Home The crystal structure of poly[μ2-aqua- aqua-(μ3-(E)-2-(4-((2-carbamothioylhydrazineylidene)methyl)phenoxy)acetato-κ3 O:S:S)sodium(I)], C10H14N3O5SNa
Article Open Access

The crystal structure of poly[μ2-aqua- aqua-(μ3-(E)-2-(4-((2-carbamothioylhydrazineylidene)methyl)phenoxy)acetato-κ3 O:S:S)sodium(I)], C10H14N3O5SNa

  • Xi-Shi Tai ORCID logo , Li-Hua Wang and Yu-Pei Xia EMAIL logo
Published/Copyright: February 15, 2022
Download Article (PDF)
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 237 Issue 2

Abstract

C10H14N3O5SNa, triclinic, P 1 ‾ (no. 2), a = 6.7015(5) Å, b = 7.5656(5) Å, c = 14.1332(8) Å, β = 93.159(5)°, V = 654.71(8) Å3, Z = 2, R gt (F) = 0.0357, wR ref (F 2) = 0.0872, T = 273 K.

CCDC no.: 2082889

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colorless block
Size: 0.11 × 0.10 × 0.08 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 0.30 mm−1
Diffractometer, scan mode: Rigaku SuperNova, ω
θ max, completeness: 25.0°, >99%
N(hkl)measured, N(hkl)unique, R int: 4268, 2284, 0.027
Criterion for I obs, N(hkl)gt: I obs > 2 σ(I obs), 1969
N(param)refined: 205
Programs: Bruker [1], Olex2 [2], SHELX [3], Diamond [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
C1 1.2614 (3) 0.8211 (3) 0.20138 (13) 0.0093 (4)
C2 0.8917 (3) 0.8458 (3) 0.36091 (14) 0.0105 (4)
H2 0.829020 0.911663 0.325921 0.013*
C3 0.8089 (3) 0.7887 (3) 0.45049 (13) 0.0096 (4)
C4 0.6266 (3) 0.8194 (3) 0.47820 (14) 0.0105 (4)
H4 0.560939 0.877113 0.439220 0.013*
C5 0.5405 (3) 0.7665 (3) 0.56205 (14) 0.0105 (4)
H5 0.417806 0.787286 0.578535 0.013*
C6 0.6382 (3) 0.6822 (3) 0.62135 (13) 0.0098 (4)
C7 0.8259 (3) 0.6554 (3) 0.59643 (14) 0.0114 (5)
H7 0.894868 0.602880 0.636993 0.014*
C8 0.9085 (3) 0.7064 (3) 0.51219 (14) 0.0113 (5)
H8 1.031726 0.686224 0.495946 0.014*
C9 0.3739 (3) 0.6464 (3) 0.73119 (14) 0.0103 (4)
H9A 0.259916 0.588714 0.678176 0.012*
H9B 0.403109 0.783253 0.744570 0.012*
C10 0.2982 (3) 0.5538 (3) 0.81928 (13) 0.0099 (5)
H2A 1.047 (4) 0.929 (3) 0.2175 (15) 0.010 (6)*
H4A −0.330 (4) 0.620 (3) 0.9382 (18) 0.029 (7)*
H4B −0.289 (4) 0.641 (4) 1.036 (2) 0.039 (8)*
H5A 0.124 (4) 0.828 (4) 0.8493 (18) 0.039 (8)*
H5B 0.259 (4) 1.004 (3) 0.8610 (17) 0.023 (8)*
N1 1.3532 (3) 0.7232 (2) 0.24710 (11) 0.0134 (4)
H1A 1.316859 0.694239 0.302336 0.016*
H1B 1.448956 0.688713 0.221483 0.016*
N2 1.1127 (3) 0.8718 (2) 0.24420 (12) 0.0107 (4)
N3 1.0488 (3) 0.8073 (2) 0.32929 (11) 0.0105 (4)
Na1 0.000000 0.500000 1.000000 0.0124 (3)
Na2 0.000000 1.000000 1.000000 0.0127 (3)
O1 0.5654 (2) 0.62119 (18) 0.70468 (9) 0.0119 (3)
O2 0.3924 (2) 0.45320 (18) 0.85119 (9) 0.0121 (3)
O3 0.1427 (2) 0.58362 (18) 0.85230 (9) 0.0118 (3)
O4 −0.2275 (2) 0.6722 (2) 0.98521 (12) 0.0132 (3)
O5 0.1361 (3) 0.9456 (2) 0.85079 (11) 0.0141 (4)
S1 1.33292 (8) 0.88919 (7) 0.09353 (3) 0.01171 (17)

