Home Physical Sciences The crystal structure of tris(tetra-n-butylammonium) hexanitrato-κ2O,O′-lanthanium(III) C48H108N9O18La
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The crystal structure of tris(tetra-n-butylammonium) hexanitrato-κ2O,O′-lanthanium(III) C48H108N9O18La

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Published/Copyright: February 20, 2024
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 239 Issue 2

Abstract

C48H108N9O18La, monoclinic, P21/n (no. 14), a = 16.5000(10) Å, b = 22.5924(14) Å, c = 17.4287(10) Å, β = 90.875(5)°, V = 6496.2(7) Å3, Z = 4, Rgt(F) = 0.0716, wRref(F2) = 0.1706, T = 100 K.

CCDC no.: 2331014

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colourless block
Size: 0.12 × 0.11 × 0.10 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 0.73 mm−1
Diffractometer, scan mode: SuperNova, ω
θmax, completeness: 25.0°, 99 %
N(hkl)measured, N(hkl)unique, Rint: 29919, 11379, 0.053
Criterion for Iobs, N(hkl)gt: Iobs > 2σ(Iobs), 9108
N(param)refined: 697
Programs: Bruker [ 1 ], CrysAlisPRO [2], Olex2 [3], SHELX [4], Diamond [5]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z Uiso*/Ueq
La1 0.65865 (2) 0.77093 (2) 0.71532 (2) 0.01618 (12)
O1 0.6025 (3) 0.8977 (2) 0.8914 (3) 0.0310 (13)
O2 0.6436 (3) 0.8097 (2) 0.8591 (3) 0.0244 (11)
O3 0.6134 (3) 0.6881 (2) 0.8163 (3) 0.0238 (11)
O4 0.6945 (3) 0.6474 (2) 0.9013 (3) 0.0299 (13)
O5 0.7420 (3) 0.7086 (2) 0.8149 (3) 0.0267 (12)
O6 0.6247 (3) 0.8760 (2) 0.7719 (3) 0.0248 (12)
O7 0.5072 (3) 0.7786 (2) 0.7545 (3) 0.0287 (12)
O8 0.4053 (3) 0.7253 (3) 0.7127 (3) 0.0354 (14)
O9 0.5261 (3) 0.7121 (2) 0.6676 (3) 0.0229 (11)
O10 0.5748 (3) 0.8346 (2) 0.6159 (3) 0.0265 (12)
O11 0.6212 (3) 0.9015 (2) 0.5390 (3) 0.0334 (13)
O12 0.7017 (3) 0.8559 (2) 0.6199 (3) 0.0241 (11)
O13 0.8150 (3) 0.7646 (2) 0.6725 (3) 0.0266 (12)
O14 0.9113 (3) 0.8233 (2) 0.7156 (3) 0.0307 (13)
O15 0.7913 (3) 0.8257 (2) 0.7655 (3) 0.0247 (12)
O16 0.6687 (3) 0.7300 (2) 0.5733 (3) 0.0215 (11)
O17 0.7055 (3) 0.6406 (2) 0.5403 (3) 0.0284 (12)
O18 0.6951 (3) 0.6635 (2) 0.6612 (3) 0.0239 (11)
N4 0.6313 (4) 0.8647 (2) 0.5904 (3) 0.0198 (13)
N5 0.8406 (4) 0.8051 (3) 0.7177 (3) 0.0203 (13)
N6 0.6902 (3) 0.6767 (3) 0.5903 (4) 0.0232 (14)
N7 0.6829 (4) 0.6805 (3) 0.8455 (3) 0.0222 (14)
N8 0.6226 (3) 0.8628 (3) 0.8415 (4) 0.0212 (14)
N9 0.4779 (3) 0.7382 (3) 0.7115 (3) 0.0190 (13)
N1 0.4080 (4) 0.7907 (3) 0.9670 (4) 0.0308 (16)
C1 0.2231 (6) 0.6273 (4) 0.8617 (5) 0.042 (2)
H1A 0.221748 0.644358 0.811257 0.063*
H1B 0.171746 0.609166 0.871929 0.063*
H1C 0.265096 0.598000 0.864759 0.063*
C2 0.2395 (5) 0.6746 (4) 0.9195 (5) 0.0331 (19)
H2A 0.237357 0.657448 0.970438 0.040*
H2B 0.197230 0.704281 0.915500 0.040*
C3 0.3226 (5) 0.7048 (4) 0.9095 (4) 0.0320 (19)
H3A 0.365709 0.675805 0.914137 0.038*
H3B 0.325364 0.722957 0.859195 0.038*
C4 0.3324 (5) 0.7518 (4) 0.9717 (4) 0.0277 (18)
H4A 0.285156 0.777360 0.969763 0.033*
H4B 0.332977 0.732226 1.021177 0.033*
C5 0.4041 (5) 0.8323 (4) 1.0355 (4) 0.0305 (19)
