Startseite Crystal structure of hexaaquazinc(II) catena-poly[bis(1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ2O,O′)-bis(μ2-1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ2O:O′)trizinc(II)] hexahydrate C26H36N4O20Zn2
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Crystal structure of hexaaquazinc(II) catena-poly[bis(1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ2O,O′)-bis(μ2-1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ2O:O′)trizinc(II)] hexahydrate C26H36N4O20Zn2

  • Hui-Bin Pan , Jia-Hao Gao , Pei-Pei Huang , Jia-Xin Wang , Ting-Ting Wu und Jiu-Fu Lu ORCID logo EMAIL logo
Veröffentlicht/Copyright: 20. Februar 2024
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 239 Heft 2

Abstract

C26H36N4O20Zn2, triclinic, P 1 ‾ (no. 2), a = 6.9872(4) Å, b = 8.9052(5) Å, c = 8.9052(5) Å, α = 94.441(4)°, β =  93.552 ( 4 ) ° , γ =  90.045 ( 5 ) ° , V = 1651.61(16) Å3, Z = 2, R g t (F) = 0.0748, w R r e f (F2) = 0.2021, T = 293 K.

CCDC no.: 2292757

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colourless block
Size: 0.14 × 0.12 × 0.11 mm
Wavelength: Cu Kα radiation (1.54184 Å)
μ: 2.63 mm−1
Diffractometer, scan mode: Xcalibur, ω
θmax, completeness: 71.1°, 99 %
N(hkl)measured, N(hkl)unique, Rint: 10,909, 6228, 0.050
Criterion for Iobs, N(hkl)gt: Iobs > 2σ(Iobs), 4370
N(param)refined: 495
Programs: Bruker [1], Olex2 [2], SHELX [3, 4]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z Uiso*/Ueq
C1 1.0119 (8) 0.2031 (7) 0.6119 (2) 0.0263 (12)
C2 1.0320 (8) 0.2934 (7) 0.5660 (2) 0.0280 (13)
C3 0.9556 (16) −0.1848 (9) 0.6609 (3) 0.065 (3)
H3A 0.854564 −0.221880 0.637086 0.098*
H3B 0.924189 −0.204988 0.694259 0.098*
H3C 1.073325 −0.234286 0.653093 0.098*
C4 0.9783 (10) −0.0195 (7) 0.6581 (2) 0.0358 (15)
C5 0.9899 (8) 0.0410 (7) 0.6106 (2) 0.0263 (12)
C6 0.9878 (10) 0.0766 (8) 0.7003 (2) 0.0374 (15)
H6 0.981352 0.038462 0.731628 0.045*
C7 1.0074 (9) 0.3336 (7) 0.7411 (2) 0.0312 (13)
C8 1.0548 (10) 0.2895 (8) 0.7887 (2) 0.0383 (15)
H8 1.092386 0.190805 0.792758 0.046*
C9 1.0467 (10) 0.3907 (8) 0.8301 (2) 0.0356 (14)
H9 1.077748 0.360372 0.862148 0.043*
C10 0.9919 (9) 0.5390 (8) 0.8238 (2) 0.0327 (14)
C11 0.9552 (10) 0.5846 (8) 0.7761 (2) 0.0371 (15)
H11 0.925560 0.684727 0.771694 0.045*
C12 0.9622 (10) 0.4823 (8) 0.7347 (2) 0.0387 (15)
H12 0.936503 0.513270 0.702433 0.046*
C13 0.9805 (9) 0.6498 (8) 0.8689 (2) 0.0356 (15)
C14 0.5169 (8) 0.2577 (7) 0.5882 (2) 0.0279 (13)
C15 0.5050 (8) 0.3189 (7) 0.6428 (2) 0.0266 (12)
C16 0.5090 (10) 0.2245 (7) 0.6812 (2) 0.0354 (15)
H16 0.518242 0.121115 0.673580 0.043*
C17 0.4995 (10) 0.2798 (8) 0.7309 (2) 0.0376 (15)
