Startseite Transformative applications of “click” chemistry in the development of MOF architectures − a mini review
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Transformative applications of “click” chemistry in the development of MOF architectures − a mini review

  • Abdelkarim Chaouiki EMAIL logo , Siti Fatimah , Hamid Ahchouch , Mohamed Bakhouch , Maryam Chafiq EMAIL logo , Jungho Ryu und Young Gun Ko EMAIL logo
Veröffentlicht/Copyright: 28. Juni 2024
Reviews in Inorganic Chemistry
Aus der Zeitschrift Reviews in Inorganic Chemistry Band 44 Heft 4

Abstract

Metal-organic frameworks (MOFs) represent a fusion of compelling porous structures, alluring physical and chemical attributes, and extensive possibilities for application. The inherent capability of employing these organic constituents has paved the path for the construction of MOFs, permitting imaginative pre-design and post-synthetic adjustments through apt reactions. This adaptability not only enriches the structural variety of MOFs but also uncovers pathways for customizing their characteristics to align with precise application needs. In this context, click chemistry has emerged as a potent and resilient tool in the creation and modification of diverse functional materials, with a promising application in MOF structures. These MOF architectures undergo postsynthetic modifications through the application of “click” chemistry. This approach, characterized by its efficiency and selectivity, proves instrumental in tailoring and enhancing the properties of MOFs, thereby expanding their utility across a spectrum of scientific and industrial applications. Herein, we illuminate recent MOF structures achieved through the postsynthetic application of “click” chemistry. Our exploration delves into the forefront of strategies propelling the postsynthetic modification process, with a dedicated focus on the structural complexities, synthesis methodologies, and the prospective applications of these modified MOF architectures. Our intention is to actively contribute to the continuous discourse on applications of click chemistry in the development of MOF architectures, encouraging scientists to dedicate their expertise and efforts towards the advancement of these multifunctional materials.

Keywords: click chemistry; metal-organic frameworks; reticular chemistry; functionalization; ligation
Corresponding authors: Abdelkarim Chaouiki, Maryam Chafiq, and Young Gun Ko, School of Materials Science and Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea, E-mail: (A. Chaouiki), (M. Chafiq), (Y. G. Ko)
Abdelkarim Chaouiki and Siti Fatimah contributed equally to this work.

  1. Research ethics: Not applicable.

  2. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  3. Competing interests: The authors declare no conflicts of interest regarding this article.

  4. Research funding: This work was supported by the Fundamental-Core National Project of the National Research Foundation (NRF) funded by the Ministry of Science and ICT, Republic of Korea (2022R1F1A1072739).

  5. Data availability: Not applicable.

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Received: 2023-12-13
Accepted: 2024-06-07
Published Online: 2024-06-28
Published in Print: 2024-11-26

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Unveiling the multifaceted roles of protonated 1,2-bis(4-pyridyl)ethylene (HBpe+) ligand in metal-driven supramolecular assembly: a comprehensive structural review
  3. Advanced synthetic routes of metal organic frameworks and their diverse applications
  4. Carbon materials derived by crystalline porous materials for capacitive energy storage
  5. BiVO4-based heterojunction nanophotocatalysts for water splitting and organic pollutant degradation: a comprehensive review of photocatalytic innovation
  6. Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base
  7. Solid-phase extraction of organophosphates from polluted waters on a matrix-imprinted sorbent
  8. Reduction mechanism and energy transfer between Eu3+ and Eu2+ in Eu-doped materials synthesized in air atmosphere
  9. Green synthesis and applications of mono/bimetallic nanoparticles on mesoporous clay: a review
  10. Hydroxyapatite biomaterials: a comprehensive review of their properties, structures, clinical applications, and producing techniques
  11. Water desalination, and energy consumption applications of 2D nano materials: hexagonal boron nitride, graphenes, and quantum dots
  12. Transformative applications of “click” chemistry in the development of MOF architectures − a mini review
  13. A review of carbon-based adsorbents for the removal of organic and inorganic components
  14. Mercury removal from water: insights from MOFs and their composites
  15. Organometallic complexes and reaction methods for synthesis: a review
  16. Comprehensive review of metal-based coordination compounds in cancer therapy: from design to biochemical reactivity
https://doi.org/10.1515/revic-2023-0037
Schlagwörter für diesen Artikel
click chemistry; metal-organic frameworks; reticular chemistry; functionalization; ligation

Artikel in diesem Heft

  1. Frontmatter
  2. Unveiling the multifaceted roles of protonated 1,2-bis(4-pyridyl)ethylene (HBpe+) ligand in metal-driven supramolecular assembly: a comprehensive structural review
  3. Advanced synthetic routes of metal organic frameworks and their diverse applications
  4. Carbon materials derived by crystalline porous materials for capacitive energy storage
  5. BiVO4-based heterojunction nanophotocatalysts for water splitting and organic pollutant degradation: a comprehensive review of photocatalytic innovation
  6. Synthesis, characterization, thermal, theoretical studies, antimicrobial, antioxidant activity, superoxide dismutase-like activity and catalase mimetics of metal(II) complexes derived from sugar and Schiff base
  7. Solid-phase extraction of organophosphates from polluted waters on a matrix-imprinted sorbent
  8. Reduction mechanism and energy transfer between Eu3+ and Eu2+ in Eu-doped materials synthesized in air atmosphere
  9. Green synthesis and applications of mono/bimetallic nanoparticles on mesoporous clay: a review
  10. Hydroxyapatite biomaterials: a comprehensive review of their properties, structures, clinical applications, and producing techniques
  11. Water desalination, and energy consumption applications of 2D nano materials: hexagonal boron nitride, graphenes, and quantum dots
  12. Transformative applications of “click” chemistry in the development of MOF architectures − a mini review
  13. A review of carbon-based adsorbents for the removal of organic and inorganic components
  14. Mercury removal from water: insights from MOFs and their composites
  15. Organometallic complexes and reaction methods for synthesis: a review
  16. Comprehensive review of metal-based coordination compounds in cancer therapy: from design to biochemical reactivity
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