H5A 0.352252 0.852533 1.033961 0.037*
H5B 0.406309 0.808881 1.082061 0.037*
C6 0.4706 (5) 0.8783 (4) 1.0397 (5) 0.037 (2)
H6A 0.522998 0.858877 1.041606 0.045*
H6B 0.468333 0.902971 0.994115 0.045*
C7 0.4608 (6) 0.9160 (4) 1.1096 (5) 0.042 (2)
H7A 0.467109 0.891004 1.154529 0.050*
H7B 0.405917 0.931406 1.109463 0.050*
C8 0.5194 (6) 0.9679 (4) 1.1175 (6) 0.049 (2)
H8A 0.511232 0.994672 1.075277 0.074*
H8B 0.574114 0.953494 1.117394 0.074*
H8C 0.509728 0.988322 1.164814 0.074*
C9 0.4842 (5) 0.7527 (4) 0.9700 (5) 0.035 (2)
H9A 0.481651 0.724832 0.927638 0.042*
H9B 0.530642 0.778139 0.961816 0.042*
C10 0.4989 (5) 0.7181 (4) 1.0434 (5) 0.042 (2)
H10A 0.448656 0.699820 1.059250 0.051*
H10B 0.516673 0.744914 1.083786 0.051*
C11 0.5627 (6) 0.6707 (4) 1.0319 (7) 0.052 (3)
H11A 0.541154 0.641357 0.996375 0.063*
H11B 0.609489 0.688671 1.008201 0.063*
C12 0.5899 (7) 0.6401 (5) 1.1031 (7) 0.069 (4)
H12A 0.636049 0.615778 1.092367 0.104*
H12B 0.546721 0.615754 1.121745 0.104*
H12C 0.604422 0.668952 1.141338 0.104*
C13 0.4088 (5) 0.8238 (4) 0.8919 (5) 0.038 (2)
H13A 0.410927 0.795016 0.850730 0.046*
H13B 0.458344 0.846861 0.890252 0.046*
C14 0.3384 (6) 0.8648 (5) 0.8760 (5) 0.051 (3)
H14A 0.336306 0.894903 0.915620 0.061*
H14B 0.288123 0.842562 0.877032 0.061*
C15 0.3470 (8) 0.8942 (5) 0.7981 (6) 0.064 (3)
H15A 0.398076 0.915413 0.797426 0.077*
H15B 0.349143 0.863630 0.759107 0.077*
C16 0.2803 (10) 0.9363 (7) 0.7774 (7) 0.100 (5)
H16A 0.291160 0.954015 0.728539 0.150*
H16B 0.277250 0.966661 0.815794 0.150*
H16C 0.229804 0.915316 0.774566 0.150*
N2 0.6832 (4) 0.5046 (3) 0.7742 (3) 0.0221 (13)
C33 0.7626 (6) 0.4921 (4) 0.4945 (5) 0.047 (2)
H33A 0.754229 0.467901 0.449855 0.071*
H33B 0.819603 0.495370 0.505510 0.071*
H33C 0.740427 0.530806 0.485304 0.071*
C34 0.7209 (5) 0.4643 (3) 0.5621 (4) 0.0309 (19)
H34A 0.742753 0.424916 0.570622 0.037*
H34B 0.663496 0.460308 0.550340 0.037*
C35 0.7318 (5) 0.5006 (3) 0.6345 (4) 0.0268 (17)
H35A 0.704466 0.538315 0.628327 0.032*
H35B 0.789028 0.508275 0.643450 0.032*
C36 0.6974 (5) 0.4680 (3) 0.7034 (4) 0.0239 (17)
H36A 0.646252 0.450174 0.687752 0.029*
H36B 0.734165 0.436036 0.716974 0.029*
C37 0.7589 (4) 0.5403 (3) 0.7942 (4) 0.0213 (16)
H37A 0.770030 0.566375 0.751399 0.026*
H37B 0.747022 0.565075 0.838006 0.026*
C38 0.8352 (4) 0.5057 (3) 0.8125 (5) 0.0263 (17)
H38A 0.847161 0.479426 0.770146 0.032*
H38B 0.826955 0.481739 0.857861 0.032*
C39 0.9057 (4) 0.5472 (3) 0.8262 (5) 0.0284 (18)
H39A 0.891397 0.575535 0.865544 0.034*
H39B 0.915878 0.569072 0.779401 0.034*
C40 0.9833 (5) 0.5149 (4) 0.8510 (6) 0.048 (3)
H40A 0.991854 0.481656 0.817819 0.072*
H40B 0.978081 0.501294 0.902900 0.072*
H40C 1.028486 0.541474 0.847940 0.072*
C41 0.6636 (5) 0.4627 (3) 0.8388 (4) 0.0230 (16)
H41A 0.618482 0.437935 0.822343 0.028*
H41B 0.709859 0.436891 0.847334 0.028*
C42 0.6425 (5) 0.4905 (4) 0.9136 (4) 0.0292 (18)
H42A 0.595545 0.515887 0.906572 0.035*
H42B 0.687345 0.514661 0.931789 0.035*
C43 0.6241 (6) 0.4430 (4) 0.9725 (5) 0.039 (2)
