Startseite Synthesis and crystal structure of [azido-bis(cis-1,2-diaminocyclohexane)copper(II)] chloride trihydrate
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Synthesis and crystal structure of [azido-bis(cis-1,2-diaminocyclohexane)copper(II)] chloride trihydrate

  • Sidra Nawaz , Muhammad Monim-ul-Mehboob , Muhammad Nawaz Tahir , Irshad Hussain , Habib-ur-Rehman , Syed Zajif Hussain und Saeed Ahmad EMAIL logo
Veröffentlicht/Copyright: 12. März 2018
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 73 Heft 3-4

Abstract

A new copper(II) complex containing cis-1,2-diaminocyclohexane (Dach) and azide as ligands, [Cu(Dach)2(N3)]Cl · 3H2O (1), was prepared and characterized by IR spectroscopy, thermal analysis and X-ray crystallography. The structure of 1 consists of a complex cation, [Cu(Dach)2(N3)]+, a chloride counter-ion and three water molecules. The coordination environment of the copper(II) atom in 1 is distorted square pyramidal attained by four nitrogen atoms of cis-1,2-diaminocyclohexane molecules and an azide ion. Thermogravimetric and differential scanning calorimetric analyses validated the molecular formula of complex 1.

Keywords: azide; cis-1,2-diaminocyclohexane; copper(II); X-ray structure

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Supplemental Material:

The online version of this article offers supplementary material (https://doi.org/10.1515/znb-2017-0175).

Received: 2017-10-4
Accepted: 2017-11-17
Published Online: 2018-3-12
Published in Print: 2018-4-25

©2018 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. In this Issue
  3. Does Lewis basicity correlate with catalytic performance in zerovalent group 8 complexes?
  4. Crystal structure and luminescence properties of a new dinuclear bismuth(III) coordination polymer containing three types of ligands
  5. Syntheses, structures, and catalytic properties of two arene-ruthenium(II) complexes bearing N-(2-pyridinyl)aminodiphenylphosphine sulfide ligands
  6. Synthesis, characterization, anticancer and antimicrobial study of arene ruthenium(II) complexes with 1,2,4-triazole ligands containing an α-diimine moiety
  7. Green synthesis of α-aminophosphonates using ZnO nanoparticles as an efficient catalyst
  8. Nano-NiZr4(PO4)6 as a superior catalyst for the synthesis of propargylamines under ultrasound irradiation
  9. Efficient pseudo five-component synthesis of 4,4′-(arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol) derivatives promoted by a novel ionic liquid catalyst
  10. Hydrothermal synthesis and crystal structure of a bisupporting Keggin-polyoxometalate hybrid compound decorated with a copper(II) complex unit
  11. Synthesis, crystal structure, luminescence and electrochemical properties of a Salamo-type trinuclear cobalt(II) complex
  12. New cholic acid analogs: synthesis and 17β-hydroxydehydrogenase (17β-HSD) inhibition activity
  13. Synthesis, vibrational spectra and single-crystal structure determination of lithium tricyanomethanide Li[C(CN)3]
  14. Silber(I)-cyanid-Komplexe mit Aminen und Azaaromaten
  15. The alkaline earth-palladium-germanides Sr3Pd4Ge4 and BaPdGe
  16. Equiatomic rare earth rhodium plumbides RERhPb (RE=Y, La–Nd, Sm, Gd–Lu) with ZrNiAl-type structure
  17. Notes
  18. Synthesis and crystal structure of [azido-bis(cis-1,2-diaminocyclohexane)copper(II)] chloride trihydrate
  19. A Co(II) complex from a pyridylamide ligand: synthesis and structural characterization
https://doi.org/10.1515/znb-2017-0175
Schlagwörter für diesen Artikel
azide; cis-1,2-diaminocyclohexane; copper(II); X-ray structure

Artikel in diesem Heft

  1. Frontmatter
  2. In this Issue
  3. Does Lewis basicity correlate with catalytic performance in zerovalent group 8 complexes?
  4. Crystal structure and luminescence properties of a new dinuclear bismuth(III) coordination polymer containing three types of ligands
  5. Syntheses, structures, and catalytic properties of two arene-ruthenium(II) complexes bearing N-(2-pyridinyl)aminodiphenylphosphine sulfide ligands
  6. Synthesis, characterization, anticancer and antimicrobial study of arene ruthenium(II) complexes with 1,2,4-triazole ligands containing an α-diimine moiety
  7. Green synthesis of α-aminophosphonates using ZnO nanoparticles as an efficient catalyst
  8. Nano-NiZr4(PO4)6 as a superior catalyst for the synthesis of propargylamines under ultrasound irradiation
  9. Efficient pseudo five-component synthesis of 4,4′-(arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol) derivatives promoted by a novel ionic liquid catalyst
  10. Hydrothermal synthesis and crystal structure of a bisupporting Keggin-polyoxometalate hybrid compound decorated with a copper(II) complex unit
  11. Synthesis, crystal structure, luminescence and electrochemical properties of a Salamo-type trinuclear cobalt(II) complex
  12. New cholic acid analogs: synthesis and 17β-hydroxydehydrogenase (17β-HSD) inhibition activity
  13. Synthesis, vibrational spectra and single-crystal structure determination of lithium tricyanomethanide Li[C(CN)3]
  14. Silber(I)-cyanid-Komplexe mit Aminen und Azaaromaten
  15. The alkaline earth-palladium-germanides Sr3Pd4Ge4 and BaPdGe
  16. Equiatomic rare earth rhodium plumbides RERhPb (RE=Y, La–Nd, Sm, Gd–Lu) with ZrNiAl-type structure
  17. Notes
  18. Synthesis and crystal structure of [azido-bis(cis-1,2-diaminocyclohexane)copper(II)] chloride trihydrate
  19. A Co(II) complex from a pyridylamide ligand: synthesis and structural characterization
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