Source of material

4-Formylphenoxyacetic acid (0.5 mmol, 0.0901 g), thiosemicarbazide (0.5 mmol, 0.0456 g) and NaOH (0.5 mmol, 0.020 g) were dissolved into 20 mL of a H2O/ethanol solution (v:v = 1:1) with stirring at 50 °C. After 20 min, MgCl2·6H2O (0.5 mmol, 0.1015 g) was added to the mixture. The mixture was continued to react for 4 h at 80 °C with stirring. The mixture was then cooled to room temperature and continued the stirring for 4 h. Filtering the reaction mixture. After 20 days, the crystals of the title compound were obtained by slowing volatilization at room temperature. Elemental analysis (%) calcd. for C10H14N3O5SNa: C, 38.55; H, 4.50; N, 13.49. Found (%): C, 38.66; H, 4.76; N, 13.17.

Experimental details

The hydrogen atoms were positioned geometrically (C–H = 0.93–0.97 Å and N–H = 0.86 Å). Their U iso values were set to 1.2U eq of the parent atoms.

Comment

Metal coordination polymers show excellent properties in many areas of chemical engineering and materials [5], [6], [7], [8], [9], [10], [11], [12]. According to the literature, the studies on synthesis and properties of metal coordination polymer mainly focuses on transition metals. In order to enrich the structure and properties of the metal coordination polymers, our research group is committed to studying the structure and properties of the alkaline earth metal coordination polymers [13], [14], [15], [16]. At the same time, we have also studied the catalytic activity of some metal complexes [16]. In order to further investigate the structure and catalytic property of alkali earth metal coordination polymers, in this work, a new Na(I) coordination polymer has been synthesized by a one-pot method. The title coordination polymer was characterized by EA and single-crystal X-ray diffraction analysis.

As shown in Figure 1, the Na(I) coordination polymer it is made up of one Na(I) ions on inversion centers, one thiosemicarbazide ligand and two coordinated water molecules. Na1 and Na2 atoms adopt a six-coordinated octahedron configuration, where Na1 is coordinated with two O atoms and S atoms of two different L ligands and two O atoms of two water molecules, and Na2 is coordinated with four O atoms of four coordinated water molecules and S atoms of two different L ligands. Thus the title structure contains two different coordinated units: Na(OL)2(SL)2(Owater)2 and Na(Owater)4(SL)2, which forms a chained structure by the Na–O coordination which is further extended by the Na–S coordination S atoms of L ligands. The Na (I) coordination polymer assembles an extended layered structure. All bond lengths and angles are in the expected ranges [17].

Corresponding author: Yu-Pei Xia, College of Chemistry and Chemical Engineering, Weifang University, Weifang, Shandong 261061, P. R. China, E-mail:

Funding source: National Natural Science Foundation of China https://doi.org/10.13039/501100001809

Award Identifier / Grant number: 21171132

Funding source: Natural Science Foundation of Shandong https://doi.org/10.13039/501100007129

Award Identifier / Grant number: ZR2014BL003

Funding source: Project of Shandong Province Higher Educational Science and Technology Program https://doi.org/10.13039/501100015642

Award Identifier / Grant number: J14LC01

Funding source: Science Foundation of Weifang

Award Identifier / Grant number: 2020ZJ1054

Funding source: Weifang University of Science and Technology https://doi.org/10.13039/501100010887

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This project was supported by the National Natural Science Foundation of China (No. 21171132), the Natural Science Foundation of Shandong (ZR2014BL003), the Project of Shandong Province Higher Educational Science and Technology Program (J14LC01), Science Foundation of Weifang (2020ZJ1054), and Weifang University of Science and Technology (https://doi.org/10.13039/501100010887).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Bruker. SAINT and SADABS; Bruker AXS Inc.: Madison, Wisconsin, USA, 2000.Search in Google Scholar

2. Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K., Puschmann, H. OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr. 2009, 42, 339–341; https://doi.org/10.1107/s0021889808042726.Search in Google Scholar

3. Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Search in Google Scholar

4. Brandenburg, K. DIAMOND. Visual Crystal Structure Information System (ver. 3.2); Crystal Impact: Bonn, Germany, 2012.Search in Google Scholar

5. Shun, K., Ryota, M., Shojiro, K., Hiroshi, N., Tetsuro, K. Radical-based coordination polymers as a platform for magnetoluminescence. J. Am. Chem. Soc. 2021, 143, 5610–5615.10.1021/jacs.1c00661Search in Google Scholar PubMed

6. Yasuchika, H., Natsumi, S., Joe, H., Yuichi, K., Koji, F. Thermo-sensitive EuIII coordination polymers with amorphous networks. ChemistrySelect 2021, 6, 2812–2816.10.1002/slct.202100531Search in Google Scholar

7. Wu, M. X., Yang, Y. W. A fluorescent pillarene coordination polymer. Polym. Chem. 2019, 10, 2980–2985; https://doi.org/10.1039/c8py01497c.Search in Google Scholar

8. Fan, W. W., Cheng, Y., Zheng, L. Y., Cao, Q. E. Reversible phase transition of porous coordination polymers. Chem. Eur J. 2020, 26, 2766–2779; https://doi.org/10.1002/chem.201903985.Search in Google Scholar PubMed

9. Hu, M. L., Abbasi-Azad, M., Habibi, B., Rouhani, F., Moghanni-Bavil-Olyaei, H., Liu, K. G., Morsali, A. Electrochemical applications of ferrocene-based coordination polymers. ChemPlusChem 2020, 85, 2397–2418; https://doi.org/10.1002/cplu.202000584.Search in Google Scholar PubMed

10. Zhu, W. J., Zhao, J. Y., Chen, Q., Liu, Z. Nanoscale metal-organic frameworks and coordination polymers as theranostic platforms for cancer treatment. Coord. Chem. Rev. 2019, 398, 113009; https://doi.org/10.1016/j.ccr.2019.07.006.Search in Google Scholar

11. Tian, F., Shen, N., Huang, K. L., Chen, S. C., Chen, Q., He, M. Y. Construction of alkali-metal-based imidazolecarboxylate coordination polymers as efficient catalysts for solvent-free ring-opening polymerization of caprolactone. Z. Anorg. Chem. 2021, 647, 704–713; https://doi.org/10.1002/zaac.202000371.Search in Google Scholar

12. Wang, L. H., Kong, F. Y., Tai, X. S. Crystal structure and catalytic activity of poly[bis(3-bromo-2-hydroxybenzaldehyde)-2-aminopyrimidinemagnesium(II)] for hydrogenation of 1,3-butadiene. Bull. Chem. React. Eng. Catal. 2021, 16, 260–266; https://doi.org/10.9767/bcrec.16.2.10421.260-266.Search in Google Scholar

13. Tai, X. S., Zhao, W. H. Synthesis, crystal structure, and antibacterial activity of magnesium(II) coordination polymers formed by hydrogen bonding. Res. Chem. Intermed. 2015, 41, 3471–3478; https://doi.org/10.1007/s11164-013-1463-y.Search in Google Scholar

14. Cao, S. H., Tai, X. S., Xin, C. L. Synthesis, crystal structure and antitumor activity of a Ca(II) coordination polymer based on 4-acetylphenoxyacetate ligands. Chin. J. Struct. Chem. 2021, 40, 324–328.Search in Google Scholar

15. Tai, X. S., Wang, X. Synthesis and crystal structure of a 1D chained coordination polymer constructed from Ca2+ and 2-[(E)-(2-furoylhydrazono)methyl]benzenesulfonate. Crystals 2015, 5, 458–465; https://doi.org/10.3390/cryst5040458.Search in Google Scholar

16. Tai, X. S., Wang, X. Synthesis, structural characterization and antitumor activity of a Ca(II) coordination polymer based on 4-formyl-1,3-benzenedisulfonate-2-furoic acid hydrazide ligands. Crystallogr. Rep. 2017, 62, 242–245; https://doi.org/10.1134/s1063774517020286.Search in Google Scholar