H43A 0.579160 0.419010 0.953837 0.047*
H43B 0.670924 0.417357 0.978467 0.047*
C44 0.6029 (5) 0.4688 (4) 1.0501 (5) 0.039 (2)
H44A 0.559930 0.497104 1.043818 0.058*
H44B 0.649681 0.487888 1.072131 0.058*
H44C 0.585555 0.437571 1.083519 0.058*
C45 0.6152 (4) 0.5492 (3) 0.7610 (4) 0.0223 (16)
H45A 0.611784 0.574035 0.806229 0.027*
H45B 0.630132 0.574567 0.718549 0.027*
C46 0.5319 (5) 0.5245 (3) 0.7439 (5) 0.0277 (18)
H46A 0.517045 0.496783 0.783862 0.033*
H46B 0.532159 0.503369 0.695485 0.033*
C47 0.4703 (5) 0.5743 (4) 0.7399 (5) 0.0316 (19)
H47A 0.486951 0.602705 0.701449 0.038*
H47B 0.469442 0.594509 0.788951 0.038*
C48 0.3844 (5) 0.5525 (5) 0.7198 (5) 0.045 (2)
H48A 0.383860 0.535314 0.669491 0.067*
H48B 0.347411 0.585322 0.720905 0.067*
H48C 0.368225 0.523377 0.756627 0.067*
N3 0.4116 (4) 0.7446 (3) 0.4623 (4) 0.0241 (14)
C17 0.1965 (5) 0.6551 (4) 0.6286 (5) 0.036 (2)
H17A 0.218974 0.615942 0.631796 0.054*
H17B 0.138810 0.653062 0.634730 0.054*
H17C 0.219771 0.679309 0.668453 0.054*
C18 0.2154 (5) 0.6820 (4) 0.5502 (4) 0.0292 (18)
H18A 0.193202 0.656918 0.509928 0.035*
H18B 0.189960 0.720599 0.545837 0.035*
C19 0.3061 (5) 0.6883 (4) 0.5402 (4) 0.0284 (18)
H19A 0.330888 0.649323 0.540870 0.034*
H19B 0.328795 0.710695 0.582919 0.034*
C20 0.3263 (4) 0.7193 (3) 0.4653 (4) 0.0236 (16)
H20A 0.319208 0.691401 0.423473 0.028*
H20B 0.287875 0.751291 0.457056 0.028*
C21 0.4227 (5) 0.7933 (3) 0.5218 (4) 0.0276 (18)
H21A 0.419888 0.775790 0.572498 0.033*
H21B 0.476497 0.810005 0.516544 0.033*
C22 0.3616 (5) 0.8428 (3) 0.5164 (5) 0.0284 (18)
H22A 0.353338 0.853611 0.463024 0.034*
H22B 0.310193 0.829179 0.536121 0.034*
C23 0.3892 (5) 0.8963 (4) 0.5611 (5) 0.036 (2)
H23A 0.441375 0.909135 0.542340 0.044*
H23B 0.396088 0.885635 0.614708 0.044*
C24 0.3290 (6) 0.9474 (4) 0.5544 (5) 0.042 (2)
H24A 0.322321 0.958355 0.501453 0.064*
H24B 0.349066 0.980690 0.583150 0.064*
H24C 0.277671 0.935292 0.574363 0.064*
C25 0.4746 (4) 0.6973 (3) 0.4827 (4) 0.0242 (17)
H25A 0.466975 0.685154 0.535454 0.029*
H25B 0.528166 0.714743 0.479415 0.029*
C26 0.4714 (5) 0.6418 (3) 0.4310 (4) 0.0286 (18)
H26A 0.418730 0.623077 0.435207 0.034*
H26B 0.478460 0.653364 0.377967 0.034*
C27 0.5369 (5) 0.5981 (4) 0.4541 (5) 0.0319 (19)
H27A 0.589199 0.617467 0.451011 0.038*
H27B 0.536382 0.565490 0.417906 0.038*
C28 0.5265 (5) 0.5735 (4) 0.5357 (5) 0.037 (2)
H28A 0.473036 0.557259 0.540425 0.055*
H28B 0.534032 0.604782 0.572319 0.055*
H28C 0.565968 0.543017 0.545098 0.055*
C29 0.4249 (4) 0.7675 (4) 0.3817 (4) 0.0250 (17)
H29A 0.377782 0.790330 0.365717 0.030*
H29B 0.429300 0.734049 0.347190 0.030*
C30 0.5002 (5) 0.8061 (4) 0.3739 (5) 0.0307 (19)
H30A 0.544048 0.790103 0.405296 0.037*
H30B 0.488769 0.845890 0.391647 0.037*
C31 0.5258 (5) 0.8079 (4) 0.2885 (5) 0.039 (2)
H31A 0.477659 0.810124 0.256031 0.047*
H31B 0.557673 0.843281 0.279765 0.047*
C32 0.5750 (6) 0.7541 (4) 0.2660 (6) 0.047 (3)
H32A 0.617580 0.765945 0.232354 0.071*
H32B 0.540370 0.726077 0.240077 0.071*
H32C 0.598091 0.736122 0.311166 0.071*

