Home Physical Sciences Crystal structure of poly-[(μ2-(carboxylatomethyl)((3-nitrophenyl)sulfonyl)amido-κ3N:O:O′)(μ2-4,4′-bipyridine-κ2N:N′) nickel(II)], C18H14NiN4O6S
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Crystal structure of poly-[(μ2-(carboxylatomethyl)((3-nitrophenyl)sulfonyl)amido-κ3N:O:O′)(μ2-4,4′-bipyridine-κ2N:N′) nickel(II)], C18H14NiN4O6S

  • Zheng-Jun Liu EMAIL logo , Xiao-Miao Chen , Jing-Song Cheng , Tao-Li Deng and Lan Qin
Published/Copyright: February 21, 2019
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 234 Issue 3

Abstract

C18H14NiN4O6S, trigonal, R3̄ (no. 148), a = 31.014(11) Å, b = 31.014(11) Å, c = 10.125(7) Å, V = 8434(8) Å3, Z = 18, Rgt(F) = 0.0380, wRref(F2) = 0.0941, T = 296(2) K.

CCDC no.: 1503985

The title crystal structure is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Green block
Size:0.26 × 0.25 × 0.21 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:1.19 mm−1
Diffractometer, scan mode:CCD, φ and ω
θmax, completeness:28.4°, >99%
N(hkl)measured, N(hkl)unique, Rint:17895, 4697, 0.046
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 3385
N(param)refined:271
Programs:Bruker [1], SHELX [2], [3], Olex2 [4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Ni10.08130(2)0.38507(2)0.30183(3)0.02756(10)
S10.18734(2)0.45589(2)0.15518(6)0.03231(15)
O10.30621(9)0.49945(10)0.5643(3)0.0795(8)
O20.34202(8)0.57868(9)0.5889(2)0.0738(7)
O30.20460(6)0.48022(7)0.02977(17)0.0475(5)
O40.20257(7)0.42085(6)0.1921(2)0.0483(5)
O50.02357(6)0.40384(6)−0.02796(16)0.0347(4)
O60.03396(6)0.37658(6)0.16340(18)0.0426(5)
N10.31029(9)0.53977(11)0.5402(2)0.0523(6)
N20.12992(7)0.43266(7)0.16831(19)0.0337(5)
N30.29729(7)0.39022(8)0.9094(2)0.0355(5)
N40.12869(7)0.39010(7)0.44477(19)0.0321(4)
C10.27523(9)0.54153(10)0.4478(2)0.0382(6)
C20.26979(11)0.58229(11)0.4457(3)0.0540(8)
H20.2879040.6088590.5027440.065*
C30.23679(13)0.58319(12)0.3571(4)0.0694(10)
H30.2322370.6106370.3552210.083*
C40.21033(11)0.54449(10)0.2712(3)0.0500(7)
H40.1881980.5458170.2116220.060*
C50.21684(8)0.50364(9)0.2741(2)0.0316(5)
C60.24906(8)0.50160(9)0.3649(2)0.0349(6)
H60.2529520.4737960.3698550.042*
C70.10423(9)0.44162(11)0.0608(3)0.0458(7)
H7A0.1180120.439278−0.0231190.055*
H7B0.1089620.4748910.0684880.055*
C80.05012(8)0.40429(8)0.0654(2)0.0278(5)
C90.29295(10)0.37192(10)0.7890(3)0.0455(7)
H90.3129510.3586320.7659520.055*
C100.26046(10)0.37155(10)0.6965(3)0.0455(7)
H100.2589810.3588040.6124500.055*
C110.22997(9)0.39044(9)0.7304(2)0.0335(5)
C120.23376(10)0.40843(11)0.8551(3)0.0448(7)
H120.2137200.4212640.8817580.054*
C130.26746(10)0.40744(11)0.9411(3)0.0446(7)
H130.2693610.4195591.0261880.054*
C140.19494(9)0.39122(9)0.6324(2)0.0319(5)
C150.18187(9)0.42784(10)0.6293(3)0.0397(6)
H150.1949550.4534820.6910060.048*
C160.14956(9)0.42597(9)0.5346(3)0.0375(6)
H160.1417320.4512670.5330270.045*
C170.14134(9)0.35504(9)0.4487(2)0.0374(6)
H170.1270910.3293740.3872260.045*
C180.17387(9)0.35459(9)0.5374(3)0.0380(6)
H180.1819860.3295150.5341660.046*

