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Crystal structure of ajacisine D monohydrate, C30H44N2O9

  • Guo-Qiang Li EMAIL logo , Qing-Peng Xu , Yi-Ting Zhao , Yun-Yi Li , Yao-Lan Li and Guo-Cai Wang
Published/Copyright: February 1, 2019
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 234 Issue 3

Abstract

C30H44N2O9, monoclinic, P21 (no. 4), a = 7.9827(3) Å, b = 12.6787(6) Å, c = 14.0183(9) Å, β = 90.903(5)°, V = 1418.62(13) Å3, Z = 2, Rgt(F) = 0.0607, wRref(F2) = 0.1298, T = 298(2) K.

CCDC no.: 1890792

The title crystal structure (systematic name: N-ethyl-18β-(o-aminobenzoyl)-6β,16β-dimethoxy-aconitane-1α,7β,8β,14α-tetraol) is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Yellow block
Size:0.26 × 0.25 × 0.25 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:0.10 mm−1
Diffractometer, scan mode:Gemini S ultra, ω
θmax, completeness:32.8°, >99%
N(hkl)measured, N(hkl)unique, Rint:19473, 9362, 0.043
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 6262
N(param)refined:386
Programs:CrysAlisPRO [1], SHELX [2]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
O1−0.0122(3)−0.09255(18)0.38972(17)0.0390(5)
H10.0830−0.08100.40990.059*
O20.2924(3)0.19199(16)0.11396(15)0.0342(5)
O30.5416(2)0.02230(17)0.23040(16)0.0341(5)
H30.59570.06420.19870.051*
O40.4506(3)0.02337(19)0.03575(16)0.0414(5)
H40.42510.08550.02810.062*
O50.2108(4)−0.1108(2)−0.07619(18)0.0541(7)
H50.2583−0.0555−0.08950.081*
O60.3160(3)−0.31633(17)0.06658(17)0.0422(5)
O70.0615(3)0.34374(16)0.34533(18)0.0406(5)
O80.2084(3)0.49181(19)0.3672(2)0.0544(7)
N10.3003(3)−0.0077(2)0.38030(17)0.0300(5)
N20.0477(4)0.6764(2)0.3377(2)0.0441(7)
H2A0.10400.68110.28590.053*
H2B0.01630.73870.35460.053*
C1−0.0596(3)−0.0120(3)0.3224(2)0.0316(6)
H1A−0.1507−0.04090.28270.038*
C2−0.1282(4)0.0845(3)0.3724(2)0.0367(7)
H2C−0.17800.13180.32550.044*
H2D−0.21510.06320.41600.044*
C30.0086(4)0.1414(3)0.4270(2)0.0370(7)
H3A0.04350.09830.48090.044*
H3B−0.03640.20670.45190.044*
C40.1649(3)0.1673(2)0.3664(2)0.0310(6)
C50.1353(3)0.1372(2)0.2593(2)0.0264(6)
