Ni2
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Crystal structure of 1,1′-((1E,1′E)-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(naphthalen-2-olato)nickel(II), C72H52N4O8Ni2

  • Guo qiang Li , Run lan Fan , Die er He und Qiang Xu EMAIL logo
Veröffentlicht/Copyright: 17. Dezember 2016
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 232 Heft 2

Abstract

C72H52N4O8Ni2, monolinic, C2/c (no. 15), a = 43.017(19) Å, b = 17.091(8) Å, c = 11.301(5) Å, β = 103.053(8)°, V = 8094(6) Å3, Z = 6, Rgt(F) = 0.0575, wRref(F2) = 0.1263, T = 296(2) K.

CCDC no.:: 1410762

One of the two crystallographically independent complexes of the title crystal structure is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.

Table 1

Data collection and handling.

Crystal:Yellow blocks
Size:0.28 × 0.24 × 0.20 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:7.7 cm−1
Diffractometer, scan mode:Bruker APEX-II, φ and ω
2θmax, completeness:50°, >99%
N(hkl)measured, N(hkl)unique, Rint:20052, 7137, 0.095
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 4083
N(param)refined:582
Programs:SHELX [3], Bruker programs [8]
Table 2

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Ni10.674963(12)0.75368(3)0.28589(5)0.03324(17)
Ni20.50000.63775(5)0.25000.0419(2)
C10.68264(10)0.6058(3)0.4244(4)0.0341(11)
C20.66780(10)0.5423(3)0.4746(4)0.0402(11)
H20.64560.54000.45880.048*
C30.68490(11)0.4864(3)0.5436(4)0.0400(12)
H30.67420.44630.57340.048*
C40.71855(10)0.4868(2)0.5723(3)0.0308(10)
C50.73483(10)0.5478(2)0.5269(3)0.0298(10)
C60.71650(9)0.6081(2)0.4500(3)0.0275(10)
C70.76839(10)0.5474(2)0.5654(3)0.0330(10)
H70.77990.58820.54150.040*
C80.78470(11)0.4894(3)0.6366(4)0.0402(11)
H80.80690.49100.65850.048*
C90.76852(11)0.4282(3)0.6764(4)0.0472(13)
H90.77960.38820.72390.057*
C100.73596(11)0.4280(3)0.6441(4)0.0427(12)
H100.72500.38720.67090.051*
C110.73342(10)0.6672(2)0.4019(3)0.0302(10)
H110.75550.66240.42000.036*
C120.74348(9)0.7778(2)0.2927(3)0.0269(10)
C130.77655(10)0.7746(2)0.3257(4)0.0327(10)
H130.78650.73650.37990.039*
C140.79497(10)0.8275(3)0.2788(4)0.0395(11)
H140.81710.82440.30130.047*
C150.78072(11)0.8848(3)0.1989(4)0.0424(12)
H150.79330.92020.16820.051*
C160.74808(10)0.8897(3)0.1644(4)0.0399(11)
H160.73850.92840.11070.048*
C170.72959(10)0.8363(2)0.2104(4)0.0322(10)
C180.68228(10)0.8341(3)0.0522(4)0.0436(12)
H18A0.69400.86600.00600.052*
H18B0.66030.85150.03420.052*
C190.68387(11)0.7504(3)0.0178(4)0.0466(12)
H19A0.67430.7439−0.06800.056*
H19B0.70600.73400.03180.056*
C200.63418(10)0.6982(2)0.0406(4)0.0359(11)
