Abstract
The contact flattening between grains has long been considered to be the densification mechanism during liquidphase sintering. Recently, however, we proposed pore filling as being the major mechanism. In this investigation, we critically examine the two densification mechanisms by calculating their contributions to the sintering. The calculation shows that the contact flattening can be operative at the early stage for systems with a dihedral angle of zero degrees. However, its contribution to grain shape change and compact shrinkage is insignificant compared with that of the grain growth. A consideration of microstructures in real systems further suggests that the contribution of contact flattening is much less than the calculated value and is negligible from the beginning of the liquid-phase sintering. In fact, pore filling, which is induced by grain growth, appears to be essentially the only densification mechanism. An exemplified calculation of densification kinetics by pore filling is also presented and its implication discussed.
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This work was done under a joint research program of the Korea Advanced Institute of Science and Technology (KAIST) and the Institut National Polytechnique de Grenoble (INPG), supported by the Korean Ministry of Science and Technology (contract No. 99-I-03-057). The authors thank Mr. Sug-Woo Jung for his assistance in the preparation of the manuscript.
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Artikel in diesem Heft
- Frontmatter
- Editorial
- “No wise man ever wish to be younger”
- Aufsätze/Articles
- Entropy, Transformations and Sustainability of Industrial Life Cycles
- Positron Annihilation in Stable and Supercooled Metallic Melts
- Local Characterization of the Diffusion Process during Discontinuous Precipitation: A Review
- The Dependence of Abnormal Grain Growth on Initial Grain Size in 316 L Stainless Steel
- Diffusion-Controlled Grain Growth in Liquid-Phase Sintering of W–Cu Nanocomposites
- Evaluation of Densification Mechanisms of Liquid-Phase Sintering
- Phase Transformation of a Dual Phase Al–Fe Alloy Prepared by Mechanical Alloying
- Discrete Element Simulation of Ceramic Powder Processing
- Strain Relaxation and Internal Friction in the Range of the Glass Transition
- A Thermodynamic Model of an Amorphous Grain Boundary Phase in Liquid-Phase Sintered β-SiAlON Ceramic
- Epitaxial Growth of Metals on (100) SrTiO3: The Influence of Lattice Mismatch and Reactivity
- Microstructure and Modifications of Cu/Al2O3 Interfaces
- Structural Transformations Induced by Swift Heavy Ions in Polysiloxanes and Polycarbosilanes
- Metastable Al–Nd–Ni and Stable Al–La–Ni Phase Equilibria
- Phase Equilibria of the Al–Nd and Al–Nd–Ni Systems
- System Pr –Pd–O: Phase Diagram and Thermodynamic Properties of Ternary Oxides Using Solid-State Cells with Special Features
- Calculation of Phase Equilibria in Candidate Solder Alloys
- Thermodynamic Assessment of the Zr–O Binary System
- Delaminating Layered Oxide Composites with Wavy Interfaces
- Contemporary Materials Issues for Advanced EB-PVD Thermal Barrier Coating Systems
- Monte Carlo Simulations of Strength Distributions of Brittle Materials – Type of Distribution, Specimen and Sample Size
- On the Optimization of the Microstructure in Powder Metallurgical Ag–SnO2–In2O3 Contact Materials
- Some New Aspects of Microstructural Design of β-Si3N4 Ceramics
- Ni-Based SOFC Anodes: Microstructure and Electrochemistry
- Effect of Copper Line Geometry and Process Parameters on Interconnect Microstructure and Degradation Processes
- Thermal Stability of Nanoscale Co/Cu Multilayers
- Methods for Characterising the Precipitation of Nanometer-Sized Secondary Hardening Carbides and Related Effects in Tool Steels
- Prediction of Local Strain and Hardness in Sheet Forming
- Novel in situ-Infiltrated Al2O3-Metal Composites
- Influence of Microstructure and Impurities on Thermal Conductivity of Aluminium Nitride Ceramics
- Notifications/Mitteilungen
- Personelles/Personal
- Bücher/Books
- Tagungen/Conferences
Artikel in diesem Heft
- Frontmatter
- Editorial
- “No wise man ever wish to be younger”
- Aufsätze/Articles
- Entropy, Transformations and Sustainability of Industrial Life Cycles
- Positron Annihilation in Stable and Supercooled Metallic Melts
- Local Characterization of the Diffusion Process during Discontinuous Precipitation: A Review
- The Dependence of Abnormal Grain Growth on Initial Grain Size in 316 L Stainless Steel
- Diffusion-Controlled Grain Growth in Liquid-Phase Sintering of W–Cu Nanocomposites
- Evaluation of Densification Mechanisms of Liquid-Phase Sintering
- Phase Transformation of a Dual Phase Al–Fe Alloy Prepared by Mechanical Alloying
- Discrete Element Simulation of Ceramic Powder Processing
- Strain Relaxation and Internal Friction in the Range of the Glass Transition
- A Thermodynamic Model of an Amorphous Grain Boundary Phase in Liquid-Phase Sintered β-SiAlON Ceramic
- Epitaxial Growth of Metals on (100) SrTiO3: The Influence of Lattice Mismatch and Reactivity
- Microstructure and Modifications of Cu/Al2O3 Interfaces
- Structural Transformations Induced by Swift Heavy Ions in Polysiloxanes and Polycarbosilanes
- Metastable Al–Nd–Ni and Stable Al–La–Ni Phase Equilibria
- Phase Equilibria of the Al–Nd and Al–Nd–Ni Systems
- System Pr –Pd–O: Phase Diagram and Thermodynamic Properties of Ternary Oxides Using Solid-State Cells with Special Features
- Calculation of Phase Equilibria in Candidate Solder Alloys
- Thermodynamic Assessment of the Zr–O Binary System
- Delaminating Layered Oxide Composites with Wavy Interfaces
- Contemporary Materials Issues for Advanced EB-PVD Thermal Barrier Coating Systems
- Monte Carlo Simulations of Strength Distributions of Brittle Materials – Type of Distribution, Specimen and Sample Size
- On the Optimization of the Microstructure in Powder Metallurgical Ag–SnO2–In2O3 Contact Materials
- Some New Aspects of Microstructural Design of β-Si3N4 Ceramics
- Ni-Based SOFC Anodes: Microstructure and Electrochemistry
- Effect of Copper Line Geometry and Process Parameters on Interconnect Microstructure and Degradation Processes
- Thermal Stability of Nanoscale Co/Cu Multilayers
- Methods for Characterising the Precipitation of Nanometer-Sized Secondary Hardening Carbides and Related Effects in Tool Steels
- Prediction of Local Strain and Hardness in Sheet Forming
- Novel in situ-Infiltrated Al2O3-Metal Composites
- Influence of Microstructure and Impurities on Thermal Conductivity of Aluminium Nitride Ceramics
- Notifications/Mitteilungen
- Personelles/Personal
- Bücher/Books
- Tagungen/Conferences