Home Physical Sciences The crystal structure of catena-poly[(μ2-4-(benzo[d]imidazol-2-yl)benzenecarboxylato-κ2N,O)-(μ2-4-(benzo[d]imidazol-2-yl)benzenecarboxylato-κ3N,O:O′)cadmium(II)]dihydrate, C28H22CdN4O6
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The crystal structure of catena-poly[(μ2-4-(benzo[d]imidazol-2-yl)benzenecarboxylato-κ2N,O)-(μ2-4-(benzo[d]imidazol-2-yl)benzenecarboxylato-κ3N,O:O′)cadmium(II)]dihydrate, C28H22CdN4O6

  • Kai-Hui Li EMAIL logo and Chong Liu
Published/Copyright: July 14, 2020
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 235 Issue 5

Abstract

C28H22CdN4O6, triclinic, P1̄ (no. 2), a = 8.8463(3) Å, b = 9.0275(3) Å, c = 15.6752(5) Å, α = 78.033(3)°, β = 88.988(3)°, γ = 84.843(3)°, V = 1219.66(7) Å3, Z = 2, Rgt(F) = 0.0333, wRref(F2) = 0.0732, T = 291 K.

CCDC no.: 2007141

A part of the polymeric structure is shown in the figure (A = 1 − x, 1 − y, 1 − z; B = 2 − x, 1 − y, −z). Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Colourless block
Size:0.21 × 0.20 × 0.18 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:0.95 mm−1
Diffractometer, scan mode:SuperNova, ω
θmax, completeness:28.4°, >99%
N(hkl)measured, N(hkl)unique, Rint:14591, 5202, 0.033
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 4658
N(param)refined:352
Programs:CrysAlisPRO [1], SHELX [2], [3]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Cd10.68235(2)0.33201(2)0.24244(2)0.02708(8)
O10.5787(3)0.5241(2)0.29394(14)0.0497(6)
O20.4117(2)0.3628(3)0.34559(16)0.0509(6)
O31.0552(2)0.6371(2)−0.22212(13)0.0427(5)
O41.2161(2)0.4731(2)−0.13856(13)0.0367(5)
N10.1874(3)1.0363(2)0.52732(15)0.0333(5)
H10.17461.07290.47250.040*
N20.2535(2)0.8724(2)0.64975(14)0.0268(5)
N30.5776(2)0.2362(2)0.13622(14)0.0271(5)
N40.4855(2)0.2063(2)0.01061(15)0.0304(5)
H40.47640.2131−0.04460.036*
C10.4072(3)0.5927(3)0.39922(17)0.0294(6)
C20.4613(3)0.7350(3)0.38981(19)0.0381(7)
H20.53380.76470.34750.046*
C30.4082(3)0.8320(3)0.44258(19)0.0382(7)
H30.44180.92870.43390.046*
C40.3051(3)0.7878(3)0.50887(17)0.0280(6)
C50.2548(3)0.6439(3)0.52011(19)0.0333(6)
H50.18710.61170.56470.040*
C60.3050(3)0.5482(3)0.46520(19)0.0336(6)
H60.26950.45240.47280.040*
C70.4669(3)0.4847(3)0.34235(19)0.0362(7)
C80.2492(3)0.8948(3)0.56325(17)0.0270(6)
C90.1488(3)1.1112(3)0.59319(18)0.0289(6)
C100.0818(3)1.2566(3)0.5932(2)0.0382(7)
H100.05191.32360.54160.046*
C110.0619(3)1.2969(3)0.6724(2)0.0424(8)
H110.01601.39270.67490.051*
C120.1089(4)1.1973(3)0.7493(2)0.0422(7)
H120.09701.22950.80180.051*
C130.1726(3)1.0521(3)0.74954(19)0.0358(7)
H130.20210.98560.80130.043*
C140.1914(3)1.0087(3)0.67009(17)0.0273(6)
C150.9544(3)0.4520(3)−0.10898(17)0.0273(6)
C160.8041(3)0.4979(3)−0.13176(19)0.0345(7)
H160.78120.5704−0.18230.041*
C170.6881(3)0.4363(3)−0.07966(19)0.0343(7)
H170.58770.4663−0.09600.041*
C180.7206(3)0.3296(3)−0.00280(17)0.0271(6)
C190.8716(3)0.2827(3)0.01944(18)0.0294(6)
H190.89500.21080.07020.035*
C200.9862(3)0.3426(3)−0.03363(18)0.0297(6)
H201.08670.3093−0.01880.036*
C211.0833(3)0.5245(3)−0.16039(18)0.0315(6)
C220.5956(3)0.2608(3)0.04967(17)0.0263(6)
C230.3900(3)0.1381(3)0.07347(18)0.0294(6)
C240.2655(3)0.0576(3)0.0684(2)0.0379(7)
H240.22990.04390.01540.045*
C250.1976(3)−0.0009(4)0.1459(2)0.0463(8)
H250.1143−0.05660.14540.056*
C260.2501(4)0.0207(4)0.2251(2)0.0467(8)
H260.1993−0.01870.27600.056*
C270.3753(3)0.0990(3)0.23027(19)0.0372(7)
H270.41020.11240.28350.045*
C280.4473(3)0.1572(3)0.15250(18)0.0277(6)
O50.1269(3)1.2499(3)0.37493(14)0.0538(6)
H5A0.09621.26450.32260.081*
H5B0.21111.28840.36410.081*
O60.4477(3)0.2081(3)−0.16039(15)0.0621(7)
H6A0.35800.1708−0.14620.093*
H6B0.43540.2988−0.18970.093*

