Home Crystal structure of catena-poly[diaqua-bis(μ2-3,5-di(1H-1,2,4-triazol-1-yl)benzoate-κ2N:N′)cobalt(II))] 2.5 hydrate, C22H23CoN12O8.50
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Crystal structure of catena-poly[diaqua-bis(μ2-3,5-di(1H-1,2,4-triazol-1-yl)benzoate-κ2N:N′)cobalt(II))] 2.5 hydrate, C22H23CoN12O8.50

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Published/Copyright: August 13, 2018
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 233 Issue 6

Abstract

C22H23CoN12O8.50, triclinic, P1̄ (no. 2), a = 9.6549(3) Å, b = 10.6027(4) Å, c = 13.4938(4) Å, α = 100.824(3)°, β = 99.707(3)°, γ = 96.642(3)°, V = 1321.76(8) Å3, Z = 2, Rgt(F) = 0.0366, wRref(F2) = 0.0914, T = 288.03(10) K.

CCDC no.: 1858180

The crystal structure is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Clear light pink block
Size:0.27 × 0.21 × 0.15 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:0.73 mm−1
Diffractometer, scan mode:SuperNova, φ and ω
θmax, completeness:25.5°, 99%
N(hkl)measured, N(hkl)unique, Rint:14128, 4844, 0.028
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 4245
N(param)refined:412
Programs:CrysAlisPRO [1], SHELX [2, 3]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Co010.50001.00001.00000.01936(12)
Co021.00000.50000.50000.01942(12)
O10.8678(2)0.32659(17)1.20232(13)0.0390(5)
O2a1.0096(6)0.2309(5)1.1044(4)0.0367(9)
O2Ab0.9388(6)0.1854(5)1.0895(4)0.0367(9)
O30.32773(19)0.89171(18)0.22653(13)0.0358(4)
O40.2417(2)1.03115(17)0.33668(13)0.0382(4)
O50.68976(17)1.02834(16)0.94737(12)0.0301(4)
H5A0.74821.09000.98960.045*
H5B0.67491.05660.89150.045*
O61.03655(18)0.67644(15)0.60434(12)0.0308(4)
H6A1.01420.73570.57290.046*
H6B1.12530.69770.62780.046*
O70.0488(3)1.1038(2)0.44923(19)0.0608(6)
H7A−0.02611.04820.43680.091*
H7B0.10821.07410.41470.091*
O80.2284(2)1.23730(19)0.24516(16)0.0502(5)
H8A0.23731.17040.27040.075*
H8B0.14861.22550.20430.075*
N10.6489(2)0.63604(18)1.00752(14)0.0234(4)
N20.5733(2)0.63768(19)1.08453(15)0.0300(5)
N30.5464(2)0.80891(18)1.01085(15)0.0246(4)
N40.8938(2)0.38858(17)0.77082(14)0.0219(4)
N50.9699(2)0.29075(19)0.74506(16)0.0322(5)
N60.9464(2)0.40871(18)0.62279(14)0.0246(4)
N70.3624(2)0.88666(18)0.67502(14)0.0238(4)
N80.2540(2)0.9546(2)0.69348(16)0.0337(5)
N90.3917(2)0.94110(18)0.84193(14)0.0251(4)
N100.5937(2)0.62392(18)0.43906(14)0.0248(4)
N110.5815(2)0.5432(2)0.34465(15)0.0322(5)
N120.7849(2)0.53384(18)0.45077(15)0.0252(4)
C10.7313(2)0.5351(2)0.98384(17)0.0215(5)
C20.7654(2)0.5079(2)0.88717(17)0.0224(5)
H20.73320.55280.83700.027*
C30.8490(2)0.4117(2)0.86740(17)0.0211(5)
C40.8922(2)0.3403(2)0.93998(17)0.0226(5)
H40.94660.27490.92500.027*
C50.8533(2)0.3677(2)1.03540(17)0.0233(5)
C60.7742(2)0.4670(2)1.05818(17)0.0235(5)
H60.75060.48741.12270.028*
C70.6313(3)0.7386(2)0.96515(18)0.0258(5)
H70.67270.75780.91130.031*
C80.5141(3)0.7425(2)1.08300(18)0.0276(5)
H80.45470.76941.12770.033*
C90.8823(3)0.4569(2)0.69663(17)0.0256(5)
H90.83530.52880.69730.031*
C100.9978(3)0.3065(2)0.65592(19)0.0297(6)
H101.04860.25230.61850.036*
C110.9023(3)0.2952(2)1.11814(18)0.0299(6)
C120.3850(2)0.8441(2)0.57319(16)0.0213(5)
C130.4696(2)0.7488(2)0.55503(17)0.0239(5)
H130.50760.70960.60740.029*
C140.4963(2)0.7136(2)0.45687(17)0.0221(5)
C150.4391(2)0.7693(2)0.37761(18)0.0239(5)
H150.45730.74330.31190.029*
C160.3540(2)0.8648(2)0.39733(17)0.0217(5)
C170.3276(2)0.9030(2)0.49574(17)0.0228(5)
H170.27180.96750.50950.027*
C180.4417(2)0.8808(2)0.76462(17)0.0256(5)
H180.52170.83960.77140.031*
C190.2761(3)0.9841(3)0.79417(19)0.0323(6)
H190.21751.03060.83010.039*
C200.3017(2)0.9342(2)0.31297(18)0.0243(5)
C210.7151(2)0.6167(2)0.49999(18)0.0250(5)
H210.74600.66320.56740.030*
C220.6992(3)0.4920(2)0.35664(19)0.0294(5)
H220.72200.43170.30470.035*
O9c0.9241(4)−0.0389(4)1.0463(3)0.0482(10)
H9Ac0.9693−0.07141.00130.072*
H9Bc0.94770.04231.04910.072*