H17 0.498654 0.214045 0.756298 0.045*
C18 0.4912 (8) 0.4323 (7) 0.7424 (2) 0.0277 (12)
C19 0.4872 (12) 0.5292 (8) 0.7044 (2) 0.0453 (18)
H19 0.481737 0.632686 0.712118 0.054*
C20 0.4913 (11) 0.4719 (7) 0.6550 (2) 0.0399 (16)
H20 0.484826 0.537441 0.629420 0.048*
C21 0.4473 (8) 0.6357 (7) 0.8090 (2) 0.0283 (12)
H21 0.408268 0.699938 0.784530 0.034*
C22 0.4587 (8) 0.6882 (7) 0.8584 (2) 0.0287 (13)
C23 0.5134 (8) 0.5885 (7) 0.8958 (2) 0.0284 (13)
C24 0.5610 (8) 0.4383 (7) 0.8765 (2) 0.0284 (13)
C25 0.6399 (9) 0.3162 (7) 0.9089 (2) 0.0329 (14)
C26 0.4113 (11) 0.8501 (7) 0.8737 (2) 0.0400 (16)
H26A 0.318502 0.853308 0.898822 0.060*
H26B 0.359499 0.897682 0.844754 0.060*
H26C 0.525602 0.902359 0.887149 0.060*
N1 1.0193 (7) 0.2905 (6) 0.65411 (18) 0.0288 (11)
N2 1.0068 (7) 0.2283 (6) 0.69750 (18) 0.0295 (11)
N3 0.4922 (7) 0.4902 (6) 0.79509 (17) 0.0288 (11)
N4 0.5520 (7) 0.3931 (6) 0.82839 (18) 0.0287 (11)
O1 1.0239 (6) 0.4328 (5) 0.57219 (16) 0.0341 (10)
O2 1.0645 (7) 0.2200 (5) 0.52502 (15) 0.0369 (11)
O3 0.9739 (7) −0.0475 (5) 0.57148 (15) 0.0345 (10)
O4 0.7075 (6) 0.0690 (5) 0.49053 (16) 0.0354 (10)
H4A 0.662279 0.086290 0.519261 0.053*
H4B 0.640249 −0.003892 0.476482 0.053*
O5 0.5215 (7) 0.1186 (5) 0.57924 (15) 0.0367 (10)
O6 0.5224 (7) 0.3501 (5) 0.55586 (15) 0.0393 (11)
O7 0.7252 (6) 0.6207 (5) 0.53825 (16) 0.0336 (10)
H7A 0.793104 0.659563 0.517213 0.050*
H7B 0.800542 0.560534 0.552854 0.050*
O8 0.3021 (6) 0.6287 (5) 0.54402 (16) 0.0355 (10)
H8A 0.207575 0.573179 0.549529 0.053*
H8B 0.252466 0.697177 0.526837 0.053*
O9 0.4554 (14) 0.8567 (7) 0.6310 (2) 0.087 (2)
H9A 0.469899 0.939677 0.617878 0.130*
H9B 0.413120 0.796137 0.606577 0.130*
O10 0.4045 (12) 0.9032 (8) 0.7377 (2) 0.081 (2)
H10A 0.390658 0.860792 0.708047 0.122*
H10B 0.524996 0.913817 0.743248 0.122*
O11 0.7490 (10) 0.9971 (7) 0.79863 (19) 0.0600 (15)
H11A 0.829903 0.940588 0.812976 0.090*
H11B 0.716410 1.060142 0.822116 0.090*
O12 0.9234 (8) 0.7816 (6) 0.86119 (18) 0.0518 (13)
O13 1.0262 (8) 0.6066 (6) 0.91103 (17) 0.0520 (14)
O14 0.7128 (8) 0.2063 (6) 0.88784 (17) 0.0527 (14)
O15 1.0668 (10) 0.7790 (7) 0.99203 (19) 0.0658 (19)
H15A 1.064927 0.739957 0.961889 0.099*
H15B 1.176150 0.756227 1.004939 0.099*
O16 0.6670 (10) 0.9161 (7) 0.9999 (3) 0.082 (2)
H16A 0.653036 0.860892 1.024848 0.124*
H16B 0.639296 0.854753 0.973478 0.124*
O17 1.0331 (10) 0.9869 (7) 1.0734 (2) 0.073 (2)
H17A 1.080131 1.069431 1.087382 0.109*
H17B 1.117883 0.921191 1.080032 0.109*
O18 0.7718 (8) 0.5877 (6) 1.0344 (2) 0.0568 (14)
H18A 0.829785 0.519230 1.049752 0.085*
H18B 0.845304 0.607262 1.011453 0.085*
O19 0.3679 (7) 0.6620 (5) 1.04379 (15) 0.0440 (12)
