Abstract
The contact flattening between grains has long been considered to be the densification mechanism during liquidphase sintering. Recently, however, we proposed pore filling as being the major mechanism. In this investigation, we critically examine the two densification mechanisms by calculating their contributions to the sintering. The calculation shows that the contact flattening can be operative at the early stage for systems with a dihedral angle of zero degrees. However, its contribution to grain shape change and compact shrinkage is insignificant compared with that of the grain growth. A consideration of microstructures in real systems further suggests that the contribution of contact flattening is much less than the calculated value and is negligible from the beginning of the liquid-phase sintering. In fact, pore filling, which is induced by grain growth, appears to be essentially the only densification mechanism. An exemplified calculation of densification kinetics by pore filling is also presented and its implication discussed.
-
This work was done under a joint research program of the Korea Advanced Institute of Science and Technology (KAIST) and the Institut National Polytechnique de Grenoble (INPG), supported by the Korean Ministry of Science and Technology (contract No. 99-I-03-057). The authors thank Mr. Sug-Woo Jung for his assistance in the preparation of the manuscript.
References
1 Kingery, W.D.: J. Appl. Phys. 30 (1959) 301.10.1063/1.1735155Search in Google Scholar
2 Lee, S.-M. ; Kang, S.-J.L.: Acta. Mater. 46 (1998) 3191.10.1016/S1359-6454(97)00489-8Search in Google Scholar
3 Cannon, H.S.; Lenel, F.V. in: F. Benesovsky (ed.), Proc. Plansee Seminar 1952, Metallwerk Plansee, Reutte (1953) 106.Search in Google Scholar
4 Huppmann, W.J.; Riegger, H.: Acta Metall. 23 (1975) 965.10.1016/0001-6160(75)90010-3Search in Google Scholar
5 Fortes, M.A.: Powd. Metall. Int. 14 (1982) 96.10.1051/gse:19820111Search in Google Scholar
6 Belhadjhamida, A.; German, R.M., in: A. Lawley, A. Swanson (eds.), Advance in Powder Metallurgy and Particulate Materials, Vol. 3, Gorden and Breach, New York (1993) 85.Search in Google Scholar
7 Lee, S.-M.; Chaix, J.M.; Martin, C.L.; Allibert, C.H.; Kang, S.-J.L.: Met. Mater. 5 (1999) 197.10.1007/BF03026053Search in Google Scholar
8 Gessinger, G.H.; Fischmeister, H.F.; Lukas, H.L.: Acta Metall. 21 (1973) 715.10.1016/0001-6160(73)90082-5Search in Google Scholar
9 Lifshitz, I.M.; Slyozov, V.V.: J. Phys. Chem. Solids 19 (1961) 35.10.1016/0022-3697(61)90054-3Search in Google Scholar
10 Wagner, C.: Z. Elektrochem. 65 (1961) 581.10.1001/archopht.1961.01840020583023Search in Google Scholar
11 Ardell, A.J.: Acta Metall. 20 (1972) 61.10.1016/0001-6160(72)90114-9Search in Google Scholar
12 Brailsford, A.D.; Wynblatt, P.: Acta Metall. 27 (1979) 489.10.1016/0001-6160(79)90041-5Search in Google Scholar
13 DeHoff, R.T.: Acta Metall. Mater. 39 (1991) 2349.10.1016/0956-7151(91)90016-TSearch in Google Scholar
14 German, R.M.; Olevsky, E.A.: Metall. Mater. Trans. A 29 (1998) 3057.10.1007/s11661-998-0213-zSearch in Google Scholar
15 Kingery, W.D.; Narasimhan, M.D.: J. Appl. Phys. 30 (1959) 307.10.1063/1.1735156Search in Google Scholar
16 Kwon, O.-J.; Yoon, D.N.: Int. J. Powder Metall. Powder Tech. 17 (1981) 127.Search in Google Scholar
17 Kang, S.-J.L.; Kaysser, W.A.; Petzow, G.; Yoon, D.N.: Powder Metall. 27 (1984) 97.10.1179/pom.1984.27.2.97Search in Google Scholar
