Synthesis and characterisation of alkaline earth-iron(III) double hydroxides
-
Mónika Sipiczki
,
Dávid Srankó
Abstract
Double hydroxides containing alkaline earth and iron(III) ions were synthesised by the co-precipitation method. The solid materials obtained were characterised by a range of instrumental methods (powder X-ray diffractometry, thermogravimetry, scanning electron microscopy, energy dispersive X-ray fluorescence spectrometry, elemental maps, and infrared spectroscopy). It was found that the Ca(II)Fe(III), Mg(II)Fe(III), and Ba(II)Fe(III) double hydroxides had layered structures, while Sr(II)Fe(III) had not. The optimum conditions for synthesis of Ca(II)Fe(III)-layered double hydroxides (materials to be used in further studies) were also elaborated.
[1] Cavani, F., Trifirò, F., & Vaccari, A. (1991). Hydrotalcitetype anionic clays: Preparation, properties and applications. Catalysis Today, 11, 173–301. DOI: 10.1016/0920-5861(91)80068-K. http://dx.doi.org/10.1016/0920-5861(91)80068-K10.1016/0920-5861(91)80068-KSearch in Google Scholar
[2] Evans, D. G., & Slade, R. C. T. (2006). Structural aspects of layered double hydroxides. Structure & Bonding, 119, 1–87. DOI: 10.1007/430 005. Search in Google Scholar
[3] Feitknecht, W., & Gerber, M. (1942). Zur kenntnis der Doppelhydroxyde und basischen Doppelsalze III. Über Magnesium-Aluminiumdoppelhydroxyd. Helvetica Chimica Acta, 25, 131–137. http://dx.doi.org/10.1002/hlca.1942025011510.1002/hlca.19420250115Search in Google Scholar
[4] Hirahara, H., Sawai, Y., Aisawa, S., Takahashi, S., Umetsu, Y., & Narita, E. (2002). Synthesis and antacid property of Mg-Fe layered double hydroxide. Nendo Kagaku, 42, 70–75. (in Japanese) Search in Google Scholar
[5] Liang, X., Hou, W., & Xu, J. (2009). Sorption of Pb(II) on Mg-Fe layered double hydroxide. Chinese Journal of Chemistry, 27, 1981–1988. DOI: 10.1002/cjoc.200990333. http://dx.doi.org/10.1002/cjoc.20099033310.1002/cjoc.200990333Search in Google Scholar
[6] Meng, W., Li, F., Evans, D. G., & Duan, X. (2004). Preparation and intercalation chemistry of magnesium-iron(III) layered double hydroxides containing exchangeable interlayer chlo ride and nitrate ions. Materials Research Bulletin, 39, 1185–1193. DOI: 10.1016/j.materresbull.2004.04.016. http://dx.doi.org/10.1016/j.materresbull.2004.04.01610.1016/j.materresbull.2004.04.016Search in Google Scholar
[7] Pálinkó, I. (2006). Organic-inorganic nanohybrids of biologically important molecules and layered double hydroxides. Nanopages, 1, 295–314. DOI: 10.1556/Nano.1.2006.3.2. http://dx.doi.org/10.1556/NANO.1.2006.3.210.1556/NANO.1.2006.3.2Search in Google Scholar
[8] Prasanna, S. V., Kamath, P. V., & Shivakumara, C. (2007). Synthesis and characterization of layered double hydroxides (LDHs) with intercalated chromate ions. Materials Research Bulletin, 42, 1028–1039. DOI: 10.1016/j.materresbull.2006.09.021. http://dx.doi.org/10.1016/j.materresbull.2006.09.02110.1016/j.materresbull.2006.09.021Search in Google Scholar
[9] Rives, V. (2001). Study of layered double hydroxides by thermal methods. In V. Rives (Ed.), Layered double hydroxides present and future (pp. 127–151). New York, NY, USA: Nova Science Publisher Inc. Search in Google Scholar
[10] Seida, Y., & Nakano, Y. (2000). Removal of humic substances by layered double hydroxide containing iron. Water Research, 34, 1487–1494. DOI: 10.1016/S0043-1354(99)00295-X. http://dx.doi.org/10.1016/S0043-1354(99)00295-X10.1016/S0043-1354(99)00295-XSearch in Google Scholar
[11] Srankó, D., Pallagi, A., Kuzmann, E., Canton, S. E., Walczak, M., Sápi, A., Kukovecz, Á., Kónya, Z., Sipos, P., & Pálinkó, I. (2010). Synthesis and properties of novel Ba(II)Fe(III) layered double hydroxides. Applied Clay Science, 48, 214–217. DOI: 10.1016/j.clay.2009.11.028. http://dx.doi.org/10.1016/j.clay.2009.11.02810.1016/j.clay.2009.11.028Search in Google Scholar
[12] Srankó, D., Pallagi, A., Pálinkó, I., Kuzmann, E., Canton, S. E., Walczak, M., & Sipos, P. (2009). Synthesis and structural features of a novel Ba(II)-Fe(III)-layered double hydroxide. In M. Melník, P. Segl’a, & M. Tatarko (Eds.), Insights into coordination, bioinorganic and applied inorganic chemistry (pp. 380–385). Bratislava, Slovakia: Slovak University of Technology Press. Search in Google Scholar
[13] Srankó, D., Sipiczki, M., Bajnóczi, É. G., Darányi, M., Kukovecz, Á., Kónya, Z., Canton, S. E., Norén, K., Sipos, P., & Pálinkó, I. (2011). A SEM, EDX and XAS characterization of Ba(II)Fe(III) layered double hydroxides. Journal of Molecular Structure, 993, 62–66. DOI: 10.1016/j.molstruc.2010.10.004. http://dx.doi.org/10.1016/j.molstruc.2010.10.00410.1016/j.molstruc.2010.10.004Search in Google Scholar
[14] Vaccari, A. (1998). Preparation and catalytic properties of cationic and anionic clays. Catalysis Today, 41, 53–71. DOI: 10.1016/S0920-5861(98)00038-8. http://dx.doi.org/10.1016/S0920-5861(98)00038-810.1016/S0920-5861(98)00038-8Search in Google Scholar
[15] Wang, L., Xu, X., Evans, D. G., Duan, X., & Li, D. (2010). Synthesis and selective IR absorption properties of iminodiacetic-acid intercalated MgAl-layered double hydroxide. Journal of Solid State Chemistry, 183, 1114–1119. DOI:10.1016/j.jssc.2010.03.022. http://dx.doi.org/10.1016/j.jssc.2010.03.02210.1016/j.jssc.2010.03.022Search in Google Scholar
[16] Woo, M. A., Kim, T.W., Paek, M.-J., Ha, H.-W., Choy, J.-H., & Hwang, S.-J. (2011). Phosphate-intercalated Ca-Fe-layered double hydroxides: Crystal structure, bonding character, and release kinetics of phosphate. Journal of Solid State Chemistry, 184, 171–176. DOI: 10.1016/j.jssc.2010.11.003. http://dx.doi.org/10.1016/j.jssc.2010.11.00310.1016/j.jssc.2010.11.003Search in Google Scholar
© 2011 Institute of Chemistry, Slovak Academy of Sciences
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