Startseite Phase Transformation of a Dual Phase Al–Fe Alloy Prepared by Mechanical Alloying
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Phase Transformation of a Dual Phase Al–Fe Alloy Prepared by Mechanical Alloying

  • Fei Zhou , Reinhard Lück EMAIL logo , Ke Lu und Manfred Rühle
Veröffentlicht/Copyright: 11. Februar 2022
Veröffentlichen auch Sie bei De Gruyter Brill
Informationen für Autor*innen
International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 92 Heft 7

Abstract

A metastable Al90Fe10 (at.%) alloy, composed of a supersaturated solid solution of face-centred cubic (fcc) Al(Fe) and an amorphous phase matrix, was prepared by mechanical alloying of a mixture of Al and Fe elemental blends. The thermally induced microstructural evolution in the dual phase alloy was characterized by X-ray diffraction, transmission electron microscopy, differential scanning calorimetry, and magnetothermal analysis. On continuous heating two stages of solid state phase transformation occurred: (i) a polymorphous crystallization of the amorphous phase to a metastable crystalline Al6Fe that structurally stabilizes over a temperature range of about 200 K, and (ii) a eutectoid decomposition of the crystalline Al6Fe into the equilibrium phases of Al13Fe4 and fcc Al(Fe). Thermodynamic and kinetic analyses of the observed phase transformation processes were given. The formation of the dual phase alloy in the as-milled state and the phase transitions can be illustrated by a hypothetical free energy diagram, implying the dual phase structure facilitates the polymorphous crystallization of Al6Fe.

Keywords: Mechanical alloying; Aluminium alloys; Thermodynamics; Polymorphous crystallization
Dr. R. Lück Max-Planck-Institut für Metallforschung Seestr. 92, D-70174 Stuttgart,Germany Fax: +49 7 11 2 26 57 22

Dedicated to Professor Dr. Dr. h. c. mult. Günter Petzow on the occasion of his 75th birthday

  1. The authors acknowledge support from the Exchange Programme Max-Planck-Gesellschaft / Chinese Academy of Sciences and the National Sciences Foundation of China (under grant No. 59701002). Helpful discussions with Prof. F. Sommer, Dr. H.-P. Lamparter, Max-Planck-Institut für Metallforschung Stuttgart, Dr. C. Beeli, Laboratory for Solid State Physics, ETH, Zürich, the critical reading by Dr. D. Warrington, and the experimental assistance of D. Lang, P. Kopold, D. Kohl and G. Wörner are gratefully acknowledged.

References

1 Inoue, A.: Progr. Mater. Sci. 43 (1998) 365.10.1016/S0079-6425(98)00005-XSuche in Google Scholar

2 He, Y.; Poon, S.J.; Shiflet, G. J.: Science 241 (1988) 1640.10.1126/science.241.4873.1640Suche in Google Scholar

3 Greer, A.L.: Science 267 (1995) 1947.10.1126/science.267.5206.1947Suche in Google Scholar

4 Kim, Y.H.; Inoue, A.; Masumoto, T.: Mater. Trans. JIM 31 (1991) 747 and 32 (1991) 331.10.2320/matertrans1989.31.747Suche in Google Scholar

5 Chen, H.; He, Y.; Shiflet, G.J.; Poon, S.J.: Scripta metall. 367 (1994) 541.Suche in Google Scholar

6 Zhong, Z.C.; Jiang, X.Y.; Greer, A.L.: Phil. Mag. B 76 (1997) 505.10.1080/01418639708241116Suche in Google Scholar

7 Chen, H.; He, Y.; Shiflet, G.J.; Poon, S.J.: Nature 367 (1994) 541.10.1038/367541a0Suche in Google Scholar

8 He, Y.; Shiflet, G.J.; Poon, S.J.: Acta metall. mater. 43 (1995) 83.10.1016/0956-7151(95)90264-3Suche in Google Scholar

9 Shingu, P.H.; Huang, H.; Nishitani, S.R.; Nasu, S.: Suppl. Trans. JIM 29 (1988) 3.Suche in Google Scholar

10 Huang, B.; Tokizane, N.; Ishihara, K.N.; Shingu, P.H.; Nasu, S.: J. Non-cryst. Solids 117/118 (1990) 688.10.1016/0022-3093(90)90622-SSuche in Google Scholar

11 Dong, Y.D.; Wang, W.H.; Liu, L.; Xiao, K.Q.; Tong, S.H.; He, Y.Z.: Mater. Sci. Eng. A 134 (1991) 867.10.1016/0921-5093(91)90879-RSuche in Google Scholar

12 Morris, M.A.; Morris, D.G.: Mater. Sci. Eng. A 136 (1991) 59.10.1016/0921-5093(91)90441-OSuche in Google Scholar

13 Mukhopadhyay, D.K.; Suryanarayana, C.; Froes, F.H.: Metall. Mater. Trans. A 26 (1995) 1939.10.1007/BF02670665Suche in Google Scholar