18 Kaysser, W.A.; Petzow, G.: Z. Metallkd. 76 (1985) 687.Search in Google Scholar
19 Park, J.K.; Kang, S.-J.L.; Eun, K. Y.; Yoon, D. N.: Metall. Trans. A 20 (1989) 837.10.1007/BF02651650Search in Google Scholar
20 Sarian, S.; Weart, H.W.: J. Appl. Phys. 37 (1966) 1675.10.1063/1.1708583Search in Google Scholar
21 Kang, S.S.; Yoon, D.N.: Metall. Trans. A 13 (1982) 1405.10.1007/BF02642878Search in Google Scholar
22 Kim, S.S.; Yoon, D.N.: Acta Metall. 31 (1983) 1151.10.1016/0001-6160(83)90177-3Search in Google Scholar
23 Lee, D.-D.; Kang, S.-J.L.; Yoon, D.N.: J. Am. Ceram. Soc. 71 (1988) 803.10.1111/j.1151-2916.1988.tb06417.xSearch in Google Scholar
24 Kang, S.-J.L.; Han, S.-M.: MRS Bull. 20 (1995) 33.10.1557/S0883769400045085Search in Google Scholar
25 Moon, H.; Kim, B.K.; Kang, S.-J.L.: Acta. Mater. 49 (2001) 1293.10.1016/S1359-6454(00)00394-3Search in Google Scholar
26 Park, H.-H.; Cho, S.-J.; Yoon, D.N.: Metall. Trans. A 15 (1984) 1075.10.1007/BF02644700Search in Google Scholar
27 Kang, S.-J.L.; Kim, K.-H.; Yoon, D.N.: J. Am. Ceram. Soc. 74 (1991) 425.10.1111/j.1151-2916.1991.tb06900.xSearch in Google Scholar
28 Kang, S.-J.L.; Kaysser, W.A.; Petzow, G.; Yoon, D.N.: Acta Metall. 33 (1985) 1919.10.1016/0001-6160(85)90014-8Search in Google Scholar
29 Kaysser, W.A.; Zivkovic, M.; Petzow, G.: J. Mater. Sci. 20 (1985) 578.10.1007/BF01026528Search in Google Scholar
30 Lee, D.-D.; Kang, S.-J.L.; Yoon, D.N.: Scripta Metall. 24 (1990) 927.10.1016/0956-716X(90)90139-8Search in Google Scholar
31 Svoboda, J.; Riedel, H.; Gaebel, R.: Acta Mater. 44 (1996) 3215.10.1016/1359-6454(95)00440-8Search in Google Scholar
32 Mortensen, A.: Acta Mater. 45 (1997) 749.10.1016/S1359-6454(96)00202-9Search in Google Scholar
33 Kingery, W.D.; Berg, M.: J. Appl. Phys. 26 (1955) 1205.10.1063/1.1721874Search in Google Scholar
34 Exner, H.E.; Bross, P.: Acta Metall. 27 (1979) 1007.10.1016/0001-6160(79)90188-3Search in Google Scholar
35 Kang, S.-J.L.; Azou, P.: Powder Metall. 28 (1985) 90.10.1179/pom.1985.28.2.90Search in Google Scholar
36 Park, H.-H.; Kang, S.-J.L.; Yoon, D.N.: Metall. Trans. A 17 (1986) 325.10.1007/BF02643908Search in Google Scholar
37 Park, H.-H.; Kwon, O.-J.; Yoon, D.N.: Metall. Trans. A 17 (1986) 1915.10.1007/BF02644989Search in Google Scholar
38 Kang, S.-J.L.; Lee, S.-M., in: R.M. German, G.L. Messing (eds.), Proc. Sintering ’99 – 2nd Int. Conf. on Science, Technology and Applications of Sintering, in press.Search in Google Scholar
39 Park, H.H.; Yoon, D.N.: Metall. Trans. A 16 (1985) 923.10.1007/BF02814844Search in Google Scholar
40 Yoon, D.N.; Huppmann W.J.: Acta Metall. 27 (1979) 693.10.1016/0001-6160(79)90020-8Search in Google Scholar
41 Heady, R.B.; Cahn, J.W.: Metall. Trans. 1 (1970) 185.10.1007/BF02819260Search in Google Scholar
42 Eremenko, V.N.; Naidich, Y.V.; Lavrinenko, I.A.: Liquid-Phase Sintering, Consultants Bureau, New York (1970).10.1007/978-1-4757-5665-4Search in Google Scholar
43 Tewari, A.; Gokhale, A.M.; German, R.M.: Acta Mater. 47 (1999) 3721.10.1016/S1359-6454(99)00164-0Search in Google Scholar
44 Louis, P.; Gokhale, A.M.: Acta, Metall. Mater. 44 (1996) 1519.10.1016/1359-6454(95)00296-0Search in Google Scholar
45 Churn, K.S.; German, R.M.: Metall. Trans. A 15 (1984) 331.10.1007/BF02645119Search in Google Scholar
46 Carter, W.C., in: L.-Q. Chen et al. (eds.), Mathematics of Microstructure Evolution, The Minerals, Metals & Materials Society, Philadelphia, PA (1996) 1.Search in Google Scholar