C210.62230(11)0.6562(3)−0.0640(4)0.0445(12)
H210.63620.6327−0.10560.053*
C220.59005(12)0.6493(3)−0.1062(4)0.0524(13)
H220.58200.6212−0.17690.063*
C230.56969(12)0.6834(3)−0.0454(5)0.0551(14)
H230.54780.6786−0.07510.066*
C240.58123(11)0.7248(3)0.0597(4)0.0452(12)
H240.56700.74620.10170.054*
C250.61384(10)0.7349(2)0.1041(4)0.0348(11)
C260.61077(10)0.8236(2)0.2600(4)0.0367(11)
H260.58940.82570.22010.044*
C270.61979(10)0.8715(2)0.3648(4)0.0336(10)
C280.65162(10)0.8733(3)0.4342(4)0.0372(11)
C290.65953(11)0.9307(3)0.5314(4)0.0498(13)
H290.68060.93590.57430.060*
C300.63678(12)0.9766(3)0.5604(4)0.0513(13)
H300.64271.01310.62230.062*
C310.60445(12)0.9710(3)0.5001(4)0.0451(12)
C320.59555(10)0.9186(3)0.4004(4)0.0393(11)
C330.56287(11)0.9139(3)0.3472(4)0.0545(14)
H330.55590.87950.28290.065*
C340.54073(12)0.9589(4)0.3876(5)0.0713(17)
H340.51920.95430.35000.086*
C350.54995(15)1.0109(3)0.4832(5)0.0712(17)
H350.53491.04140.50930.085*
C360.58116(14)1.0165(3)0.5375(5)0.0631(15)
H360.58751.05140.60150.076*
C370.51839(12)0.7401(3)0.4637(5)0.0530(13)
C380.50833(13)0.7916(3)0.5478(5)0.0669(16)
H380.48670.80050.54070.080*
C390.52947(13)0.8273(3)0.6363(5)0.0677(17)
H390.52190.86110.68790.081*
C400.56291(12)0.8159(3)0.6551(4)0.0512(13)
C410.57445(11)0.7654(2)0.5746(4)0.0395(11)
C420.55178(10)0.7263(2)0.4766(4)0.0388(11)
C430.56354(10)0.6751(2)0.3977(4)0.0377(11)
H430.58560.67230.40920.045*
C440.60774(11)0.7567(3)0.5961(4)0.0453(12)
H440.61630.72330.54690.054*
C450.62800(12)0.7967(3)0.6887(5)0.0575(14)
H450.64990.78980.70020.069*
C460.61641(14)0.8467(3)0.7642(5)0.0652(15)
H460.63030.87390.82530.078*
C470.58438(14)0.8557(3)0.7482(4)0.0633(15)
H470.57650.88880.79970.076*
C480.56346(10)0.5812(2)0.2440(4)0.0338(10)
C490.54465(10)0.5298(3)0.1619(4)0.0352(11)
C500.55796(11)0.4781(3)0.0943(4)0.0468(13)
H500.54490.44480.03950.056*
C510.59061(11)0.4755(3)0.1075(4)0.0487(13)
H510.59970.43950.06370.058*
C520.60946(11)0.5265(3)0.1859(4)0.0491(13)
H520.63150.52560.19420.059*
C530.59617(10)0.5791(3)0.2522(4)0.0399(11)
H530.60930.61390.30370.048*
C540.49745(11)0.4633(3)0.1815(4)0.0510(13)
H54A0.50760.41770.15520.061*
H54B0.47480.46120.14440.061*
N10.72163(8)0.72722(19)0.3354(3)0.0291(8)
N20.62871(8)0.77669(19)0.2122(3)0.0327(9)
N30.54697(8)0.6314(2)0.3105(3)0.0354(9)
O10.66385(6)0.65647(17)0.3588(3)0.0451(8)
O20.69616(6)0.84219(15)0.1815(2)0.0365(7)
O30.66723(7)0.70252(16)0.0886(2)0.0384(7)
O40.67480(7)0.82853(17)0.4188(2)0.0400(8)
O50.49594(7)0.7091(2)0.3811(3)0.0647(10)
O60.51123(6)0.53409(17)0.1447(2)0.0398(8)