17. Naveen Tittal, R. K., Ghule, V. D., Kumar, N., Kumar, L., Lal, K., Kumar, A. Design, synthesis, biological activity, molecular docking and computational studies on novel 1,4-disubstituted-1,2,3-triazole-thiosemicarbazone hybrid molecules. J. Mol. Struct. 2020, 1209, 127951; https://doi.org/10.1016/j.molstruc.2020.127951.Search in Google Scholar
Received: 2022-01-09
Accepted: 2022-01-24
Published Online: 2022-02-15
Published in Print: 2022-04-26

© 2022 Xi-Shi Tai et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of {2,2′-{cyclohexane-1,2-diylbis[(azanylylidene)methylylidene]}bis(2,4-dibromophenolato)-κ4 N,N′,O,O′}copper(II) ─ diethylformamide (1/1), C23H23Br4CuN3O3
  4. The crystal structure of 2-(2-methyl-6-phenyl-4H-pyran-4-ylidene)-1H-indene-1,3(2H)-dione, C21H14O3
  5. Crystal structure of bis((1-methylbenzimidazol-2-yl)methyl)amine, C18H19N5
  6. Crystal structure of (E)-N′-(1-(2-hydroxy-4-methoxyphenyl)ethylidene) isonicotinohydrazide, C15H15N3O3
  7. Crystal structure of 2-((4-phenyl-5-(pyridin-4-yl)-4H-1,2,4-triazol-3-yl)thio)acetonitrile, C15H11N5S
  8. The crystal structure of 2,2′-((1E,1′E)-hydrazine-1,2-diylidenebis(methaneylylidene))bis(4-chlorophenol), C14H10Cl2N2O2
  9. Dichlorido-{2,6-bis(4,5-dihydro-1H-pyrazol-3-yl)pyridine-κ3 N,N′,N″}zinc(II), C11H9C12N5Zn
  10. The crystal structure of dichlorido-(2-((4-phenyl-2H-1,2,3-triazol-2-yl)methyl)pyridine-κ2N,N′)palladium(II), C14H12Cl2N4Pd
  11. The crystal structure of 1-(N1-benzyl-2-methyl-4-nitro-imidazol-5-yl)-4-(prop-2-yn-1-yl) piperazine, C18H21N5O2
  12. Crystal structure of (μ4-(1,2,4,5-tetra(1,2,4-triazol-1-ylmethyl)-benzene-κ4N:N1:N2:N3)disilver(I) diperchlorate
  13. The crystal structure of 1-(2-bromoethane)-4-amine-3,5-dinitropyrazole, C5H6Br1N5O4
  14. Crystal structure of (E)-1-(4-benzyl-3,5-dioxomorpholin-2-ylidene)ethyl acetate, C15H15N1O5
  15. The crystal structure of poly[diaqua-(μ2-1,2,4,5-tetrakis(1,2,4-triazol-1-ylmethyl)-benzene-κ2N:N′)-bis(μ3-terephthalato-κ3O:O′:O′′)dicadmium(II)], C17H15N6O5Cd
  16. Crystal structure of (E)-N′-(1-(5-chloro-2-hydroxyphenyl) ethylidene)thiophene-2-carbohydrazide, C13H11ClN2O2S
  17. The crystal structure of [(2,2′-bipyridine-k2 N,N)-bis(6-phenylpyridine-2-carboxylato-k2 N,O)cobalt(II)]-monohydrate, C36H26N4O5Co
  18. Crystal structure of (E)-N′-(2-chloro-6-hydroxybenzylidene)-3-hydroxybenzo-hydrazide monohydrate, C14H13ClN2O4
  19. Crystal structure of 1,1′-(methylene)bis(pyridin-1-ium) bis(1,2-dicyanoethene-1,2-dithiolato-κ2S:S)nickel(II), C42H30N14Ni2S8
  20. Crystal structure of 1,1′-(1,2-ethanediyl)bis(pyridin-1-ium) bis(1,2-dicyanoethene-1,2-dithiolato-κ2 S:S)nickel(II), C20H14N6NiS4
  21. The crystal structure of 1-methyl-1H-pyrazol-2-ium nitrate, C4H7O3N3
  22. The crystal structure of 4,4′-diselanediylbis(8-(hexyloxy)-3,6-dimethyl-1-(piperidin-1-yl)isoquinoline-7-carbonitrile), C46H60N6O2Se2
  23. The crystal structure of tris(6-methylpyridin-2-yl)phosphine selenide, C18H18N3PSe
