Startseite Technik Thermodynamic properties of cerium molybdate
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Thermodynamic properties of cerium molybdate

  • Ai Nozaki , Masao Morishita , Yoshiki Kinoshita und Hiroaki Yamamoto
Veröffentlicht/Copyright: 7. August 2019
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 110 Heft 8

Abstract

Ce2(MoO4)3 is a harmful phase formed in waste glasses from nuclear fuel. To determine the third-law entropy of Ce2(MoO4)3, the isobaric heat capacities, Cp,m°, were measured with a relaxation-method instrument at 2–300 K. The standard entropy, Δ0TSm°, at 298.15 K was determined with fitting functions including the Debye–Einstein formula including electronic and spin-wave terms. The Néel temperature, TN, was estimated by extrapolation from the magnetic term in this fitting function. The phase stability of Ce2(MoO4)3 is discussed in terms of its standard Gibbs energy of formation, ΔfGm°, which was derived by combining the values for Sm°determined in this study with reference data for the standard enthalpy of formation, ΔfHm°.

Keywords: Thermodynamic properties; Heat capacity; Nuclear fuel waste glass; Fission product; Yellow phase
∗Correspondence address, Dr. Ai Nozaki, Department of Chemical Engineering and Materials Science, University of Hyogo, 2167 Shosha, Himeji, 6771-2201, Japan, Tel: +81-79-267-4005, e-mail:

References

[1] M.E.Ragoussi, S.Brassinnes: Radiochim. Acta103 (2015) 679–685. 10.1515/ract-2015-2392Suche in Google Scholar

[2] H.Gamsjäger, J.Bugajski, T.Gajda, R.J.Lemire, W.Preis: Chemical Thermodynamics of Nickel, Nuclear Energy Agency, Organization for Economic Co-operation, Develpopment, Eds., Vol. 6, Chemical Thermodynamics, North Holland Elsevier Science Publisher B.V., Amsterdam (2005) 44.Suche in Google Scholar

[3] M.Morishita, H.Houshiyama: Mater. Trans.56 (2015) 545–549. 10.2320/matertrans.M2014470Suche in Google Scholar

[4] H.Gamsjäger, M.Morishita: Pure Appl. Chem.87 (2015) 461–476. 10.1515/pac-2014-1105Suche in Google Scholar

[5] M.Morishita, M.Fukushima, H.Houshiyama: Mater. Trans.57 (2016) 46–51. 10.2320/matertrans.M2015189Suche in Google Scholar

[6] E.Gamsjäger, M.Morishita, H.Gamsjäger: Monatsh. Chem. Chem. Mon.147 (2016) 263–267. 10.1007/s00706-015-1588-3Suche in Google Scholar

[7] Y.Kinoshita, M.Morishita, A.Nozaki, H.Yamamoto: J. Jpn. Ins. Metal.81 (2017) 485–493. 10.2320/jinstmet.JAW201703Suche in Google Scholar

[8] M.Morishita, H.Houshiyama, Y.Kinoshita, A.Nozaki, H.Yamamoto: Mater. Trans58 (2017) 868. 10.2320/matertrans.M2017005Suche in Google Scholar

[9] M.Morishita, Y.Kinoshita, H.Houshiyama, A.Nozaki, H.Yamamoto: J. Chem. Thermodyn.114 (2017) 30–43. 10.1016/j.jct.2017.05.021Suche in Google Scholar

[10] M.Morishita, Y.Kinoshita, H.Tanaka, A.Nozaki, H.Yamamoto: Monatsh. Chem. Chem. Mon.149 (2018) 341–356. 10.1007/s00706-017-2128-0Suche in Google Scholar

[11] Y.Kinoshita, M.Morishita, A.Nozaki, H.Yamamoto: Mater. Trans.60 (2018) 111–120. 10.2320/matertrans.M2018305Suche in Google Scholar

[12] M.Morishita, Y.Kinoshita, A.Nozaki, H.Yamamoto: Appl. Geochem.98 (2018) 310–320. 10.1016/j.apgeochem.2018.08.023Suche in Google Scholar

[13] M.Morishita, A.Navrotsky, M.C.Wilding: J. Am. Ceram. Soc.87 (2004) 1550–1555. 10.1111/j.1551-2916.2004.01550.xSuche in Google Scholar

[14] W.Haller, D.H.Blackburn, F.E.Wagstaff, R.J.Charles: J. Am. Ceram. Soc.53 (1970) 34–39. 10.1111/j.1151-2916.1970.tb11995.xSuche in Google Scholar