Source of material

To a 20 mL Teflon-lined reaction vessel was added nickel(II) acetate tetrahydrate (124.4 mg, 0.5 mmol), 3-nitrobenzenesulfonylglycine (H2nbs) (130.1 mg, 0. 5 mmol), 4,4′-bipyridine (4,4′-bipy) (78.1 mg, 0.5 mmol) and 15 mL water. Then the pH of the resulting mixture was adjusted to 7 with 1 mol/L NaOH aqueous solution. After heating at 120 °C for 24 h, the mixture was cooled to room temperature at a rate of 10 °C per hour to give green block crystals.

Experimental details

The structure was solved with the ShelXT [2] structure solution program using intrinsic phasing and refined with the ShelXL [3] refinement package.

Comment

The sulfonylated amino acid has a plurality of coordination sites because it contains both an amino group and a carboxyl group. It can be used to assemble MOFs and CPs [5], [6], [7], [8] which have potential applications in gas adsorption and separations [9], [10], [11], sensors [12], [13], catalysis [14], [15], and fluorescent materials [16].

In this paper, we report the synthesis and the crystal structure of a new nickel(II) complex with 4,4′-bipyridine (4,4′-bipy) and 3-nitrobenzenesulfonylglycine (H2nbs). The asymmetric unit is composed of one Ni(II) ion, one nbs ligand and one 4,4′-bipy ligand. The Ni2+ ion is five-coordinated by two N atoms (N3, N4) from 4,4′-bipy group, two O atoms (O5, O6) and one N atom (N2) from nbs group (Ni1—O, 1.9500(18) ∼ 2.0255(17) Å, Ni1—N, 2.013(2) ∼ 2.168(2) Å). A three-dimensional coordination polymer was formed by Ni—O and Ni—N bonds.

Funding source: Key Project of Guizhou Provincial Education Department

Award Identifier / Grant number: KY[2015]385

Funding source: Youth Science and Technology Talents Growth Project of Guizhou Provincial Education Department

Award Identifier / Grant number: KY[2018]329

Funding source: Platform Project of Anshun University

Award Identifier / Grant number: 2015PT03

Funding statement: The project was supported by Key Project of Guizhou Provincial Education Department (KY[2015]385), Youth Science and Technology Talents Growth Project of Guizhou Provincial Education Department (KY[2018]329) and Platform Project of Anshun University (2015PT03).

References

1. BRUKER. SAINT, APEX2 and SADABS. Bruker AXS Inc., Madison, WI, USA (2009).Search in Google Scholar

2. Sheldrick, G. M.: SHELXT-integrated space-group and crystal-structure determination. Acta Crystallogr. A71 (2015) 3–8.10.1107/S2053273314026370Search in Google Scholar PubMed PubMed Central

3. Sheldrick, G. M.: Crystal structure refinement with SHELXL. Acta Crystallogr. C71 (2015) 3–8.10.1107/S2053229614024218Search in Google Scholar PubMed PubMed Central

4. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H.: OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr. 42 (2009) 339–341.10.1107/S0021889808042726Search in Google Scholar

5. Chen, X.; Liu, Z.; Deng, T.: Crystal structure of poly-{diaqua-bis[(μ2-3-nitrobenzenesulfonylglycine-κ3N:O:O′)(4,4′-bipyridine)manganese(II)]}-dimethylformamide (1/1), C39H35Mn2N9O15S2. Z. Kristallogr. NCS 233 (2018) 893–895.10.1515/ncrs-2018-0082Search in Google Scholar

6. Liu, Z. J.; Chen, X. M.; Hao, S. Y.; Cheng, M. Q.: Syntheses, crystal structures, and thermal properties of two transition metal complexes with 4-chlorobenzenesulfonyl-glycine acid ligand. Synth. React. Inorg. Met.-Org. Nano-Met. Chem. 46 (2016) 529–533.10.1080/15533174.2014.988810Search in Google Scholar

