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Immobilization of zinc oxide nanoparticles on cotton fabrics using poly 4-styrenesulfonic acid polyelectrolyte

  • Yuwanda Iamphaojeen and Punnama Siriphannon
Published/Copyright: June 11, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 103 Issue 5

Abstract

Immobilization of ZnO nanoparticles on cotton fabrics using poly 4-styrenesulfonic acid (PSS) was studied. The cotton fabrics were firstly cationized using 3-chloro-2-hydroxypropyl trimethylammonium chloride (CHTAC) solution. The surfaces of cationized cotton were coated using a layer-by-layer technique by stepwise dipping the cationized cotton into a solution of anionic PSS polyelectrolyte and Zn(NO3)2 · 6H2O solution. The coating procedure was repeated 2, 4, and 6 times to obtain the PSS/Zn2+ multilayers coated on the cotton fabrics. The treated cotton fabrics were hydrothermally treated in NH4OH solution at 90 oC for 24 h, resulting in immobilization of ZnO nanocrystals on the cotton fabrics. The SEM, XRF, and XPS data revealed the accomplishment of ZnO immobilization on the surfaces of the treated cotton fabrics. The higher the number of PSS/Zn2+ coating layers on the fabrics, the more hydrothermally grown ZnO nanoparticles could be obtained, resulting in a higher UV protection factor when testing by the AATCC 183–2004 standard test method. All cotton fabrics with the ZnO immobilized on the surfaces were classified according to the AS/NZS 4339:1997 standard in the range of “VERY GOOD” UV protection category. The ZnO-immobilized cotton fabrics with the six PSS/Zn2+ coating layers could inhibit the growth of Staphylococcusaureus when testing by the AATCC 147–2004 standard test method.

Keywords: ZnO nanoparticles; Cotton fabrics; Polyelectrolytes; Layer-by-layer technique; Hydrothermal reaction
* Correspondence address Dr. Punnama Siriphannon Department of Chemistry, Faculty of Science King Mongkut's Institute of Technology Ladkrabang Chalongkrung Road, Ladkrabang, Bangkok 10520, Thailand Tel.: +66-2-329-84 00 ext. 344 Fax: +66-2-329-84 28 E-mail:

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Received: 2011-1-24
Accepted: 2011-12-15
Published Online: 2013-06-11
Published in Print: 2012-05-01

© 2012, Carl Hanser Verlag, München

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https://doi.org/10.3139/146.110726
Keywords for this article
ZnO nanoparticles; Cotton fabrics; Polyelectrolytes; Layer-by-layer technique; Hydrothermal reaction

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Phase equilibria in the “SnO”–SiO2–“FeO” system in equilibrium with tin–iron alloy and the potential application for electronic scrap recycling
  5. A model to calculate the viscosity of silicate melts
  6. Surface structure of different interstitial austenitic steels after impact wear
  7. Microstructural study of boron-doped Co–Re–Cr alloys by means of transmission electron microscopy and electron energy-loss spectroscopy
  8. Orientation relationship between 14H-LPSO structured X phase and DO3-type (Mg,Zn)3RE phase in an Mg–Gd–Y–Zn–Zr alloy
  9. Microstructural, optical, and dielectric properties of nanocrystalline TiO2 films prepared via ion-assisted magnetron sputtering
  10. An investigation of the microstructure and properties of the explosively welded Gr5–SS304 clad plates for golf heads
  11. Cyclic fibre texture in hot extruded Ni50Mn29Ga21
  12. Development of high-strength pure magnesium and wrought magnesium alloys AZ31, AZ61, and AZ91 processed by hydrostatic extrusion with back pressure
  13. Effect of cerium and aluminium on the hot-deformation behaviour of magnesium
  14. Effect of alloying elements on stage-III work-hardening behaviour of Al–Zn–Mg(–Cu) alloys
  15. Effect of titanium on the as-cast microstructure and impact toughness of hypereutectic high-chromium cast iron
  16. Microstructure and mechanical properties of nanocrystalline WC-particle-reinforced Ti-based composites with nano/ultrafine-grained intermetallic matrix from spark plasma sintering and crystallization of amorphous phase
  17. Plasticity enhancement in centrally confined Zr-based bulk metallic glass
  18. In-situ observation of the fracture process in Al–Zn–Mg–Cu alloys
  19. Relationship between the mechanical properties and the surface roughness of marble
  20. Light, multi-layer, screening textiles with a high capacity for absorbing electromagnetic fields in the high frequency range
  21. Immobilization of zinc oxide nanoparticles on cotton fabrics using poly 4-styrenesulfonic acid polyelectrolyte
  22. People
  23. Prof. Dr. rer. nat. Ludwig Schultz
  24. DGM News
  25. DGM News
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