  24. The crystal structure of 1,2-bis(2,4-dinitro-1H-imidazol-1-yl)ethane ─ acetone (1/1), C11H12N8O9
  25. Crystal structure of [diaqua[2,2′-(1,2-phenylene)bis(1H-imidazole-4-carboxylato-5-carboxy)-κ4N,N′,O,O′]nickel(II)] tetrahydrate, C16H12N4NiO10·4H2O
  26. The crystal structure of tris(4-methyl-1H-pyrazol-1-yl)methane, C13H16N6
  27. The crystal structure of 5,6-dichloro-2-(quinolin-8-yl)isoindoline-1,3-dione, C17H8Cl2N2O2
  28. Crystal structure of (E)-(2-methoxy-benzylidene)-(4-[1,2,4]triazol-1-yl-phenyl)-amine, C16H14N4O
  29. The crystal structure of (Z)-2-(4-(4-bromophenyl)thiazol-2-yl)-4-(3-hydroxybut-2-enoyl)-5-methyl -1,2-dihydro-3H-pyrazol-3-one – methanol (1/1), C18H18N3O4S
  30. Crystal structure of tetraaqua-tris(nitrato-κ2 O,O′) erbium(III) monohydrate, Er(NO3)3·5H2O, H10ErN3O14
  31. The crystal structure of 1-methyl-2-nitro-1H-imidazole 3-oxide, C4H5N3O3
  32. The crystal structure of 1-methyl-2-nitroimidazole, C4H5N3O2
  33. The crystal structure of 2-carboxyl-4-nitroimidazole monohydrate, C4H5N3O5
  34. Crystal structure of bis[hydrido-hexaphenylcarbodiphosphoran][tetra-trifluoromethyl-(μ-diiodo)-diplatinat]
  35. The crystal structure of poly[μ2-aqua- aqua-(μ3-(E)-2-(4-((2-carbamothioylhydrazineylidene)methyl)phenoxy)acetato-κ3 O:S:S)sodium(I)], C10H14N3O5SNa
  36. The twinned crystal structure of [4,4′-bipyridine]-1,1′-diium hexachloridostannate(IV), C10H10N2SnCl6
  37. The crystal structure of [(2,2′-bipyridine-k2 N,N)-bis(6-phenylpyridine-2-carboxylate-k2 N,O)copper(II)], C34H24N4O4Cu
  38. Crystal structure of trans-1,2-bis(pyridinium-4-yl) ethylene bis(2-carboxy-4-bromobenzoate) – water (1/4), C14H14BrNO6
  39. Crystal structure of poly[diaqua-(μ3-fumarato)-(μ3-maleato)-(μ4-1,2,4,5-tetrakis((1H-1,2,4-triazol-1-yl)methyl)benzene)tetracadmium(II)] dihydrate, C34H32N12O9Cd4
  40. Crystal structure of a second modification of Pachypodol, C18H16O7
  41. Crystal structure of methyl 2-(4-(2-(cyclopentyl-amino)-1-(N-(4-methoxyphenyl)-1-methyl-5-phenyl-1-H-pyrazole-3-carboxamido)-2-oxoethyl)phenyl)acetate, C34H36N4O5
  42. The crystal structure of catena-poly[(m2-4,4′-bipyridine-κ2 N:N)-bis(6-phenylpyridine-2-carboxylato-κ2 N,O) zinc(II)], C34H24N4O4Zn
  43. The crystal structure of hexaquamagnesium(II) (2,4-bis(nitroimino)-6-oxo-1,3,5-triazinane-1,3-diide), C3H15MgN7O12
  44. The crystal structure of 7-Bromo-2-(4-chloro-phenyl)-quinoxaline, C14H9BrClN2
  45. Crystal structure of methyl 4-{[4-(4-cyanobenzamido)phenyl]amino}benzofuro[2,3-d]pyrimidine-6-carboxylate, C26H17N5O4
  46. The crystal structure of (4SR)-7-(3,4-dichlorobenzyl)-4,8,8-trimethyl-7,8-dihydroimidazo[5,1c][1,2,4]triazine-3,6(2H,4H)-dione, C15H16Cl2N4O2
  47. Crystal structure of catena-poly[{μ2-3-carboxy-2,3-bis((4-methylbenzoyl)oxy)propanoato-κ2 O:O′}tris(methanol-κ1 O)lanthanum(III)], C63H63LaO27
https://doi.org/10.1515/ncrs-2022-0006
Creative Commons
BY 4.0

Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of {2,2′-{cyclohexane-1,2-diylbis[(azanylylidene)methylylidene]}bis(2,4-dibromophenolato)-κ4 N,N′,O,O′}copper(II) ─ diethylformamide (1/1), C23H23Br4CuN3O3
  4. The crystal structure of 2-(2-methyl-6-phenyl-4H-pyran-4-ylidene)-1H-indene-1,3(2H)-dione, C21H14O3
  5. Crystal structure of bis((1-methylbenzimidazol-2-yl)methyl)amine, C18H19N5
  6. Crystal structure of (E)-N′-(1-(2-hydroxy-4-methoxyphenyl)ethylidene) isonicotinohydrazide, C15H15N3O3
  7. Crystal structure of 2-((4-phenyl-5-(pyridin-4-yl)-4H-1,2,4-triazol-3-yl)thio)acetonitrile, C15H11N5S
  8. The crystal structure of 2,2′-((1E,1′E)-hydrazine-1,2-diylidenebis(methaneylylidene))bis(4-chlorophenol), C14H10Cl2N2O2
  9. Dichlorido-{2,6-bis(4,5-dihydro-1H-pyrazol-3-yl)pyridine-κ3 N,N′,N″}zinc(II), C11H9C12N5Zn
  10. The crystal structure of dichlorido-(2-((4-phenyl-2H-1,2,3-triazol-2-yl)methyl)pyridine-κ2N,N′)palladium(II), C14H12Cl2N4Pd
  11. The crystal structure of 1-(N1-benzyl-2-methyl-4-nitro-imidazol-5-yl)-4-(prop-2-yn-1-yl) piperazine, C18H21N5O2
  12. Crystal structure of (μ4-(1,2,4,5-tetra(1,2,4-triazol-1-ylmethyl)-benzene-κ4N:N1:N2:N3)disilver(I) diperchlorate
  13. The crystal structure of 1-(2-bromoethane)-4-amine-3,5-dinitropyrazole, C5H6Br1N5O4
  14. Crystal structure of (E)-1-(4-benzyl-3,5-dioxomorpholin-2-ylidene)ethyl acetate, C15H15N1O5
  15. The crystal structure of poly[diaqua-(μ2-1,2,4,5-tetrakis(1,2,4-triazol-1-ylmethyl)-benzene-κ2N:N′)-bis(μ3-terephthalato-κ3O:O′:O′′)dicadmium(II)], C17H15N6O5Cd
  16. Crystal structure of (E)-N′-(1-(5-chloro-2-hydroxyphenyl) ethylidene)thiophene-2-carbohydrazide, C13H11ClN2O2S
  17. The crystal structure of [(2,2′-bipyridine-k2 N,N)-bis(6-phenylpyridine-2-carboxylato-k2 N,O)cobalt(II)]-monohydrate, C36H26N4O5Co
  18. Crystal structure of (E)-N′-(2-chloro-6-hydroxybenzylidene)-3-hydroxybenzo-hydrazide monohydrate, C14H13ClN2O4
  19. Crystal structure of 1,1′-(methylene)bis(pyridin-1-ium) bis(1,2-dicyanoethene-1,2-dithiolato-κ2S:S)nickel(II), C42H30N14Ni2S8
  20. Crystal structure of 1,1′-(1,2-ethanediyl)bis(pyridin-1-ium) bis(1,2-dicyanoethene-1,2-dithiolato-κ2 S:S)nickel(II), C20H14N6NiS4
  21. The crystal structure of 1-methyl-1H-pyrazol-2-ium nitrate, C4H7O3N3
  22. The crystal structure of 4,4′-diselanediylbis(8-(hexyloxy)-3,6-dimethyl-1-(piperidin-1-yl)isoquinoline-7-carbonitrile), C46H60N6O2Se2
  23. The crystal structure of tris(6-methylpyridin-2-yl)phosphine selenide, C18H18N3PSe
  24. The crystal structure of 1,2-bis(2,4-dinitro-1H-imidazol-1-yl)ethane ─ acetone (1/1), C11H12N8O9
  25. Crystal structure of [diaqua[2,2′-(1,2-phenylene)bis(1H-imidazole-4-carboxylato-5-carboxy)-κ4N,N′,O,O′]nickel(II)] tetrahydrate, C16H12N4NiO10·4H2O