  1. aOccupancy: 0.517(5), bOccupancy: 0.483(5), cOccupancy: 0.5.

Source of material

The title compound was prepared by hydrothermal method. A mixture of Co(OAc)2 ⋅ 4 H2O (0.049 g, 0.2 mmol), 3,5-di(1,2,4-triazole-4)benzenecarboxylic acid (0.0256 g, 0.1 mmol), and H2O (10 mL) was sealed in a 25 mL Teflon-lined stainless steel vessel and heated at 160 °C for 4 days. The reaction mixture was slowly cooled to room temperature at a rate of 5 °C/h, and the red block crystals were collected, washed with water, and dried in air.

Experimental details

The hydrogen atoms were assigned with common isotropic displacement factors Uiso(H) = 1.2 times Ueq (C, aromatic ring), and Uiso(H) = 1.5 times Ueq(O, water). The final refinement by using geometrical restraints, with C—H = 0.93 Å (aromatic ring), and O—H = 0.85 Å (water).

Comment

Coordination polymer (CPs) or organic-inorganic hybrid materials, constructed by inorganic secondary building units and organic bridging ligands has taken wide attention owing to their intriguing structural as well as distinctive properties such as catalytic, luminescence, gas adsorption, and magnetism [4], [5], [6]. It is well known that the structures and properties of the CPs are strongly dependent on the organic ligands and the metal ions [7]. Bifunctional ligands containing carboxylate groups and nitrogen donors have attracted great interests in construction of CPs [8].

The asymmetric unit of the title compound consists of two-half Co(II) ions, two 3,5-di(1,2,4-triazole-4)benzenecarboxylic acid anions (L−), two coordinated water molecules and two and a half lattice water molecules (Figure). The two Co1 centers are both six-coordinated with slightly distorted octahedral geometry. The coordinations are completed by four nitrogen atoms from four different L− anions, and two oxygen atoms from coordinated water molecules. The Co—N bond lengths are in the range of 2.1506(18)–2.1737(18) Å, and the Co—O bond lengths are 2.0840(16) and 2.0728(16) Å, respectively. In the title compound, each L− ligand coordinated to two center Co(II) ions by two nitrogen atoms. Thus adjacent Co(II) ions are connected into 1D chain structure. The carboxyl group of L− did not participate in the coordination.