H5A0.04970.18210.22920.032*
C60.3040(3)0.1445(2)0.2065(2)0.0275(6)
H60.38180.18640.24570.033*
C70.3700(3)0.0289(2)0.2037(2)0.0264(6)
C80.3406(3)−0.0239(2)0.1050(2)0.0290(6)
C90.1574(3)−0.0063(2)0.0715(2)0.0305(6)
H90.14580.06280.04090.037*
C100.0295(3)−0.0174(2)0.1525(2)0.0281(6)
H10−0.06870.02490.13450.034*
C110.0857(3)0.0184(2)0.2536(2)0.0255(5)
C12−0.0246(4)−0.1363(2)0.1471(2)0.0343(7)
H12A−0.0056−0.17080.20810.041*
H12B−0.1424−0.14220.13000.041*
C130.0842(4)−0.1868(3)0.0700(2)0.0351(7)
H130.0255−0.24550.03860.042*
C140.1024(4)−0.0936(3)0.0025(2)0.0378(7)
H14−0.0090−0.0756−0.02290.045*
C150.3925(4)−0.1413(2)0.1055(2)0.0334(7)
H15A0.4528−0.15520.04730.040*
H15B0.4704−0.15210.15840.040*
C160.2534(4)−0.2229(2)0.1133(2)0.0330(7)
H160.2376−0.23910.18090.040*
C170.2606(3)−0.0280(2)0.2792(2)0.0262(6)
H170.2607−0.10420.26730.031*
C180.2059(4)0.2838(2)0.3775(3)0.0367(7)
H18A0.23160.29980.44380.044*
H18B0.30260.30170.33970.044*
C190.3165(4)0.1043(2)0.4045(2)0.0331(7)
H19A0.41830.13220.37720.040*
H19B0.32490.11210.47320.040*
C200.4420(4)−0.0706(3)0.4205(3)0.0385(7)
H20A0.4812−0.03800.47930.046*
H20B0.5336−0.06980.37590.046*
C210.3944(5)−0.1821(3)0.4403(4)0.0633(12)
H21A0.3559−0.21500.38230.095*
H21B0.3066−0.18350.48630.095*
H21C0.4901−0.21960.46500.095*
C220.2951(5)0.3037(3)0.1174(3)0.0488(9)
H22A0.29120.33140.05370.073*
H22B0.39620.32680.14910.073*
H22C0.19990.32860.15190.073*
C230.2399(5)−0.4112(3)0.0995(3)0.0555(10)
H23A0.2809−0.46990.06340.083*
H23B0.1206−0.40620.09130.083*
H23C0.2672−0.42120.16580.083*
C24−0.0825(4)0.5027(2)0.3244(2)0.0344(7)
C25−0.0907(4)0.6144(3)0.3226(2)0.0365(7)
C26−0.2465(5)0.6616(3)0.3051(3)0.0545(10)
H26−0.25460.73480.30400.065*
C27−0.3867(5)0.6021(4)0.2895(4)0.0674(13)
H27−0.48850.63560.27750.081*
C28−0.3806(5)0.4931(4)0.2911(3)0.0635(11)
H28−0.47730.45340.28090.076*
C29−0.2290(4)0.4443(3)0.3082(3)0.0477(9)
H29−0.22370.37110.30890.057*
C300.0761(4)0.4492(2)0.3478(2)0.0349(7)
O90.2853(4)−0.3169(3)−0.1356(3)0.0584(7)
H9A0.301(7)−0.321(5)−0.071(5)0.11(2)*
H9B0.250(6)−0.257(4)−0.141(4)0.069(15)*

