Silber(I)-cyanid-Komplexe mit Aminen und Azaaromaten
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Mark Strey
Abstract
Silver cyanide can be treated with liquid amines or azaaromatics L to give crystalline complexes of various compositions, among them complexes of the simple type cyanido(amine)silver(I): L=isobutylamine and 4-picoline. Other AgCN:L ratios obtained were: 1:2 (benzylamine and 4-benzylpiperidine), 2:1 (2,4-lutidine), 2:3 (morpholine and 3,4-lutidine) and 3:4 (3,5-lutidine). The packing diagrams were analyzed in terms of Ag–Ag and Ag–CN contacts and N–H···N hydrogen bonds. The contacts often give rise to chains, which are sometimes linked to layers by hydrogen bonds.
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Articles in the same Issue
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Articles in the same Issue
- Frontmatter
- In this Issue
- Does Lewis basicity correlate with catalytic performance in zerovalent group 8 complexes?
- Crystal structure and luminescence properties of a new dinuclear bismuth(III) coordination polymer containing three types of ligands
- Syntheses, structures, and catalytic properties of two arene-ruthenium(II) complexes bearing N-(2-pyridinyl)aminodiphenylphosphine sulfide ligands
- Synthesis, characterization, anticancer and antimicrobial study of arene ruthenium(II) complexes with 1,2,4-triazole ligands containing an α-diimine moiety
- Green synthesis of α-aminophosphonates using ZnO nanoparticles as an efficient catalyst
- Nano-NiZr4(PO4)6 as a superior catalyst for the synthesis of propargylamines under ultrasound irradiation
- Efficient pseudo five-component synthesis of 4,4′-(arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol) derivatives promoted by a novel ionic liquid catalyst
- Hydrothermal synthesis and crystal structure of a bisupporting Keggin-polyoxometalate hybrid compound decorated with a copper(II) complex unit
- Synthesis, crystal structure, luminescence and electrochemical properties of a Salamo-type trinuclear cobalt(II) complex
- New cholic acid analogs: synthesis and 17β-hydroxydehydrogenase (17β-HSD) inhibition activity
- Synthesis, vibrational spectra and single-crystal structure determination of lithium tricyanomethanide Li[C(CN)3]
- Silber(I)-cyanid-Komplexe mit Aminen und Azaaromaten
- The alkaline earth-palladium-germanides Sr3Pd4Ge4 and BaPdGe
- Equiatomic rare earth rhodium plumbides RERhPb (RE=Y, La–Nd, Sm, Gd–Lu) with ZrNiAl-type structure
- Notes
- Synthesis and crystal structure of [azido-bis(cis-1,2-diaminocyclohexane)copper(II)] chloride trihydrate
- A Co(II) complex from a pyridylamide ligand: synthesis and structural characterization