References

Agilent Technologies: CrysAlisPRO Software System, Agilent Technologies UK Ltd, Oxford, UK (2011).Search in Google Scholar

Sheldrick, G. M.: SHELXS97. Program for the solution of crystal structures. University of Göttingen, Germany (1997).Search in Google Scholar

Sheldrick, G. M.: SHELXTL. Structure determination software suite. Version 5.10. Bruker AXS, Madison, WI, USA (1998).Search in Google Scholar

Janiak, C.: Engineering coordination polymers towards applications. Dalton Trans. 14 (2003) 2781–2804.10.1039/b305705bSearch in Google Scholar

Miao, S. B.; Li, Z. H.; Xu, C. Y.; Ji, B. M.: A new 3-fold interpenetrating 3D Zn(II) metal-organic framework: synthesis, structures and luminescent property. Chin. J. Struct. Chem. 35 (2016) 1960–1966.Search in Google Scholar

Kurmoo, M.: Magnetic metal-organic frameworks. Chem. Soc. Rev. 38 (2009) 1353–1379.10.1039/b804757jSearch in Google Scholar PubMed

Yang, J.; Ma, J. F.; Liu, Y. Y.; Ma, J. C.; Batten, S. R.: A series of Cu(II) complexes based on different bis(imidazole) ligands and organic acids: formation of water clusters and fixation of atmospheric carbon dioxide. Cryst. Growth Des. 8 (2008) 4383–4393.10.1021/cg701119gSearch in Google Scholar

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Received: 2018-03-24
Accepted: 2018-07-25
Published Online: 2018-08-13
Published in Print: 2018-11-27

