Abstract
Cast products of two-phase titanium aluminides suffer from microsegregation of the alloying elements, which arises from the peritectic solidification pathway. The resulting variation in composition and microstructure occurs on a length scale in the range of 1 mm and, thus, cannot be tolerated for the anticipated applications of the materials. A significant structural and chemical consolidation can be achieved by homogenization and hot-working procedures, however, the processing experience is limited. This problem is addressed in the present paper in that the evolution of the microstructure of two-phase alloys after different stages of wrought processing is characterized by structural and chemical microanalysis involving scanning electron microscopy and energy dispersive X-ray analysis. The investigations involve different two-phase alloys in order to assess the effects of ternary and higher alloying elements on the finally obtained microstructure.
-
The authors thank U. Christoph, J. D. H. Paul, S. Eggert and J. Müllauer for technical assistance and discussion. The financial support of the HGF Strategiefondsprojekt “Gasturbine” is appreciated.
References
1 Huang, S.-C., in: R. Darolia, J.J. Lewandowski, C.T. Liu, P.L. Martin, D.B. Miracle, M.V. Nathal (eds.), Structural Intermetallics, TMS, Warrendale, PA (1993) 299.Search in Google Scholar
2 Kim, Y.-W.: J. Met. 46 (1994) 30.10.1007/BF03220745Search in Google Scholar
3 Bartolotta, P.A.; Krause, D.L., in: Y.-W. Kim, D.M. Dimiduk, M.H. Loretto (eds.), Gamma Titanium Aluminides 1999, TMS, Warrendale, PA (1999) 3.Search in Google Scholar
4 Dimiduk, D.M.: Mater. Sci. Eng. A 263 (1999) 281.10.1016/S0921-5093(98)01158-7Search in Google Scholar
5 Clemens, H.; Kestler, H.: Adv. Eng. Mater. (2000) 551.10.1002/1527-2648(200009)2:9<551::AID-ADEM551>3.0.CO;2-USearch in Google Scholar
6 Appel, F.; Oehring, M.; Wagner, R.: Intermetallics 8 (2000) 1283.10.1016/S0966-9795(00)00036-4Search in Google Scholar
7 Appel, F.; Brossmann, U.; Christoph, U.; Eggert, S.; Janschek, P.; Lorenz, U.; Müllauer, J.; Oehring, M.; Paul, J.D.H.: Adv. Eng. Mater. (2000) 699.10.1002/1527-2648(200011)2:11<699::AID-ADEM699>3.0.CO;2-JSearch in Google Scholar
8 Güther, V.; Otto, A.; Kestler, H.; Clemens, H.: As Ref. [3], p. 225.Search in Google Scholar
9 Reed, S., in: Y-W. Kim, R. Wagner, M. Yamaguchi (eds.), Gamma Titanium Aluminides, TMS, Warrendale, PA (1995) 475.Search in Google Scholar
10 Martin, P.L.; Rhodes, C.G.; McQuay, P.A.: As Ref. [1], p. 177.Search in Google Scholar
11 Semiatin, S.L.: As Ref. [9], p. 509.Search in Google Scholar
12 Imayev, R.M.; Salishchev, G. A.; Imayev, V.M.; Shagiev, M.R.; Kuznetsov, A.V.; Appel, F.; Oehring, M.; Senkov, O.N.; Froes, F.H.: As Ref. [3], p. 565.Search in Google Scholar
13 Appel, F.; Lorenz, U.; Paul, J.D.H.; Oehring, M.: As Ref. [3], p. 381.Search in Google Scholar
14 Oehring, M.; Lorenz, U.; Niefanger, R.; Christoph, U.; Appel, F.; Wagner, R.; Clemens, H.; Eberhardt, N.: As Ref. [3], p. 439.Search in Google Scholar
15 Yoshihara, M.; Miura, K.: Intermetallics 5 (1995) 357.10.1016/0966-9795(95)94254-CSearch in Google Scholar
16 Paul, J.D.H.; Appel, F.; Wagner, R.: Acta Mater. 46 (1998) 1075.10.1016/S1359-6454(97)00332-7Search in Google Scholar
17 Chen, G.L.; Zhang, W.J.; Liu, Z.C.; Li, S.J.; Kim, Y-W.: As Ref. [3], p. 371.Search in Google Scholar
18 Brossmann, U.; Oehring, M.; Appel, F., in: K.J. Hemker (ed.), Structural Intermetallics 2001, TMS, Warrendale, PA (2001) to be published.Search in Google Scholar
19 Zhang, W.J; Chen, G.L.; Appel, F., in: D.G. Morris, S. Naka, P. Caron (eds.), Intermetallics and Superalloys, Proc. Euromat 99, Vol. 10, Wiley-VCH, Weinheim (2000) 362.Search in Google Scholar
20 Mishin, Y.; Herzig, C.: Acta Mater. 48 (2000) 589.10.1016/S1359-6454(99)00400-0Search in Google Scholar
21 Rossouw, C.J.; Forwood, C.T.; Gibson, M.A.; Miller, P.R.: Phil. Mag. A 74 (1996) 77.10.1080/01418619608239691Search in Google Scholar
© 2001 Carl Hanser Verlag, München
Articles in the same Issue
- Frontmatter
- Editorial
- Günter Lange 65 Years
- Aufsätze/Articles
- Deformation and Microstructure of Titanium Chips and Workpiece
- Eigenspannungsabbau in zügig und zyklisch beanspruchten Schweißverbindungen
- Bruchmechanische Nachweise zur Stahlgütewahl für moderne Feinkornbaustähle
- Experimental Analysis of the Interaction of “Hot” and “Cold” Volume Elements during Thermal Fatigue of a Cooled Component Made from AISI 3161 Steel
