Abstract
After catalyst screening for oxidative desulfurization of fuel oil within several polyoxometalates, H3PW6Mo6O40 was confirmed for the first time to be an effective and recoverable catalyst for the oxidative removal of thiophene, being also effective for the desulfurization of real diesel and gasoline.
[1] Al-Shahrani, F., Xiao, T., Liewellyn, S. A., Barri S., Jiang, Z., Shi, H., Martinie, G., & Green, M. L. H. (2007). Desulfurization of diesel via the H2O2 oxidation of aromatic sulfides to sulfones using a tungstste catalyst. Applied Catalysis B: Environmental, 73, 311–316. DOI: 10.1016/j.apcatb.2006.12.016. http://dx.doi.org/10.1016/j.apcatb.2006.12.01610.1016/j.apcatb.2006.12.016Search in Google Scholar
[2] Collins, F. M., Lucy, A. R., & Sharp, C. (1997). Oxidative desulphurization of oils via hydrogen peroxide and heteropolyanion catalysis. Journal of Molecular Catalysis A: Chemical, 117, 397–403. DOI: 10.1016/S1381-1169(96)00251-8. http://dx.doi.org/10.1016/S1381-1169(96)00251-810.1016/S1381-1169(96)00251-8Search in Google Scholar
[3] García-Gutiérrez, J. L., Fuentes, G. A., Hernández-Terán, M. E., Murrieta, F., Navarrete, J., & Jiménez-Cruz, F. (2006). Ultra-deep oxidative desulfurization of diesel fuel with H2O2 catalyzed under mild conditions by polymolybdates supported on Al2O3. Applied Catalysis A: General, 305, 15–20. DOI: 10.1016/j.apcata.2006.01.027. http://dx.doi.org/10.1016/j.apcata.2006.01.02710.1016/j.apcata.2006.01.027Search in Google Scholar
[4] Kong, L. Y., Li, G., Wang, X. S., & Wang, Y. (2004). Thiophene oxidation over titanium silicalite using hydrogen peroxide. Chinese Journal of Catalysis, 25, 89–90. Search in Google Scholar
[5] Kozhevnikov, I. V. (2002). Catalysts for fine chemical synthesis, Volume 2, Catalysis by polyoxometalates. Chichester: John Wiley & Sons. Search in Google Scholar
[6] Li, C., Jiang, Z., Gao, J., Yang, Y., Wang, S., Tian, F., Sun, F., Sun, X., Ying, P., & Han, C. (2004). Ultra-deep desulfurization of diesel: Oxidation with a recoverable catalyst assembled in emulsion. Chemistry — A European Journal, 10, 2277–2280. DOI: 10.1002/chem.200305679. http://dx.doi.org/10.1002/chem.20030567910.1002/chem.200305679Search in Google Scholar
[7] Otsuki, S., Nonaka, T., Takashima, N., Qian, W., Ishihara, A., Imai, T., & Kabe, T. (2000). Oxidative desulfurization of light gas oil and vacuum gas oil by oxidation and solvent extraction. Energy & Fuels, 14, 1232–1239. DOI: 10.1021/ef000096i. http://dx.doi.org/10.1021/ef000096i10.1021/ef000096iSearch in Google Scholar
[8] Te, M., Fairbridge, C., & Ring, Z. (2001). Oxidation reactivities of dibenzothiophenes in polyoxometalate/H2O2 and formic acid/H2O2 systems. Applied Catalysis A: General, 219, 267–280. DOI: 10.1016/S0926-860X(01)00699-8. http://dx.doi.org/10.1016/S0926-860X(01)00699-810.1016/S0926-860X(01)00699-8Search in Google Scholar
[9] Yazu, K., Furuya, T., Miki, K., & Ukegawa, K. (2003). Tungstophosphoric acid-catalyzed oxidative desulfurization of light oil with hydrogen peroxide in a light oil/acetic acid biphasic system. Chemistry Letters, 32, 920–921. DOI: 10.1246/cl.2003.920. http://dx.doi.org/10.1246/cl.2003.92010.1246/cl.2003.920Search in Google Scholar
[10] Zapata, B., Pedraza, F., & Valenzuela, M. A. (2005). Catalyst screening for oxidative desulfurization using hydrogen peroxide. Catalysis Today, 106, 219–221. DOI: 10.1016/j.cattod.2005.07.134. http://dx.doi.org/10.1016/j.cattod.2005.07.13410.1016/j.cattod.2005.07.134Search in Google Scholar
© 2009 Institute of Chemistry, Slovak Academy of Sciences
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Articles in the same Issue
- Magnetic nano- and microparticles in biotechnology
- Application of gas chromatography-mass spectrometry in research of traditional Chinese medicine
- Copper determination using ICP-MS with hexapole collision cell
- Reactivation of a palladium catalyst during glucose oxidation by molecular oxygen
- Robust stabilization of a chemical reactor
- Influence of production progress on the heavy metal content in flax fibers
- In vitro antifungal and antibacterial properties of thiodiamine transition metal complexes
- Synthesis, characterization, and antimicrobial activity of new benzoylthiourea ligands
- Investigation of DNA cleavage activities of new oxime-type ligand complexes and molecular modeling of complex-DNA interactions
- Characterization of mechanochemically synthesized lead selenide
- Hydroxyapatite modified with silica used for sorption of copper(II)
- Corrosion resistance of zinc electrodeposited from acidic and alkaline electrolytes using pulse current
- Ternary composites of multi-wall carbon nanotubes, polyaniline, and noble-metal nanoparticles for potential applications in electrocatalysis
- Synthesis of 2-[3-(trifluoromethyl)phenyl]furo[3,2-c]pyridine derivatives
- Key side products due to reactivity of dimethylmaleoyl moiety as amine protective group
- Comparative DFT study on the α-glycosidic bond in reactive species of galactosyl diphosphates
- Gas chromatographic retention times prediction for components of petroleum condensate fraction
- Gas chromatography with surface ionization detection of nitro pesticides
- Clean fuel-oriented investigation of thiophene oxidation by hydrogen peroxide using polyoxometalate as catalyst
- Aqueous foam stabilized by polyoxyethylene dodecyl ether