©2018 Hong-Hong Lan, published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of di-μ2-aqua-tetraaqua-bis(4-(1H-1,2,4-triazol-1-yl)benzoato-κN)disodium(I) C18H24N6Na2O10
  3. Crystal structure of diaqua-bis(2-bromo-4-chloro-6-formylphenolato-κ2O,O′)cobalt(II), C16H16Cl2CrN3O7
  4. Crystal structure of catena-poly[(μ2-1-(4-(1H-pyrazol-1-yl)phenyl)ethan-1-one-κ2N:O)-bis(1,1,1-trifluoro-4-oxo-4-(thiophen-2-yl)but-2-en-2-olato-κ2O,O′)copper(II)], C27H18CuF6N2O5S2
  5. Crystal structure of ethyl 2-amino-4-(3,5-difluorophenyl)-7-methyl-5-oxo-4H,5H-pyrano[4,3-b]pyran-3-carboxylate, C18H15F2NO5
  6. Crystal structure of 5,5′-dimethoxy-2,2′-[1,1′-(ethylenedioxydinitrilo)diethylidyne]diphenol, C20H24N2O6
  7. Crystal structure of (E)-1-(4-(((E)-3,5-dichloro-2-hydroxybenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C16H14Cl2N2O2
  8. Crystal structure of 2,3,9,10,16,17,23,24-octakis(2,6-dimethylphenoxy)phthalocyanine - trichloromethane (1/2), C98H84Cl6N8O8
  9. Crystal structure of methyl 2-((1-(2-(methoxycarbonyl)benzyl)-1H-1,2,3-triazol-4-yl)methoxy)-1-naphthoate, C24H21N3O5
  10. Crystal structure of catena-poly[(μ2-3,3′-thiodipropionato-κ2O:O′)-(bipyridine-κ2N,N′)copper(II)] C16H16CuN2O4S
  11. Crystal structure of [4-chloro-2-(((2-((3-ethoxy-2-oxidobenzylidene)amino)phenyl)imino)(phenyl)methyl)phenolato-κ4N,N′,O,O′}nickel(II) - ethyl acetate (1/1), C32H29ClN2NiO5
  12. Crystal structure of (4-(4-chlorophenyl)-5-ethyl-1,3-dioxane-5-carboxylato-κ2O,O′)-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate, C29H52Cl2N4NiO9
  13. Crystal structure of ethyl 2-amino-4-(3,4-dimethylphenyl)-7-methyl-5-oxo-4H,5H-pyrano[4,3-b]pyran-3-carboxylate, C20H21NO5
  14. Structure and photochromism of 1,2-bis[2-methyl-5-(3-quinolyl)-3-thienyl]-3,3,4,4,5,5-hexafluorocyclopent-1-ene, C33H20F6N2S2
  15. Crystal structure of catena-poly[diaqua-bis(μ2-3,5-di(1H-1,2,4-triazol-1-yl)benzoate-κ2N:N′)cobalt(II))] 2.5 hydrate, C22H23CoN12O8.50
  16. The crystal structure of dichlorido(1,3-dimesityl-1H-3λ4-imidazol-2-yl)(morpholine-κN)palladium(IV), C25H33Cl2N3OPd
  17. Crystal structure of catena-poly[bis(4,4′-dipyridylaminium-kN)-(μ2-germanowolframato-κ2O:O′)-(2,2′-bipyridine-κ2N,N′)copper(II)] with a Keggin-type heteropolyoxoanion, [Cu(C10H8N2)(C10H10N3)2][GeW12O40] ⋅ H2O
  18. Crystal structure of diaqua-(N-(1-(pyrazin-2-yl)ethylidene)pyridin-1-ium-4-carbohydrazonate-κ3N,N′,O)-tris[nitrato-κ2O,O′)lanthanum(III), C12H15N8O12La
  19. The crystal structure of 2-hydroxy-4-((2-hydroxy-4-methoxy-3,6-dimethylbenzoyl)oxy)-3,6-dimethylbenzoic acid–methanol (1/1), C20H24O8
  20. Crystal structure of guanidinium tetrapropylammonium bis(hydrogencarbonate) dihydrate, C15H40N4O8
  21. Crystal structure of (Z)-2-bromo-3-(3,5-di-tert-butyl-4-hydroxyphenyl)-1-phenylprop-2-en-1-one, C23H27BrO2
  22. Crystal structure of 2-(4-(4H-1,2,4-triazol-4-yl)phenyl)acetic acid, C10H9N3O4
  23. Crystal structure of 4,4′-(1,4-phenylene)bis(1H-imidazol-3-ium)bis(2-carboxybenzoate), C30H26N4O8