Source of material

A mixture of Cd(CH3COO)2 ⋅ 2 H2O (0.0266 g, 0.1 mmol), 4-(benzo[d]imidazol-2-yl)benzoic acid (0.0238 g, 0.1 mmol), and H2O (15 mL) was sealed in a 25 mL Teflon-lined stainless steel vessel and heated at 120 °C for 4 days. The colorless block crystals of the title compound were obtained, which were washed with water and dried in air with a 44% yield.

Experimental details

The hydrogen atoms were assigned with common isotropic displacement factors Uiso(H) = 1.2 times Ueq(C) and Ueq(N), refined with riding coordinates, Uiso(H) = 1.5 times Ueq(O), refined as rotating group.

Comment

Coordination polymer (CPs), a fascinating kind of crystalline solides have drawn attention in the past decades because of their porosity, tunable frameworks, and application in many fields [4], [5], [6], [7]. Up to now various techniques have been developed to bulid CPs due to the aesthetic appeal of their frameworks and topologies. A number of CPs have been assembled from metal centers with aromatic carboxylates since they can provide the structural rigidity and give diverse coordination modes for the generation of CPs chains, layers, or networks [8], [9], [10]. On the other hand, N-donor coligands can be incorporated, thereby enhancing the structural scope and imparting additional multi-functional behavior [11], [12], [13]. Recently, we have been interested in the construction of CPs bearing bifunctional ligands with aromatic carboxylates and N-heterocyclics present together [14], [15], [16]. As an extension of this project, we herein report the title structure.

The title compound exhibits one dimensional chain structure. The asymmetric unit of the title structure contains two 4-(benzo[d]imidazol-2-yl)benzoate anions, one Cd(II) ion, and two lattice water molecules. As shown in the figure, Cd1 is five-coordinated by three oxygen atoms from two different 4-(benzo[d]imidazol-2-yl)benzoate ligands and two nitrogen atoms from two other ligands. The coordination geometry of Cd1 can be described as a distorted trigonal bipyramid. The Cd—O bond lengths are in the range of 2.183(2)–2.372(2) Å, and the Cd—N bond lengths are 2.266(2) and 2.275(2) Å, respectively. The two 4-(benzo[d]imidazol-2-yl)benzoate ligands adopt different μ2 coordination modes and each Cd(II) center is coordinated by four ligands. Cd(II) cations are connected into one-dimensional chains. There are several intermolecular hydrogen bonds in the structure of the title compound. The one-dimensional chains are joined by these hydrogen bonds to form a three-dimensional framework.

References

1. Agilent Technologies: CrysAlisPRO Software system, version 1.171.35.19. Agilent Technologies UK Ltd, Oxford, UK (2011).Search in Google Scholar

2. Sheldrick, G. M.: SHELXT – Integrated space-group and crystal-structure determination. Acta Crystallogr. A71 (2015) 3–8.10.1107/S2053273314026370Search in Google Scholar PubMed PubMed Central

3. Sheldrick, G. M.: Crystal structure refinement with SHELXL. Acta Crystallogr. C71 (2015) 3–8.10.1107/S2053229614024218Search in Google Scholar PubMed PubMed Central

4. Miao, S.-B.; Ji, B.-M.; Wang, Y.-F.; Li, Z.-H.; Deng, D.-S.; Xu, C.-Y.; Zhou, L.: A new 3D pillared-layer porous framework with interesting open channels in the Co/triazolate/carboxylate system: synthesis, structure and magnetism. Inorg. Chem. Commun. 62 (2015) 47–50.10.1016/j.inoche.2015.10.024Search in Google Scholar