  26. The crystal structure of tris(4-methyl-1H-pyrazol-1-yl)methane, C13H16N6
  27. The crystal structure of 5,6-dichloro-2-(quinolin-8-yl)isoindoline-1,3-dione, C17H8Cl2N2O2
  28. Crystal structure of (E)-(2-methoxy-benzylidene)-(4-[1,2,4]triazol-1-yl-phenyl)-amine, C16H14N4O
  29. The crystal structure of (Z)-2-(4-(4-bromophenyl)thiazol-2-yl)-4-(3-hydroxybut-2-enoyl)-5-methyl -1,2-dihydro-3H-pyrazol-3-one – methanol (1/1), C18H18N3O4S
  30. Crystal structure of tetraaqua-tris(nitrato-κ2 O,O′) erbium(III) monohydrate, Er(NO3)3·5H2O, H10ErN3O14
  31. The crystal structure of 1-methyl-2-nitro-1H-imidazole 3-oxide, C4H5N3O3
  32. The crystal structure of 1-methyl-2-nitroimidazole, C4H5N3O2
  33. The crystal structure of 2-carboxyl-4-nitroimidazole monohydrate, C4H5N3O5
  34. Crystal structure of bis[hydrido-hexaphenylcarbodiphosphoran][tetra-trifluoromethyl-(μ-diiodo)-diplatinat]
  35. The crystal structure of poly[μ2-aqua- aqua-(μ3-(E)-2-(4-((2-carbamothioylhydrazineylidene)methyl)phenoxy)acetato-κ3 O:S:S)sodium(I)], C10H14N3O5SNa
  36. The twinned crystal structure of [4,4′-bipyridine]-1,1′-diium hexachloridostannate(IV), C10H10N2SnCl6
  37. The crystal structure of [(2,2′-bipyridine-k2 N,N)-bis(6-phenylpyridine-2-carboxylate-k2 N,O)copper(II)], C34H24N4O4Cu
  38. Crystal structure of trans-1,2-bis(pyridinium-4-yl) ethylene bis(2-carboxy-4-bromobenzoate) – water (1/4), C14H14BrNO6
  39. Crystal structure of poly[diaqua-(μ3-fumarato)-(μ3-maleato)-(μ4-1,2,4,5-tetrakis((1H-1,2,4-triazol-1-yl)methyl)benzene)tetracadmium(II)] dihydrate, C34H32N12O9Cd4
  40. Crystal structure of a second modification of Pachypodol, C18H16O7
  41. Crystal structure of methyl 2-(4-(2-(cyclopentyl-amino)-1-(N-(4-methoxyphenyl)-1-methyl-5-phenyl-1-H-pyrazole-3-carboxamido)-2-oxoethyl)phenyl)acetate, C34H36N4O5
  42. The crystal structure of catena-poly[(m2-4,4′-bipyridine-κ2 N:N)-bis(6-phenylpyridine-2-carboxylato-κ2 N,O) zinc(II)], C34H24N4O4Zn
  43. The crystal structure of hexaquamagnesium(II) (2,4-bis(nitroimino)-6-oxo-1,3,5-triazinane-1,3-diide), C3H15MgN7O12
  44. The crystal structure of 7-Bromo-2-(4-chloro-phenyl)-quinoxaline, C14H9BrClN2
  45. Crystal structure of methyl 4-{[4-(4-cyanobenzamido)phenyl]amino}benzofuro[2,3-d]pyrimidine-6-carboxylate, C26H17N5O4
  46. The crystal structure of (4SR)-7-(3,4-dichlorobenzyl)-4,8,8-trimethyl-7,8-dihydroimidazo[5,1c][1,2,4]triazine-3,6(2H,4H)-dione, C15H16Cl2N4O2
  47. Crystal structure of catena-poly[{μ2-3-carboxy-2,3-bis((4-methylbenzoyl)oxy)propanoato-κ2 O:O′}tris(methanol-κ1 O)lanthanum(III)], C63H63LaO27
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 23.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2022-0006/html
Scroll to top button