  24. Crystal structure of 4,4′-(4,10-diphenyl-4,10-dihydropyreno[4,5-d:9,10-d′]diimidazole-5,11-diyl)bis(N,N-diphenylaniline), C66H44N6
  25. Crystal structure of catena-poly[diaqua-bis(μ2-5-(3-(1H-imidazol-5-yl)phenyl)tetrazol-2-ido-κ2N:N′)cobalt(II)], C20H18CoN12O2
  26. Crystal structure of 1,3-dimethyl-2-(p-tolyl)-1H-perimidin-3-ium iodide 1.5 hydrate, C20H22IN2O1.5
  27. Crystal structure of 2-(4-methoxyphenyl)chromane, C16H16O2
  28. Crystal structure of poly[(μ2-2-carboxy-5-nitroisophthalato-κ2O:O′)-(μ2-4-((1H-imidazol-1-yl)methyl)pyridine-κ2N:N′)zinc(II)], C18H12N4O8Zn
  29. Crystal structure of bis(1-((2-ethyl-4-methyl-1H-imidazol-1-yl)methyl)-1H-benzo[d][1,2,3]triazole-κ2N:N′)tetraiodidodicadmium(II), [Cd2(C13H15N5)2I4]
  30. Crystal structure of tetramethylammonium bis(acetato-κ1O)-tetrakis(μ3-3-((hydroxyimino)methyl)-5-methoxy-2-oxidobenzoate-κ5O,O′:O′,N:O′′)tetrazinc(II) — N,N′-dimethylformamide — water (1/2/2), C62H96Zn4N10O28
  31. Crystal structure of poly[(μ4-5-tert-butylisophthalato-κ4O:O′:O′′:O′′′)-(1,3-dimethyl-2-imidazolidinone-κO)zinc(II)] C17H22N2O5Zn
  32. Crystal structure of [tris(2-benzimidazolylmethyl)amine-κ4N,N′,N′′,N′′′]-[(pyridine-2,6-dicarboxylato-κ2O,N)]cadmium(II)–methanol (1:3) C34H36CdN8O7
  33. The crystal structure of bis(1H-benzo[d]imidazol-2-amine-κN)-diiodidocadmium(II), C14H14CdI2N6
  34. Crystal structure of tetrakis(1H-benzimidazol-2-amine)-κN)-bis(μ2-sulfonato-κ2O:O′)dizinc(II) - methanol (1/1), C30H36N12O10S2Zn2
  35. Crystal structure of 3β-methoxy-20α-dimethylamino-pregn-5-ene, C24H41NO
  36. Crystal structure of dimethyl 4,4′-oxydibenzoate, C16H14O5
  37. Crystal structure of catena-poly[diiodido-(μ2-1,5-dimethyl-2-phenyl-4-((pyridin-3-ylmethylene)amino)-1,2-dihydro-3H-pyrazol-3-one-κ2N:O)zinc(II)], C17H16I2N4OZn
  38. Crystal structure of 4-((E)-((E)-5-(2-fluorobenzylidene)-1-((4-fluorophenyl)sulfonyl)-4-oxopiperidin-3-ylidene)methyl)benzonitrile, C26H18F2N2O3S
  39. Crystal structure of bis(acetato-κ1O)-bis(1-(pyridin-2-yl)ethan-1-one oxime-κ2N,N′)zinc(II), C18H22N4O6Zn
  40. The crystal structure of 9-butoxy-2-(hydroxymethyl)-2H-imidazo[1,5-a]quinolin-10-ium bromide, C17H21O2N2Br
  41. Crystal stucture of 2-(tert-butyl)-6-(hydroxymethyl)-4-methylphenol, C12H18O2
  42. Crystal structure of catena-poly[(2-(5-chloroquinolin-8-yloxy)-1-(pyrrolidin-1-yl)ethan-1-one-κ3N,O,O′)-(dinitrato-κ2O,O′)mercury(II)], C15H15N4O8ClHg
  43. Crystal structure of dimethyl (3aS,6R,6aS,7S)-1H,3H,6H,7H-3a,6:7,9a-diepoxybenzo[de]isochromene-3a1,6a-dicarboxylate, C16H16O7
  44. The crystal structure of 2-(dimethoxymethyl)-4-(4-methylphenyl)-1H-imidazole—petroleum ether-chloroform (3/1), C27H33Cl3N4O4
  45. Crystal structure of 8-(trifluoromethyl)imidazo[1,2-a]pyridine-3-carbaldehyde, C9H5F3N2O
  46. The crystal structure of N,N-diethyl-4,6-bis(naphthalen-2-yloxy)-1,3,5-triazin-2-amine, C27H24N4O2
  47. Crystal structure of 5-bromo-7-chloro-3,3a-dihydrocyclopenta[b]chromen-1(2H)-one, C12H8BrClO2
  48. Crystal structure of 2-(bis(4-fluorophenyl)methylene)hydrazine-1-carbothioamide, C14H11F2N3S
https://doi.org/10.1515/ncrs-2018-0120