5. Ma, S.; Zhou, H.-C.: Gas storage in porous metal-organic frameworks for clean energy applications. Chem. Commun. 46 (2010) 44–53.10.1039/B916295JSearch in Google Scholar PubMed

6. Li, Z.-H.; Xue, L.-P.; Qin, Q.-P.; Zhao, Y.-J.: Synthesis, structure, and catalytic properties of a copper(II) coordination polymer material constructed from 5-nitro-1,2,3-benzenetricarboxylic acid and bis(4-pyridylformyl)piperazine mixed ligands. J. Solid State Chem. 278 (2019) 120908.10.1016/j.jssc.2019.120908Search in Google Scholar

7. Wang, Z. Q.; Zheng, C. J.; Wang, W. Z.; Xu, C.; Ji, B. M.; Zhang, X. H.: Synthesis, structure, and photophysical properties of two four-coordinate CuI-NHC complexes with efficient delayed fluorescence. Inorg. Chem. 55 (2016) 2157–2164.10.1021/acs.inorgchem.5b02546Search in Google Scholar PubMed

8. Chen, Z.-X.; Zhou, Y.-M.; Weng, L.-H.; Zhao, D.-Y.: Mixed-solvothermal syntheses and structures of six new zinc phosphonocarboxylates with zeolite-type and pillar-layered frameworks. Cryst. Growth Des. 8 (2008) 4045–4053.10.1021/cg800374sSearch in Google Scholar

9. Xue, L.-P.; Li, Z.-H.; Li, S.-H.; Wang, J.-G.: Synthesis, crystal structure and fluorescent property of a new one-dimensional cadmium(II) coordination polymer based on 3,4-thiophenedicarboxylic acid and 1,10-phenanthroline. Chin. J. Struct. Chem. 32 (2013) 704–708.Search in Google Scholar

10. Liu, G.-Z.; Xin, L.-Y.; Wang, L. Y.: Ancillary ligand-mediated syntheses and fluorescence properties of zinc(II) complexes based on flexible benzene dicarboxylic acid. CrystEngComm 13 (2011) 3013–3020.10.1039/c0ce00873gSearch in Google Scholar

11. Miao, S.-B.; Li, Z.-H.; Xu, C.-Y.; Ji, B.-M.: A new 3-fold interpenetrating 3D Zn(II) metal-organic framework: synthesis, structure and luminescent property. Chin. J. Struct. Chem. 35 (2016) 1960–1966.Search in Google Scholar

12. Lan, H.-H.; Li, X.-T.; Chu, W.-J.; Xu, C.-Y.; Ji, B.-M.: Syntheses, crystal structures and luminescence properties of two Zn(II) coordination polymers based on flexible bisbenzimidazole ligand. Chin. J. Inorg. Chem. 35 (2019) 1896–1902.Search in Google Scholar

13. Miao, S.-B.; Wang, Y.-F.; Deng, D.-S.; Xu, C.-Y.; Li, Z.-H.; Ji, B.-M.: A new Cu-based metal-organic framework built upon infinite 1D rod-shaped secondary building units. Inorg. Chem. Commun. 78 (2017) 25–27.10.1016/j.inoche.2017.02.003Search in Google Scholar

14. Deng, D.-S.; Kang, G.-H.; Ji, B.-M.; Li, H.-L.; Qu, G.-R.; Fan, X.-S.: Syntheses photoluminescent properties, and structural investigation of five complexes based on a new T-shaped 2-(pyridin-3-yl)-4,6-pyrimidine dicarboxylic acid ligand: structure evolution from one-dimensional chains to three-dimensional architectures. Aust. J. Chem. 66 (2013) 1342–1351.10.1071/CH13163Search in Google Scholar

15. Miao, S.-B.; Wang, Y.-F.; Deng, D.-S.; Xu, C.-Y.; Li, Z.-H.; Ji, B.-M.: Two Co(II) coordination polymers based on 3,5-di(4H-1,2,4-triazole-4-yl)benzoic acid ligand: syntheses, structures and magnetic property. Chin. J. Struct. Chem. 37 (2018) 1102–1108.Search in Google Scholar

16. Miao, S.-B.: Crystal structure of poly[aqua-(μ3-3,5-di(4H-1,2,4-triazolyl-4-κ3N,N′:N′′)benzenecarboxylato) silver(I)], C11H9AgN6O3. Z. Kristallogr. NCS 232 (2017) 711–712.10.1515/ncrs-2016-0349Search in Google Scholar

