Electrochemical behaviour of iron and AISI 304 stainless steel in simulated acid rain solution
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Zora Pilić
Abstract
The growth mechanism and properties of the oxide films on iron and AISI 304 stainless steel were studied in simulated acid rain (pH 4.5) by means of electrochemical techniques and atomic absorption spectrometry. The layer-pore resistance model was applied to explain a potentiodynamic formation of surface oxides. It was found that the growth of the oxide film on iron takes place by the low-field migration mechanism, while that on the stainless steel takes place by the high-field mechanism. Kinetic parameters were determined. Impedance measurements revealed that Fe surface film has no protective properties at the open circuit potential, while the resistance of stainless steel oxide film is very high. The concentration of the metallic ions released into solution and measured by atomic absorption spectroscopy was in accordance with the results obtained from the electrochemical techniques.
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© 2016, Carl Hanser Verlag, München
Articles in the same Issue
- Contents
- Contents
- Original Contributions
- A metastable phase diagram for the dynamic transformation of austenite at temperatures above the Ae3
- Experimental investigation of phase equilibria in the Co–Ni–Zr ternary system
- Phase equilibria of the Ni–Sb–Zn system at 600 °C
- High frequency cycling behaviour of three AZ magnesium alloys – microstructural characterisation
- Influence of auxetic foam in quasi-static axial crushing
- Electrochemical behaviour of iron and AISI 304 stainless steel in simulated acid rain solution
- Mechanochemical synthesis of CaMoO4 nanoparticles: kinetics and characterization
- Synthesis and characterization of iron oxide nanoparticles prepared hydrothermally at different reaction temperatures and pH
- Influence of SPS parameters on the density and hardness of zinc selenide
- Investigation into the kinetic behavior of molten aluminum pressureless infiltration into SiC preforms
- Review
- Centrifugal casting technique baseline knowledge, applications, and processing parameters: overview
- People
- Prof. Dr.-Ing. Jürgen Hirsch on the occasion of his 65th birthday
- DGM News
- DGM News
Articles in the same Issue
- Contents
- Contents
- Original Contributions
- A metastable phase diagram for the dynamic transformation of austenite at temperatures above the Ae3
- Experimental investigation of phase equilibria in the Co–Ni–Zr ternary system
- Phase equilibria of the Ni–Sb–Zn system at 600 °C
- High frequency cycling behaviour of three AZ magnesium alloys – microstructural characterisation
- Influence of auxetic foam in quasi-static axial crushing
- Electrochemical behaviour of iron and AISI 304 stainless steel in simulated acid rain solution
- Mechanochemical synthesis of CaMoO4 nanoparticles: kinetics and characterization
- Synthesis and characterization of iron oxide nanoparticles prepared hydrothermally at different reaction temperatures and pH
- Influence of SPS parameters on the density and hardness of zinc selenide
- Investigation into the kinetic behavior of molten aluminum pressureless infiltration into SiC preforms
- Review
- Centrifugal casting technique baseline knowledge, applications, and processing parameters: overview
- People
- Prof. Dr.-Ing. Jürgen Hirsch on the occasion of his 65th birthday
- DGM News
- DGM News