Source of material

Air-dry roots of the plant Delphinium grandiflorum were purchased from Guangzhou qingping medicine market, Guangdong, China. Powder of roots (10 kg) was extracted with 95% ethanol at room temperature. The total alkaloids (63 g) was then obtained by acid extraction and alkali precipitation method. The total alkaloids was loaded on a silica gel column chromatography and eluted with CHCl3—CH3OH solvent system (100:0–0:100) to afford six fractions (Fr. 1–6). The title compound was obtained from Fr. 5 and crystallized in a mixture of methanol and water.

Experimental details

The C-bound H atoms were positioned geometrically and were included in the refinement in the riding-model approximation. The crystal structure was solved by direct method and refined by full-matrix least-squares refinement with SHELX program [2]. The Flack parameter is not conclusive.

Comment

According to our previous work, many alkaloids have been isolated from Delphinium grandiflorum [3], [4]. The title compound, ajacisine D monohydrate, is one of the diterpenoid alkaloids which have been proved to be the main chemical components of genus Delphinium [5], [6]. These diterpenoid alkaloids have complex structure skeletons and posess multiple biological activities such as anastalsis, antibacterial activity [7], [8], [9], [10]. The single crystals were obtained by slow evaporation from a mixture of methanol and water.

There is one ajacisine D molecule (C30H42N2O8) and one water molecule (H2O) in the asymmetric unit (cf. the figure). In the crystal structure, the typical bond lengths of C1—O1, N1—C20, O8—C30 and N2—C25 are 1.437(4) Å, 1.488(4) Å, 1.213(4) Å, 1.370(5) Å respectively. The torsion angle of O7—C30—C24—C29 is 3.7(4)°, which demonstrates that the aryl moiety (mean deviation 0.002 Å) and the ester group are not exactly coplanar. The angle of C4—C19—N1 is 110.9(2)°, which is smaller than 114.2(2)° of C17—N1—C19. Intermolecular hydrogen-bonding interactions involving the water molecule, methoxy group, the hydroxy and the phenyl amine give a three-dimensional stucture. Two short intramolecular interactions between the C1 hydroxy and N1, C8 hydroxy and methoxy O at C6 are also present [cf. the figure; O1—H1⋯N1 = 2.722(3) Å, 144°; O4—H4⋯O2 = 2.722(3) Å, 132°].

Funding source: National Natural Science Foundation of China

Award Identifier / Grant number: 21405013

Funding source: Natural Science Foundation of Guangdong Province

Award Identifier / Grant number: A030310079

Funding statement: This work was supported financially by grants from the national Natural Science Foundation of China (no. 21405013), Postgraduate demonstration course construction fundation of Guangdong Education Department (2016SFKC-43), the Fundamental Research Funds for the Central Universities (Grant gg040971), the Natural Science Foundation of Guangdong Province (Grant 2016 A030310079

References

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Received: 2018-11-26
Accepted: 2019-01-14
Published Online: 2019-02-01
Published in Print: 2019-03-26

©2019 Guo-Qiang Li et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 Public License.

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  61. Crystal structure of poly-[(μ2(carboxylatomethyl)((3-nitrophenyl)sulfonyl)amido-κ3N: O:O′)(μ2-4,4′-bipyridine-κ2N:N′)copper(II)], C18H14CuN4O6S
  62. Crystal structure of poly-[(μ2-(carboxylatomethyl)((3-nitrophenyl)sulfonyl)amido-κ3N:O:O′)(μ2-4,4′-bipyridine-κ2N:N′) nickel(II)], C18H14NiN4O6S
  63. Crystal structure of N-((3R,10S,13S,17S)-17-((S)-1-(dimethylamino)ethyl)-10,13-dimethylhexadecahydro-1H-cyclopenta[a]phenanthren-3-yl)-N-methylbenzamide, C31H48N2O
  64. The crystal structure of dichloroido(1,3-bis(2,6-dimethyl-phenyl)-1H-3l4-imidazol-2-yl)(2-methyl-4,5-dihydrooxazol-κN)palladium(IV)-water (1/1), C23H29Cl2N3O2Pd
  65. Crystal structure of catena-poly[dibromido-{μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4-ylmethylene)amino)-1,2-dihydro-3H-pyrazol-3-one-κ2N:O}zinc(II)], C34H32Br4N8O2Zn2
  66. Crystal structure of diaqua-dichlorido-bis(μ2-2-(((1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino)methyl)phenolato-κ4O:O,N,O′)dicobalt(II), C36H36Cl2N6O6Co2
  67. Crystal structure of catena-poly[diaqua-(μ2-1,2-bis(4-pyridinyl)ethyane-κ2N:N′)-(μ2–pyridazine-4,5-dicarboxylato-κ2O:O′)]dizinc(II) dihydrate, C12H12ZnN3O6
  68. The crystal structure of 2-(4-chloro-2,6-dinitrophenyl)-1-(4-chloro)diazene oxide, C12H6Cl2N4O5
  69. Crystal structure of 2-isopropylthioxanthone, C16H14OS
  70. Crystal structure of methyl 2-(4-(3-(1-methyl-1H-pyrazol-4-yl)pyrazolo[1,5-a]pyrimidin-6-yl)phenyl)acetate, C19H17N5O2
  71. Crystal structure of 4,4-dimethyl-2-(trifluoromethyl)-4,5-dihydro-1H-imidazole, C6H9F3N2
  72. Crystal structure of N-methylanilinium 5,7-dihydroxy-4-oxo-2-phenyl-4H-chromene-8-sulfonate monohydrate, C22H21NO8S
  73. Crystal structure of methyl 4-acetoxybenzoate, C10H10O4
  74. Crystal structure of catena-poly[(bis(μ-1,1′-[(5-methoxy-2,4,6-trimethyl-1,3-phenylene)bis(methylene)]bis(1H-1,2,4-triazole)-κ2N:N′)-bis(isothiocyanato-κN)manganese(II)], C34H40MnN14O2S2
  75. Crystal structure of N-(2-methylphenyl)(propan-2-yloxy)carbothioamide, C11H15NOS
https://doi.org/10.1515/ncrs-2018-0531
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Articles in the same Issue