Received: 2020-03-19
Accepted: 2020-06-02
Published Online: 2020-07-14
Published in Print: 2020-08-26

©2020 Kai-Hui Li et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  59. Crystal structure of ethyl 3-(trifluoromethyl)-1H-pyrazole-4-carboxylate, C7H7F3N2O2
  60. Crystal structure of tetrakis(1H-benzo[d]imidazol-3-ium) bis(μ5-phenylphosphonato)-pentakis(μ2-oxido)-decaoxo-penta-molybdenum dihydrate, C40H42Mo5N8O23P2
  61. Structure of 7-(3,3,4,4,5,5-hexafluoro-2-(2-methylbenzo[b]thiophen-3-yl)cyclopent-1-en-1-yl)-8-methylquinoline, C24H15F6NS
  62. Crystal structure of monocarbonyl[2-((cyclopentylmethylene)amino)-5-methylphenolato-κ2N,O] (tricyclohexylphosphine)rhodium(I), C32H48NO2PRh
  63. The crystal structure of fac-tricarbonyl(1,10-phenanthroline-κ2N,N′)-(pyrazole-κN)rhenium(I)nitrate, C18H12O3N4Re
  64. Crystal structure of poly[diaqua-bis(μ2-4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoato-κ2N:O)nickel(II)], C28H22O6N8Ni
  65. Crystal structure of 4,4′-bis(pyridin-1-ium-4-yl)biphenyl poly[bis(μ2-4,4′-bis(pyrid-4-yl)biphenyl-K2N:N′)-tetrakis(μ4-4′-methyl-[1,1′-biphenyl]-3,5-dicarboxylato-K4O,O′:O′′:O′′′)-bis[[μ2-1,1′-biphenyl]-3-carboxyl-5-carboxylato-K2O:O′]tetracobalt(II)]— [1,1′-biphenyl]-3,5-dicarboxylic acid (1/2), C93H68N3O16Co2
  66. The crystal structure of 4a-formyl-1,2,3,4,4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-icosahydro-1-2-6a,6b,9,9,12a-heptamethylpicen-10-yl acetate, C32H50O3
  67. Crystal structure of 3,3′-(1,2-phenylenebis(methylene))bis(1-methyl-1H-imidazol-3-ium) bis(hexafluoridophosphate), C16H20F12N4P2
  68. Crystal structure of catena-poly[diaqua-(μ2-tartrato-κ4O,O′:O′′,O′′′)zinc(II)], C4H8O8Zn
  69. The crystal structure of (6aR,6bS,8aS,8bR,9S,11aS,12aS,12bS)-10-(4-acetoxy-3-methylbutyl)-6a,8a,9-trimethyl-3,4,5,6,6a,6b,7,8,8a,8b,9,10,11a,12,12a,12b-hexadecahydro-1H-naphtho[2′,1′:4,5]indeno[2,1-b]furan-4-yl acetate, C31H48O5
  70. Crystal structure of 4,4′-(oxybis(methylene))bis(bromobenzene), C14H12Br2O
  71. Crystal structure of (N,N-dimethylsulphoxide)-[N-(3-ethoxy-2-(oxide)benzylidene)-3-methoxybenzenecarbohydrazonato-κ3N,O,O′]-dioxo-molybdenum(VI), C19H22MoN2O7S
  72. Crystal structure of dichlorido-bis(dimethyl sulphoxide-κO)-bis(4-methylbenzyl-κC1)tin(IV), C20H30Cl2O2S2Sn
  73. Crystal structure of (E)-2-amino-N′-(2-hydroxy-4-(2-(piperidin-1-yl)ethoxy)benzylidene)benzohydrazide monohydrate, C21H26N4O3 ⋅ H2O
  74. Crystal structure of chloridotris(4-chlorophenyl)(dimethyl sulfoxide-κO)tin(IV), C20H18Cl4OSSn
  75. Crystal structure of catena{di-aqua-sodium-[N-(hydroxyethyl), N-isopropyl-dithiocarbamato]}n, [C6H16NNaO2S2]n
  76. Crystal structure of 2,2,4,4,6,6-hexakis(4-chlorophenyl)-1,3,5,2,4,6-trithiatristanninane, C36H24Cl6S3Sn3
  77. Crystal structure of 6-methoxy-3-(5-(3-methoxyphenyl)-1,3,4-oxadiazol-2-yl)-4H-chromen-4-one-methanol (1/1), C20H18N2O6
  78. Crystal structure of hexanedihydrazide, C6H14N4O2
  79. Crystal structure of tert-butyl 2-(hydroxymethyl)-5-{4-[(methoxycarbonyl)amino]phenyl}-2,5-dihydro-1H-pyrrole-1-carboxylate, C18H24N2O5
  80. Crystal structure of [(Z)-O-isopropyl N-(4-nitrophenyl)thiocarbamato-κS]-(triphenylphosphine-κP)-gold(I), C28H26AuN2O3PS
  81. Crystal structure of [O-ethyl N-(4-nitrophenyl)thiocarbamato-κS](tri-4-tolylphosphine-κP)gold(I) tetrahydrofuran solvate, C30H30AuN2O3PS, C4H8O
https://doi.org/10.1515/ncrs-2020-0149
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Articles in the same Issue