O20 0.5212 (7) 0.6344 (5) 0.94260 (16) 0.0394 (11)
Zn1 1.000000 0.000000 0.500000 0.0263 (3)
Zn2 0.500000 0.500000 0.500000 0.0270 (3)
Zn3 0.500000 0.500000 1.000000 0.0387 (3)
Zn4 1.000000 1.000000 1.000000 0.0823 (7)

1 Source of material

The mixture of zinc nitrate hexahydrate 29.7 mg (0.1 mmol), 1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylic acid 27.4 mg (0.1 mmol), NaOH 8 mg (0.2 mmol) and ethyl alcohol (10 mL) were placed in the autoclave lined with PTFE and heated at 110 °C for 48 h, then cooled to room temperature over 24 h. Colourless block crystals were collected after cooling to room temperature.

2 Experimental details

Using Olex2 [2], the structure was solved with the ShelXT [3] structure solution program and refined with the ShelXL [4] refinement package.

3 Comment

In recent years, metal coordination polymers have provoked great interest for their promising applications [5–7]. However, the diversity in the framework architectures of such coordination polymers counts on many factors, such as the metal atom species, the coordination geometry of metal centers, the coordination ability of organic ligands and the reaction conditions (pH, temperature, solvent and so on) [8], [9], [10], [11], So that the selection of organic ligands and metal ions is the key to constructing fluorescent coordination polymers. The coordination polymers constructed by rigid N-donor and carboxyl groups mixed ligands were a widely effective adopted strategy in this field. For example, the incorporation of functional groups including pyridyl, imidazole and carboxyl group into the internal of coordination polymers could enhance the fluorescence sensing capability through various host–guest interactions, for synthesis of coordination polymers with appropriate luminous performance and are vital [12].

As shown in Figure, each Zn(II) ion exhibits a different coordination geometry, where Zn1 is six-coordinated with two oxygen atoms from two coordinated water molecules and four oxygen atoms from two organic ligands. Meanwhile, Zn2 is six-coordinated with four oxygen atoms from four coordinated water molecules, two carbonyl oxygen atoms and two carboxyl oxygen atoms from two organic ligands. Zn4 is six-coordinated with six oxygen atoms from six organic ligands as a bidentate ligand bridging adjacent above-mentioned two crystallographically independent Zn(II) ions to form a 1D zigzag chain. The chains and hydrated zinc ions are linked by intermolecular hydrogen bonding to form a 3D supermolecular structure. All bonding parameters are in the expected ranges [13].

