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Deposition of ceramic materials from aqueous solution induced by organic templates

  • J. Bill EMAIL logo , R. C. Hoffmann , T. M. Fuchs and F. Aldinger
Published/Copyright: January 31, 2022
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 93 Issue 5

Abstract

Besides conventional high-temperature sintering processes for the preparation of ceramics, synthesis routes like chemical and physical vapor phase deposition or molecular beam epitaxy as well as sol-gel and polymer thermolysis carried out at decreased temperatures gain in significance. Such a trend is especially pronounced in the case of the deposition of oxide-based solids from aqueous solutions induced by organic templates. This approach is inspired by biomineralization that in general involves the formation of well-structured and complex-shaped organic/inorganic composites by the deposition of an inorganic solid on an organic matrix that consists of biomolecules like proteins. It occurs at ambient conditions with respect to temperature, pressure and atmosphere.

The imitation of these processes by technical means is the deposition of thin oxide films from aqueous solutions in the presence of organic self-assembled monolayers. Besides general features of this technique like low synthesis temperatures, processing costs and equipment expenditure as well as the line-of-sight deposition suitable for coating complex shaped and/or temperature-sensitive substrates the characteristics of the films and their mechanisms of formation are discussed by way of the oxide systems TiO2, ZrO2 and ZnO.

Abstract

Neben den klassischen Sinterverfahren zur Herstellung von keramischen Materialien bei hohen und höchsten Temperaturen etablieren sich zunehmend Synthesewege wie chemische und physikalische Bedampfungsmethoden oder Molekularstrahlepitaxie sowie Sol-Gel-Verfahren und die Thermolyse prökeramischer Polymere, welche teilweise bei wesentlich niedrigeren Prozesstemperaturen durchgeführt werden. Besonders ausgepragt ist dieser Trend bei der Erzeugung von oxidischen Festkörpern mittels einer durch organische Template induzierten Abscheidung aus wässriger Lösung. Ansatzpunkte für derartige neue Verfahren liefert die Biomineralisation, die im Allgemeinen mit der Bildung eines anorganischen Materials durch eine Biopolymermatrix und der Entstehung komplexer anorganischorganischer Verbundmaterialien bei Umgebungsbedingungen verbunden ist.

Eine Nachahmung dieser material- und strukturbildenden Prozesse mit technischen Mitteln ist die Abscheidung dünner oxidischer Schichten aus wässriger Losung in Gegenwart synthetischer organischer Grenzflächen. Die Strukturmerkmale und möglichen Bildungsmechanismen der Schichtsysteme werden an oxidischen Systemen wie TiO2, ZrO2 oder ZnO besprochen. Darüber hinaus werden wesentliche Charakteristika dieses Verfahrens und dessen Unterschiede gegenüber den konventionellen Techniken aufgezeigt. Hierzu gehören neben der niedrigen Abscheidungstemperatur der vergleichsweise geringe apparative Aufwand und die Möglichkeit einer gleichförmigen Beschichtung auch komplex geformter Körper und insbesondere temperaturempfindlicher Substrate.

Keywords: Template-induced deposition; Self-assembled monolayers; Ceramic materials
Dr. J. Bill Max-Planck-Institut für Metallforschung Heisenbergstr. 3, 70569 Stuttgart, Germany Tel.: +49 711 689 3228 Fax: +49 711 689 3131

  1. We thank Prof. Mark De Guire for helpful discussions and for reviewing the manuscript. This project was supported by the Deutsche Forschungsgemeinschaft and the BMBF through grant 03C0294C/8. Polymers for ZnO deposition were kindly supplied by Dr. J. Rieger and Dr. M. Kroner, BASFAG, Ludwigshafen.

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Received: 2002-03-16
Published Online: 2022-01-31

© 2002 Carl Hanser Verlag, München

Articles in the same Issue

  1. Frontmatter
  2. Editorial
  3. Editorial
  4. Max-Planck-Institut für Metallforschung
  5. Articles/Aufsätze
  6. Towards a micromechanical understanding of biological surface devices
  7. Solid state phase transformation kinetics: a modular transformation model
  8. Electronic structure investigations of Ni and Cr films on (100)SrTiO3 substrates using electron energy-loss spectroscopy
  9. Surface magnetization reversal of sputtered CrO2
  10. Magnetic imaging with full-field soft X-ray microscopy
  11. Dislocation dynamics in sub-micron confinement: recent progress in Cu thin film plasticity
  12. Fatigue behavior of polycrystalline thin copper films
  13. Grain growth in magnetron-sputtered nickel films
  14. Thin Pd films on SrTiO3 (001) substrates: ab initio local-density-functional theory
  15. Coupled grain boundary and surface diffusion in a polycrystalline thin film constrained by substrate
  16. Gallium segregation at grain boundaries in aluminium
  17. Current work at the Stuttgart UHV diffusion bonding facility
  18. Bonding between Cu and α-Al2O3
  19. Compressive deformation of niobium sandwich-bonded to alumina
  20. SiO2-coated carbon nanotubes: theory and experiment
  21. Simulation of solidification structures of binary alloys
  22. Gaseous nitriding of iron-chromium alloys
  23. Deposition of ceramic materials from aqueous solution induced by organic templates
  24. Notifications/Mitteilungen
  25. Personen
  26. Books
  27. Information
  28. DGM Further Training
https://doi.org/10.3139/ijmr-2002-0079
Keywords for this article
Template-induced deposition; Self-assembled monolayers; Ceramic materials

Articles in the same Issue

  1. Frontmatter
  2. Editorial
  3. Editorial
  4. Max-Planck-Institut für Metallforschung
  5. Articles/Aufsätze
  6. Towards a micromechanical understanding of biological surface devices
  7. Solid state phase transformation kinetics: a modular transformation model
  8. Electronic structure investigations of Ni and Cr films on (100)SrTiO3 substrates using electron energy-loss spectroscopy
  9. Surface magnetization reversal of sputtered CrO2
  10. Magnetic imaging with full-field soft X-ray microscopy
  11. Dislocation dynamics in sub-micron confinement: recent progress in Cu thin film plasticity
  12. Fatigue behavior of polycrystalline thin copper films
  13. Grain growth in magnetron-sputtered nickel films
  14. Thin Pd films on SrTiO3 (001) substrates: ab initio local-density-functional theory
  15. Coupled grain boundary and surface diffusion in a polycrystalline thin film constrained by substrate
  16. Gallium segregation at grain boundaries in aluminium
  17. Current work at the Stuttgart UHV diffusion bonding facility
  18. Bonding between Cu and α-Al2O3
  19. Compressive deformation of niobium sandwich-bonded to alumina
  20. SiO2-coated carbon nanotubes: theory and experiment
  21. Simulation of solidification structures of binary alloys
  22. Gaseous nitriding of iron-chromium alloys
  23. Deposition of ceramic materials from aqueous solution induced by organic templates
  24. Notifications/Mitteilungen
  25. Personen
  26. Books
  27. Information
  28. DGM Further Training
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