  1. Cover and Frontmatter
  2. Crystal structure of poly[aqua-μ2-4,4′-bis(pyrid-4-yl)biphenyl-κ2N:N′)-μ4-4′-methyl-[1,1′-biphenyl]-3,5-dicarboxylato-κ4O:O′:O′′:O′′′)manganese(II)], C52H40N2O10Mn2
  3. Crystal structure of bis[2-(((3-aminopropyl)imino)methyl)-4-nitro-phenolato-κ3N,N′,O]nickel(II), C20H24N6NiO6
  4. Synthesis and crystal structure of bis{2-((E)-((4-((E)-1-(methoxyimino)ethyl)phenyl)imino)methyl) phenolato-κ2N,O}cobalt(II) — ethanol (1/1), C34H36CoN4O5
  5. Crystal structure of 1-(4-{2,5-dichloro-3-hydroxy-4-[4-(1-methoxyimino-ethyl)-phenylamino]-6-methyl-phenylamino}-phenyl)-ethanone O-methyl-oxime, C24H22Cl2N4O4
  6. The pseudosymmetric crystal structure of 2,4,6,8,10,12-hexanitrohexaazaisowurtzitane dimethyl carbonate (2/3), C21H30N24O33
  7. Crystal structure of (1,4-diazepane)4CuII2(μ-Cl)10CuI6, C20H48Cl10Cu8N8
  8. Crystal structure of methyl 2,7,7-trimethyl-4-(3-methylthiophen-2-yl)-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carboxylate, C19H23NO3S
  9. Crystal structure of methyl 2-(4-(pyrazolo[1,5-a]pyrimidin-6-yl)phenyl)acetate, C15H13N3O2
  10. Crystal structure of (1S,3aR,3bR,10aR,10bR,12aR)-8-amino-3a,3b,6,6,10a-pentamethyl-1-((S)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-2,3,3a,3b,4,5,5a,6,10,10a,10b,11,12,12a-tetradecahydro-1H-cyclopenta[7,8]phenanthro[2,3-d]thiazol-12-ol – a panaxadiol dervative, C31H50N2O2S
  11. Crystal structure of bis[(((4-fluorophenyl)amino)methyl)triphenylphosphonium] tetrachloridocobaltate(II), C50H44Cl4CoF2N2P2
  12. Crystal structure of 5,4′-dihydroxy-7,3′-dimethoxyflavanone, C17H16O6
  13. Crystal structure of 3-methyl-cyclobis(1-(1,1′-ferrocenylmethyl)-4-butyl-1H-1,2,3-triazole) tetrafluoroborate, C21H25FeN6⋅BF4
  14. Crystal structure of 3-(2-diethylaminoethyl)-2,3-dihydro-2-thioxoquinazolin-4(1H)-one, C14H19N3OS
  15. Crystal structure of 2-(bis(3,5-dimethylphenyl) ((methyldiphenylsilyl)oxy)methyl) pyrrolidine, C34H39NOSi
  16. The crystal structure of 1,4-dinitro-2,3,5,6-tetraacetoxy-piperazine, C12H16N4O12
  17. Crystal structure of rac-3,6-dimethyl-5-(prop-1-en-2-yl)-6-vinyl-1,4,5,6-tetrahydro-2H-indol-2-one, C15H19NO
  18. Crystal structure of (Cu0.51In0.49)tet[Cr1.74In0.26]octSe4 selenospinel, Cu0.51In0.75Cr1.74Se4
  19. Crystal structure of 7-hydroxy-5-methoxy-4,6-dimethylisobenzofuran-1(3H)-one, C11H12O4
  20. Crystal structure of trans-tetrakis(acetonitrile-κN)bis(triphenylphosphine-κP)ruthenium(II) dihexafluorophosphate - dichloroform (1/2), C46H44Cl6F12N4P4Ru