Corresponding author: Jiu-Fu Lu, Shaanxi Key Laboratory of Catalysis, College of Chemical & Environment Science, Shaanxi University of Technology, Hanzhong, 723001, P.R. China, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The Innovation Team of Shaanxi Universities (No. 2022-94), Research project of Shaanxi University of Science and Technology (SLGKYXM2304) and Shaanxi provincial science and technology Department surface project (2024JC-YBMS-139).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2023-09-05
Accepted: 2024-02-05
Published Online: 2024-02-20
Published in Print: 2024-04-25

© 2023 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
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  4. Crystal structure of hexaaquazinc(II) catena-poly[bis(1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ2O,O′)-bis(μ2-1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ2O:O′)trizinc(II)] hexahydrate C26H36N4O20Zn2
  5. The crystal structure of valinyl-N-ium-4-(5-(thiophen-2-yl)isoxazol-3-yl)phenyl trifluoroacetate
  6. Crystal structure of bis(3,5-diisopropyl-1H-pyrazol-4-ammonium) tetrafluoroterephthalate, 2[C9H18N3][C8F4O4]
  7. Crystal structure of aqua-octakis(μ3-salicylato)-(1,10-phenanthroline)-(acetonitrile)-dicobalt(II)-trititanium(IV), C70H45N3O25Co2Ti3
  8. Crystal structure of catena-poly[aqua-(μ2-4,4′-diimidazole diphenyl ether-κ2N:N′)-(sulfato-κ1O)-cobalt(II)] – dimethylformamide (2/1), C39H37CoN9O8S
  9. Crystal structure of (5R,8R,9R,10R,12R, 13R,14R,17S)-2-(E-3-fluorobenzylidene)-12-hydroxy-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl) hexadecahydro-3H-cyclopenta[a]phenanthren-3-one, C37H53FO3
  10. Crystal structure of (Z)-4-((4,5,6-trimethoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)phenyl diphenylphosphinate, C30H25O7P
  11. Crystal structure of 3-((5-methylpyridin-2-yl)amino)-1-phenylpropan-1-one, C15H16N2O
  12. The crystal structure of (R)-9-(5-methoxy-2-methyl-2,3-dihydro-1H-cyclopenta[a]naphthalen-1-ylidene)-9H-thioxanthene, C28H22OS
  13. Crystal structure of diaqua-bis[1-(1-(hydroxymethyl)-1H-pyrazol-3-yl)-5-methyl-1H-1,2,3-triazole-4-carboxylato-κ2N,O)] manganese(II), C16H20MnN10O8
  14. The crystal structure of t-butyl 7-[4-(4-fluorophenyl)-2-[(methanesulfonyl)(methyl)amino]-6-(propan-2-yl)pyrimidin-5-yl]-3,5-dihydroxyhept-6-enoate, C26H36FN3O6S
  15. The crystal structure of samarium sulfate pentahydrate, Sm2(SO4)3(H2O)5
  16. The crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylate-κ 4 N,O,O,O)-zinc(II)] monohydrate, C12H15NO9Zn
  17. The crystal structure of 2,3-difluoro-11H-benzo-[4,5]imidazo[2,1-a]isoindol-11-one, C14H6F2N2O
  18. The crystal structure of 2,3-di(9H-carbazol-9-yl)-9H-fluoren-9-one, C37H22N2O
  19. The crystal structure of 5-(2-chloro-3-(3,6-di-tert-butyl-9H-carbazol-9-yl)phenyl)-10,11-dihydro-5H-dibenzo[b,f]azepine, C40H39ClN2