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Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of di-μ2-aqua-tetraaqua-bis(4-(1H-1,2,4-triazol-1-yl)benzoato-κN)disodium(I) C18H24N6Na2O10
  3. Crystal structure of diaqua-bis(2-bromo-4-chloro-6-formylphenolato-κ2O,O′)cobalt(II), C16H16Cl2CrN3O7
  4. Crystal structure of catena-poly[(μ2-1-(4-(1H-pyrazol-1-yl)phenyl)ethan-1-one-κ2N:O)-bis(1,1,1-trifluoro-4-oxo-4-(thiophen-2-yl)but-2-en-2-olato-κ2O,O′)copper(II)], C27H18CuF6N2O5S2
  5. Crystal structure of ethyl 2-amino-4-(3,5-difluorophenyl)-7-methyl-5-oxo-4H,5H-pyrano[4,3-b]pyran-3-carboxylate, C18H15F2NO5
  6. Crystal structure of 5,5′-dimethoxy-2,2′-[1,1′-(ethylenedioxydinitrilo)diethylidyne]diphenol, C20H24N2O6
  7. Crystal structure of (E)-1-(4-(((E)-3,5-dichloro-2-hydroxybenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C16H14Cl2N2O2
  8. Crystal structure of 2,3,9,10,16,17,23,24-octakis(2,6-dimethylphenoxy)phthalocyanine - trichloromethane (1/2), C98H84Cl6N8O8
  9. Crystal structure of methyl 2-((1-(2-(methoxycarbonyl)benzyl)-1H-1,2,3-triazol-4-yl)methoxy)-1-naphthoate, C24H21N3O5
  10. Crystal structure of catena-poly[(μ2-3,3′-thiodipropionato-κ2O:O′)-(bipyridine-κ2N,N′)copper(II)] C16H16CuN2O4S
  11. Crystal structure of [4-chloro-2-(((2-((3-ethoxy-2-oxidobenzylidene)amino)phenyl)imino)(phenyl)methyl)phenolato-κ4N,N′,O,O′}nickel(II) - ethyl acetate (1/1), C32H29ClN2NiO5
  12. Crystal structure of (4-(4-chlorophenyl)-5-ethyl-1,3-dioxane-5-carboxylato-κ2O,O′)-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate, C29H52Cl2N4NiO9
  13. Crystal structure of ethyl 2-amino-4-(3,4-dimethylphenyl)-7-methyl-5-oxo-4H,5H-pyrano[4,3-b]pyran-3-carboxylate, C20H21NO5
  14. Structure and photochromism of 1,2-bis[2-methyl-5-(3-quinolyl)-3-thienyl]-3,3,4,4,5,5-hexafluorocyclopent-1-ene, C33H20F6N2S2
  15. Crystal structure of catena-poly[diaqua-bis(μ2-3,5-di(1H-1,2,4-triazol-1-yl)benzoate-κ2N:N′)cobalt(II))] 2.5 hydrate, C22H23CoN12O8.50
  16. The crystal structure of dichlorido(1,3-dimesityl-1H-3λ4-imidazol-2-yl)(morpholine-κN)palladium(IV), C25H33Cl2N3OPd
  17. Crystal structure of catena-poly[bis(4,4′-dipyridylaminium-kN)-(μ2-germanowolframato-κ2O:O′)-(2,2′-bipyridine-κ2N,N′)copper(II)] with a Keggin-type heteropolyoxoanion, [Cu(C10H8N2)(C10H10N3)2][GeW12O40] ⋅ H2O
  18. Crystal structure of diaqua-(N-(1-(pyrazin-2-yl)ethylidene)pyridin-1-ium-4-carbohydrazonate-κ3N,N′,O)-tris[nitrato-κ2O,O′)lanthanum(III), C12H15N8O12La
  19. The crystal structure of 2-hydroxy-4-((2-hydroxy-4-methoxy-3,6-dimethylbenzoyl)oxy)-3,6-dimethylbenzoic acid–methanol (1/1), C20H24O8
  20. Crystal structure of guanidinium tetrapropylammonium bis(hydrogencarbonate) dihydrate, C15H40N4O8
  21. Crystal structure of (Z)-2-bromo-3-(3,5-di-tert-butyl-4-hydroxyphenyl)-1-phenylprop-2-en-1-one, C23H27BrO2
  22. Crystal structure of 2-(4-(4H-1,2,4-triazol-4-yl)phenyl)acetic acid, C10H9N3O4
  23. Crystal structure of 4,4′-(1,4-phenylene)bis(1H-imidazol-3-ium)bis(2-carboxybenzoate), C30H26N4O8