  1. Frontmatter
  2. Crystal structure of isopimara-7,15-dien-3-one, C20H30O
  3. Crystal structure of bis(6-aminopyridine-2-carboxylato-κ2O,N)-copper(II), C12H10O6N4Cu
  4. Crystal structure of 5,6-diphenyldibenzo[c, g]chrysene, C38H24
  5. Poly[bis(dimethylformamide-κO)-(μ8-5,5′′-dicarboxy-[1,1′:4′,1′′-terphenyl]-2′,3,3′′,5′-tetracarboxylato-κ8O:O1:O2:O3:O4:O5:O6:O7)dizinc(II)] — dimethylformamide (1/2), C18H19N2O8Zn
  6. The crystal structure of poly[bis(N,N-dimethylformamide-κ1O)(μ4- 2′,5,5′,5′′-tetracarboxy-[1,1′:4′,1′′-terphenyl]-3,3′′-dicarboxylato-κ4O:O′:O′′:O′′′)manganese(II)] — N,N-dimethylformamide (1/2), C36H40N4O16Mn
  7. Crystal structure of N,N-dimethyl-4-((7-nitrobenzo[c][1,2,5]thiadiazol-4-yl)ethynyl)aniline, C16H12N4O2S
  8. The crystal structure of 8a-methoxy 8a-methoxy-1,5,8a,9a-tetrahydro-4H-8,9-dioxa-3a1λ4-aza-8aλ4, C18H14BNO3
  9. Crystal structure of poly[diaqua-(μ2-5-isopropoxyisophthalato-κ2O:O′)-(μ2-(1,3-bis(3,5-di(1H-imidazol-1-yl)pyridine))-κ2N:N′)cobalt(II)] monohydrate, C22H25N5O8Co
  10. The crystal structure of acetoximium 1′-hydroxy-1H,1H′-5,5′-bitetrazole-1-olate monohydrate, C5H11N9O4
  11. Crystal structure of 3-(2-ethoxy-2-oxoethyl)-1-vinyl-1H-imidazol-3-ium hexafluoridophosphate(V), C9H13F6N2O2P
  12. The crystal structure of catena-poly[(μ2-4-(benzo[d]imidazol-2-yl)benzenecarboxylato-κ2N,O)-(μ2-4-(benzo[d]imidazol-2-yl)benzenecarboxylato-κ3N,O:O′)cadmium(II)]dihydrate, C28H22CdN4O6
  13. Enzyme-mediated synthesis and crystal structure of (2R,4S)-hydroxyketamine, C13H16ClNO2
  14. The crystal structure of bis(isothiocyanato-κ1N)-(methanol-κ1O)-[2-morpholine-4-yl-4,6-di(pyrazol-1-yl)-1,3,5-triazine-κ3N,N′,N′′] manganese(II), C16H18MnN10O2S2
  15. Crystal structure of bis{5-chloro-2-(((4-trifluoromethyl)imino)methyl)phenolato-κ2N,O}copper(II), C28H16Cl2CuF6N2O2
  16. Crystal structure of bis(1,3-phenylenedimethanaminium) bis(triiodide) tetraiodide – water (1/2) , C8H16I5N2O
  17. Crystal structure and anti-inflammatory activity of (3E,5E)-3,5-bis(2-fluorobenzylidene)-1-((4-fluorophenyl)sulfonyl)piperidin-4-one, C25H18F3NO3S
  18. The crystal structure of bis{3-(diphenylphosphaneyl)propanoato-κ2O,P}platinum(II) dihydrate, C30H28O6P2Pt
  19. The crystal structure of (E)-2-(4-((4-fluorobenzyl)oxy)styryl)-4,6-dimethoxybenzaldehyde, C24H21FO4
  20. Crystal structure of bis[3-methoxy-N-(1-(pyrazin-2-yl)ethylidene)benzohydrazonato-κ3O,N,N′]nickel(II), C28H26N8O4Ni
  21. Crystal structure of 1-(2-(pyridin-2-yl)-5-(pyridin-3-yl)-1,3,4-oxadiazol-3(2H)-yl)ethan-1-one, C14H12N4O2
  22. Synthesis and crystal structure of 3-N-acetyl-5-(pyridin-3-yl)-2-(quinolin-2-yl)-1,3,4-oxadiazoline, C18H14N4O2