  20. Crystal structure of 2-bromo-1-hydroxy-3-(3-methylbut-2-enyloxy)-9H-xanthen-9-one, C18H15BrO4
  21. Crystal structure of bis(μ2-benzenesulfonato-κ2O:O′)-bis(μ2-6,6′-((ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene))-bis(2-methoxyphenolato-κ6O,O′:O′,N,N′,O′′:O′′,O′′′))disodium(I)dicopper(II)
  22. The crystal structure of (E)-1,2-bis(benzo[e][1,2]azaborinin-2(1H)-yl)ethene, C18H16B2N2
  23. Crystal structure of 3-oxo-urs-12-en-28-benzyl ester, C37H52O3
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  25. The crystal structure of 4,4′-((5-bromo-2-iodo-1,3-phenylene)bis(oxy))bis(tert-butylbenzene) ─ ethanol (2/1), C26H28BrIO2
  26. Crystal structure of (E)-1-(4-(benzyloxy)-2-hydroxyphenyl)-3-(dimethylamino)prop-2-en-1-one, C18H19NO3
  27. The crystal structure of N1,N3-bis(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)\ propanediamide hydrate, C25H26N6O4, 2(H2O)
  28. The crystal structure of 2,5-bis[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)amino]cyclohexa-2,5-diene-1,4-dione, C28H26N6O4
  29. Crystal structure of 3,4-bis[2-(hydroxymethyl)-pyrrolidin-1-yl] cyclobut-3-ene-1,2-dione hydrate, C14H22N2O5
  30. The crystal structure of 2-(3,4–dichlorobenzyl)-1H-benzimidazole, C14H10Cl2N2
  31. The crystal structure of 2-(2-((4,6-dimethoxypyrimidin-2-yl)oxy)phenyl)-4-(piperidin-1-yl)-5H-chromeno[2,3-d]pyrimidine, C28H27N5O4
  32. The crystal structure of 6-(benzofuran-2-yl)-2-oxo-4,5-diphenyl-3,4-dihydro-2H-pyran-3-carbonitrile, C26H17NO3
  33. Crystal structure of N-(4-bromobenzyl)-3-(difluoromethyl)-1-methyl-N-(pyridin-2-yl)-1H-pyrazole-4-carboxamide, C18H15BrF2N4O
  34. The crystal structure of the host-guest complex: N′-{5-[2-(2,6-dimethylphenoxy)acetamido]-4-hydroxy-1,6-diphenylhexan-2-yl}-3-methyl-2-(2-oxo-1,3-diazinan-1-yl)butanamide-diethyl ether (2/1)
  35. The crystal structure of (Z)-4-amino-N′-(1-(4-hydroxyphenyl)propylidene)benzohydrazide, C16H17N3O2
  36. The crystal structure of diethyl 1,4-dihydro-2,6-dimethyl-4-(3-cyanophenyl)-3,5-pyridinedicarboxylate, C20H22N2O4
  37. Crystal structure of 3-(5-((4-(difluoromethoxy)phenyl) sulfonyl)-3,4,5,6-tetrahydropyrrolo[3,4-c]pyrrol-2(1H)-yl) oxetane-3-carboxamide, C17H19F2N3O5S
  38. Crystal structure of 2-((2,6-dichloro-4-(3,5-dimethylisoxazol-4-yl)phenyl)amino)-N-(2-(4-methylpiperazin-1-yl)ethyl)benzamide hydrate, C25H37Cl2N5O6
  39. Crystal structure of 3-(benzo[d]thiazol-2-yl)-5-bromo-2-hydroxybenzaldehyde, C14H8BrNO2S
  40. Crystal structure of 3-(difluoromethyl)-1-methyl-N-(pyridin-2-yl)-1H-pyrazole-4-carboxamide, C11H10F2N4O
  41. Crystal structure of 3-(2-ethoxy-2-oxoethyl)-1-isopropyl-1H-imidazol-3-ium hexafluoridophosphate(V), C20H34F12N4P2
  42. Crystal structure of ethyl 5,6-dichloro-2-methyl-2,3-dihydro-1 H-benzo[d]imidazole-2-carboxylate, C11H12Cl2N2O2
  43. The crystal of structure of (OC-6-22)-pentakis(acetonitrile)bromidoruthenium(II)bromide monohydrate, C10H15Br2N5Ru