  21. Crystal structure of 2-((4-nitrophenyl)thio)ethan-1-ol, C8H9NO3S
  22. Crystal structure of diaqua-dichlorido-bis(μ3-6,6′-(hydrazine-1,2-diylidenebis(methanylylidene))bis(2-methoxyphenolato)κ6O,N:N′,O′,O′:O′′)trizinc(II) - ethanol (1/2), C36H44Cl2N4O12Zn3
  23. Crystal structure of the co-crystal 2-[(2-carboxyphenyl)disulfanyl]benzoic acid – 3-chlorobenzoic acid (2/1), C35H25ClO10S4
  24. The crystal structure of 4-(3-chloro-4-fluorophenylamino)-7-methoxyquinazolin-6-ol, C15H11ClFN3O2
  25. Crystal structure of ethyl (E)-1-(3-ethoxy-3-oxoprop-1-en-1-yl)-2-(4-nitrophenyl)-2,5-dihydro-1H-benzo[b][1,4]diazepine-3-carboxylate, C23H23N3O6
  26. Crystal structure of (E)-2-(4-cyanophenyl)ethenesulfonyl fluoride, C9H6FNO2S
  27. Crystal structure of bis(4-bromo-2-(((3-chloropropyl)imino)methyl)phenolato-κ2N,O)-oxidovanadium(IV), C20H20Br2Cl2N2O3V
  28. The crystal structure of 1,1,1,3,3,3-hexaphenyldistannoxane – 2,2′-bipyridine (1/1), C46H38N2OSn2
  29. Crystal structure of coordination polymer catena-poly[diaqua-(2,6-dichloropyridine-4-carboxyliato-κ2O,O′)-bis(μ2-2,6-dichloropyridine-4-carboxyliato-κ2O:O′)terbium(III), C18H10Cl6N3O8Tb
  30. The crystal structure of 4-((2-(4,5-dihydro-1,5-diphenyl-1H-pyrazol-3-yl)anthracen-10-yl) methyl)morpholine, C34H31N3O
  31. The crystal structure of bis(N,N-dimethylformamide-κO)-tetrakis(9H-xanthene-9-carboxylic-carboxylate-κ2O:O′)dicopper(II) - acetonitrile (1/2), C66H56Cu2N4O14
  32. Crystal structure of trans-dichlorido-(1,3-dimesityl-1H-imidazol-2(3H)-ylidene)-(5-methyl-3,4-dihydro-2H-pyrrole-κN)palladium(II), C25H31Cl2N3OPd
  33. Crystal structure of 8,8′-di-p-tolyl-8′H-7,8′-biacenaphtho[1,2-d]imidazole, C40H26N4
  34. The crystal structure of 3-amino-(2,4-dioxopent-3-yl)-4,5-dihydro-1,2,4-triazinium nitrate, C8H13N5O5
  35. Crystal structure of 4,4′,5,5′-tetraphenyl-2,2′-di-p-tolyl-2′H-1,2′-biimidazole, C44H34N4
  36. Halogen bonds in the crystal structure of 2-bromo-1,10-phenanthroline – 1,4-diiodotetrafluorobenzene (2/1), C30H14Br2F4I2N4
  37. Crystal structure of tris(1-phenyl-1,2-propanedione-2-oximato-κ2N,O)cobalt(III), C27H24N3O6Co
  38. Crystal structure of chlorido-(6,6′-((1,2-phenylenebis(azanylylidene))bis(methanylylidene))bis(3-methoxyphenolato)-κ4O,N,N′,O′)iron(III), C22H18ClN2FeO4