47 Hough, R.R.; Rolls R.: Metall. Trans. 2 (1971) 2471.10.1007/BF02814884Search in Google Scholar
48 Ejima, T.; Kameda, M.: J. Jpn. Inst. Met. 33 (1969) 96.10.2320/jinstmet1952.33.1_96Search in Google Scholar
49 Kleebe, H.-J.; Cinibulk, M.K.; Cannon, R.M.; Rühle, M.: J. Am. Ceram. Soc. 76 (1993) 1969.10.1111/j.1151-2916.1993.tb08319.xSearch in Google Scholar
50 Luo, J.; Wang H.; Chiang, Y.-M.: J. Am. Ceram. Soc. 82 (1999) 916.10.1111/j.1151-2916.1999.tb01853.xSearch in Google Scholar
51 Chung, S.-Y.: Ph. D. Thesis, Korea Advanced Institute of Science and Technology, Taejon (2001).Search in Google Scholar
52 Hansen, M.; Anderko, K.: Constitution of Binary Alloys, McGraw-Hill, New York (1958).10.1149/1.2428700Search in Google Scholar
53 Gans, W.; Pawlek, F., Rüpenack A.V.: Z. Metallkd. 54 (1963) 147.10.1515/ijmr-1963-540305Search in Google Scholar
54 B.D. Cullity: Elements of X-Ray Diffraction, Addison-Wesley, Reading, MA (1978).Search in Google Scholar
55 Hwang, N.-M.; Kang, S.-J.L.; Yoon, D.N.: Metall. Trans. A 17 (1986) 1429.10.1007/BF02650124Search in Google Scholar
56 Kim, Y.-P.: M.S. Thesis, Korea Advanced Institute of Science and Technology, Taejon (2000).Search in Google Scholar
57 Yoon, D.N.; Huppmann, W. J.: Acta Metall. 27 (1979) 973.10.1016/0001-6160(79)90185-8Search in Google Scholar
58 King, A.H.: Int. Mater. Rev. 32 (1987) 173.10.1179/095066087790150304Search in Google Scholar
59 Yoon, D.Y.: Int. Mater. Rev. 40 (1995) 149.10.1179/imr.1995.40.4.149Search in Google Scholar
60 Jeon, J.H.; Kang, S.-J.L.: J. Am. Ceram. Soc. 77 (1994) 1688.10.1111/j.1151-2916.1994.tb09781.xSearch in Google Scholar
61 Lee, H.-Y.; Kim, J.-S.; Kang, S.-J.L.: Interface Sci. 8 (2000) 223.10.1023/A:1008768320484Search in Google Scholar
© 2001 Carl Hanser Verlag, München
Articles in the same Issue
- Frontmatter
- Editorial
- “No wise man ever wish to be younger”
- Aufsätze/Articles
- Entropy, Transformations and Sustainability of Industrial Life Cycles
- Positron Annihilation in Stable and Supercooled Metallic Melts
- Local Characterization of the Diffusion Process during Discontinuous Precipitation: A Review
- The Dependence of Abnormal Grain Growth on Initial Grain Size in 316 L Stainless Steel
- Diffusion-Controlled Grain Growth in Liquid-Phase Sintering of W–Cu Nanocomposites
- Evaluation of Densification Mechanisms of Liquid-Phase Sintering
- Phase Transformation of a Dual Phase Al–Fe Alloy Prepared by Mechanical Alloying
- Discrete Element Simulation of Ceramic Powder Processing
- Strain Relaxation and Internal Friction in the Range of the Glass Transition
- A Thermodynamic Model of an Amorphous Grain Boundary Phase in Liquid-Phase Sintered β-SiAlON Ceramic
- Epitaxial Growth of Metals on (100) SrTiO3: The Influence of Lattice Mismatch and Reactivity
- Microstructure and Modifications of Cu/Al2O3 Interfaces
- Structural Transformations Induced by Swift Heavy Ions in Polysiloxanes and Polycarbosilanes
- Metastable Al–Nd–Ni and Stable Al–La–Ni Phase Equilibria
- Phase Equilibria of the Al–Nd and Al–Nd–Ni Systems
- System Pr –Pd–O: Phase Diagram and Thermodynamic Properties of Ternary Oxides Using Solid-State Cells with Special Features
- Calculation of Phase Equilibria in Candidate Solder Alloys
- Thermodynamic Assessment of the Zr–O Binary System
- Delaminating Layered Oxide Composites with Wavy Interfaces
- Contemporary Materials Issues for Advanced EB-PVD Thermal Barrier Coating Systems
- Monte Carlo Simulations of Strength Distributions of Brittle Materials – Type of Distribution, Specimen and Sample Size