7. Cheng, M. Q.; Chen, X. M.; Liu, Z. J.; Li, Y. J.: Crystal structure of ((4-acetamidophenyl)sulfonyl)(carboxylatomethyl) amide-κ2N,O)bis(1,10-phenantroline-κ2N,N′) nickel(II) heptahydrate, [Ni(abgly)(phen)2]⋅7 H2O, C34H40N6NiO12S. Z. Kristallogr. NCS 228 (2013) 491–493.10.1515/ncrs.2013.0228Search in Google Scholar

8. Cheng, M. Q.; Chen, X. M.; Liu, Z. J.; Feng, C. Q.: Syntheses, structures, and thermal properties of two new Mn(II) and Ni(II) complexes of 3-nitrobenzenesulfonyl- glycine acid and 4-chlorobenzenesulfonyl-glycine acid ligands. Synth. React. Inorg. Met.-Org. Nano-Met. Chem. 44 (2013) 27–32.10.1080/15533174.2013.763278Search in Google Scholar

9. Alhamami, M.; Doan, H.; Cheng, C.: A review on breathing behaviors of metal-organic-frameworks (MOFs) for gas adsorption. Materials 7 (2014) 3198–3250.10.3390/ma7043198Search in Google Scholar PubMed PubMed Central

10. Wang, Z.; Sezen, H.; Liu, J.; Yang, C.; Roggenbuck, S. E.; Peikert, K.; Fröba, M.; Mavrandonakis, A.; Supronowicz, B.; Heine, T.; Gliemann, H.; Wöll, C.: Tunable coordinative defects in UHM-3 surface-mounted MOFs for gas adsorption and separation: a combined experimental and theoretical study. Mesoporous Mater. 207 (2015) 53–60.10.1016/j.micromeso.2014.12.033Search in Google Scholar

11. Adil, K.; Belmabkhout, Y.; Pillai, R. S.: Gas/vapour separation using ultra-microporous metal–organic frameworks: insights into the structure/separation relationship. Chem. Soc. Rev. 46 (2017) 3402–3430.10.1039/C7CS00153CSearch in Google Scholar PubMed

12. Schönfeld, F.; Meyer, L. V.; Mühlbach, F.; Zottnick, S. H.; Müller-Buschbaum, K.: Optical isotherms as a fundamental characterization method for gas sensing with luminescent MOFs by comparison of open and dense frameworks. J. Mater. Chem. C 6 (2018) 2588–2595.10.1039/C7TC05002JSearch in Google Scholar

13. Wu, Y.; Xu, G.; Dong, W.; Zhao, J.; Li, D.-S.; Zhang, J.; Bu, X.: Anionic lanthanide MOFs as a platform for iron-selective sensing, systematic color tuning, and efficient nanoparticle catalysis. Inorg. Chem. 56 (2017) 1402–1411.10.1021/acs.inorgchem.6b02476Search in Google Scholar PubMed

14. Deria, P.; Gómez-Gualdrón, D. A.; Hod, I.: Framework-topology-dependent catalytic activity of zirconium-based (porphinato)zinc(II) MOFs. J. Am. Chem. Soc. 138 (2016) 14449–14457.10.1021/jacs.6b09113Search in Google Scholar PubMed

15. Chen, L.; Xu, Q.: Converting MOFs into amination catalysts. Science 358 (2017) 304–305.10.1126/science.aap8004Search in Google Scholar PubMed

16. Chen, C.; Qiu, Q.; Pan, M.; Cao, C.-C.; Zhu, N.-X.; Wang, H.-P.; Jiang, J.-J.; Wei, Z.-W.; Su, C.-Y.: Tunability of fluorescent metal-organic frameworks through dynamic spacer installation with multivariate fluorophores. Chem. Commun. 54 (2018) 13666–13669.10.1039/C8CC07441KSearch in Google Scholar

Received: 2018-12-02
Accepted: 2019-01-31
Published Online: 2019-02-21
Published in Print: 2019-03-26

©2019 Zheng-Jun Liu et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 Public License.

Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of poly[aqua-μ2-4,4′-bis(pyrid-4-yl)biphenyl-κ2N:N′)-μ4-4′-methyl-[1,1′-biphenyl]-3,5-dicarboxylato-κ4O:O′:O′′:O′′′)manganese(II)], C52H40N2O10Mn2
  3. Crystal structure of bis[2-(((3-aminopropyl)imino)methyl)-4-nitro-phenolato-κ3N,N′,O]nickel(II), C20H24N6NiO6
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  65. Crystal structure of catena-poly[dibromido-{μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4-ylmethylene)amino)-1,2-dihydro-3H-pyrazol-3-one-κ2N:O}zinc(II)], C34H32Br4N8O2Zn2
  66. Crystal structure of diaqua-dichlorido-bis(μ2-2-(((1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino)methyl)phenolato-κ4O:O,N,O′)dicobalt(II), C36H36Cl2N6O6Co2
  67. Crystal structure of catena-poly[diaqua-(μ2-1,2-bis(4-pyridinyl)ethyane-κ2N:N′)-(μ2–pyridazine-4,5-dicarboxylato-κ2O:O′)]dizinc(II) dihydrate, C12H12ZnN3O6
  68. The crystal structure of 2-(4-chloro-2,6-dinitrophenyl)-1-(4-chloro)diazene oxide, C12H6Cl2N4O5
  69. Crystal structure of 2-isopropylthioxanthone, C16H14OS
  70. Crystal structure of methyl 2-(4-(3-(1-methyl-1H-pyrazol-4-yl)pyrazolo[1,5-a]pyrimidin-6-yl)phenyl)acetate, C19H17N5O2
  71. Crystal structure of 4,4-dimethyl-2-(trifluoromethyl)-4,5-dihydro-1H-imidazole, C6H9F3N2
  72. Crystal structure of N-methylanilinium 5,7-dihydroxy-4-oxo-2-phenyl-4H-chromene-8-sulfonate monohydrate, C22H21NO8S
  73. Crystal structure of methyl 4-acetoxybenzoate, C10H10O4
  74. Crystal structure of catena-poly[(bis(μ-1,1′-[(5-methoxy-2,4,6-trimethyl-1,3-phenylene)bis(methylene)]bis(1H-1,2,4-triazole)-κ2N:N′)-bis(isothiocyanato-κN)manganese(II)], C34H40MnN14O2S2
  75. Crystal structure of N-(2-methylphenyl)(propan-2-yloxy)carbothioamide, C11H15NOS
https://doi.org/10.1515/ncrs-2018-0551
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Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of poly[aqua-μ2-4,4′-bis(pyrid-4-yl)biphenyl-κ2N:N′)-μ4-4′-methyl-[1,1′-biphenyl]-3,5-dicarboxylato-κ4O:O′:O′′:O′′′)manganese(II)], C52H40N2O10Mn2
  3. Crystal structure of bis[2-(((3-aminopropyl)imino)methyl)-4-nitro-phenolato-κ3N,N′,O]nickel(II), C20H24N6NiO6
  4. Synthesis and crystal structure of bis{2-((E)-((4-((E)-1-(methoxyimino)ethyl)phenyl)imino)methyl) phenolato-κ2N,O}cobalt(II) — ethanol (1/1), C34H36CoN4O5
  5. Crystal structure of 1-(4-{2,5-dichloro-3-hydroxy-4-[4-(1-methoxyimino-ethyl)-phenylamino]-6-methyl-phenylamino}-phenyl)-ethanone O-methyl-oxime, C24H22Cl2N4O4
  6. The pseudosymmetric crystal structure of 2,4,6,8,10,12-hexanitrohexaazaisowurtzitane dimethyl carbonate (2/3), C21H30N24O33
  7. Crystal structure of (1,4-diazepane)4CuII2(μ-Cl)10CuI6, C20H48Cl10Cu8N8
  8. Crystal structure of methyl 2,7,7-trimethyl-4-(3-methylthiophen-2-yl)-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate, C19H23NO3S
  9. Crystal structure of methyl 2-(4-(pyrazolo[1,5-a]pyrimidin-6-yl)phenyl)acetate, C15H13N3O2