Source of material

The protonated form of the organic ligand (H2L) was synthesized following reported literature [1, 2], other reagents were obtained commercially and used directly without further purification. The title compound C72H52N4O8Ni2 was prepared by a vapor diffusion method. A mixture of Ni(ClO4)2⋅6H2O (36.57 mg, 0.1 mmol) and H2L (55.26 mg, 0.1 mmol) in 12 mL methanol was stirred for 1 h to afford a clear purple sulution. The mixture was filtered and the filtrate was placed in a sealed bottle filled with diethyl ether atmosphere. After twelve hours, light yellow block crystals were obtained in a yield of 46% (based on Ni).

Experimental details

The structure was solved by direct methods and refined using the SHELX software [3]. All of the hydrogen atoms were placed in the calculated positions and all the non-hydrogen atoms were refined anisotropically.

Discussion

In the last decade, the Salen-type ligand plays an important roles in the field of modern coordination chemistry. Ligands in this class are tetradentate, containing two phenolic O and two imine N donors that can easily coordinate with transition metal ions to form some diversified structure and perfect property of complexes [4, 5]. Thus, in continuation of our previous study, we report the synthesis and structure of a novel Ni(II) complex based on such a ligand. The title crystal structure is a mononuclear structure. In each of the two crystallographically independent complexes Ni(II) is six-coordinated by two nitrogen and four oxygen atoms from the hexadentate Salen-type L2- dianion to form a slightly distored-octahedral geometry. The axial positions are occupied by two phenolic oxygen atoms and the equatorial plane are completed by two ether oxygen atoms and two imine nitrogen atoms. In the second crystallographically independent complex the phenolato oxygen atoms are coordinated in the cis to each other (cf. the figure). The bond angles and bond lengths around Ni(II) are in accordance with previously studies on other Ni(II) complexes [6, 7].

Acknowledgements

We acknowledge support for the publication fee by the Chongqing Education Commission (KJ1401114), Chongqing University of Arts and Sciences (Z2015CH02) and Chongqing University of Arts and Sciences (XSKY2014031).

References

1 Zhang, Q. L.; Zhang, Y. Q.; Zhu, B. X.: Crystal structure of Ag(I) schiff base complex. Chin. J. Inorg. Chem. 27 (2011) 2191–2194.Suche in Google Scholar

2 Zhang, Q. L.; Zhang, Y. Q.; Zhu, B. X.: Synthesis and crystal structure of Co(II) and Zn(II) complexes with one-dimensional chain structure. Chin. J. Inorg. Chem. 27 (2011) 923–927.Suche in Google Scholar

3 Sheldrick, G. M.: SHELXL-97, Program for solution of crystal structures, University of Göttingen, Göttingen, Germany, (1997).Suche in Google Scholar

4 Peng, Y. S.; Hong, F. L.; Peng, C.: Synthesis, crystal structure, and single molecule magnetic properties of a Salen-type Zn-Dy-Zn complex. Z. Anorg. Allg. Chem. 641 (2015) 1119–1124.10.1002/zaac.201400610Suche in Google Scholar

5 Yu, L. C.; Ming, W. C.; Yuan, C. T.: New salen-type dysprosium(III) double decker and triple-decker complexes. Polyhedron 102 (2015) 8–15.10.1016/j.poly.2015.07.048Suche in Google Scholar

6 Sun, Y. X.; Dong, W. K.; Wang, L.: Synthesis and crystal structure of Nickel(II) cluster with Salen-type bisoxime ligand. Chin. J. Inorg. Chem. 25 (2009) 1478–1482.Suche in Google Scholar

7 Soumavo, G.; Ashutosh, G.: Coordination of metalloligand [NiL] (H2L = salen type N2O2 Schiff base ligand) to the f-block elements: structure elucidation and spectrophotometric investigation. Inorg. Chim. Acta 442 (2016) 64–69.10.1016/j.ica.2015.11.029Suche in Google Scholar

8 Bruker. APEX2, SAINT and SADABS. Brucker AXS Inc., Madison, Wisconsin, USA, (2009).Suche in Google Scholar

Received: 2016-6-7
Accepted: 2016-11-8
Published Online: 2016-12-17
Published in Print: 2017-3-1

©2016 Guo qiang Li et al., published by De Gruyter.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Artikel in diesem Heft