  23. Crystal structure of 2-methyl-1H-perimidine, C12H10N2
  24. Crystal structure of (E)-2-(5,5-dimethyl-3-(4-((7-nitrobenzo[c][1,2,5]oxadiazol-4-yl)oxy)styryl)cyclohex-2-en-1-ylidene)malononitrile, C25H19N5O4
  25. Structural elucidation of 1-(3-acetyl-2,6-dihydroxy-4-methoxyphenyl)-4,5-dihydroxy-2-methylanthracene-9,10-dione isolated from Bulbine latifolia (L.) Wild, C24H18O8
  26. Crystal structure of 3-cinnamoyl-4-hydroxybenzoic acid, C16H12O4
  27. The crystal structure of poly[bis(μ4-2,3-pyridinedicarboxylato)-(μ2-oxalyl dihydrazide)-dicadmium(II) dihydrate], C16H16O12N6Cd2
  28. Synthesis and crystal structure of 1-{4-[(3-bromo-2-hydroxy-benzylidene)amino]phenyl}ethanone, C15H12BrNO2
  29. Synthesis and crystal structure of 1-{4-[(2-bromo-6-hydroxy-benzylidene)amino]phenyl}ethanone, C15H12BrNO2
  30. Crystal structure of (4-aminobenzoato-κ2O,O′)-[5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′]nickel(II) perchlorate monohydrate, C23H44ClN5NiO7
  31. Crystal structure of 1-{4-[(4-fluoro-2-hydroxy-benzylidene)amino]phenyl}ethanone, C15H12FNO2
  32. Preparation and crystal structure of a non-symmetrical vanadium(II) dimer: tri-μ2-bromido-(hydrogen-tris(3-isopropyl-4-bromopyrazol-1-yl)borato-κ3N,N′,N′′)-tris(tetrahydrofuran-κO)divanadium(II) – tetrahydrofuran (1/1), C34H57BBr6N6O4V2
  33. Crystal structure of bis{2-(((4-(1-(hydroxyl-imino)ethyl)phenyl)imino)methyl)phenolato-κ2N,O}cobalt(II), C30H26CoN4O4
  34. Crystal structure of 3-((3-nitrophenyl)sulfonamido)propanoic acid — 4,4′-bipyridine (1/1), C19H18N4O6S
  35. Crystal structure of cyclo[diaqua-bis(μ2-3′,5-dicarboxy-[1,1′-biphenyl]-3,4′-dicarboxylato-κ4O,O′:O′′,O′′′)-bis(4,4′-bis(pyrid-4-yl)biphenyl-K1N)dicadmium(II)], C76H52Cd2N4O18
  36. Crystal structure of 1-(adamantan-1-yl)-3-aminothiourea, C11H19N3S
  37. Crystal structure of catena-poly[triaqua-(μ2-1,4-di(pyridin-4-yl)benzene-κ2N:N′)-(3′,5-dicarboxy-[1,1′-biphenyl]-3,4′-dicarboxylato-κO)nickel(II)], C32H26N2O11Ni
  38. Crystal structure of catena-poly[aqua-(μ4-4,4′-(pyridine-3,5-diyl)dibenzoato-κ4O,O′:O′′:O′′′)zinc(II)], C19H13NO5Zn
  39. Crystal structure of 4-(4′-(pyridin-4-yl)-[1,1′-biphenyl]-4-yl)pyridin-1-ium 2-carboxy-4-(3,5-dicarboxyphenoxy)benzoate hydrate, C38H28N2O10
  40. Crystal structure of 3-[(triisopropylsilanyl)-ethynyl]-6a,12a-dihydro-1H-1,4-diaza-benzo[α]anthracene-2,7,12-trione, C27H28N2O3Si
  41. Crystal structure of [(bis(1,10-phenanthroline-κ2N,N′)-(2-carboxy-4-(3-carboxy-5-carboxylatophenoxy)benzoato-κ2O:O′))nickel(II) monohydrate, (1,10-phenanthroline-κ2N:N′)-(μ2-(5-(3′,4′-dicarboxylphenoxy)-isophthalate-κ2O:O′))nickel(II)], C40H24N4O9Ni ⋅ H2O
  42. Crystal structure of 4-(3-(pyridin-3-yl)ureido)benzoic acid — adipic acid (2/1), C16H16N3O5
