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A model to calculate the viscosity of silicate melts

Part V: Borosilicate melts containing alkali metals
  • Eli Brosh , Arthur D. Pelton und Sergei A. Decterov
Veröffentlicht/Copyright: 11. Juni 2013
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 103 Heft 5

Abstract

Our recently developed model for the viscosity of borosilicate melts is extended to describe and predict the viscosities of melts containing alkali oxides. In addition to the two model parameters that are required for each B2O3–MOx melt, where MOx is a basic oxide, three more parameters are needed when MOx is an alkali oxide to account for the formation of clusters near the tetraborate composition. The additional parameters represent the size and Gibbs energy of formation of these clusters and their contribution to the activation energy of the viscous flow. A general algorithm for the calculation of the viscosity is presented which summarizes the application of the viscosity model to melts that can contain two network formers, SiO2 and B2O3, any basic oxide and amphoteric oxides exhibiting the Charge Compensation Effect such as Al2O3. The predictive ability of the model is tested on all ternary subsystems of the B2O3–Na2O–K2O–CaO–MgO–PbO–ZnO–Al2O3–SiO2 system containing both an alkali oxide and B2O3 for which experimental data are available and on several multicomponent glass-forming melts around commercial glass compositions.

Keywords: Viscosity; Thermodynamic modeling; Silicates; Glass Melts; Borosilicate melts
* Correspondence address Dr. Sergei A. Decterov Centre de Recherche en Calcul Thermochimique Genie Chimique, École Polytechnique C.P. 6079, Station Centre-ville, Montréal (QC), Canada, H3C 3A7 Tel.: +15143404711 ext. 5796 Fax: +15143405840 E-mail:

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Received: 2011-5-6
Accepted: 2011-10-18
Published Online: 2013-06-11
Published in Print: 2012-05-01

© 2012, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Phase equilibria in the “SnO”–SiO2–“FeO” system in equilibrium with tin–iron alloy and the potential application for electronic scrap recycling
  5. A model to calculate the viscosity of silicate melts
  6. Surface structure of different interstitial austenitic steels after impact wear
  7. Microstructural study of boron-doped Co–Re–Cr alloys by means of transmission electron microscopy and electron energy-loss spectroscopy
  8. Orientation relationship between 14H-LPSO structured X phase and DO3-type (Mg,Zn)3RE phase in an Mg–Gd–Y–Zn–Zr alloy
  9. Microstructural, optical, and dielectric properties of nanocrystalline TiO2 films prepared via ion-assisted magnetron sputtering
  10. An investigation of the microstructure and properties of the explosively welded Gr5–SS304 clad plates for golf heads
  11. Cyclic fibre texture in hot extruded Ni50Mn29Ga21
  12. Development of high-strength pure magnesium and wrought magnesium alloys AZ31, AZ61, and AZ91 processed by hydrostatic extrusion with back pressure
  13. Effect of cerium and aluminium on the hot-deformation behaviour of magnesium
  14. Effect of alloying elements on stage-III work-hardening behaviour of Al–Zn–Mg(–Cu) alloys
  15. Effect of titanium on the as-cast microstructure and impact toughness of hypereutectic high-chromium cast iron
  16. Microstructure and mechanical properties of nanocrystalline WC-particle-reinforced Ti-based composites with nano/ultrafine-grained intermetallic matrix from spark plasma sintering and crystallization of amorphous phase
  17. Plasticity enhancement in centrally confined Zr-based bulk metallic glass
  18. In-situ observation of the fracture process in Al–Zn–Mg–Cu alloys
  19. Relationship between the mechanical properties and the surface roughness of marble
  20. Light, multi-layer, screening textiles with a high capacity for absorbing electromagnetic fields in the high frequency range
  21. Immobilization of zinc oxide nanoparticles on cotton fabrics using poly 4-styrenesulfonic acid polyelectrolyte
  22. People
  23. Prof. Dr. rer. nat. Ludwig Schultz
  24. DGM News
  25. DGM News
https://doi.org/10.3139/146.110639
Schlagwörter für diesen Artikel
Viscosity; Thermodynamic modeling; Silicates; Glass Melts; Borosilicate melts

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Phase equilibria in the “SnO”–SiO2–“FeO” system in equilibrium with tin–iron alloy and the potential application for electronic scrap recycling
  5. A model to calculate the viscosity of silicate melts
  6. Surface structure of different interstitial austenitic steels after impact wear
  7. Microstructural study of boron-doped Co–Re–Cr alloys by means of transmission electron microscopy and electron energy-loss spectroscopy
  8. Orientation relationship between 14H-LPSO structured X phase and DO3-type (Mg,Zn)3RE phase in an Mg–Gd–Y–Zn–Zr alloy
  9. Microstructural, optical, and dielectric properties of nanocrystalline TiO2 films prepared via ion-assisted magnetron sputtering
  10. An investigation of the microstructure and properties of the explosively welded Gr5–SS304 clad plates for golf heads
  11. Cyclic fibre texture in hot extruded Ni50Mn29Ga21
  12. Development of high-strength pure magnesium and wrought magnesium alloys AZ31, AZ61, and AZ91 processed by hydrostatic extrusion with back pressure
  13. Effect of cerium and aluminium on the hot-deformation behaviour of magnesium
  14. Effect of alloying elements on stage-III work-hardening behaviour of Al–Zn–Mg(–Cu) alloys
  15. Effect of titanium on the as-cast microstructure and impact toughness of hypereutectic high-chromium cast iron
  16. Microstructure and mechanical properties of nanocrystalline WC-particle-reinforced Ti-based composites with nano/ultrafine-grained intermetallic matrix from spark plasma sintering and crystallization of amorphous phase
  17. Plasticity enhancement in centrally confined Zr-based bulk metallic glass
  18. In-situ observation of the fracture process in Al–Zn–Mg–Cu alloys
  19. Relationship between the mechanical properties and the surface roughness of marble
  20. Light, multi-layer, screening textiles with a high capacity for absorbing electromagnetic fields in the high frequency range
  21. Immobilization of zinc oxide nanoparticles on cotton fabrics using poly 4-styrenesulfonic acid polyelectrolyte
  22. People
  23. Prof. Dr. rer. nat. Ludwig Schultz
  24. DGM News
  25. DGM News
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