1 Source of materials

The [(nBu4N)3][La(NO3)6] compound was synthesized by the following method: 0.3874 g (1.0 mmol) tetrabutylammonium hexafluorophosphate, and 0.1443 g (0.3 mmol) lanthanum trinitrate hexahydrate were added to a water-95% ethanol (v:v = 1:1) solution with stirring at room temperature. The mixture was heated to 65 °C and continued to heat warm and stirred the reaction for 4 h. After cooling to room temperature, the solution was filtered. The filtrate was transferred to a small beaker, the colourless crystals of the title compound were received by slowing volatile filtrate in 30 days.

2 Experimental details

The hydrogen atoms were positioned geometrically (C–H = 0.96–0.97 Å and O–H = 0.85 Å). Their Uiso values were set to 1.2 Ueq (All C(H,H) groups) or 1.5 Ueq (All C(H,H,H) groups).

3 Comment

Many compounds containing tetrabutylammonium counter ions show excellent properties such as luminescent property, electrochemical property, ionic liquid, magnetic property, catalytic property and novel structure [6–11]. A number of rare earth metal complexes have been synthesized and structurally characterized due to the unique electronic structure, strong oxygen affinity and Lewis acidity of rare earth metals [12], and the similar structures of tris(tetra-n-butylammonium) hexakis-(nitrato–O,O′)-cerium(III) and tris(tetra-n-butylammonium) hexanitrato-praseodymium have also been reported [13, 14]. The structural analysis of the [(nBu4N)3][La(NO3)6] complex indicated that the complex is made up of one complex anion constructed by one La(III) and six nitrate ions, and three tetrabutylammonium counter cations. The central La(III) ion is coordinated with 12 oxygen atoms (O2, O3, O5, O6, O7, O9, O10, O12, O13, O15, O16 and O18) from six nitrate ions, forming a distorted icosahedral geometry. The lengths of La–O bonds are 2.610(5)–2.701(5) Å. The two oxygen atoms of the same nitrate have almost identical bond angles with the lanthanum atom. These bond lengths and angles are almost consistent with the reported compounds in Ref. [15]. In the crystal packing, the [La(NO3)6]3− units are surrounded by tetrabutylammonium counter ions.

Corresponding author: Tai Xi-Shi, College of Chemistry and Chemical Engineering, Weifang University, Weifang, Shandong 261061, P.R. China, E-mail:

Funding source: National Natural Science Foundation of China

Award Identifier / Grant number: (No. 21171132)

Funding source: Natural Science Foundation of Shandong

Award Identifier / Grant number: (ZR2014BL003)

Funding source: Project of Shandong Province Higher Educational Science and Technology Program

Award Identifier / Grant number: (J14LC01, 13039/501100015642)

Funding source: Science Foundation of Weifang

Award Identifier / Grant number: (2020ZJ1054)

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: National Natural Science Foundation of China (No. 21171132, https://doi.org/10.13039/501100001809), the Natural Science Foundation of Shandong (ZR2014BL003, https://doi.org/10.13039/501100007129), the Project of Shandong Province Higher Educational Science and Technology Program (J14LC01, https://doi.org/10. 13039/501100015642) and Science Foundation of Weifang (2020ZJ1054).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2024-01-08
Accepted: 2024-02-05
Published Online: 2024-02-20
Published in Print: 2024-04-25