  1. Cover and Frontmatter
  2. The crystal structure of triphenylphosphineoxide – 2,5-dichloro-3,6-dihydroxycyclohexa-2,5-diene-1,4-dione (2/1), C42H32Cl2O6P2
  3. Crystal structure of poly-[diaqua-[bis(μ2-hydroxy)-bis(μ4-3,4,5,6-tetrachlorophthalato-κ3O,O′:O′; κ2O′′:O′′′)dilanthanum(III)], C8H3Cl4LaO6
  4. Crystal structure of 1,1′-(3,4-diphenylthieno[2,3-b]thiophene-2,5-diyl)bis[1-phenyl-methanone], C32H20O2S2
  5. Crystal structure of 4a-hydroxy-9-(3,5-dibromo-phenyl)-3,4,4a,5,6,7,9,9a-octahydro-2H-xanthene-1,8-dione, C19H18Br2O4
  6. Crystal structure of 5-hydroxy-4,6,9,10-tetramethyl-1-oxo-6-vinyldecahydro-3a,9-propanocyclopenta[8]annulen-8-yl 2-((2-methyl-1-(3-methylbenzamido)propan-2-yl)thio)acetate, C34H49NO5S
  7. Crystal structure of pyridinium bis(naphthalane-2,3-diolato-κ2O,O′)borate monohydrate, C25H20BNO5
  8. Crystal structure of 1,1′-((1E,1′E)-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(naphthalen-2-olato)nickel(II), C72H52N4O8Ni2
  9. The crystal structure of 3-(2-acetyl-4-butyramido-phenoxy)-2-hydroxy-N-isopropylpropan-1-aminium tetraphenylborate, C42H49BN2O4
  10. Crystal structure of 4-bromobenzyl (Z)-N′-(adamantan-1-yl)-4-phenylpiperazine-1-carbothioimidate, C28H34BrN3S
  11. Crystal structure of poly-[(μ6-benzene-1,2,4,5-tetracarboxylato)-(μ2-1,2-bis(imidazol-1-ylmethyl)benzene)dicobalt(II)], Co2C24H16N4O8
  12. Crystal structure of catena-(bis(μ2-1, 2-bis(imidazole-1-ylmethyl)benzene-κN:N′)-dichlororido-nickel(II)), C28H28Cl2N8Ni
  13. Crystal structure of (Z)-1-(1,5-dimethyl-1H-pyrazol-3-yl)-3-hydroxy-3-(4-methoxyphenyl)prop-2-en-1-one, C15H16N2O3
  14. Crystal structure of (Z)-1-(1,5-dimethyl-1H-pyrazol-3-yl)-3-hydroxy-3-phenylprop-2-en-1-one, C14H14N2O2
  15. Crystal structure of (E)-2-(4-hydroxy-3-methoxybenzylidene)-6-methoxy-3,4-dihydronaphthalen-1(2H)-one, C19H18O4
  16. Crystal structure of (Z)-1-(1,5-dimethyl-1H-pyrazol-3-yl)-3-(4-ethoxyphenyl)-3-hydroxyprop-2-en-1-one, C16H18N2O3
  17. Crystal structure of (Z)-1-(1,5-dimethyl-1H-pyrazol-3-yl)-3-hydroxy-3-(p-toly)prop-2-en-1-one, C15H16N2O2
  18. Crystal structure of 1-acetyl-3-(3-chlorophenyl)-5-(4-isopropylphenyl)-4,5-dihydro-(1H)-pyrazole, C20H21ClN2O
  19. The crystal structure of 1-methyl-2,4-dinitro-5-iodoimidazole, C4H3IN4O4
  20. The crystal structure of 4-chloro-3,5-dinitroaniline, C6H4ClN3O4
  21. Crystal structure of N,N-dimethyl-N′-(2-methyl-4-oxo-5,6,7,8-tetrahydrobenzo[4,5]thieno[2,3-d]pyrimidin-3(4H)-yl)formimidamide, C14H18N4OS