14 Froes, F.H.; Suryanarayana, C.: Int. J. Powder Metall. 28 (1992) 202.Suche in Google Scholar

15 Sheng, H.W.; Zhao, Y.H.; Hu, Z.Q.; Lu, K.: Phys. Rev. B 56 (1997) 2302.10.1103/PhysRevB.56.2302Suche in Google Scholar

16 Zhou, F.; Lück, R.; Scheffer, M.; Lang, D.; Lu, K.: J. Non-cryst. Solids 250–252 (1999) 704.10.1016/S0022-3093(99)00164-7Suche in Google Scholar

17 Zhou, F.; Zhang, X.H.; Lu, K.: J. Mater. Res. 13 (1998) 784.10.1557/JMR.1998.0100Suche in Google Scholar

18 Ye, F.; Lu, K.: Acta mater. 48 (1999) 2449.10.1016/S1359-6454(99)00104-4Suche in Google Scholar

19 Lu, K.: Mater. Sci. Eng. Report 16 (1995) 161.10.1016/0927-796X(95)00187-5Suche in Google Scholar

20 Kattner, U.R.; Burton, B.P., in: H. Okamoto (ed.), Phase Diagrams of Binary Iron Alloys, ASM International, Materials Park, OH (1992) 12.Suche in Google Scholar

21 Boettinger, W.J.; Bendersky, L.; Early, J.G.: Metall. Trans. A 17 (1986) 781.10.1007/BF02643853Suche in Google Scholar

22 Skjerpe, P.: Metall. Trans. A 18 (1987) 189.10.1007/BF02825700Suche in Google Scholar

23 Beisswenger, H.; Wachtel, E.,: Z. Metallkd. 46 (1955) 504.10.1515/ijmr-1955-460706Suche in Google Scholar

24 Griger, A.; Stefaniay, V.; Turmezey, T.: Z. Metallkd. 77 (1986) 30.10.1515/ijmr-1986-770107Suche in Google Scholar

25 Köster, U.; Herold, U., in: H.J. Güntherodt, H. Bech (eds.), Glassy Metals, Springer-Verlag, Berlin (1981) 225.10.1007/3540104402_10Suche in Google Scholar

26 Scott, M. G.in: F.E. Luborsky (ed.), Amorphous Metallic Alloys, Butterworths (1983) 144.10.1016/B978-0-408-11030-3.50015-7Suche in Google Scholar

27 Zhou, F.; Lück, R.; Lu, K.; Rühle, M.: unpublished results.Suche in Google Scholar

28 Kissinger, H.E.: Anal. Chem. 29 (1957) 1702.10.1021/ac60131a045Suche in Google Scholar

29 Allen, C..M.; O’Reilly, K.A.Q.; Evans, P.V.; Cantor, B.: Mater. Res. Soc. Symp. Proc. 481 (1998) 3.10.1557/PROC-481-3Suche in Google Scholar

30 Sheng, H.W.; Ren, G.; Peng, L.M.; Hu, Z.Q.; Lu, K.: Phil. Mag. Lett. 73 (1996) 179.10.1080/095008396180812Suche in Google Scholar
Received: 2001-03-15
Published Online: 2022-02-11