© 2024 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  7. Crystal structure of aqua-octakis(μ3-salicylato)-(1,10-phenanthroline)-(acetonitrile)-dicobalt(II)-trititanium(IV), C70H45N3O25Co2Ti3
  8. Crystal structure of catena-poly[aqua-(μ2-4,4′-diimidazole diphenyl ether-κ2N:N′)-(sulfato-κ1O)-cobalt(II)] – dimethylformamide (2/1), C39H37CoN9O8S
  9. Crystal structure of (5R,8R,9R,10R,12R, 13R,14R,17S)-2-(E-3-fluorobenzylidene)-12-hydroxy-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl) hexadecahydro-3H-cyclopenta[a]phenanthren-3-one, C37H53FO3
  10. Crystal structure of (Z)-4-((4,5,6-trimethoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)phenyl diphenylphosphinate, C30H25O7P
  11. Crystal structure of 3-((5-methylpyridin-2-yl)amino)-1-phenylpropan-1-one, C15H16N2O
  12. The crystal structure of (R)-9-(5-methoxy-2-methyl-2,3-dihydro-1H-cyclopenta[a]naphthalen-1-ylidene)-9H-thioxanthene, C28H22OS
  13. Crystal structure of diaqua-bis[1-(1-(hydroxymethyl)-1H-pyrazol-3-yl)-5-methyl-1H-1,2,3-triazole-4-carboxylato-κ2N,O)] manganese(II), C16H20MnN10O8
  14. The crystal structure of t-butyl 7-[4-(4-fluorophenyl)-2-[(methanesulfonyl)(methyl)amino]-6-(propan-2-yl)pyrimidin-5-yl]-3,5-dihydroxyhept-6-enoate, C26H36FN3O6S
  15. The crystal structure of samarium sulfate pentahydrate, Sm2(SO4)3(H2O)5
  16. The crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylate-κ 4 N,O,O,O)-zinc(II)] monohydrate, C12H15NO9Zn
  17. The crystal structure of 2,3-difluoro-11H-benzo-[4,5]imidazo[2,1-a]isoindol-11-one, C14H6F2N2O
  18. The crystal structure of 2,3-di(9H-carbazol-9-yl)-9H-fluoren-9-one, C37H22N2O
  19. The crystal structure of 5-(2-chloro-3-(3,6-di-tert-butyl-9H-carbazol-9-yl)phenyl)-10,11-dihydro-5H-dibenzo[b,f]azepine, C40H39ClN2
  20. Crystal structure of 2-bromo-1-hydroxy-3-(3-methylbut-2-enyloxy)-9H-xanthen-9-one, C18H15BrO4
  21. Crystal structure of bis(μ2-benzenesulfonato-κ2O:O′)-bis(μ2-6,6′-((ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene))-bis(2-methoxyphenolato-κ6O,O′:O′,N,N′,O′′:O′′,O′′′))disodium(I)dicopper(II)
  22. The crystal structure of (E)-1,2-bis(benzo[e][1,2]azaborinin-2(1H)-yl)ethene, C18H16B2N2
  23. Crystal structure of 3-oxo-urs-12-en-28-benzyl ester, C37H52O3
  24. The crystal structure of ethyl (E)-1-chloro-3-(4-chloro-1-methyl-1H-indole-2-carbonyl)-4-oxo-2-phenylcyclooct-2-ene-1-carboxylate, C27H25Cl2NO4
  25. The crystal structure of 4,4′-((5-bromo-2-iodo-1,3-phenylene)bis(oxy))bis(tert-butylbenzene) ─ ethanol (2/1), C26H28BrIO2
  26. Crystal structure of (E)-1-(4-(benzyloxy)-2-hydroxyphenyl)-3-(dimethylamino)prop-2-en-1-one, C18H19NO3
  27. The crystal structure of N1,N3-bis(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)\ propanediamide hydrate, C25H26N6O4, 2(H2O)
  28. The crystal structure of 2,5-bis[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)amino]cyclohexa-2,5-diene-1,4-dione, C28H26N6O4
  29. Crystal structure of 3,4-bis[2-(hydroxymethyl)-pyrrolidin-1-yl] cyclobut-3-ene-1,2-dione hydrate, C14H22N2O5
  30. The crystal structure of 2-(3,4–dichlorobenzyl)-1H-benzimidazole, C14H10Cl2N2
  31. The crystal structure of 2-(2-((4,6-dimethoxypyrimidin-2-yl)oxy)phenyl)-4-(piperidin-1-yl)-5H-chromeno[2,3-d]pyrimidine, C28H27N5O4