  44. Crystal structure of (2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-2-(((4aS,5R,6S)-1-oxo-5-vinyl-4,4a,5,6-tetrahydro-1H,3H-pyrano[3,4-c]pyran-6-yl)oxy)tetrahydro-2H-pyran-3-yl 2,3-dihydroxybenzoate hydrate, C23H26O12·H2O
  45. The crystal structure of (E)-4-amino-N′-(1-(4-fluorophenyl)propylidene)benzohydrazide, C16H16FN3O
  46. The crystal structure of 2′-(9H-carbazol-9-yl)-[1,1′-binaphthalen]-2-amine, C32H22N2
  47. Crystal structure of poly[μ3-diiodido-[μ2-di(1H-pyrazol-1-yl)methane-κ2N,N′)]dicopper(I)], C7H8Cu2I2N4
  48. Crystal structure of 3-amino-N′-hydroxy-1H-pyrazole-4-carboximidamide, C4H7N5O
  49. The crystal structure of 1,3-diacetyltetrahydroimidazo[4,5-d]imidazole-2,5(1H,3H)-dione, C8H10O4N4
  50. Crystal structure of catena-poly[aqua-(μ2-1,4-diazabicyclo[2.2.2]octane-k2N: N′)-bis(sorbato-κ1O)-copper(II), C18H28CuN2O5
  51. Crystal structure of catena-poly[triaqua-(μ2 -1-(4-carboxylatophenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ3O,O′:O′′)manganese(II)], C12H12N2O8Mn
  52. The crystal structure of [hexaaquamagnesium(II)] 4-[(pyridine-4-carbonyl)-amino]-phthalate trihydrate, C14H26N2O14Mg
  53. Crystal structure of 1-(p-tolylphenyl)-4-(2-furoyl)-3-methyl-1H-pyrazol-5-ol, C16H14N2O3
  54. The crystal structure of bis(1,4,7,10,13-pentaoxacyclopentadecane)-potassium(I) dichloridocopper(I), C20H40Cl2CuKO10
  55. The crystal structure of tris(tetra-n-butylammonium) hexanitrato-κ2O,O′-lanthanium(III) C48H108N9O18La
https://doi.org/10.1515/ncrs-2023-0398
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Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. Solvothermal synthesis and crystal structure of aqua-tris(p-acetamidobenzoate-κ2O,O′)-(2,2′-bipyridine-κ2N,N′)terbium(III) - water - methanol (1/1/1)
  4. Crystal structure of hexaaquazinc(II) catena-poly[bis(1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ2O,O′)-bis(μ2-1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ2O:O′)trizinc(II)] hexahydrate C26H36N4O20Zn2
  5. The crystal structure of valinyl-N-ium-4-(5-(thiophen-2-yl)isoxazol-3-yl)phenyl trifluoroacetate
  6. Crystal structure of bis(3,5-diisopropyl-1H-pyrazol-4-ammonium) tetrafluoroterephthalate, 2[C9H18N3][C8F4O4]
  7. Crystal structure of aqua-octakis(μ3-salicylato)-(1,10-phenanthroline)-(acetonitrile)-dicobalt(II)-trititanium(IV), C70H45N3O25Co2Ti3
  8. Crystal structure of catena-poly[aqua-(μ2-4,4′-diimidazole diphenyl ether-κ2N:N′)-(sulfato-κ1O)-cobalt(II)] – dimethylformamide (2/1), C39H37CoN9O8S
  9. Crystal structure of (5R,8R,9R,10R,12R, 13R,14R,17S)-2-(E-3-fluorobenzylidene)-12-hydroxy-4,4,8,10,14-pentamethyl-17-((R)-2,6,6-trimethyltetrahydro-2H-pyran-2-yl) hexadecahydro-3H-cyclopenta[a]phenanthren-3-one, C37H53FO3
  10. Crystal structure of (Z)-4-((4,5,6-trimethoxy-3-oxobenzofuran-2(3H)-ylidene)methyl)phenyl diphenylphosphinate, C30H25O7P
