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Mechanochemical synthesis of CaMoO4 nanoparticles: kinetics and characterization

  • Arman Hoseinpur , Malihe Mohammadi Bezanaj and Jalil Vahdati Khaki
Published/Copyright: September 29, 2016
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 107 Issue 10

Abstract

This research introduces the mechanosynthesis process for CaMoO4 nanoparticles by using MoO3 and CaO as initial reactants. An empirical model was developed to describe the kinetics of the reaction. X-ray diffraction was used at each step of the milling to evaluate the developed model. The experimental data and the results from the model are in good agreement. The synthesized powders in this research were characterized using X-ray diffraction, electron microscopy, dynamic laser scattering, and photoluminescence spectroscopy techniques. Photoluminescence characterizations revealed that the synthesized CaMoO4 generated two photoluminescence emissions, at 377 nm (violet) and 515 nm (green). It was also observed that further milling of the synthesized powders changed the photoluminescence properties of the product. After 12 h of milling, the synthesized CaMoO4 generated a novel photoluminescence emission at 564 nm. The results of this research indicate that mechanical milling can be employed to control the photoluminescent properties of CaMoO4.

Keywords: Kinetics; Mechanosynthesis; Photoluminescence; X-ray diffraction (XRD); Nanoparticle
*Correspondence address, Arman Hoseinpur, Energy Storage Department, Sun-Air Research Institute (SARI), Ferdowsi University of Mashhad, Azadi Square, Mashhad, P.O. Box 9177-948974, I.R. Iran, Tel.: +989158279093, Fax: +985118763305, E-mail:

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Received: 2016-01-23
Accepted: 2016-06-02
Published Online: 2016-09-29
Published in Print: 2016-10-14

© 2016, Carl Hanser Verlag, München

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. A metastable phase diagram for the dynamic transformation of austenite at temperatures above the Ae3
  5. Experimental investigation of phase equilibria in the Co–Ni–Zr ternary system
  6. Phase equilibria of the Ni–Sb–Zn system at 600 °C
  7. High frequency cycling behaviour of three AZ magnesium alloys – microstructural characterisation
  8. Influence of auxetic foam in quasi-static axial crushing
  9. Electrochemical behaviour of iron and AISI 304 stainless steel in simulated acid rain solution
  10. Mechanochemical synthesis of CaMoO4 nanoparticles: kinetics and characterization
  11. Synthesis and characterization of iron oxide nanoparticles prepared hydrothermally at different reaction temperatures and pH
  12. Influence of SPS parameters on the density and hardness of zinc selenide
  13. Investigation into the kinetic behavior of molten aluminum pressureless infiltration into SiC preforms
  14. Review
  15. Centrifugal casting technique baseline knowledge, applications, and processing parameters: overview
  16. People
  17. Prof. Dr.-Ing. Jürgen Hirsch on the occasion of his 65th birthday
  18. DGM News
  19. DGM News
https://doi.org/10.3139/146.111416
Keywords for this article
Kinetics; Mechanosynthesis; Photoluminescence; X-ray diffraction (XRD); Nanoparticle

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. A metastable phase diagram for the dynamic transformation of austenite at temperatures above the Ae3
  5. Experimental investigation of phase equilibria in the Co–Ni–Zr ternary system
  6. Phase equilibria of the Ni–Sb–Zn system at 600 °C
  7. High frequency cycling behaviour of three AZ magnesium alloys – microstructural characterisation
  8. Influence of auxetic foam in quasi-static axial crushing
  9. Electrochemical behaviour of iron and AISI 304 stainless steel in simulated acid rain solution
  10. Mechanochemical synthesis of CaMoO4 nanoparticles: kinetics and characterization
  11. Synthesis and characterization of iron oxide nanoparticles prepared hydrothermally at different reaction temperatures and pH
  12. Influence of SPS parameters on the density and hardness of zinc selenide
  13. Investigation into the kinetic behavior of molten aluminum pressureless infiltration into SiC preforms
  14. Review
  15. Centrifugal casting technique baseline knowledge, applications, and processing parameters: overview
  16. People
  17. Prof. Dr.-Ing. Jürgen Hirsch on the occasion of his 65th birthday
  18. DGM News
  19. DGM News
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