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A Co(II) complex from a pyridylamide ligand: synthesis and structural characterization

  • Xiao-Hong Zhu EMAIL logo , Ding-Yun Jiang , Tao Hu and Deng-Hao Li
Published/Copyright: March 10, 2018
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 73 Issue 3-4

Abstract

The hydrothermal reaction of N3,N5-di(pyridin-4-yl)pyridine-3,5-dicarboxamide (L) with Co(NO3)2·6H2O and ErCl3·6H2O yields a new complex, {[Co(L)2(NO3)1.15(Cl)0.85]·4DMF}n (1). Complex 1 has been characterized by single-crystal and powder X-ray diffraction, IR, and elemental and thermogravimetric analysis. It crystallizes in the orthorhombic space group Fddd and shows a chain structure.

Keywords: Co(II); hetero-anion; structural characterization

Acknowledgements

The authors gratefully acknowledge Natural Science Foundation for Universities in Jiangsu Province (16KJB150005) and Huaiyin Institute of Technology (15HGZ006 and 491713325) for financial support of this work.

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Received: 2017-11-2
Accepted: 2017-12-15
Published Online: 2018-3-10
Published in Print: 2018-4-25

©2018 Walter de Gruyter GmbH, Berlin/Boston

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  5. Syntheses, structures, and catalytic properties of two arene-ruthenium(II) complexes bearing N-(2-pyridinyl)aminodiphenylphosphine sulfide ligands
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  19. A Co(II) complex from a pyridylamide ligand: synthesis and structural characterization
https://doi.org/10.1515/znb-2017-0199
Keywords for this article
Co(II); hetero-anion; structural characterization

Articles in the same Issue

  1. Frontmatter
  2. In this Issue
  3. Does Lewis basicity correlate with catalytic performance in zerovalent group 8 complexes?
  4. Crystal structure and luminescence properties of a new dinuclear bismuth(III) coordination polymer containing three types of ligands
  5. Syntheses, structures, and catalytic properties of two arene-ruthenium(II) complexes bearing N-(2-pyridinyl)aminodiphenylphosphine sulfide ligands
  6. Synthesis, characterization, anticancer and antimicrobial study of arene ruthenium(II) complexes with 1,2,4-triazole ligands containing an α-diimine moiety
  7. Green synthesis of α-aminophosphonates using ZnO nanoparticles as an efficient catalyst
  8. Nano-NiZr4(PO4)6 as a superior catalyst for the synthesis of propargylamines under ultrasound irradiation
  9. Efficient pseudo five-component synthesis of 4,4′-(arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol) derivatives promoted by a novel ionic liquid catalyst
  10. Hydrothermal synthesis and crystal structure of a bisupporting Keggin-polyoxometalate hybrid compound decorated with a copper(II) complex unit
  11. Synthesis, crystal structure, luminescence and electrochemical properties of a Salamo-type trinuclear cobalt(II) complex
  12. New cholic acid analogs: synthesis and 17β-hydroxydehydrogenase (17β-HSD) inhibition activity
  13. Synthesis, vibrational spectra and single-crystal structure determination of lithium tricyanomethanide Li[C(CN)3]
  14. Silber(I)-cyanid-Komplexe mit Aminen und Azaaromaten
  15. The alkaline earth-palladium-germanides Sr3Pd4Ge4 and BaPdGe
  16. Equiatomic rare earth rhodium plumbides RERhPb (RE=Y, La–Nd, Sm, Gd–Lu) with ZrNiAl-type structure
  17. Notes
  18. Synthesis and crystal structure of [azido-bis(cis-1,2-diaminocyclohexane)copper(II)] chloride trihydrate
  19. A Co(II) complex from a pyridylamide ligand: synthesis and structural characterization
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