  11. Crystal structure of 3-((5-methylpyridin-2-yl)amino)-1-phenylpropan-1-one, C15H16N2O
  12. The crystal structure of (R)-9-(5-methoxy-2-methyl-2,3-dihydro-1H-cyclopenta[a]naphthalen-1-ylidene)-9H-thioxanthene, C28H22OS
  13. Crystal structure of diaqua-bis[1-(1-(hydroxymethyl)-1H-pyrazol-3-yl)-5-methyl-1H-1,2,3-triazole-4-carboxylato-κ2N,O)] manganese(II), C16H20MnN10O8
  14. The crystal structure of t-butyl 7-[4-(4-fluorophenyl)-2-[(methanesulfonyl)(methyl)amino]-6-(propan-2-yl)pyrimidin-5-yl]-3,5-dihydroxyhept-6-enoate, C26H36FN3O6S
  15. The crystal structure of samarium sulfate pentahydrate, Sm2(SO4)3(H2O)5
  16. The crystal structure of [triaqua-(8-carboxymethoxy-quinoline-2-carboxylate-κ 4 N,O,O,O)-zinc(II)] monohydrate, C12H15NO9Zn
  17. The crystal structure of 2,3-difluoro-11H-benzo-[4,5]imidazo[2,1-a]isoindol-11-one, C14H6F2N2O
  18. The crystal structure of 2,3-di(9H-carbazol-9-yl)-9H-fluoren-9-one, C37H22N2O
  19. The crystal structure of 5-(2-chloro-3-(3,6-di-tert-butyl-9H-carbazol-9-yl)phenyl)-10,11-dihydro-5H-dibenzo[b,f]azepine, C40H39ClN2
  20. Crystal structure of 2-bromo-1-hydroxy-3-(3-methylbut-2-enyloxy)-9H-xanthen-9-one, C18H15BrO4
  21. Crystal structure of bis(μ2-benzenesulfonato-κ2O:O′)-bis(μ2-6,6′-((ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene))-bis(2-methoxyphenolato-κ6O,O′:O′,N,N′,O′′:O′′,O′′′))disodium(I)dicopper(II)
  22. The crystal structure of (E)-1,2-bis(benzo[e][1,2]azaborinin-2(1H)-yl)ethene, C18H16B2N2
  23. Crystal structure of 3-oxo-urs-12-en-28-benzyl ester, C37H52O3
  24. The crystal structure of ethyl (E)-1-chloro-3-(4-chloro-1-methyl-1H-indole-2-carbonyl)-4-oxo-2-phenylcyclooct-2-ene-1-carboxylate, C27H25Cl2NO4
  25. The crystal structure of 4,4′-((5-bromo-2-iodo-1,3-phenylene)bis(oxy))bis(tert-butylbenzene) ─ ethanol (2/1), C26H28BrIO2
  26. Crystal structure of (E)-1-(4-(benzyloxy)-2-hydroxyphenyl)-3-(dimethylamino)prop-2-en-1-one, C18H19NO3
  27. The crystal structure of N1,N3-bis(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)\ propanediamide hydrate, C25H26N6O4, 2(H2O)
  28. The crystal structure of 2,5-bis[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)amino]cyclohexa-2,5-diene-1,4-dione, C28H26N6O4
  29. Crystal structure of 3,4-bis[2-(hydroxymethyl)-pyrrolidin-1-yl] cyclobut-3-ene-1,2-dione hydrate, C14H22N2O5
  30. The crystal structure of 2-(3,4–dichlorobenzyl)-1H-benzimidazole, C14H10Cl2N2
  31. The crystal structure of 2-(2-((4,6-dimethoxypyrimidin-2-yl)oxy)phenyl)-4-(piperidin-1-yl)-5H-chromeno[2,3-d]pyrimidine, C28H27N5O4
  32. The crystal structure of 6-(benzofuran-2-yl)-2-oxo-4,5-diphenyl-3,4-dihydro-2H-pyran-3-carbonitrile, C26H17NO3
  33. Crystal structure of N-(4-bromobenzyl)-3-(difluoromethyl)-1-methyl-N-(pyridin-2-yl)-1H-pyrazole-4-carboxamide, C18H15BrF2N4O