  24. Crystal structure of 4,4′-(4,10-diphenyl-4,10-dihydropyreno[4,5-d:9,10-d′]diimidazole-5,11-diyl)bis(N,N-diphenylaniline), C66H44N6
  25. Crystal structure of catena-poly[diaqua-bis(μ2-5-(3-(1H-imidazol-5-yl)phenyl)tetrazol-2-ido-κ2N:N′)cobalt(II)], C20H18CoN12O2
  26. Crystal structure of 1,3-dimethyl-2-(p-tolyl)-1H-perimidin-3-ium iodide 1.5 hydrate, C20H22IN2O1.5
  27. Crystal structure of 2-(4-methoxyphenyl)chromane, C16H16O2
  28. Crystal structure of poly[(μ2-2-carboxy-5-nitroisophthalato-κ2O:O′)-(μ2-4-((1H-imidazol-1-yl)methyl)pyridine-κ2N:N′)zinc(II)], C18H12N4O8Zn
  29. Crystal structure of bis(1-((2-ethyl-4-methyl-1H-imidazol-1-yl)methyl)-1H-benzo[d][1,2,3]triazole-κ2N:N′)tetraiodidodicadmium(II), [Cd2(C13H15N5)2I4]
  30. Crystal structure of tetramethylammonium bis(acetato-κ1O)-tetrakis(μ3-3-((hydroxyimino)methyl)-5-methoxy-2-oxidobenzoate-κ5O,O′:O′,N:O′′)tetrazinc(II) — N,N′-dimethylformamide — water (1/2/2), C62H96Zn4N10O28
  31. Crystal structure of poly[(μ4-5-tert-butylisophthalato-κ4O:O′:O′′:O′′′)-(1,3-dimethyl-2-imidazolidinone-κO)zinc(II)] C17H22N2O5Zn
  32. Crystal structure of [tris(2-benzimidazolylmethyl)amine-κ4N,N′,N′′,N′′′]-[(pyridine-2,6-dicarboxylato-κ2O,N)]cadmium(II)–methanol (1:3) C34H36CdN8O7
  33. The crystal structure of bis(1H-benzo[d]imidazol-2-amine-κN)-diiodidocadmium(II), C14H14CdI2N6
  34. Crystal structure of tetrakis(1H-benzimidazol-2-amine)-κN)-bis(μ2-sulfonato-κ2O:O′)dizinc(II) - methanol (1/1), C30H36N12O10S2Zn2
  35. Crystal structure of 3β-methoxy-20α-dimethylamino-pregn-5-ene, C24H41NO
  36. Crystal structure of dimethyl 4,4′-oxydibenzoate, C16H14O5
  37. Crystal structure of catena-poly[diiodido-(μ2-1,5-dimethyl-2-phenyl-4-((pyridin-3-ylmethylene)amino)-1,2-dihydro-3H-pyrazol-3-one-κ2N:O)zinc(II)], C17H16I2N4OZn
  38. Crystal structure of 4-((E)-((E)-5-(2-fluorobenzylidene)-1-((4-fluorophenyl)sulfonyl)-4-oxopiperidin-3-ylidene)methyl)benzonitrile, C26H18F2N2O3S
  39. Crystal structure of bis(acetato-κ1O)-bis(1-(pyridin-2-yl)ethan-1-one oxime-κ2N,N′)zinc(II), C18H22N4O6Zn
  40. The crystal structure of 9-butoxy-2-(hydroxymethyl)-2H-imidazo[1,5-a]quinolin-10-ium bromide, C17H21O2N2Br
  41. Crystal stucture of 2-(tert-butyl)-6-(hydroxymethyl)-4-methylphenol, C12H18O2
  42. Crystal structure of catena-poly[(2-(5-chloroquinolin-8-yloxy)-1-(pyrrolidin-1-yl)ethan-1-one-κ3N,O,O′)-(dinitrato-κ2O,O′)mercury(II)], C15H15N4O8ClHg
  43. Crystal structure of dimethyl (3aS,6R,6aS,7S)-1H,3H,6H,7H-3a,6:7,9a-diepoxybenzo[de]isochromene-3a1,6a-dicarboxylate, C16H16O7
  44. The crystal structure of 2-(dimethoxymethyl)-4-(4-methylphenyl)-1H-imidazole—petroleum ether-chloroform (3/1), C27H33Cl3N4O4
  45. Crystal structure of 8-(trifluoromethyl)imidazo[1,2-a]pyridine-3-carbaldehyde, C9H5F3N2O
  46. The crystal structure of N,N-diethyl-4,6-bis(naphthalen-2-yloxy)-1,3,5-triazin-2-amine, C27H24N4O2
  47. Crystal structure of 5-bromo-7-chloro-3,3a-dihydrocyclopenta[b]chromen-1(2H)-one, C12H8BrClO2
  48. Crystal structure of 2-(bis(4-fluorophenyl)methylene)hydrazine-1-carbothioamide, C14H11F2N3S
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