© 2001 Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Frontmatter
  2. Editorial
  3. “No wise man ever wish to be younger”
  4. Aufsätze/Articles
  5. Entropy, Transformations and Sustainability of Industrial Life Cycles
  6. Positron Annihilation in Stable and Supercooled Metallic Melts
  7. Local Characterization of the Diffusion Process during Discontinuous Precipitation: A Review
  8. The Dependence of Abnormal Grain Growth on Initial Grain Size in 316 L Stainless Steel
  9. Diffusion-Controlled Grain Growth in Liquid-Phase Sintering of W–Cu Nanocomposites
  10. Evaluation of Densification Mechanisms of Liquid-Phase Sintering
  11. Phase Transformation of a Dual Phase Al–Fe Alloy Prepared by Mechanical Alloying
  12. Discrete Element Simulation of Ceramic Powder Processing
  13. Strain Relaxation and Internal Friction in the Range of the Glass Transition
  14. A Thermodynamic Model of an Amorphous Grain Boundary Phase in Liquid-Phase Sintered β-SiAlON Ceramic
  15. Epitaxial Growth of Metals on (100) SrTiO3: The Influence of Lattice Mismatch and Reactivity
  16. Microstructure and Modifications of Cu/Al2O3 Interfaces
  17. Structural Transformations Induced by Swift Heavy Ions in Polysiloxanes and Polycarbosilanes
  18. Metastable Al–Nd–Ni and Stable Al–La–Ni Phase Equilibria
  19. Phase Equilibria of the Al–Nd and Al–Nd–Ni Systems
  20. System Pr –Pd–O: Phase Diagram and Thermodynamic Properties of Ternary Oxides Using Solid-State Cells with Special Features
  21. Calculation of Phase Equilibria in Candidate Solder Alloys
  22. Thermodynamic Assessment of the Zr–O Binary System
  23. Delaminating Layered Oxide Composites with Wavy Interfaces
  24. Contemporary Materials Issues for Advanced EB-PVD Thermal Barrier Coating Systems
  25. Monte Carlo Simulations of Strength Distributions of Brittle Materials – Type of Distribution, Specimen and Sample Size
  26. On the Optimization of the Microstructure in Powder Metallurgical Ag–SnO2–In2O3 Contact Materials
  27. Some New Aspects of Microstructural Design of β-Si3N4 Ceramics
  28. Ni-Based SOFC Anodes: Microstructure and Electrochemistry
  29. Effect of Copper Line Geometry and Process Parameters on Interconnect Microstructure and Degradation Processes
  30. Thermal Stability of Nanoscale Co/Cu Multilayers
  31. Methods for Characterising the Precipitation of Nanometer-Sized Secondary Hardening Carbides and Related Effects in Tool Steels
  32. Prediction of Local Strain and Hardness in Sheet Forming
  33. Novel in situ-Infiltrated Al2O3-Metal Composites
  34. Influence of Microstructure and Impurities on Thermal Conductivity of Aluminium Nitride Ceramics
  35. Notifications/Mitteilungen
  36. Personelles/Personal
  37. Bücher/Books
  38. Tagungen/Conferences
https://doi.org/10.1515/ijmr-2001-0129
Schlagwörter für diesen Artikel
Mechanical alloying; Aluminium alloys; Thermodynamics; Polymorphous crystallization

Artikel in diesem Heft

  1. Frontmatter
  2. Editorial
  3. “No wise man ever wish to be younger”
  4. Aufsätze/Articles
  5. Entropy, Transformations and Sustainability of Industrial Life Cycles
  6. Positron Annihilation in Stable and Supercooled Metallic Melts
  7. Local Characterization of the Diffusion Process during Discontinuous Precipitation: A Review
  8. The Dependence of Abnormal Grain Growth on Initial Grain Size in 316 L Stainless Steel
  9. Diffusion-Controlled Grain Growth in Liquid-Phase Sintering of W–Cu Nanocomposites
  10. Evaluation of Densification Mechanisms of Liquid-Phase Sintering
  11. Phase Transformation of a Dual Phase Al–Fe Alloy Prepared by Mechanical Alloying
  12. Discrete Element Simulation of Ceramic Powder Processing
  13. Strain Relaxation and Internal Friction in the Range of the Glass Transition
  14. A Thermodynamic Model of an Amorphous Grain Boundary Phase in Liquid-Phase Sintered β-SiAlON Ceramic
  15. Epitaxial Growth of Metals on (100) SrTiO3: The Influence of Lattice Mismatch and Reactivity
  16. Microstructure and Modifications of Cu/Al2O3 Interfaces
  17. Structural Transformations Induced by Swift Heavy Ions in Polysiloxanes and Polycarbosilanes
  18. Metastable Al–Nd–Ni and Stable Al–La–Ni Phase Equilibria
  19. Phase Equilibria of the Al–Nd and Al–Nd–Ni Systems
  20. System Pr –Pd–O: Phase Diagram and Thermodynamic Properties of Ternary Oxides Using Solid-State Cells with Special Features
  21. Calculation of Phase Equilibria in Candidate Solder Alloys
  22. Thermodynamic Assessment of the Zr–O Binary System
  23. Delaminating Layered Oxide Composites with Wavy Interfaces
  24. Contemporary Materials Issues for Advanced EB-PVD Thermal Barrier Coating Systems
  25. Monte Carlo Simulations of Strength Distributions of Brittle Materials – Type of Distribution, Specimen and Sample Size
  26. On the Optimization of the Microstructure in Powder Metallurgical Ag–SnO2–In2O3 Contact Materials
  27. Some New Aspects of Microstructural Design of β-Si3N4 Ceramics
  28. Ni-Based SOFC Anodes: Microstructure and Electrochemistry
  29. Effect of Copper Line Geometry and Process Parameters on Interconnect Microstructure and Degradation Processes
  30. Thermal Stability of Nanoscale Co/Cu Multilayers
  31. Methods for Characterising the Precipitation of Nanometer-Sized Secondary Hardening Carbides and Related Effects in Tool Steels
  32. Prediction of Local Strain and Hardness in Sheet Forming
  33. Novel in situ-Infiltrated Al2O3-Metal Composites
  34. Influence of Microstructure and Impurities on Thermal Conductivity of Aluminium Nitride Ceramics
  35. Notifications/Mitteilungen
  36. Personelles/Personal
  37. Bücher/Books
  38. Tagungen/Conferences
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 20.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ijmr-2001-0129/html
Button zum nach oben scrollen