  22. Crystal structure of tetrakis(μ2-acetato-κ2O:O′)-bis[μ3-4-chloro-2,6-bis((methylimino)methyl)phenolato-κ2N,O:O,N′]-(μ4-oxido)tetracopper(II), C28H32Cl2Cu4N4O11
  23. Crystal structure of catena-poly[diaqua-bis(μ2-ethane-1,2-diyl-bis(pyridine-3-carboxylate-κ2N:N′))copper(II)] dinitrate, C28H28CuN6O16
  24. Synthesis and crystal structure of catena-poly[(μ2-nicotinato-κ2O,O′: κ1N)-(nitrato-κ1O)-(bis(2-benzimidazol-ylmethyl)amine-κ3N,N′,N′′)lead(II)], C22H18N7O5Pb
  25. The twinned crystal structure of (4SR)-7-benzyl-2,4,8,8-tetramethyl-7,8-dihydroimidazo[5,1-c][1,2,4]triazine-3,6(2H,4H)-dione, C16H20N4O2
  26. Crystal structure of (Z)-3-hydroxy-3-(4-methoxyphenyl)-1-(pyridin-2-yl)prop-2-en-1-one, C15H13NO3
  27. Crystal structure of 2-amino-4-(2,3-dichlorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H12Cl2N2O2
  28. Crystal structure of catena-poly[(μ2-butane-1,4-diyl-bis(pyridine-3-carboxylato-κN))silver(I)] tetrafluoroborate, C16H16AgN2O4BF4
  29. Crystal structure of poly[diaqua-(1,10-phenanthroline-κ2N,N′)-(μ2-2,5-dihydroxytere-phthalato)-bis(μ4-2,5-dihydroxyterephthalato)dicerium(III)], C24H16CeN2O10
  30. Crystal structure of 5,7,4′-trihydroxy-3,8,3′-trymethoxyflavone, C18H16O8
  31. Crystal structure of N-(3,4-dichlorobenzylidene)-4-methylaniline, C14H11Cl2N
  32. Crystal structure of 4-(3-Methoxy-phenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydro-quinoline-3-carboxylic acid ethyl ester, C22H27NO4
  33. Crystal structure of 2-amino-4-(3-fluorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H13FN2O2
  34. Crystal structure of 1,1,(3,4-dihydroxythieno[2,3-b] thiophene-2,5-diyl)bis(2-bromoethanone), C10H6Br2O4S2
  35. The crystal structure of N,N′-(4,4′-oxydibenzyl)-bisisonicotinamide 3.5 hydrate, C24H24N4O6
  36. Crystal structure of catena-poly[hexakis(μ2-chlorido)-hexakis(4-(1H-pyrazol-5-yl)pyridine-κN)tricadmium(II)], Cd3C48H42Cl6N18
  37. Crystal structure of 2-(4-(dimethylamino)phenyl)-1,3-dimethyl-1H-perimidin-3-ium iodide, C21H22I1N3
  38. Crystal structure of 4-(1,3-dimethyl-2,3-dihydro-1H-perimidin-2-yl)benzonitrile, C20H17N3
  39. Crystal structure of tetrakis(μ2-acetato-κ2O:O′)-bis(2,2′-sulfonyldipyrazine-κ1N)dicopper(II), C24H24Cu2N8O12S2
  40. Crystal structure of 1-(4-chlorophenyl)-6,8-diphenyl-1H-pyrazolo[4,3-c]quinoline, C28H18ClN3
  41. Crystal structure of methyl 3-((1-(2-(methoxycarbonyl)benzyl)-1H-1,2,3-triazol-4-yl)methoxy)-2-naphthoate, C24H21N3O5
  42. Crystal structure of (tris(2-pyridylmethyl)amine-κ4N,N′,N′′,N′′′′)-chloranilato-κO,O′-zinc(II) – methanol (1/1), C25H22Cl2N4O5Zn
