Startseite Equiatomic rare earth rhodium plumbides RERhPb (RE=Y, La–Nd, Sm, Gd–Lu) with ZrNiAl-type structure
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Equiatomic rare earth rhodium plumbides RERhPb (RE=Y, La–Nd, Sm, Gd–Lu) with ZrNiAl-type structure

  • Lukas Heletta und Rainer Pöttgen EMAIL logo
Veröffentlicht/Copyright: 19. Februar 2018
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 73 Heft 3-4

Abstract

The equiatomic plumbides RERhPb (RE=Y, La–Nd, Sm, Gd–Lu) were synthesized by induction melting of the elements in sealed niobium ampoules. The samples were characterized by X-ray powder diffraction, confirming their ZrNiAl-type structure, space group P6̅2m. Four structures were refined from single-crystal X-ray diffractometer data: a=769.42(5), c=415.60(3) pm, wR=0.0415, 343 F2 values, 15 variables for LaRhPb, a=767.91(6), c=369.37(4) pm, wR=0.0798, 284 F2 values, 15 variables for ErRhPb, a=767.01(8), c=366.21(4) pm, wR=0.0380, 341 F2 values, 15 variables for YbRhPb and a=766.9(1), c=363.42(6) pm, wR=0.0699, 290 F2 values, 15 variables for LuRhPb. The RERhPb plumbides contain two crystallographically independent rhodium atoms, both in tricapped trigonal prismatic coordination: Rh1@Pb3RE6 and Rh2@RE6Pb3. Short Rh–Pb distances (277 and 284 pm in ErRhPb) are indicative of covalent Rh–Pb bonding. The crystal chemical details of the RERhPb series are compared with the silver plumbides REAgPb which show different transition metal-lead coloring. Temperature dependent magnetic susceptibility data show Pauli paramagnetism for YRhPb, LaRhPb and LuRhPb. An antiferromagnetic ground state below the Néel temperatures of 13.5, 21.0 and 6.9 K was found for PrRhPb, TbRhPb and DyRhPb, respectively. HoRhPb exhibits Curie-Weiss behavior in the observed temperature range.

Keywords: crystal structure; magnetic properties; plumbides; rare earth intermetallics

Acknowledgments

We thank Dipl.-Ing. U. Ch. Rodewald, Dipl.-Ing. J. Kösters and Dr. R.-D. Hoffmann for the collection of the single crystal diffractometer data.

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Received: 2018-1-15
Accepted: 2018-1-18
Published Online: 2018-2-19
Published in Print: 2018-4-25

©2018 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. In this Issue
  3. Does Lewis basicity correlate with catalytic performance in zerovalent group 8 complexes?
  4. Crystal structure and luminescence properties of a new dinuclear bismuth(III) coordination polymer containing three types of ligands
  5. Syntheses, structures, and catalytic properties of two arene-ruthenium(II) complexes bearing N-(2-pyridinyl)aminodiphenylphosphine sulfide ligands
  6. Synthesis, characterization, anticancer and antimicrobial study of arene ruthenium(II) complexes with 1,2,4-triazole ligands containing an α-diimine moiety
  7. Green synthesis of α-aminophosphonates using ZnO nanoparticles as an efficient catalyst
  8. Nano-NiZr4(PO4)6 as a superior catalyst for the synthesis of propargylamines under ultrasound irradiation
  9. Efficient pseudo five-component synthesis of 4,4′-(arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol) derivatives promoted by a novel ionic liquid catalyst
  10. Hydrothermal synthesis and crystal structure of a bisupporting Keggin-polyoxometalate hybrid compound decorated with a copper(II) complex unit
  11. Synthesis, crystal structure, luminescence and electrochemical properties of a Salamo-type trinuclear cobalt(II) complex
  12. New cholic acid analogs: synthesis and 17β-hydroxydehydrogenase (17β-HSD) inhibition activity
  13. Synthesis, vibrational spectra and single-crystal structure determination of lithium tricyanomethanide Li[C(CN)3]
  14. Silber(I)-cyanid-Komplexe mit Aminen und Azaaromaten
  15. The alkaline earth-palladium-germanides Sr3Pd4Ge4 and BaPdGe
  16. Equiatomic rare earth rhodium plumbides RERhPb (RE=Y, La–Nd, Sm, Gd–Lu) with ZrNiAl-type structure
  17. Notes
  18. Synthesis and crystal structure of [azido-bis(cis-1,2-diaminocyclohexane)copper(II)] chloride trihydrate
  19. A Co(II) complex from a pyridylamide ligand: synthesis and structural characterization
https://doi.org/10.1515/znb-2018-0012
Schlagwörter für diesen Artikel
crystal structure; magnetic properties; plumbides; rare earth intermetallics

Artikel in diesem Heft

  1. Frontmatter
  2. In this Issue
  3. Does Lewis basicity correlate with catalytic performance in zerovalent group 8 complexes?
  4. Crystal structure and luminescence properties of a new dinuclear bismuth(III) coordination polymer containing three types of ligands
  5. Syntheses, structures, and catalytic properties of two arene-ruthenium(II) complexes bearing N-(2-pyridinyl)aminodiphenylphosphine sulfide ligands
  6. Synthesis, characterization, anticancer and antimicrobial study of arene ruthenium(II) complexes with 1,2,4-triazole ligands containing an α-diimine moiety
  7. Green synthesis of α-aminophosphonates using ZnO nanoparticles as an efficient catalyst
  8. Nano-NiZr4(PO4)6 as a superior catalyst for the synthesis of propargylamines under ultrasound irradiation
  9. Efficient pseudo five-component synthesis of 4,4′-(arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol) derivatives promoted by a novel ionic liquid catalyst
  10. Hydrothermal synthesis and crystal structure of a bisupporting Keggin-polyoxometalate hybrid compound decorated with a copper(II) complex unit
  11. Synthesis, crystal structure, luminescence and electrochemical properties of a Salamo-type trinuclear cobalt(II) complex
  12. New cholic acid analogs: synthesis and 17β-hydroxydehydrogenase (17β-HSD) inhibition activity
  13. Synthesis, vibrational spectra and single-crystal structure determination of lithium tricyanomethanide Li[C(CN)3]
  14. Silber(I)-cyanid-Komplexe mit Aminen und Azaaromaten
  15. The alkaline earth-palladium-germanides Sr3Pd4Ge4 and BaPdGe
  16. Equiatomic rare earth rhodium plumbides RERhPb (RE=Y, La–Nd, Sm, Gd–Lu) with ZrNiAl-type structure
  17. Notes
  18. Synthesis and crystal structure of [azido-bis(cis-1,2-diaminocyclohexane)copper(II)] chloride trihydrate
  19. A Co(II) complex from a pyridylamide ligand: synthesis and structural characterization
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