  39. Crystal structure of bis(μ2-1-(4-chlorophenyl)-3-phenyl-4-thenoyl-1H-pyrazol-5-olato-κ3O,O′:O′)-bis-(1-(4-chlorophenyl)-3-phenyl-4-thenoyl-1H-pyrazol-5-olato-κ2O,O)-bis(ethyl acetate-κO)dicadmium(II), C88H64Cl4N8O12S4Cd2
  40. Crystal structure of catena-poly[dichlorido-(μ2-3-(2-pyridyl)-4-(4-pyridyl)-5-(3-pyridyl)-1,2,4-triazole-κ2N:N′)] copper(II), C17H12N6Cl2Cu
  41. Crystal structure of dichlorido-([2,2′:6′,2′′-terpyridine]-4′-carboxylic acid-κ3N,N′,N′′)copper(II) monohydrate, C16H13Cl2CuN3O3
  42. Crystal structure of triethylammonium(5-carboxypyridine-2-thiolato-κ2N,S)-bis(dimethylsulfoxide-κ1S)-(6-sulfidonicotinato-κ2N,S)ruthenium(II) trihydrate, C22H41N3O9RuS4
  43. The crystal structure of poly[(μ5-2,5-dicarboxy-benzoato-κ4O:O:O′:O′′,O′′′)silver(I)], C9H5AgO6
  44. Crystal structure of (E)-1-(thiophen-2-yl)-N-(5-((triphenylstannyl)thio)-1,3,4-thiadiazol-2-yl)methanimine, C25H19N3S3Sn
  45. Crystal structure of diaqua-bis(3,5-dichloroisonicotinato-κ1O)-bis(1,3-di(pyridin-4-yl)propane-κ1N)cobalt(II), C38H36Cl4N6O6Co
  46. Crystal structure of dodecaaqua-bis(μ2-4,4′-bipyridine-κ2N:N′)-bis(4,4′-((5-carboxylato-1,3-phenylene)bis(oxy))dibenzoato-κ1O)tricopper(II) - water (1/4), C62H70Cu3N4O32
  47. Crystal structure of bis(5-methoxy-2-(((2-oxidoethyl)imino)methyl)phenolate-κ3O,N,O′)manganes(IV), C20H22N2O6Mn
  48. Crystal structure of tetramethylammonium (2-(3-ethoxy-2-oxidobenzylidene)-1-(2-hydroxybenzoyl)hydrazin-1-ido-κ3N,N′,O)cobalt(III), C36H40N5O8Co
  49. Crystal structure of 6-cyclohexyl-6,7-dihydrodibenzo[c,f][1,5]azabismocin-12(5H)-yl nitrate, C20H23O3N2Bi
  50. Crystal structure of (E)-N-((2S,3S,4R,10R,13S, 17S)-17-(1-(dimethylamino) ethyl)-2,4-dihydroxy-10,13-dimethylhexadecahydro-1H-cyclopenta[a]phenanthren-3-yl)-2-methylbut-2-enamide, C24H48N2O3
  51. Crystal structure of (E)-2-((4-chlorophenyl)(phenyl)methylene)hydrazine-1-carbothioamide, C14H12ClN3S
  52. Crystal structure of 1-benzyl-3-cyano-6-phenyl-1,2-dihydropyridine, C19H16N2
  53. Isolation and crystal structure of 4-((2-(methoxycarbonyl)phenyl)amino)-2-methyl-4-oxobutanoic acid from Delphinium Grandiflorum, C13H15N1O5
  54. Crystal structure of tetraqua-bis(4-(hydroxymethyl)benzoato-κO)nickel(II), C16H22O10Ni
  55. Crystal structure of ajacisine D monohydrate, C30H44N2O9
  56. The crystal structure of (E)-4-(1-(2-aminophenylimino)ethyl)benzene-1,3-diol, C14H14N2O2
  57. Crystal structure of poly[(μ4-(4H-1,2,4-triazol-4-yl)phenyl)acetato-κ4N,N′,O,O′)(formiato-κ1O)cobalt(II)], C11H9CoN3O4