  43. Crystal structure of poly[bis{μ2-5-carboxy-4′-methyl-[1,1′-biphenyl]-3-carboxylato-κ2O:O′}-{μ2-4,4′-bipyridine-κ2N:N′}]cobalt(II), C40H30N2O8Co
  44. Crystal structure of aqua-(2,2′-bipyridine-κ2N,N′)(((3-nitrophenyl)sulfonyl)glycine-κ2N,O)copper(II) dihydrate, C18H20CuN4O9S
  45. Crystal structure of bis{2-bromo-6-(((4-(1-(methoxyimino)ethyl)phenyl)imino)methyl)phenolato-κ2N,O}copper(II), C32H28Br2CuN4O4
  46. Crystal structure of bis(2-(2-((2,6-dichlorophenyl)amino)phenyl)acetato-κ2O,O′)-(1,10-phenanthroline-κ2N,N′)zinc(II), C40H28Cl4N4O4Zn
  47. Crystal structure of 2-(3,6-dimethyl-2,3-dihydro-4H-benzo[b][1,4]oxazin-4-yl)-2-oxoethyl acetate, C14H17NO4
  48. Crystal structure of poly[dibromido-bis(μ2-1,6-di(1H-imidazol-1-yl)hexane-κ2N:N′)cadmium(II)], C24H36Br2N8Cd
  49. Synthesis and crystal structure of ((6R,7S)-3-ethyl-6-phenyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazin-7-yl)(phenyl)methanone hemihydrate, 2(C19H18N4OS) ⋅ H2O
  50. Crystal structure of 2-(5-(pyridin-3-yl)-4-(pyridin-4-yl)-4H-1,2,4-triazol-3-yl)pyridine, C17H12N6
  51. The crystal structure of N-((1E,2E)-1,3-bis(4-fluorophenyl)but-2-en-1-ylidene)-4-methylbenzenesulfonamide, C23H19F2NO2S
  52. Crystal structure of diacetato-κ1O-diethanol-κ1O-bis(μ2-2-(((2-hydroxyethyl)imino)methyl)-5-methoxyphenolato-κ4O,N,O′:O′′)dinickel(II), C28H42Ni2N2O12
  53. The crystal structure of catena-poly[chlorido-(μ2-1,4-bis(pyridin-3-yl-methoxy)benzene-κ2N:N′)copper(II)], C18H16ClN2O2Cu
  54. N′,N′′′-(((ethane-1,2-diylbis(oxy))bis(2,1-phenylene))bis(methaneylylidene))bis(2-hydroxybenzohydrazide)nickel(II), C30H24N4NiO6
  55. Crystal structure of (E)-3′,6′-bis(ethylamino)-2′,7′-dimethyl-2-(2-((quinolin-2-ylmethylene)amino)ethyl)spiro[isoindoline-1,9′-xanthen]-3-one, C38H37N5O2
  56. Crystal structure of 4,4′-di(1H-imidazol-1-yl)-1,1′-biphenyl-1-ium 5,3′,5′-tricarboxy-[1,10-biphenyl]-2-carboxylate, C25H17N2O8
  57. The crystal structure of 1-carboxy-2-(1H-indol-3-yl)-N,N,N-trimethylethan-1-ammonium chloride, C14H19N2O2Cl
  58. The crystal structure of 5-bromo-2-fluoronicotinic acid monohydrate, C6H5BrFNO3
  59. Crystal structure of ethyl 3-(trifluoromethyl)-1H-pyrazole-4-carboxylate, C7H7F3N2O2
  60. Crystal structure of tetrakis(1H-benzo[d]imidazol-3-ium) bis(μ5-phenylphosphonato)-pentakis(μ2-oxido)-decaoxo-penta-molybdenum dihydrate, C40H42Mo5N8O23P2
  61. Structure of 7-(3,3,4,4,5,5-hexafluoro-2-(2-methylbenzo[b]thiophen-3-yl)cyclopent-1-en-1-yl)-8-methylquinoline, C24H15F6NS
  62. Crystal structure of monocarbonyl[2-((cyclopentylmethylene)amino)-5-methylphenolato-κ2N,O] (tricyclohexylphosphine)rhodium(I), C32H48NO2PRh