- Microstructure and Cyclic Deformation Behavior of Wheel and Tire Steels in Technically Relevant Heat Treatments
- Dehnratenabhängige Beschreibung der Fließkurven für erhoöhte Temperaturen
- Ein einfaches Modell für die Kinetik der Rekristallisation
- Determination of the Elastic Modulus of Wear Resistant Coatings by Quantitative Acoustic Microscopy
- Processing, Microstructure and Properties of Nb–TiO2 ODS Materials for Surgical Implants
- Influence of Surface Treatment on the Pitting Corrosion Behaviour of High Alloyed Stainless Steels in a Chloride Solution
- Unfall durch Drahtseilriss in einer Tunnelbaustelle
- Synthesis of Nanocrystalline B2 Structured (Ru, Ir) Al in the Ternary Ru–Al–Ir System by Mechanical Alloying and its Thermal Stability
- Preparation of Ca-α-sialon Ceramics with Compositions along the Si3N4-1/2 Ca3N2:3AIN Line
- SiC–Si3N4 Nanocomposite Prepared by the Addition of SiO2 + C
- Ceramics in the Si3N4–ZrO2–CeO2 System: Phase Composition Changes and Properties
- The Al–Ca System, Part 1: Experimental Investigation of Phase Equilibria and Crystal Structures
- The Al–Ca System, Part 2: Calorimetrie Measurements and Thermodynamic Assessment
- Phase Relationships of the Gd-Zn System
- Ableitung des Kristallisationspfades in ternären Gusslegierungen
- Bildanalyse komplexer Werkstoffgefüge durch Texturanalyse und Korrelation mit den Eigenschaften durch neuronale Netze
- Grain Growth in the Nanocrystalline W–Cu and Cu–Pb Composite Powders Prepared by Mechanical Alloying
- Toughening and Strengthening Response in Ni3Al-Bonded Titanium Carbide Cermets
- Creep Behavior of γ-TiAl-Based Alloys with Fully Lamellar Microstore
- Elevated Temperature Deformation of P/M Dispersion - Strengthened Copper and Aluminium
- Evolution of the Microstructure during Hot Working of Gamma-Based TiAl Alloys
- Interface Motion of β-Silicon Nitride in a Liquid Phase
- Internal Friction and Creep of Titanium Aluminides with Different Microstructure
- Mitteilungen/Notifications
- Personen
- Conferences
Articles in the same Issue
- Frontmatter
- Editorial
- Günter Lange 65 Years
- Aufsätze/Articles
- Deformation and Microstructure of Titanium Chips and Workpiece
- Eigenspannungsabbau in zügig und zyklisch beanspruchten Schweißverbindungen
- Bruchmechanische Nachweise zur Stahlgütewahl für moderne Feinkornbaustähle
- Experimental Analysis of the Interaction of “Hot” and “Cold” Volume Elements during Thermal Fatigue of a Cooled Component Made from AISI 3161 Steel
- Microstructure and Cyclic Deformation Behavior of Wheel and Tire Steels in Technically Relevant Heat Treatments
- Dehnratenabhängige Beschreibung der Fließkurven für erhoöhte Temperaturen
- Ein einfaches Modell für die Kinetik der Rekristallisation
- Determination of the Elastic Modulus of Wear Resistant Coatings by Quantitative Acoustic Microscopy
- Processing, Microstructure and Properties of Nb–TiO2 ODS Materials for Surgical Implants
- Influence of Surface Treatment on the Pitting Corrosion Behaviour of High Alloyed Stainless Steels in a Chloride Solution
- Unfall durch Drahtseilriss in einer Tunnelbaustelle
- Synthesis of Nanocrystalline B2 Structured (Ru, Ir) Al in the Ternary Ru–Al–Ir System by Mechanical Alloying and its Thermal Stability
- Preparation of Ca-α-sialon Ceramics with Compositions along the Si3N4-1/2 Ca3N2:3AIN Line
- SiC–Si3N4 Nanocomposite Prepared by the Addition of SiO2 + C
- Ceramics in the Si3N4–ZrO2–CeO2 System: Phase Composition Changes and Properties
- The Al–Ca System, Part 1: Experimental Investigation of Phase Equilibria and Crystal Structures
- The Al–Ca System, Part 2: Calorimetrie Measurements and Thermodynamic Assessment
- Phase Relationships of the Gd-Zn System
- Ableitung des Kristallisationspfades in ternären Gusslegierungen
- Bildanalyse komplexer Werkstoffgefüge durch Texturanalyse und Korrelation mit den Eigenschaften durch neuronale Netze
- Grain Growth in the Nanocrystalline W–Cu and Cu–Pb Composite Powders Prepared by Mechanical Alloying
- Toughening and Strengthening Response in Ni3Al-Bonded Titanium Carbide Cermets
- Creep Behavior of γ-TiAl-Based Alloys with Fully Lamellar Microstore
- Elevated Temperature Deformation of P/M Dispersion - Strengthened Copper and Aluminium
- Evolution of the Microstructure during Hot Working of Gamma-Based TiAl Alloys
- Interface Motion of β-Silicon Nitride in a Liquid Phase
- Internal Friction and Creep of Titanium Aluminides with Different Microstructure
- Mitteilungen/Notifications
- Personen
- Conferences