  43. Crystal structure of 1,1-dimethyl-3-(4-methoxyphenyl)urea, C10H14N2O2
  44. Crystal structure of 4a-Hydroxy-9-(2-nitro-phenyl)-3,4,4a,5,6,7,9,9a-octahydro-2H-xanthene-1,8-dione, C19H19NO6
  45. Crystal structure of chlorido-(η6–1-isopropyl-4-methyl benzene)-(1-(pyridin-2-yl)-N-(p-tolyl)methanimine-κ2N,N′)ruthenium(II) hexafluorophosphate(V), C23H26ClF6N2PRu
  46. Crystal structure of phenyl(2-phenyl-2,3-dihydro-1H-perimidin-2-yl)methanone, C24H18N2O
  47. Crystal structure of (E)-3-methyl-4-((3-(5-methyl-1-phenyl-1H-1,2,3-triazol-4-yl)-1-phenyl-1H-pyrazol-4-yl)methylene)-1-phenyl-1H-pyrazol-5(4H)-one, C29H23N7O
  48. Crystal structure of 2-(4-(2-butyl-1,3-dioxo-2,3-dihydro-1H-benzo[de]isoquinolin-6-yl)piperazin-1-yl)-2-oxoethyldiethylcarbamodithioate, C27H34N4O3S2
  49. Crystal structure of poly-[diaqua-bis(μ-4,4′-bipyridine-κ2N:N′)cobalt(II)] bis(4-chlorobenzenesulfonate) – 4,4′-bipyridine – water (1/1/2), C42H40Cl2CoN6O10S2
  50. Crystal structure of (η6-benzene)-(N-(2,6-dimethylphenyl)-1-(pyridin-2-yl)methanimine-κ2N,N′)ruthenium(II) perchlorate monohydrate, C20H20Cl2N2O5Ru
  51. Crystal structure of 4,10,16,22-tetrahydroxy-6,12,18,24-tetramethoxy-2,8,14,20-tetraethylphenylresorcin[4]arene – ethyl acetate (1/1), C68H72O10
  52. Crystal structure of chlorido-(N-(2,5-dichlorophenyl)-1-(pyridin-2-yl)methanimine-κ2N,N′)(η6-1-isopropyl-4-methyl benzene) ruthenium (II) tetrafluoroborate, C22H22Cl3N2BF4Ru
  53. Crystal structure of 3-(5-methyl-1-p-tolyl-1H-1,2,3-triazol-4-yl)-1-phenyl-1H-pyrazole-4-carbaldehyde, a rare Z′ = 3 structure, C20H17N5O
  54. Crystal structure of 5-(5-(4-chlorophenyl)-1-phenyl-1H-pyrazol-3-yl)-N-phenyl-1,3,4-thiadiazol-2-amine, C23H16ClN5S
  55. Crystal structure of 7-hydroxy-3-(4-hydroxyphenyl)-4H-1-benzopyran-4-one-N,N-dimethylformamide (1/1), C18H17NO5
  56. Crystal structure of halogen-bonded 2-chloro-1,10-phenanthroline—1,4-diiodotetrafluorobenzene (2/1), C30H14Cl2F4I2N4
  57. Crystal structure of 1-(4,4-dimethyl-2,6-dithioxo-1,3,5-triazinan-1-yl)-3-(diethylaminocarbonyl)thiourea, C11H20N6OS3
  58. Crystal structure of methyl 1-(4-fluorobenzyl)-3-phenyl-1H-pyrazole-5-carboxylate, C18H15FN2O2
  59. Crystal structure of 1,1-dimethyl-3-(4-methylphenyl)urea, C10H14N2O
  60. Crystal structure of yttrium gallium antimonide, Y5Ga1.24Sb2.77
  61. Crystal structure of 2-(bis(4-methoxyphenyl)amino)-2-oxoacetic acid, C16H15NO5
https://doi.org/10.1515/ncrs-2016-0182
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Artikel in diesem Heft