  34. The crystal structure of the host-guest complex: N′-{5-[2-(2,6-dimethylphenoxy)acetamido]-4-hydroxy-1,6-diphenylhexan-2-yl}-3-methyl-2-(2-oxo-1,3-diazinan-1-yl)butanamide-diethyl ether (2/1)
  35. The crystal structure of (Z)-4-amino-N′-(1-(4-hydroxyphenyl)propylidene)benzohydrazide, C16H17N3O2
  36. The crystal structure of diethyl 1,4-dihydro-2,6-dimethyl-4-(3-cyanophenyl)-3,5-pyridinedicarboxylate, C20H22N2O4
  37. Crystal structure of 3-(5-((4-(difluoromethoxy)phenyl) sulfonyl)-3,4,5,6-tetrahydropyrrolo[3,4-c]pyrrol-2(1H)-yl) oxetane-3-carboxamide, C17H19F2N3O5S
  38. Crystal structure of 2-((2,6-dichloro-4-(3,5-dimethylisoxazol-4-yl)phenyl)amino)-N-(2-(4-methylpiperazin-1-yl)ethyl)benzamide hydrate, C25H37Cl2N5O6
  39. Crystal structure of 3-(benzo[d]thiazol-2-yl)-5-bromo-2-hydroxybenzaldehyde, C14H8BrNO2S
  40. Crystal structure of 3-(difluoromethyl)-1-methyl-N-(pyridin-2-yl)-1H-pyrazole-4-carboxamide, C11H10F2N4O
  41. Crystal structure of 3-(2-ethoxy-2-oxoethyl)-1-isopropyl-1H-imidazol-3-ium hexafluoridophosphate(V), C20H34F12N4P2
  42. Crystal structure of ethyl 5,6-dichloro-2-methyl-2,3-dihydro-1 H-benzo[d]imidazole-2-carboxylate, C11H12Cl2N2O2
  43. The crystal of structure of (OC-6-22)-pentakis(acetonitrile)bromidoruthenium(II)bromide monohydrate, C10H15Br2N5Ru
  44. Crystal structure of (2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-2-(((4aS,5R,6S)-1-oxo-5-vinyl-4,4a,5,6-tetrahydro-1H,3H-pyrano[3,4-c]pyran-6-yl)oxy)tetrahydro-2H-pyran-3-yl 2,3-dihydroxybenzoate hydrate, C23H26O12·H2O
  45. The crystal structure of (E)-4-amino-N′-(1-(4-fluorophenyl)propylidene)benzohydrazide, C16H16FN3O
  46. The crystal structure of 2′-(9H-carbazol-9-yl)-[1,1′-binaphthalen]-2-amine, C32H22N2
  47. Crystal structure of poly[μ3-diiodido-[μ2-di(1H-pyrazol-1-yl)methane-κ2N,N′)]dicopper(I)], C7H8Cu2I2N4
  48. Crystal structure of 3-amino-N′-hydroxy-1H-pyrazole-4-carboximidamide, C4H7N5O
  49. The crystal structure of 1,3-diacetyltetrahydroimidazo[4,5-d]imidazole-2,5(1H,3H)-dione, C8H10O4N4
  50. Crystal structure of catena-poly[aqua-(μ2-1,4-diazabicyclo[2.2.2]octane-k2N: N′)-bis(sorbato-κ1O)-copper(II), C18H28CuN2O5
  51. Crystal structure of catena-poly[triaqua-(μ2 -1-(4-carboxylatophenyl)-4-oxo-1,4-dihydropyridazine-3-carboxylato-κ3O,O′:O′′)manganese(II)], C12H12N2O8Mn
  52. The crystal structure of [hexaaquamagnesium(II)] 4-[(pyridine-4-carbonyl)-amino]-phthalate trihydrate, C14H26N2O14Mg
  53. Crystal structure of 1-(p-tolylphenyl)-4-(2-furoyl)-3-methyl-1H-pyrazol-5-ol, C16H14N2O3
  54. The crystal structure of bis(1,4,7,10,13-pentaoxacyclopentadecane)-potassium(I) dichloridocopper(I), C20H40Cl2CuKO10
  55. The crystal structure of tris(tetra-n-butylammonium) hexanitrato-κ2O,O′-lanthanium(III) C48H108N9O18La
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Heruntergeladen am 7.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2023-0398/html
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