  63. The crystal structure of fac-tricarbonyl(1,10-phenanthroline-κ2N,N′)-(pyrazole-κN)rhenium(I)nitrate, C18H12O3N4Re
  64. Crystal structure of poly[diaqua-bis(μ2-4-(3-(pyridin-3-yl)-1H-1,2,4-triazol-5-yl)benzoato-κ2N:O)nickel(II)], C28H22O6N8Ni
  65. Crystal structure of 4,4′-bis(pyridin-1-ium-4-yl)biphenyl poly[bis(μ2-4,4′-bis(pyrid-4-yl)biphenyl-K2N:N′)-tetrakis(μ4-4′-methyl-[1,1′-biphenyl]-3,5-dicarboxylato-K4O,O′:O′′:O′′′)-bis[[μ2-1,1′-biphenyl]-3-carboxyl-5-carboxylato-K2O:O′]tetracobalt(II)]— [1,1′-biphenyl]-3,5-dicarboxylic acid (1/2), C93H68N3O16Co2
  66. The crystal structure of 4a-formyl-1,2,3,4,4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-icosahydro-1-2-6a,6b,9,9,12a-heptamethylpicen-10-yl acetate, C32H50O3
  67. Crystal structure of 3,3′-(1,2-phenylenebis(methylene))bis(1-methyl-1H-imidazol-3-ium) bis(hexafluoridophosphate), C16H20F12N4P2
  68. Crystal structure of catena-poly[diaqua-(μ2-tartrato-κ4O,O′:O′′,O′′′)zinc(II)], C4H8O8Zn
  69. The crystal structure of (6aR,6bS,8aS,8bR,9S,11aS,12aS,12bS)-10-(4-acetoxy-3-methylbutyl)-6a,8a,9-trimethyl-3,4,5,6,6a,6b,7,8,8a,8b,9,10,11a,12,12a,12b-hexadecahydro-1H-naphtho[2′,1′:4,5]indeno[2,1-b]furan-4-yl acetate, C31H48O5
  70. Crystal structure of 4,4′-(oxybis(methylene))bis(bromobenzene), C14H12Br2O
  71. Crystal structure of (N,N-dimethylsulphoxide)-[N-(3-ethoxy-2-(oxide)benzylidene)-3-methoxybenzenecarbohydrazonato-κ3N,O,O′]-dioxo-molybdenum(VI), C19H22MoN2O7S
  72. Crystal structure of dichlorido-bis(dimethyl sulphoxide-κO)-bis(4-methylbenzyl-κC1)tin(IV), C20H30Cl2O2S2Sn
  73. Crystal structure of (E)-2-amino-N′-(2-hydroxy-4-(2-(piperidin-1-yl)ethoxy)benzylidene)benzohydrazide monohydrate, C21H26N4O3 ⋅ H2O
  74. Crystal structure of chloridotris(4-chlorophenyl)(dimethyl sulfoxide-κO)tin(IV), C20H18Cl4OSSn
  75. Crystal structure of catena{di-aqua-sodium-[N-(hydroxyethyl), N-isopropyl-dithiocarbamato]}n, [C6H16NNaO2S2]n
  76. Crystal structure of 2,2,4,4,6,6-hexakis(4-chlorophenyl)-1,3,5,2,4,6-trithiatristanninane, C36H24Cl6S3Sn3
  77. Crystal structure of 6-methoxy-3-(5-(3-methoxyphenyl)-1,3,4-oxadiazol-2-yl)-4H-chromen-4-one-methanol (1/1), C20H18N2O6
  78. Crystal structure of hexanedihydrazide, C6H14N4O2
  79. Crystal structure of tert-butyl 2-(hydroxymethyl)-5-{4-[(methoxycarbonyl)amino]phenyl}-2,5-dihydro-1H-pyrrole-1-carboxylate, C18H24N2O5
  80. Crystal structure of [(Z)-O-isopropyl N-(4-nitrophenyl)thiocarbamato-κS]-(triphenylphosphine-κP)-gold(I), C28H26AuN2O3PS
  81. Crystal structure of [O-ethyl N-(4-nitrophenyl)thiocarbamato-κS](tri-4-tolylphosphine-κP)gold(I) tetrahydrofuran solvate, C30H30AuN2O3PS, C4H8O
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