  1. Cover and Frontmatter
  2. The crystal structure of triphenylphosphineoxide – 2,5-dichloro-3,6-dihydroxycyclohexa-2,5-diene-1,4-dione (2/1), C42H32Cl2O6P2
  3. Crystal structure of poly-[diaqua-[bis(μ2-hydroxy)-bis(μ4-3,4,5,6-tetrachlorophthalato-κ3O,O′:O′; κ2O′′:O′′′)dilanthanum(III)], C8H3Cl4LaO6
  4. Crystal structure of 1,1′-(3,4-diphenylthieno[2,3-b]thiophene-2,5-diyl)bis[1-phenyl-methanone], C32H20O2S2
  5. Crystal structure of 4a-hydroxy-9-(3,5-dibromo-phenyl)-3,4,4a,5,6,7,9,9a-octahydro-2H-xanthene-1,8-dione, C19H18Br2O4
  6. Crystal structure of 5-hydroxy-4,6,9,10-tetramethyl-1-oxo-6-vinyldecahydro-3a,9-propanocyclopenta[8]annulen-8-yl 2-((2-methyl-1-(3-methylbenzamido)propan-2-yl)thio)acetate, C34H49NO5S
  7. Crystal structure of pyridinium bis(naphthalane-2,3-diolato-κ2O,O′)borate monohydrate, C25H20BNO5
  8. Crystal structure of 1,1′-((1E,1′E)-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(naphthalen-2-olato)nickel(II), C72H52N4O8Ni2
  9. The crystal structure of 3-(2-acetyl-4-butyramido-phenoxy)-2-hydroxy-N-isopropylpropan-1-aminium tetraphenylborate, C42H49BN2O4
  10. Crystal structure of 4-bromobenzyl (Z)-N′-(adamantan-1-yl)-4-phenylpiperazine-1-carbothioimidate, C28H34BrN3S
  11. Crystal structure of poly-[(μ6-benzene-1,2,4,5-tetracarboxylato)-(μ2-1,2-bis(imidazol-1-ylmethyl)benzene)dicobalt(II)], Co2C24H16N4O8
  12. Crystal structure of catena-(bis(μ2-1, 2-bis(imidazole-1-ylmethyl)benzene-κN:N′)-dichlororido-nickel(II)), C28H28Cl2N8Ni
  13. Crystal structure of (Z)-1-(1,5-dimethyl-1H-pyrazol-3-yl)-3-hydroxy-3-(4-methoxyphenyl)prop-2-en-1-one, C15H16N2O3
  14. Crystal structure of (Z)-1-(1,5-dimethyl-1H-pyrazol-3-yl)-3-hydroxy-3-phenylprop-2-en-1-one, C14H14N2O2
  15. Crystal structure of (E)-2-(4-hydroxy-3-methoxybenzylidene)-6-methoxy-3,4-dihydronaphthalen-1(2H)-one, C19H18O4
  16. Crystal structure of (Z)-1-(1,5-dimethyl-1H-pyrazol-3-yl)-3-(4-ethoxyphenyl)-3-hydroxyprop-2-en-1-one, C16H18N2O3
  17. Crystal structure of (Z)-1-(1,5-dimethyl-1H-pyrazol-3-yl)-3-hydroxy-3-(p-toly)prop-2-en-1-one, C15H16N2O2
  18. Crystal structure of 1-acetyl-3-(3-chlorophenyl)-5-(4-isopropylphenyl)-4,5-dihydro-(1H)-pyrazole, C20H21ClN2O
  19. The crystal structure of 1-methyl-2,4-dinitro-5-iodoimidazole, C4H3IN4O4
  20. The crystal structure of 4-chloro-3,5-dinitroaniline, C6H4ClN3O4
  21. Crystal structure of N,N-dimethyl-N′-(2-methyl-4-oxo-5,6,7,8-tetrahydrobenzo[4,5]thieno[2,3-d]pyrimidin-3(4H)-yl)formimidamide, C14H18N4OS
  22. Crystal structure of tetrakis(μ2-acetato-κ2O:O′)-bis[μ3-4-chloro-2,6-bis((methylimino)methyl)phenolato-κ2N,O:O,N′]-(μ4-oxido)tetracopper(II), C28H32Cl2Cu4N4O11
  23. Crystal structure of catena-poly[diaqua-bis(μ2-ethane-1,2-diyl-bis(pyridine-3-carboxylate-κ2N:N′))copper(II)] dinitrate, C28H28CuN6O16
  24. Synthesis and crystal structure of catena-poly[(μ2-nicotinato-κ2O,O′: κ1N)-(nitrato-κ1O)-(bis(2-benzimidazol-ylmethyl)amine-κ3N,N′,N′′)lead(II)], C22H18N7O5Pb
  25. The twinned crystal structure of (4SR)-7-benzyl-2,4,8,8-tetramethyl-7,8-dihydroimidazo[5,1-c][1,2,4]triazine-3,6(2H,4H)-dione, C16H20N4O2
  26. Crystal structure of (Z)-3-hydroxy-3-(4-methoxyphenyl)-1-(pyridin-2-yl)prop-2-en-1-one, C15H13NO3
  27. Crystal structure of 2-amino-4-(2,3-dichlorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H12Cl2N2O2
  28. Crystal structure of catena-poly[(μ2-butane-1,4-diyl-bis(pyridine-3-carboxylato-κN))silver(I)] tetrafluoroborate, C16H16AgN2O4BF4
  29. Crystal structure of poly[diaqua-(1,10-phenanthroline-κ2N,N′)-(μ2-2,5-dihydroxytere-phthalato)-bis(μ4-2,5-dihydroxyterephthalato)dicerium(III)], C24H16CeN2O10
  30. Crystal structure of 5,7,4′-trihydroxy-3,8,3′-trymethoxyflavone, C18H16O8
  31. Crystal structure of N-(3,4-dichlorobenzylidene)-4-methylaniline, C14H11Cl2N