  32. The crystal structure of 6-(benzofuran-2-yl)-2-oxo-4,5-diphenyl-3,4-dihydro-2H-pyran-3-carbonitrile, C26H17NO3
  33. Crystal structure of N-(4-bromobenzyl)-3-(difluoromethyl)-1-methyl-N-(pyridin-2-yl)-1H-pyrazole-4-carboxamide, C18H15BrF2N4O
  34. The crystal structure of the host-guest complex: N′-{5-[2-(2,6-dimethylphenoxy)acetamido]-4-hydroxy-1,6-diphenylhexan-2-yl}-3-methyl-2-(2-oxo-1,3-diazinan-1-yl)butanamide-diethyl ether (2/1)
  35. The crystal structure of (Z)-4-amino-N′-(1-(4-hydroxyphenyl)propylidene)benzohydrazide, C16H17N3O2
  36. The crystal structure of diethyl 1,4-dihydro-2,6-dimethyl-4-(3-cyanophenyl)-3,5-pyridinedicarboxylate, C20H22N2O4
  37. Crystal structure of 3-(5-((4-(difluoromethoxy)phenyl) sulfonyl)-3,4,5,6-tetrahydropyrrolo[3,4-c]pyrrol-2(1H)-yl) oxetane-3-carboxamide, C17H19F2N3O5S
  38. Crystal structure of 2-((2,6-dichloro-4-(3,5-dimethylisoxazol-4-yl)phenyl)amino)-N-(2-(4-methylpiperazin-1-yl)ethyl)benzamide hydrate, C25H37Cl2N5O6
  39. Crystal structure of 3-(benzo[d]thiazol-2-yl)-5-bromo-2-hydroxybenzaldehyde, C14H8BrNO2S
  40. Crystal structure of 3-(difluoromethyl)-1-methyl-N-(pyridin-2-yl)-1H-pyrazole-4-carboxamide, C11H10F2N4O
  41. Crystal structure of 3-(2-ethoxy-2-oxoethyl)-1-isopropyl-1H-imidazol-3-ium hexafluoridophosphate(V), C20H34F12N4P2
  42. Crystal structure of ethyl 5,6-dichloro-2-methyl-2,3-dihydro-1 H-benzo[d]imidazole-2-carboxylate, C11H12Cl2N2O2
  43. The crystal of structure of (OC-6-22)-pentakis(acetonitrile)bromidoruthenium(II)bromide monohydrate, C10H15Br2N5Ru
  44. Crystal structure of (2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-2-(((4aS,5R,6S)-1-oxo-5-vinyl-4,4a,5,6-tetrahydro-1H,3H-pyrano[3,4-c]pyran-6-yl)oxy)tetrahydro-2H-pyran-3-yl 2,3-dihydroxybenzoate hydrate, C23H26O12·H2O
  45. The crystal structure of (E)-4-amino-N′-(1-(4-fluorophenyl)propylidene)benzohydrazide, C16H16FN3O
  46. The crystal structure of 2′-(9H-carbazol-9-yl)-[1,1′-binaphthalen]-2-amine, C32H22N2
  47. Crystal structure of poly[μ3-diiodido-[μ2-di(1H-pyrazol-1-yl)methane-κ2N,N′)]dicopper(I)], C7H8Cu2I2N4
  48. Crystal structure of 3-amino-N′-hydroxy-1H-pyrazole-4-carboximidamide, C4H7N5O
  49. The crystal structure of 1,3-diacetyltetrahydroimidazo[4,5-d]imidazole-2,5(1H,3H)-dione, C8H10O4N4
  50. Crystal structure of catena-poly[aqua-(μ2-1,4-diazabicyclo[2.2.2]octane-k2N: N′)-bis(sorbato-κ1O)-copper(II), C18H28CuN2O5
  51. Crystal structure of catena-poly[triaqua-(μ2 -1-(4-carboxylatophenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ3O,O′:O′′)manganese(II)], C12H12N2O8Mn
  52. The crystal structure of [hexaaquamagnesium(II)] 4-[(pyridine-4-carbonyl)-amino]-phthalate trihydrate, C14H26N2O14Mg
  53. Crystal structure of 1-(p-tolylphenyl)-4-(2-furoyl)-3-methyl-1H-pyrazol-5-ol, C16H14N2O3
  54. The crystal structure of bis(1,4,7,10,13-pentaoxacyclopentadecane)-potassium(I) dichloridocopper(I), C20H40Cl2CuKO10
  55. The crystal structure of tris(tetra-n-butylammonium) hexanitrato-κ2O,O′-lanthanium(III) C48H108N9O18La
https://doi.org/10.1515/ncrs-2024-0006
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Solvothermal synthesis and crystal structure of aqua-tris(p-acetamidobenzoate-κ2O,O′)-(2,2′-bipyridine-κ2N,N′)terbium(III) - water - methanol (1/1/1)
