Startseite Adsorptive Removal of Cetyltrimethyl Ammonium Bromide (CTAB) Surfactant from Aqueous Solution: Crossbreed Pilot Plant Membrane Studies
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Adsorptive Removal of Cetyltrimethyl Ammonium Bromide (CTAB) Surfactant from Aqueous Solution: Crossbreed Pilot Plant Membrane Studies

  • Muhammad Ali , Sultan Alam , Najeeb ur Rehman , Muhammad Zahoor und Muhammad Sufaid Khan
Veröffentlicht/Copyright: 13. November 2019
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 56 Heft 6

Abstract

Magnetic carbon nanocomposite (MCNC) was prepared from peanut shells and then characterized by FTIR, SEM, TGA/DTA and BET surface area. The removal of cetyltrimethyl ammonium bromide (CTAB) surfactant from aqueous solution was carried out by MCNC and membrane. The effect of contact time, initial concentration of CTAB and the temperature on the adsorption of CTAB was also investigated. Initially, the adsorption of CTAB on MCNC was rapid up to 20 min and then gradually slowed down. Different kinetic models i. e. 2nd pseudo order kinetics, power function and intraparticle diffusion were applied to determine different kinetic parameters. Intraparticle diffusion model showed that the adsorption of CTAB is a diffusion controlled process. Thermodynamic parameters i. e. ΔH° (–33.74 kJ/mol), ΔS° (0.98 J/mol K) and ΔG° (–62.91 kJ/mol, −64.37 kJ/mol and −66.33 kJ/mol) were calculated and the process was found to be exothermic and spontaneous in nature. The prepared adsorbent (MCNC) was used for controlling fouling of ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes caused by CTAB. Improved permeate fluxes and percent retention of CTAB were observed for MCNC crossbreed membrane. About 100 % retention with no effect on permeate flux was observed with RO membrane when MCNC pretreatment was applied.

Kurzfassung

Magnetische Kohlenstoff-Nanocomposite (MCNC) wurde aus Erdnussschalen hergestellt und anschließend mit FTIR-, SEM-, TGA/DTA- und BET charakterisiert. Die Entfernung des Tensids Cetyltrimethylammoniumbromid (CTAB) aus der wässrigen Lösung wurde mittels MCNC und Membran durchgeführt. Der Einfluss von Kontaktzeit, Anfangskonzentration des CTAB und Temperatur auf die Adsorption von CTAB wurde ebenfalls untersucht. Zu Beginn war die Adsorption von CTAB an MCNC schnell und verlangsamte sich nach 20 Minuten allmählich. Unterschiedliche kinetische Modelle, wie z. B. die Zweite-Pseudoordnung-Kinetik, die Potenzfunktion und die Intrapartikel-Diffusion, wurden angewendet, um die verschiedenen kinetischen Parameter zu bestimmen. Das Intrapartikel-Diffusionsmodell zeigte, dass die Adsorption von CTAB ein diffusionskontrollierter Prozess ist. Die thermodynamischen Parameter, wie ΔH° (–33,74 kJ/mol), ΔS° (0,98 J/mol K) und ΔG° (–62,91 kJ/mol, −64,37 kJ/mol und −66,33 kJ/mol) wurden berechnet; die Ergebnisse zeigten, dass der Prozess exotherm und spontan ist. Das hergestellte Adsorptionsmittel (MCNC) wurde dann zur Kontrolle der durch CTAB verursachten Verschmutzung von Ultrafiltrations- (UF), Nanofiltrations- (NF) und Umkehrosmosemembranen (RO) verwendet. Mit den MCNC-Cross-Breed-Membranen wurden verbesserte Permeatflüsse und prozentuale Retentionen von CTAB beobachtet. Mit der MCNC-Vorbehandlung wurde mit einer RO-Membran eine etwa 100 %-ige Retention ohne Auswirkung auf den Permeatfluss beobachtet.

Key words: CTAB removal; adsorption; magnetic carbon nanocomposites; crossbreed pilot plant
Stichwörter: CTAB-Entfernung; Adsorption; magnetische Kohlenstoff-Nanokomposite; Cross-Breet-Versuchsanlage
∗Correspondence address, Dr. Muhammad Khan, Department of Chemistry, University of Malakand, Chakdara Dir Lower, Khyber Pakhtunkhwa, Pakistan, E-Mail:

Muhammad Ali is currently doing his PhD at the Department of Chemistry University of Malakand Chakdara Dir lower, KPK Pakistan. He is working under the kind supervision of Prof. Dr. Sultan Alam research group. His current research interests cross breed pilot plant membrane separation of surfactant from waste water using fused magnetite carbon nanocomposites as an adsorbent. E-Mail:

Prof. Dr. Sultan Alam is currently working in Department of Chemistry, University of Malakand Chakdara, Dir lower, KPK Pakistan. His research interest includes Surface Chemistry, low cost adsorbent application for waste water removal, food chemistry and environmental chemistry. E-Mail:

Dr. Muhammad Zahoor is currently working as Assistant professor in Department of Chemistry, University of Malakand Chakdara, Dir lower, KPK Pakistan. His area of interest includes membrane separation, adsorption, clinical biochemistry. E-Mail:

Dr. Muhammad Sufaid Khan working in Department of Chemistry University of Malakand Chakdara Dir lower, KPK, Pakistan as assistant Professor (IPFP). Muhammad got his PhD degree from (UNESP) Brazil under the supervision of Profa Dra Hebe de las Mercedes villulas, s. His current research interest includes the development of non-Pt electrocatalysts for ORR in fuel cell cathode applications. E-Mail:

Dr. Najeeb ur Rehman is Assistant Professor in Department of Chemistry, University of Malakand. His research interest is Polymer and surfactant Chemistry. E-Mail:

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Received: 2019-02-16
Accepted: 2019-05-20
Published Online: 2019-11-13
Published in Print: 2019-11-15

© 2019, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Dish Washing
  4. Potential of Near-Infrared Spectroscopy to Evaluate the Cleaning Performance of Dishwashing Processes
  5. Socio-demographic Differences in Washing-up Behaviour in Germany
  6. Physical Chemistry
  7. Dynamic Surface Properties of Eco-Friendly Cationic Saccharide Surfactants at the Water/Air Interface
  8. Dependence of Surface Tension on Surface Concentration in Ionic Surfactant Solutions and Influences of Supporting Electrolyte Therein
  9. Solubilization and Thermodynamic Attributes of Nickel Phenanthroline Complex in Micellar Media of Sodium 2-Ethyl Hexyl Sulfate and Sodium Bis(2-ethyl hexyl) Sulfosuccinate
  10. Novel Surfactants
  11. Synthesis and Properties of Novel Catanionic Surfactant Phosphonium Benzene Sulfonate
  12. A Micellar-Enhanced Spectrofluorimetric Method for the Determination of Ciprofloxacin in Pure Form, Pharmaceutical Preparations and Biological Samples
  13. Micellar Catalysis
  14. A Review on Micellar Catalyzed Oxidation Reactions of Organic Functional Groups in Aqueous Medium Using Various Transition Metals
  15. Application
  16. Application of Oxidative Fatty Acid Esters in Amino Acid Surfactants
  17. Environmental Chemistry
  18. Adsorptive Removal of Cetyltrimethyl Ammonium Bromide (CTAB) Surfactant from Aqueous Solution: Crossbreed Pilot Plant Membrane Studies
https://doi.org/10.3139/113.110656
Schlagwörter für diesen Artikel
CTAB removal; adsorption; magnetic carbon nanocomposites; crossbreed pilot plant

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Dish Washing
  4. Potential of Near-Infrared Spectroscopy to Evaluate the Cleaning Performance of Dishwashing Processes
  5. Socio-demographic Differences in Washing-up Behaviour in Germany
  6. Physical Chemistry
  7. Dynamic Surface Properties of Eco-Friendly Cationic Saccharide Surfactants at the Water/Air Interface
  8. Dependence of Surface Tension on Surface Concentration in Ionic Surfactant Solutions and Influences of Supporting Electrolyte Therein
  9. Solubilization and Thermodynamic Attributes of Nickel Phenanthroline Complex in Micellar Media of Sodium 2-Ethyl Hexyl Sulfate and Sodium Bis(2-ethyl hexyl) Sulfosuccinate
  10. Novel Surfactants
  11. Synthesis and Properties of Novel Catanionic Surfactant Phosphonium Benzene Sulfonate
  12. A Micellar-Enhanced Spectrofluorimetric Method for the Determination of Ciprofloxacin in Pure Form, Pharmaceutical Preparations and Biological Samples
  13. Micellar Catalysis
  14. A Review on Micellar Catalyzed Oxidation Reactions of Organic Functional Groups in Aqueous Medium Using Various Transition Metals
  15. Application
  16. Application of Oxidative Fatty Acid Esters in Amino Acid Surfactants
  17. Environmental Chemistry
  18. Adsorptive Removal of Cetyltrimethyl Ammonium Bromide (CTAB) Surfactant from Aqueous Solution: Crossbreed Pilot Plant Membrane Studies
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