  10. Crystal structure of (1S,3aR,3bR,10aR,10bR,12aR)-8-amino-3a,3b,6,6,10a-pentamethyl-1-((S)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-2,3,3a,3b,4,5,5a,6,10,10a,10b,11,12,12a-tetradecahydro-1H-cyclopenta[7,8]phenanthro[2,3-d]thiazol-12-ol – a panaxadiol dervative, C31H50N2O2S
  11. Crystal structure of bis[(((4-fluorophenyl)amino)methyl)triphenylphosphonium] tetrachloridocobaltate(II), C50H44Cl4CoF2N2P2
  12. Crystal structure of 5,4′-dihydroxy-7,3′-dimethoxyflavanone, C17H16O6
  13. Crystal structure of 3-methyl-cyclobis(1-(1,1′-ferrocenylmethyl)-4-butyl-1H-1,2,3-triazole) tetrafluoroborate, C21H25FeN6⋅BF4
  14. Crystal structure of 3-(2-diethylaminoethyl)-2,3-dihydro-2-thioxoquinazolin-4(1H)-one, C14H19N3OS
  15. Crystal structure of 2-(bis(3,5-dimethylphenyl) ((methyldiphenylsilyl)oxy)methyl) pyrrolidine, C34H39NOSi
  16. The crystal structure of 1,4-dinitro-2,3,5,6-tetraacetoxy-piperazine, C12H16N4O12
  17. Crystal structure of rac-3,6-dimethyl-5-(prop-1-en-2-yl)-6-vinyl-1,4,5,6-tetrahydro-2H-indol-2-one, C15H19NO
  18. Crystal structure of (Cu0.51In0.49)tet[Cr1.74In0.26]octSe4 selenospinel, Cu0.51In0.75Cr1.74Se4
  19. Crystal structure of 7-hydroxy-5-methoxy-4,6-dimethylisobenzofuran-1(3H)-one, C11H12O4
  20. Crystal structure of trans-tetrakis(acetonitrile-κN)bis(triphenylphosphine-κP)ruthenium(II) dihexafluorophosphate - dichloroform (1/2), C46H44Cl6F12N4P4Ru
  21. Crystal structure of 2-((4-nitrophenyl)thio)ethan-1-ol, C8H9NO3S
  22. Crystal structure of diaqua-dichlorido-bis(μ3-6,6′-(hydrazine-1,2-diylidenebis(methanylylidene))bis(2-methoxyphenolato)κ6O,N:N′,O′,O′:O′′)trizinc(II) - ethanol (1/2), C36H44Cl2N4O12Zn3
  23. Crystal structure of the co-crystal 2-[(2-carboxyphenyl)disulfanyl]benzoic acid – 3-chlorobenzoic acid (2/1), C35H25ClO10S4
  24. The crystal structure of 4-(3-chloro-4-fluorophenylamino)-7-methoxyquinazolin-6-ol, C15H11ClFN3O2
  25. Crystal structure of ethyl (E)-1-(3-ethoxy-3-oxoprop-1-en-1-yl)-2-(4-nitrophenyl)-2,5-dihydro-1H-benzo[b][1,4]diazepine-3-carboxylate, C23H23N3O6
  26. Crystal structure of (E)-2-(4-cyanophenyl)ethenesulfonyl fluoride, C9H6FNO2S
  27. Crystal structure of bis(4-bromo-2-(((3-chloropropyl)imino)methyl)phenolato-κ2N,O)-oxidovanadium(IV), C20H20Br2Cl2N2O3V
  28. The crystal structure of 1,1,1,3,3,3-hexaphenyldistannoxane – 2,2′-bipyridine (1/1), C46H38N2OSn2
  29. Crystal structure of coordination polymer catena-poly[diaqua-(2,6-dichloropyridine-4-carboxyliato-κ2O,O′)-bis(μ2-2,6-dichloropyridine-4-carboxyliato-κ2O:O′)terbium(III), C18H10Cl6N3O8Tb
  30. The crystal structure of 4-((2-(4,5-dihydro-1,5-diphenyl-1H-pyrazol-3-yl)anthracen-10-yl) methyl)morpholine, C34H31N3O
  31. The crystal structure of bis(N,N-dimethylformamide-κO)-tetrakis(9H-xanthene-9-carboxylic-carboxylate-κ2O:O′)dicopper(II) - acetonitrile (1/2), C66H56Cu2N4O14
