Abstract
New experimental results on the liquid + graphite + M7C3 equilibrium are presented. The solubility of Co in the M7C3 carbide has been measured at 1523 and 1723 K. These measurements together with recently published measurements on the fcc + graphite + M7C3 equilibrium show that the solubility of Co in the M7C3 is much higher than predicted from thermodynamic calculations. A new thermodynamic description of the Co–Cr –C system is presented which accurately describes the solubility of Co in the M7C3 carbide in the temperature range 1373 – 1723 K.
We would like to thank Dr. Marian Mikus at Sandvik Tooling for the EPMA work and Dr. Jenni Zackrisson at Seco Tools for all the valuable comments on the present work.
This work was performed within the Centre for Computational Thermodynamics (CCT), which is financed by The Swedish Foundation for Strategic Research (SSF), Jernkontoret, Sandvik Tooling, Seco Tools, SSAB Tunnplåt, SSAB Oxelösund, Uddeholm Tooling, Höganäs, Ovako Steel, Outokumpu Stainless, Sandvik Materials Technology, Åkers Sweden, Erasteel Kloster and TCSAB.
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© 2006 Carl Hanser Verlag, München
Articles in the same Issue
- Contents
- Editorial
- Nanoindentation creep and stress relaxation tests of polycarbonate: Analysis of viscoelastic properties by different rheological models
- Investigation of SiO2 thin films on Si substrates for use as standards for laser-acoustic measuring devices
- Determination of the critical tensile stress of sapphire by spherical indentation with additional lateral forces
- The deformation behaviour of electrodeposited nanocrystalline Ni in an atomic force microscope with a newly developed in situ bending machine
- In situ electrochemical nanoindentation of a nickel (111) single crystal: hydrogen effect on pop-in behaviour
- Indentation behaviour of (011) thin films of III–V semiconductors: polarity effect differences between GaAs and InP
- Multiwall carbon nanotubes-based composites – mechanical characterization using the nanoindentation technique
- Nanoindentation studies of stamp materials for nanoimprint lithography
- Experimental and thermodynamic evaluation of the Co–Cr–C system
- Thermodynamics of high-temperature cuprous sulfide
- Sintering of Si3N4 with Li-exchanged zeolite additive
- Effect of LiYO2 addition on sintering behavior and indentation properties of silicon nitride ceramics
- Mechanism of quasi-viscous flow of zinc single crystals
- The absolute thermoelectric power of chromium, molybdenum, and tungsten
- Modelling of metal – mould interface resistance in the Al-11.5 wt.% Si alloy casting process
- Award/Preisverleihung
- Personal
- Conferences
- Contents
- Editorial
- Editorial
- Basic
- Nanoindentation creep and stress relaxation tests of polycarbonate: Analysis of viscoelastic properties by different rheological models
- Investigation of SiO2 thin films on Si substrates for use as standards for laser-acoustic measuring devices
- Determination of the critical tensile stress of sapphire by spherical indentation with additional lateral forces
- The deformation behaviour of electrodeposited nanocrystalline Ni in an atomic force microscope with a newly developed in situ bending machine
- In situ electrochemical nanoindentation of a nickel (111) single crystal: hydrogen effect on pop-in behaviour
- Indentation behaviour of (011) thin films of III–V semiconductors: polarity effect differences between GaAs and InP
- Multiwall carbon nanotubes-based composites – mechanical characterization using the nanoindentation technique
- Nanoindentation studies of stamp materials for nanoimprint lithography
- Experimental and thermodynamic evaluation of the Co–Cr–C system
- Applied
- Thermodynamics of high-temperature cuprous sulfide
- Sintering of Si3N4 with Li-exchanged zeolite additive
- Effect of LiYO2 addition on sintering behavior and indentation properties of silicon nitride ceramics
- Mechanism of quasi-viscous flow of zinc single crystals
- The absolute thermoelectric power of chromium, molybdenum, and tungsten
- Modelling of metal – mould interface resistance in the Al-11.5 wt.% Si alloy casting process
- Kösterpreis
- Award/Preisverleihung
- Notifications
- Personal
- Conferences
Articles in the same Issue
- Contents
- Editorial
- Nanoindentation creep and stress relaxation tests of polycarbonate: Analysis of viscoelastic properties by different rheological models
- Investigation of SiO2 thin films on Si substrates for use as standards for laser-acoustic measuring devices
- Determination of the critical tensile stress of sapphire by spherical indentation with additional lateral forces
- The deformation behaviour of electrodeposited nanocrystalline Ni in an atomic force microscope with a newly developed in situ bending machine
- In situ electrochemical nanoindentation of a nickel (111) single crystal: hydrogen effect on pop-in behaviour
- Indentation behaviour of (011) thin films of III–V semiconductors: polarity effect differences between GaAs and InP
- Multiwall carbon nanotubes-based composites – mechanical characterization using the nanoindentation technique
- Nanoindentation studies of stamp materials for nanoimprint lithography
- Experimental and thermodynamic evaluation of the Co–Cr–C system
- Thermodynamics of high-temperature cuprous sulfide
- Sintering of Si3N4 with Li-exchanged zeolite additive
- Effect of LiYO2 addition on sintering behavior and indentation properties of silicon nitride ceramics
- Mechanism of quasi-viscous flow of zinc single crystals
- The absolute thermoelectric power of chromium, molybdenum, and tungsten
- Modelling of metal – mould interface resistance in the Al-11.5 wt.% Si alloy casting process
- Award/Preisverleihung
- Personal
- Conferences
- Contents
- Editorial
- Editorial
- Basic
- Nanoindentation creep and stress relaxation tests of polycarbonate: Analysis of viscoelastic properties by different rheological models
- Investigation of SiO2 thin films on Si substrates for use as standards for laser-acoustic measuring devices
- Determination of the critical tensile stress of sapphire by spherical indentation with additional lateral forces
- The deformation behaviour of electrodeposited nanocrystalline Ni in an atomic force microscope with a newly developed in situ bending machine
- In situ electrochemical nanoindentation of a nickel (111) single crystal: hydrogen effect on pop-in behaviour
- Indentation behaviour of (011) thin films of III–V semiconductors: polarity effect differences between GaAs and InP
- Multiwall carbon nanotubes-based composites – mechanical characterization using the nanoindentation technique
- Nanoindentation studies of stamp materials for nanoimprint lithography
- Experimental and thermodynamic evaluation of the Co–Cr–C system
- Applied
- Thermodynamics of high-temperature cuprous sulfide
- Sintering of Si3N4 with Li-exchanged zeolite additive
- Effect of LiYO2 addition on sintering behavior and indentation properties of silicon nitride ceramics
- Mechanism of quasi-viscous flow of zinc single crystals
- The absolute thermoelectric power of chromium, molybdenum, and tungsten
- Modelling of metal – mould interface resistance in the Al-11.5 wt.% Si alloy casting process
- Kösterpreis
- Award/Preisverleihung
- Notifications
- Personal
- Conferences