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Experimental and thermodynamic evaluation of the Co–Cr–C system

  • Andreas Markström EMAIL logo , Susanne Norgren , Karin Frisk , Bo Jansson and Thérèse Sterneland
Published/Copyright: January 21, 2022
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Abstract

New experimental results on the liquid + graphite + M7C3 equilibrium are presented. The solubility of Co in the M7C3 carbide has been measured at 1523 and 1723 K. These measurements together with recently published measurements on the fcc + graphite + M7C3 equilibrium show that the solubility of Co in the M7C3 is much higher than predicted from thermodynamic calculations. A new thermodynamic description of the Co–Cr –C system is presented which accurately describes the solubility of Co in the M7C3 carbide in the temperature range 1373 – 1723 K.


Andreas Markström, M.Sc, Swedish Corrosion and Metals Research Institute, Drottning Kristinas väg 48, SE 11428 Stockholm, Sweden, Tel.: +46 8440 4834, Fax: +46 8440 535

  1. We would like to thank Dr. Marian Mikus at Sandvik Tooling for the EPMA work and Dr. Jenni Zackrisson at Seco Tools for all the valuable comments on the present work.

    This work was performed within the Centre for Computational Thermodynamics (CCT), which is financed by The Swedish Foundation for Strategic Research (SSF), Jernkontoret, Sandvik Tooling, Seco Tools, SSAB Tunnplåt, SSAB Oxelösund, Uddeholm Tooling, Höganäs, Ovako Steel, Outokumpu Stainless, Sandvik Materials Technology, Åkers Sweden, Erasteel Kloster and TCSAB.

References

[1] A. Kusoffsky, B. Jansson: Calphad, 21 (1977) 321.10.1016/S0364-5916(97)00033-3Search in Google Scholar

[2] W. Köster, F. Sperner: Arch. Eisenhutten. 26 (1955) 555.10.1002/srin.195502078Search in Google Scholar

[3] J. Zacrisson, B. Jansson, G.S. Uphadyaya, H.-O. Andrén: Int. J. Refractory Metals and Hard Materials. 16 (1998) 417.10.1016/S0263-4368(98)00048-1Search in Google Scholar

[4] T. Sterneland, A. Markström. R.E. Aune, S. Norgren, S. Seetharamen: submitted to Metallurgical and Materials Transaction A, July 2005.Search in Google Scholar

[5] K. Frisk et al., to be publishedSearch in Google Scholar

[6] H. Tuma, K. Löbl: Kovové Materialy. 10 (1971) 221.Search in Google Scholar

[7] E.R. Thompson, F.D. Lemkey: Metal. Trans. 1 (1970) 2799.10.1007/BF03037817Search in Google Scholar

[8] P.R. Sahm, D.J. Watts: Metal. Trans. 2 (1971) 1260.10.1007/BF02664267Search in Google Scholar

[9] N. Sounders, A.P. Miodownik, in: R.W. Cahn (Ed.), Pergamont Materials Series. 1 (1998).Search in Google Scholar

[10] B. Jansson, Thesis, Royal Inst. of Technology, Sweden, 1984.Search in Google Scholar

[11] B. Sundman, B. Jansson, J.-O. Andersson: Calphad. 9 (1985) 153.10.1016/0364-5916(85)90021-5Search in Google Scholar

[12] A. Fernàndez Guillermet: Z. Metallkd. 78 (1987) 700.10.1515/ijmr-1987-781005Search in Google Scholar

[13] J. Bratberg, K. Frisk: Met. Mat. Trans. A, A 35 (2004) 3649.10.1007/s11661-004-0271-9Search in Google Scholar

[14] M. Hillert: J. Alloys and Compounds. 320 (2001) 161.10.1016/S0925-8388(00)01481-XSearch in Google Scholar

[15] G. Inden: Physica. B 103 (1981) 82.10.1016/0378-4363(81)91004-4Search in Google Scholar

[16] M. Hillert, M. Jarl: Calphad. 2 (1978) 227.10.1016/0364-5916(78)90011-1Search in Google Scholar

[17] A. Fernàndez Guillermet, G. Grimvall: Phys. Rev. B 53 (1992) 105.10.1016/0022-3697(92)90019-ASearch in Google Scholar

Received: 2005-10-18
Accepted: 2006-06-02
Published Online: 2022-01-21

© 2006 Carl Hanser Verlag, München

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  1. Contents
  2. Editorial
  3. Nanoindentation creep and stress relaxation tests of polycarbonate: Analysis of viscoelastic properties by different rheological models
  4. Investigation of SiO2 thin films on Si substrates for use as standards for laser-acoustic measuring devices
  5. Determination of the critical tensile stress of sapphire by spherical indentation with additional lateral forces
  6. The deformation behaviour of electrodeposited nanocrystalline Ni in an atomic force microscope with a newly developed in situ bending machine
  7. In situ electrochemical nanoindentation of a nickel (111) single crystal: hydrogen effect on pop-in behaviour
  8. Indentation behaviour of (011) thin films of III–V semiconductors: polarity effect differences between GaAs and InP
  9. Multiwall carbon nanotubes-based composites – mechanical characterization using the nanoindentation technique
  10. Nanoindentation studies of stamp materials for nanoimprint lithography
  11. Experimental and thermodynamic evaluation of the Co–Cr–C system
  12. Thermodynamics of high-temperature cuprous sulfide
  13. Sintering of Si3N4 with Li-exchanged zeolite additive
  14. Effect of LiYO2 addition on sintering behavior and indentation properties of silicon nitride ceramics
  15. Mechanism of quasi-viscous flow of zinc single crystals
  16. The absolute thermoelectric power of chromium, molybdenum, and tungsten
  17. Modelling of metal – mould interface resistance in the Al-11.5 wt.% Si alloy casting process
  18. Award/Preisverleihung
  19. Personal
  20. Conferences
  21. Contents
  22. Editorial
  23. Editorial
  24. Basic
  25. Nanoindentation creep and stress relaxation tests of polycarbonate: Analysis of viscoelastic properties by different rheological models
  26. Investigation of SiO2 thin films on Si substrates for use as standards for laser-acoustic measuring devices
  27. Determination of the critical tensile stress of sapphire by spherical indentation with additional lateral forces
  28. The deformation behaviour of electrodeposited nanocrystalline Ni in an atomic force microscope with a newly developed in situ bending machine
  29. In situ electrochemical nanoindentation of a nickel (111) single crystal: hydrogen effect on pop-in behaviour
  30. Indentation behaviour of (011) thin films of III–V semiconductors: polarity effect differences between GaAs and InP
  31. Multiwall carbon nanotubes-based composites – mechanical characterization using the nanoindentation technique
  32. Nanoindentation studies of stamp materials for nanoimprint lithography
  33. Experimental and thermodynamic evaluation of the Co–Cr–C system
  34. Applied
  35. Thermodynamics of high-temperature cuprous sulfide
  36. Sintering of Si3N4 with Li-exchanged zeolite additive
  37. Effect of LiYO2 addition on sintering behavior and indentation properties of silicon nitride ceramics
  38. Mechanism of quasi-viscous flow of zinc single crystals
  39. The absolute thermoelectric power of chromium, molybdenum, and tungsten
  40. Modelling of metal – mould interface resistance in the Al-11.5 wt.% Si alloy casting process
  41. Kösterpreis
  42. Award/Preisverleihung
  43. Notifications
  44. Personal
  45. Conferences
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