- On the Optimization of the Microstructure in Powder Metallurgical Ag–SnO2–In2O3 Contact Materials
- Some New Aspects of Microstructural Design of β-Si3N4 Ceramics
- Ni-Based SOFC Anodes: Microstructure and Electrochemistry
- Effect of Copper Line Geometry and Process Parameters on Interconnect Microstructure and Degradation Processes
- Thermal Stability of Nanoscale Co/Cu Multilayers
- Methods for Characterising the Precipitation of Nanometer-Sized Secondary Hardening Carbides and Related Effects in Tool Steels
- Prediction of Local Strain and Hardness in Sheet Forming
- Novel in situ-Infiltrated Al2O3-Metal Composites
- Influence of Microstructure and Impurities on Thermal Conductivity of Aluminium Nitride Ceramics
- Notifications/Mitteilungen
- Personelles/Personal
- Bücher/Books
- Tagungen/Conferences
Articles in the same Issue
- Frontmatter
- Editorial
- “No wise man ever wish to be younger”
- Aufsätze/Articles
- Entropy, Transformations and Sustainability of Industrial Life Cycles
- Positron Annihilation in Stable and Supercooled Metallic Melts
- Local Characterization of the Diffusion Process during Discontinuous Precipitation: A Review
- The Dependence of Abnormal Grain Growth on Initial Grain Size in 316 L Stainless Steel
- Diffusion-Controlled Grain Growth in Liquid-Phase Sintering of W–Cu Nanocomposites
- Evaluation of Densification Mechanisms of Liquid-Phase Sintering
- Phase Transformation of a Dual Phase Al–Fe Alloy Prepared by Mechanical Alloying
- Discrete Element Simulation of Ceramic Powder Processing
- Strain Relaxation and Internal Friction in the Range of the Glass Transition
- A Thermodynamic Model of an Amorphous Grain Boundary Phase in Liquid-Phase Sintered β-SiAlON Ceramic
- Epitaxial Growth of Metals on (100) SrTiO3: The Influence of Lattice Mismatch and Reactivity
- Microstructure and Modifications of Cu/Al2O3 Interfaces
- Structural Transformations Induced by Swift Heavy Ions in Polysiloxanes and Polycarbosilanes
- Metastable Al–Nd–Ni and Stable Al–La–Ni Phase Equilibria
- Phase Equilibria of the Al–Nd and Al–Nd–Ni Systems
- System Pr –Pd–O: Phase Diagram and Thermodynamic Properties of Ternary Oxides Using Solid-State Cells with Special Features
- Calculation of Phase Equilibria in Candidate Solder Alloys
- Thermodynamic Assessment of the Zr–O Binary System
- Delaminating Layered Oxide Composites with Wavy Interfaces
- Contemporary Materials Issues for Advanced EB-PVD Thermal Barrier Coating Systems
- Monte Carlo Simulations of Strength Distributions of Brittle Materials – Type of Distribution, Specimen and Sample Size
- On the Optimization of the Microstructure in Powder Metallurgical Ag–SnO2–In2O3 Contact Materials
- Some New Aspects of Microstructural Design of β-Si3N4 Ceramics
- Ni-Based SOFC Anodes: Microstructure and Electrochemistry
- Effect of Copper Line Geometry and Process Parameters on Interconnect Microstructure and Degradation Processes
- Thermal Stability of Nanoscale Co/Cu Multilayers
- Methods for Characterising the Precipitation of Nanometer-Sized Secondary Hardening Carbides and Related Effects in Tool Steels
- Prediction of Local Strain and Hardness in Sheet Forming
- Novel in situ-Infiltrated Al2O3-Metal Composites
- Influence of Microstructure and Impurities on Thermal Conductivity of Aluminium Nitride Ceramics
- Notifications/Mitteilungen
- Personelles/Personal
- Bücher/Books
- Tagungen/Conferences