  32. Crystal structure of trans-dichlorido-(1,3-dimesityl-1H-imidazol-2(3H)-ylidene)-(5-methyl-3,4-dihydro-2H-pyrrole-κN)palladium(II), C25H31Cl2N3OPd
  33. Crystal structure of 8,8′-di-p-tolyl-8′H-7,8′-biacenaphtho[1,2-d]imidazole, C40H26N4
  34. The crystal structure of 3-amino-(2,4-dioxopent-3-yl)-4,5-dihydro-1,2,4-triazinium nitrate, C8H13N5O5
  35. Crystal structure of 4,4′,5,5′-tetraphenyl-2,2′-di-p-tolyl-2′H-1,2′-biimidazole, C44H34N4
  36. Halogen bonds in the crystal structure of 2-bromo-1,10-phenanthroline – 1,4-diiodotetrafluorobenzene (2/1), C30H14Br2F4I2N4
  37. Crystal structure of tris(1-phenyl-1,2-propanedione-2-oximato-κ2N,O)cobalt(III), C27H24N3O6Co
  38. Crystal structure of chlorido-(6,6′-((1,2-phenylenebis(azanylylidene))bis(methanylylidene))bis(3-methoxyphenolato)-κ4O,N,N′,O′)iron(III), C22H18ClN2FeO4
  39. Crystal structure of bis(μ2-1-(4-chlorophenyl)-3-phenyl-4-thenoyl-1H-pyrazol-5-olato-κ3O,O′:O′)-bis-(1-(4-chlorophenyl)-3-phenyl-4-thenoyl-1H-pyrazol-5-olato-κ2O,O)-bis(ethyl acetate-κO)dicadmium(II), C88H64Cl4N8O12S4Cd2
  40. Crystal structure of catena-poly[dichlorido-(μ2-3-(2-pyridyl)-4-(4-pyridyl)-5-(3-pyridyl)-1,2,4-triazole-κ2N:N′)] copper(II), C17H12N6Cl2Cu
  41. Crystal structure of dichlorido-([2,2′:6′,2′′-terpyridine]-4′-carboxylic acid-κ3N,N′,N′′)copper(II) monohydrate, C16H13Cl2CuN3O3
  42. Crystal structure of triethylammonium(5-carboxypyridine-2-thiolato-κ2N,S)-bis(dimethylsulfoxide-κ1S)-(6-sulfidonicotinato-κ2N,S)ruthenium(II) trihydrate, C22H41N3O9RuS4
  43. The crystal structure of poly[(μ5-2,5-dicarboxy-benzoato-κ4O:O:O′:O′′,O′′′)silver(I)], C9H5AgO6
  44. Crystal structure of (E)-1-(thiophen-2-yl)-N-(5-((triphenylstannyl)thio)-1,3,4-thiadiazol-2-yl)methanimine, C25H19N3S3Sn
  45. Crystal structure of diaqua-bis(3,5-dichloroisonicotinato-κ1O)-bis(1,3-di(pyridin-4-yl)propane-κ1N)cobalt(II), C38H36Cl4N6O6Co
  46. Crystal structure of dodecaaqua-bis(μ2-4,4′-bipyridine-κ2N:N′)-bis(4,4′-((5-carboxylato-1,3-phenylene)bis(oxy))dibenzoato-κ1O)tricopper(II) - water (1/4), C62H70Cu3N4O32
  47. Crystal structure of bis(5-methoxy-2-(((2-oxidoethyl)imino)methyl)phenolate-κ3O,N,O′)manganes(IV), C20H22N2O6Mn
  48. Crystal structure of tetramethylammonium (2-(3-ethoxy-2-oxidobenzylidene)-1-(2-hydroxybenzoyl)hydrazin-1-ido-κ3N,N′,O)cobalt(III), C36H40N5O8Co
  49. Crystal structure of 6-cyclohexyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl nitrate, C20H23O3N2Bi
  50. Crystal structure of (E)-N-((2S,3S,4R,10R,13S, 17S)-17-(1-(dimethylamino) ethyl)-2,4-dihydroxy-10,13-dimethylhexadecahydro-1H-cyclopenta[a]phenanthren-3-yl)-2-methylbut-2-enamide, C24H48N2O3
  51. Crystal structure of (E)-2-((4-chlorophenyl)(phenyl)methylene)hydrazine-1-carbothioamide, C14H12ClN3S
  52. Crystal structure of 1-benzyl-3-cyano-6-phenyl-1,2-dihydropyridine, C19H16N2
  53. Isolation and crystal structure of 4-((2-(methoxycarbonyl)phenyl)amino)-2-methyl-4-oxobutanoic acid from Delphinium Grandiflorum, C13H15N1O5