  4. Crystal structure of hexaaquazinc(II) catena-poly[bis(1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ2O,O′)-bis(μ2-1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ2O:O′)trizinc(II)] hexahydrate C26H36N4O20Zn2
  5. The crystal structure of valinyl-N-ium-4-(5-(thiophen-2-yl)isoxazol-3-yl)phenyl trifluoroacetate
  6. Crystal structure of bis(3,5-diisopropyl-1H-pyrazol-4-ammonium) tetrafluoroterephthalate, 2[C9H18N3][C8F4O4]
  7. Crystal structure of aqua-octakis(μ3-salicylato)-(1,10-phenanthroline)-(acetonitrile)-dicobalt(II)-trititanium(IV), C70H45N3O25Co2Ti3
  8. Crystal structure of catena-poly[aqua-(μ2-4,4′-diimidazole diphenyl ether-κ2N:N′)-(sulfato-κ1O)-cobalt(II)] – dimethylformamide (2/1), C39H37CoN9O8S
  9. Crystal structure of (5R,8R,9R,10R,12R, 13R,14R,17S)-2-(E-3-fluorobenzylidene)-12-hydroxy-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl) hexadecahydro-3H-cyclopenta[a]phenanthren-3-one, C37H53FO3
  10. Crystal structure of (Z)-4-((4,5,6-trimethoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)phenyl diphenylphosphinate, C30H25O7P
  11. Crystal structure of 3-((5-methylpyridin-2-yl)amino)-1-phenylpropan-1-one, C15H16N2O
  12. The crystal structure of (R)-9-(5-methoxy-2-methyl-2,3-dihydro-1H-cyclopenta[a]naphthalen-1-ylidene)-9H-thioxanthene, C28H22OS
  13. Crystal structure of diaqua-bis[1-(1-(hydroxymethyl)-1H-pyrazol-3-yl)-5-methyl-1H-1,2,3-triazole-4-carboxylato-κ2N,O)] manganese(II), C16H20MnN10O8
  14. The crystal structure of t-butyl 7-[4-(4-fluorophenyl)-2-[(methanesulfonyl)(methyl)amino]-6-(propan-2-yl)pyrimidin-5-yl]-3,5-dihydroxyhept-6-enoate, C26H36FN3O6S
  15. The crystal structure of samarium sulfate pentahydrate, Sm2(SO4)3(H2O)5
  16. The crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylate-κ 4 N,O,O,O)-zinc(II)] monohydrate, C12H15NO9Zn
  17. The crystal structure of 2,3-difluoro-11H-benzo-[4,5]imidazo[2,1-a]isoindol-11-one, C14H6F2N2O
  18. The crystal structure of 2,3-di(9H-carbazol-9-yl)-9H-fluoren-9-one, C37H22N2O
  19. The crystal structure of 5-(2-chloro-3-(3,6-di-tert-butyl-9H-carbazol-9-yl)phenyl)-10,11-dihydro-5H-dibenzo[b,f]azepine, C40H39ClN2
  20. Crystal structure of 2-bromo-1-hydroxy-3-(3-methylbut-2-enyloxy)-9H-xanthen-9-one, C18H15BrO4
  21. Crystal structure of bis(μ2-benzenesulfonato-κ2O:O′)-bis(μ2-6,6′-((ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene))-bis(2-methoxyphenolato-κ6O,O′:O′,N,N′,O′′:O′′,O′′′))disodium(I)dicopper(II)
  22. The crystal structure of (E)-1,2-bis(benzo[e][1,2]azaborinin-2(1H)-yl)ethene, C18H16B2N2
  23. Crystal structure of 3-oxo-urs-12-en-28-benzyl ester, C37H52O3
  24. The crystal structure of ethyl (E)-1-chloro-3-(4-chloro-1-methyl-1H-indole-2-carbonyl)-4-oxo-2-phenylcyclooct-2-ene-1-carboxylate, C27H25Cl2NO4
  25. The crystal structure of 4,4′-((5-bromo-2-iodo-1,3-phenylene)bis(oxy))bis(tert-butylbenzene) ─ ethanol (2/1), C26H28BrIO2
  26. Crystal structure of (E)-1-(4-(benzyloxy)-2-hydroxyphenyl)-3-(dimethylamino)prop-2-en-1-one, C18H19NO3
  27. The crystal structure of N1,N3-bis(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)\ propanediamide hydrate, C25H26N6O4, 2(H2O)
  28. The crystal structure of 2,5-bis[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)amino]cyclohexa-2,5-diene-1,4-dione, C28H26N6O4
  29. Crystal structure of 3,4-bis[2-(hydroxymethyl)-pyrrolidin-1-yl] cyclobut-3-ene-1,2-dione hydrate, C14H22N2O5