  58. The crystal structure of bis tetrabutylammonium bis(μ3-2,2,2-tri(hydroxymethyl)ethyl-4-((3-methoxy-3-oxopropyl)amino)-4-oxobutanoato)-(μ6-oxido)-hexakis(μ2-oxido)-hexaoxido-hexavanadium(V), C58H112N4O29V6
  59. Crystal structure of (N-benzylpropane-1,3-diamine-κ2N, N′)(2,2′-bipyridine-κ2N,N′)platinum(II) chloride, C20H24Cl2N4Pt
  60. Crystal structure of 5-(5-(4-chlorophenyl)-1-phenyl-1H-pyrazol-3-yl)-N-phenyl-2-amine, C23H16ClN5O
  61. Crystal structure of poly-[(μ2(carboxylatomethyl)((3-nitrophenyl)sulfonyl)amido-κ3N: O:O′)(μ2-4,4′-bipyridine-κ2N:N′)copper(II)], C18H14CuN4O6S
  62. Crystal structure of poly-[(μ2-(carboxylatomethyl)((3-nitrophenyl)sulfonyl)amido-κ3N:O:O′)(μ2-4,4′-bipyridine-κ2N:N′) nickel(II)], C18H14NiN4O6S
  63. Crystal structure of N-((3R,10S,13S,17S)-17-((S)-1-(dimethylamino)ethyl)-10,13-dimethylhexadecahydro-1H-cyclopenta[a]phenanthren-3-yl)-N-methylbenzamide, C31H48N2O
  64. The crystal structure of dichloroido(1,3-bis(2,6-dimethyl-phenyl)-1H-3l4-imidazol-2-yl)(2-methyl-4,5-dihydrooxazol-κN)palladium(IV)-water (1/1), C23H29Cl2N3O2Pd
  65. Crystal structure of catena-poly[dibromido-{μ2-1,5-dimethyl-2-phenyl-4-((pyridin-4-ylmethylene)amino)-1,2-dihydro-3H-pyrazol-3-one-κ2N:O}zinc(II)], C34H32Br4N8O2Zn2
  66. Crystal structure of diaqua-dichlorido-bis(μ2-2-(((1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino)methyl)phenolato-κ4O:O,N,O′)dicobalt(II), C36H36Cl2N6O6Co2
  67. Crystal structure of catena-poly[diaqua-(μ2-1,2-bis(4-pyridinyl)ethyane-κ2N:N′)-(μ2–pyridazine-4,5-dicarboxylato-κ2O:O′)]dizinc(II) dihydrate, C12H12ZnN3O6
  68. The crystal structure of 2-(4-chloro-2,6-dinitrophenyl)-1-(4-chloro)diazene oxide, C12H6Cl2N4O5
  69. Crystal structure of 2-isopropylthioxanthone, C16H14OS
  70. Crystal structure of methyl 2-(4-(3-(1-methyl-1H-pyrazol-4-yl)pyrazolo[1,5-a]pyrimidin-6-yl)phenyl)acetate, C19H17N5O2
  71. Crystal structure of 4,4-dimethyl-2-(trifluoromethyl)-4,5-dihydro-1H-imidazole, C6H9F3N2
  72. Crystal structure of N-methylanilinium 5,7-dihydroxy-4-oxo-2-phenyl-4H-chromene-8-sulfonate monohydrate, C22H21NO8S
  73. Crystal structure of methyl 4-acetoxybenzoate, C10H10O4
  74. Crystal structure of catena-poly[(bis(μ-1,1′-[(5-methoxy-2,4,6-trimethyl-1,3-phenylene)bis(methylene)]bis(1H-1,2,4-triazole)-κ2N:N′)-bis(isothiocyanato-κN)manganese(II)], C34H40MnN14O2S2
  75. Crystal structure of N-(2-methylphenyl)(propan-2-yloxy)carbothioamide, C11H15NOS
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