  32. Crystal structure of 4-(3-Methoxy-phenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydro-quinoline-3-carboxylic acid ethyl ester, C22H27NO4
  33. Crystal structure of 2-amino-4-(3-fluorophenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C16H13FN2O2
  34. Crystal structure of 1,1,(3,4-dihydroxythieno[2,3-b] thiophene-2,5-diyl)bis(2-bromoethanone), C10H6Br2O4S2
  35. The crystal structure of N,N′-(4,4′-oxydibenzyl)-bisisonicotinamide 3.5 hydrate, C24H24N4O6
  36. Crystal structure of catena-poly[hexakis(μ2-chlorido)-hexakis(4-(1H-pyrazol-5-yl)pyridine-κN)tricadmium(II)], Cd3C48H42Cl6N18
  37. Crystal structure of 2-(4-(dimethylamino)phenyl)-1,3-dimethyl-1H-perimidin-3-ium iodide, C21H22I1N3
  38. Crystal structure of 4-(1,3-dimethyl-2,3-dihydro-1H-perimidin-2-yl)benzonitrile, C20H17N3
  39. Crystal structure of tetrakis(μ2-acetato-κ2O:O′)-bis(2,2′-sulfonyldipyrazine-κ1N)dicopper(II), C24H24Cu2N8O12S2
  40. Crystal structure of 1-(4-chlorophenyl)-6,8-diphenyl-1H-pyrazolo[4,3-c]quinoline, C28H18ClN3
  41. Crystal structure of methyl 3-((1-(2-(methoxycarbonyl)benzyl)-1H-1,2,3-triazol-4-yl)methoxy)-2-naphthoate, C24H21N3O5
  42. Crystal structure of (tris(2-pyridylmethyl)amine-κ4N,N′,N′′,N′′′′)-chloranilato-κO,O′-zinc(II) – methanol (1/1), C25H22Cl2N4O5Zn
  43. Crystal structure of 1,1-dimethyl-3-(4-methoxyphenyl)urea, C10H14N2O2
  44. Crystal structure of 4a-Hydroxy-9-(2-nitro-phenyl)-3,4,4a,5,6,7,9,9a-octahydro-2H-xanthene-1,8-dione, C19H19NO6
  45. Crystal structure of chlorido-(η6–1-isopropyl-4-methyl benzene)-(1-(pyridin-2-yl)-N-(p-tolyl)methanimine-κ2N,N′)ruthenium(II) hexafluorophosphate(V), C23H26ClF6N2PRu
  46. Crystal structure of phenyl(2-phenyl-2,3-dihydro-1H-perimidin-2-yl)methanone, C24H18N2O
  47. Crystal structure of (E)-3-methyl-4-((3-(5-methyl-1-phenyl-1H-1,2,3-triazol-4-yl)-1-phenyl-1H-pyrazol-4-yl)methylene)-1-phenyl-1H-pyrazol-5(4H)-one, C29H23N7O
  48. Crystal structure of 2-(4-(2-butyl-1,3-dioxo-2,3-dihydro-1H-benzo[de]isoquinolin-6-yl)piperazin-1-yl)-2-oxoethyldiethylcarbamodithioate, C27H34N4O3S2
  49. Crystal structure of poly-[diaqua-bis(μ-4,4′-bipyridine-κ2N:N′)cobalt(II)] bis(4-chlorobenzenesulfonate) – 4,4′-bipyridine – water (1/1/2), C42H40Cl2CoN6O10S2
  50. Crystal structure of (η6-benzene)-(N-(2,6-dimethylphenyl)-1-(pyridin-2-yl)methanimine-κ2N,N′)ruthenium(II) perchlorate monohydrate, C20H20Cl2N2O5Ru
  51. Crystal structure of 4,10,16,22-tetrahydroxy-6,12,18,24-tetramethoxy-2,8,14,20-tetraethylphenylresorcin[4]arene – ethyl acetate (1/1), C68H72O10
  52. Crystal structure of chlorido-(N-(2,5-dichlorophenyl)-1-(pyridin-2-yl)methanimine-κ2N,N′)(η6-1-isopropyl-4-methyl benzene) ruthenium (II) tetrafluoroborate, C22H22Cl3N2BF4Ru
  53. Crystal structure of 3-(5-methyl-1-p-tolyl-1H-1,2,3-triazol-4-yl)-1-phenyl-1H-pyrazole-4-carbaldehyde, a rare Z′ = 3 structure, C20H17N5O
  54. Crystal structure of 5-(5-(4-chlorophenyl)-1-phenyl-1H-pyrazol-3-yl)-N-phenyl-1,3,4-thiadiazol-2-amine, C23H16ClN5S
  55. Crystal structure of 7-hydroxy-3-(4-hydroxyphenyl)-4H-1-benzopyran-4-one-N,N-dimethylformamide (1/1), C18H17NO5
  56. Crystal structure of halogen-bonded 2-chloro-1,10-phenanthroline—1,4-diiodotetrafluorobenzene (2/1), C30H14Cl2F4I2N4
  57. Crystal structure of 1-(4,4-dimethyl-2,6-dithioxo-1,3,5-triazinan-1-yl)-3-(diethylaminocarbonyl)thiourea, C11H20N6OS3
  58. Crystal structure of methyl 1-(4-fluorobenzyl)-3-phenyl-1H-pyrazole-5-carboxylate, C18H15FN2O2
  59. Crystal structure of 1,1-dimethyl-3-(4-methylphenyl)urea, C10H14N2O
  60. Crystal structure of yttrium gallium antimonide, Y5Ga1.24Sb2.77
  61. Crystal structure of 2-(bis(4-methoxyphenyl)amino)-2-oxoacetic acid, C16H15NO5
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Heruntergeladen am 1.10.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2016-0182/html
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