  30. The crystal structure of 2-(3,4–dichlorobenzyl)-1H-benzimidazole, C14H10Cl2N2
  31. The crystal structure of 2-(2-((4,6-dimethoxypyrimidin-2-yl)oxy)phenyl)-4-(piperidin-1-yl)-5H-chromeno[2,3-d]pyrimidine, C28H27N5O4
  32. The crystal structure of 6-(benzofuran-2-yl)-2-oxo-4,5-diphenyl-3,4-dihydro-2H-pyran-3-carbonitrile, C26H17NO3
  33. Crystal structure of N-(4-bromobenzyl)-3-(difluoromethyl)-1-methyl-N-(pyridin-2-yl)-1H-pyrazole-4-carboxamide, C18H15BrF2N4O
  34. The crystal structure of the host-guest complex: N′-{5-[2-(2,6-dimethylphenoxy)acetamido]-4-hydroxy-1,6-diphenylhexan-2-yl}-3-methyl-2-(2-oxo-1,3-diazinan-1-yl)butanamide-diethyl ether (2/1)
  35. The crystal structure of (Z)-4-amino-N′-(1-(4-hydroxyphenyl)propylidene)benzohydrazide, C16H17N3O2
  36. The crystal structure of diethyl 1,4-dihydro-2,6-dimethyl-4-(3-cyanophenyl)-3,5-pyridinedicarboxylate, C20H22N2O4
  37. Crystal structure of 3-(5-((4-(difluoromethoxy)phenyl) sulfonyl)-3,4,5,6-tetrahydropyrrolo[3,4-c]pyrrol-2(1H)-yl) oxetane-3-carboxamide, C17H19F2N3O5S
  38. Crystal structure of 2-((2,6-dichloro-4-(3,5-dimethylisoxazol-4-yl)phenyl)amino)-N-(2-(4-methylpiperazin-1-yl)ethyl)benzamide hydrate, C25H37Cl2N5O6
  39. Crystal structure of 3-(benzo[d]thiazol-2-yl)-5-bromo-2-hydroxybenzaldehyde, C14H8BrNO2S
  40. Crystal structure of 3-(difluoromethyl)-1-methyl-N-(pyridin-2-yl)-1H-pyrazole-4-carboxamide, C11H10F2N4O
  41. Crystal structure of 3-(2-ethoxy-2-oxoethyl)-1-isopropyl-1H-imidazol-3-ium hexafluoridophosphate(V), C20H34F12N4P2
  42. Crystal structure of ethyl 5,6-dichloro-2-methyl-2,3-dihydro-1 H-benzo[d]imidazole-2-carboxylate, C11H12Cl2N2O2
  43. The crystal of structure of (OC-6-22)-pentakis(acetonitrile)bromidoruthenium(II)bromide monohydrate, C10H15Br2N5Ru
  44. Crystal structure of (2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-2-(((4aS,5R,6S)-1-oxo-5-vinyl-4,4a,5,6-tetrahydro-1H,3H-pyrano[3,4-c]pyran-6-yl)oxy)tetrahydro-2H-pyran-3-yl 2,3-dihydroxybenzoate hydrate, C23H26O12·H2O
  45. The crystal structure of (E)-4-amino-N′-(1-(4-fluorophenyl)propylidene)benzohydrazide, C16H16FN3O
  46. The crystal structure of 2′-(9H-carbazol-9-yl)-[1,1′-binaphthalen]-2-amine, C32H22N2
  47. Crystal structure of poly[μ3-diiodido-[μ2-di(1H-pyrazol-1-yl)methane-κ2N,N′)]dicopper(I)], C7H8Cu2I2N4
  48. Crystal structure of 3-amino-N′-hydroxy-1H-pyrazole-4-carboximidamide, C4H7N5O
  49. The crystal structure of 1,3-diacetyltetrahydroimidazo[4,5-d]imidazole-2,5(1H,3H)-dione, C8H10O4N4
  50. Crystal structure of catena-poly[aqua-(μ2-1,4-diazabicyclo[2.2.2]octane-k2N: N′)-bis(sorbato-κ1O)-copper(II), C18H28CuN2O5
  51. Crystal structure of catena-poly[triaqua-(μ2 -1-(4-carboxylatophenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ3O,O′:O′′)manganese(II)], C12H12N2O8Mn
  52. The crystal structure of [hexaaquamagnesium(II)] 4-[(pyridine-4-carbonyl)-amino]-phthalate trihydrate, C14H26N2O14Mg
  53. Crystal structure of 1-(p-tolylphenyl)-4-(2-furoyl)-3-methyl-1H-pyrazol-5-ol, C16H14N2O3
  54. The crystal structure of bis(1,4,7,10,13-pentaoxacyclopentadecane)-potassium(I) dichloridocopper(I), C20H40Cl2CuKO10
  55. The crystal structure of tris(tetra-n-butylammonium) hexanitrato-κ2O,O′-lanthanium(III) C48H108N9O18La
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