  54. Crystal structure of tetraqua-bis(4-(hydroxymethyl)benzoato-κO)nickel(II), C16H22O10Ni
  55. Crystal structure of ajacisine D monohydrate, C30H44N2O9
  56. The crystal structure of (E)-4-(1-(2-aminophenylimino)ethyl)benzene-1,3-diol, C14H14N2O2
  57. Crystal structure of poly[(μ4-(4H-1,2,4-triazol-4-yl)phenyl)acetato-κ4N,N′,O,O′)(formiato-κ1O)cobalt(II)], C11H9CoN3O4
  58. The crystal structure of bis tetrabutylammonium bis(μ3-2,2,2-tri(hydroxymethyl)ethyl-4-((3-methoxy-3-oxopropyl)amino)-4-oxobutanoato)-(μ6-oxido)-hexakis(μ2-oxido)-hexaoxido-hexavanadium(V), C58H112N4O29V6
  59. Crystal structure of (N-benzylpropane-1,3-diamine-κ2N, N′)(2,2′-bipyridine-κ2N,N′)platinum(II) chloride, C20H24Cl2N4Pt
  60. Crystal structure of 5-(5-(4-chlorophenyl)-1-phenyl-1H-pyrazol-3-yl)-N-phenyl-2-amine, C23H16ClN5O
  61. Crystal structure of poly-[(μ2(carboxylatomethyl)((3-nitrophenyl)sulfonyl)amido-κ3N: O:O′)(μ2-4,4′-bipyridine-κ2N:N′)copper(II)], C18H14CuN4O6S
  62. Crystal structure of poly-[(μ2-(carboxylatomethyl)((3-nitrophenyl)sulfonyl)amido-κ3N:O:O′)(μ2-4,4′-bipyridine-κ2N:N′) nickel(II)], C18H14NiN4O6S
  63. Crystal structure of N-((3R,10S,13S,17S)-17-((S)-1-(dimethylamino)ethyl)-10,13-dimethylhexadecahydro-1H-cyclopenta[a]phenanthren-3-yl)-N-methylbenzamide, C31H48N2O
  64. The crystal structure of dichloroido(1,3-bis(2,6-dimethyl-phenyl)-1H-3l4-imidazol-2-yl)(2-methyl-4,5-dihydrooxazol-κN)palladium(IV)-water (1/1), C23H29Cl2N3O2Pd
  65. Crystal structure of catena-poly[dibromido-{μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4-ylmethylene)amino)-1,2-dihydro-3H-pyrazol-3-one-κ2N:O}zinc(II)], C34H32Br4N8O2Zn2
  66. Crystal structure of diaqua-dichlorido-bis(μ2-2-(((1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino)methyl)phenolato-κ4O:O,N,O′)dicobalt(II), C36H36Cl2N6O6Co2
  67. Crystal structure of catena-poly[diaqua-(μ2-1,2-bis(4-pyridinyl)ethyane-κ2N:N′)-(μ2–pyridazine-4,5-dicarboxylato-κ2O:O′)]dizinc(II) dihydrate, C12H12ZnN3O6
  68. The crystal structure of 2-(4-chloro-2,6-dinitrophenyl)-1-(4-chloro)diazene oxide, C12H6Cl2N4O5
  69. Crystal structure of 2-isopropylthioxanthone, C16H14OS
  70. Crystal structure of methyl 2-(4-(3-(1-methyl-1H-pyrazol-4-yl)pyrazolo[1,5-a]pyrimidin-6-yl)phenyl)acetate, C19H17N5O2
  71. Crystal structure of 4,4-dimethyl-2-(trifluoromethyl)-4,5-dihydro-1H-imidazole, C6H9F3N2
  72. Crystal structure of N-methylanilinium 5,7-dihydroxy-4-oxo-2-phenyl-4H-chromene-8-sulfonate monohydrate, C22H21NO8S
  73. Crystal structure of methyl 4-acetoxybenzoate, C10H10O4
  74. Crystal structure of catena-poly[(bis(μ-1,1′-[(5-methoxy-2,4,6-trimethyl-1,3-phenylene)bis(methylene)]bis(1H-1,2,4-triazole)-κ2N:N′)-bis(isothiocyanato-κN)manganese(II)], C34H40MnN14O2S2
  75. Crystal structure of N-(2-methylphenyl)(propan-2-yloxy)carbothioamide, C11H15NOS
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