[15] Y.Kawamoto, K.Clemens, M.Tomozawa: J. Am. Ceram. Soc.64 (1981) 292–296. 10.1111/j.1151-2916.1981.tb09605.xSuche in Google Scholar

[16] H.Wakabayashi, S.Fukumoto, H.Yanaka, R.Terai: Yogyo-Kyokai-Shi95 (1987) 486. 10.2109/jcersj1950.95.1101_486Suche in Google Scholar

[17] N.C.Hyatt, R.J.Short, R.J.Hand, W.E.Lee: Ceram. Trans.168 (2005) 179–187.Suche in Google Scholar

[18] M.Morishita, K.Koyama: Z. Metallkd.94 (2003) 967–971. 10.3139/146.030967Suche in Google Scholar

[19] M.Morishita, K.Koyama, K.Tsuboki: Z. Metallkd.95 (2004) 708–712. 10.3139/146.018007Suche in Google Scholar

[20] M.Morishita, K.Koyama, S.Shikata, M.Kusumoto: Metallkd. Mater. Trans.B 35 (2004) 891–895. 10.1007/s11663-004-0083-8Suche in Google Scholar

[21] M.Morishita, K.Koyama, S.Shikata, M.Kusumoto: Z. Metallkd.96 (2005) 32–37. 10.3139/146.018072Suche in Google Scholar

[22] M.Morishita, H.Yamamoto, K.Tsuboki, Y.Matsumoto: Mater. Trans.47 (2006) 1555–1559. 10.2320/matertrans.47.1555Suche in Google Scholar

[23] M.Morishita, H.Yamamoto, M.Kodera, K.Ikeda, S.Miura, Y.Yamada: Thermochim. Acta526 (2011) 90–98. 10.1016/j.tca.2011.08.025Suche in Google Scholar

[24] M.Morishita, K.Ikeda, N.Nishimura, S.Miura, Y.Yamada: J. Phys. Chem.C 116 (2012) 20489–20495. 10.1021/jp301259nSuche in Google Scholar

[25] M.Morishita, H.Yamamoto, S.Shikada, M.Kusumoto, Y.Matsumoto, A.Onoue, N.Nishimura, H.Ohtani: Int. J. Quantum Chem.109 (2009) 2695–2705. 10.1002/qua.22060Suche in Google Scholar

[26] M.Morishita, H.Yamamoto, S.Shikada, M.Kusumoto, Y.Matsumoto: Mater. Trans.51 (2010) 1705–1708. 10.2320/matertrans.MAW201024Suche in Google Scholar

[27] S.Dash, N.K.Shukla: J. Therm. Anal. Calorim.112 (2013) 193–200. 10.1007/s10973-012-2850-0Suche in Google Scholar

[28] R.Pankajavalli, O.M.Sreedharan: J. Nucl. Mater.172 (1990) 151–154. 10.1016/0022-3115(90)90432-MSuche in Google Scholar

[29] M.S.Samant, S.R.Bharadwaj, A.S.Kerkar, S.R.Dharwadkar: J. Nucl. Mater.200 (1993) 157–161. 10.1016/0022-3115(93)90325-SSuche in Google Scholar

[30] Z.Singh, S.Dash, R.Prasad, V.Venugopal: J. Alloys Compd.244 (1996) 85–89. 10.1016/S0925-8388(96)02429-2Suche in Google Scholar

[31] M.Morishita, A.Navrotsky: J. Am. Ceram. Soc.86 (2003) 1927–1932. 10.1111/j.1151-2916.2003.tb03583.xSuche in Google Scholar

[32] K.Koyama, M.Morishita, T.Harada, N.Maekawa: Metall. Mater. Trans. B,34 (2003) 653–659. 10.1007/s11663-003-0036-7Suche in Google Scholar

[33] S.Dash, Z.Singh, N.D.Dahale, R.Prasad, V.Venugopal: J. Alloys Compd.302 (2000) 75–81. 10.1016/s0925-8388(99)00822-1Suche in Google Scholar

[34] E.V.Suleimanov, A.V.Golubev, E.V.Alekseev, C.A.Geiger, W.Depmeier, V.G.Krivovichev: J. Chem. Thermodyn.42 (2010) 873–878. 10.1016/j.jct.2010.02.011Suche in Google Scholar

[35] G.Chattopadhyay, S.N.Tripathi, A.S.Kerkar: J. Am. Ceram. Soc.67 (1984) 610–614. 10.1111/j.1151-2916.1984.tb19604.xSuche in Google Scholar

[36] S.N.Tripathi, G.Chattopadhyay, A.S.Kerkar, M.S.Chandrasekharaiah: J. Am. Ceram. Soc.68 (1985) 232–235. 10.1111/j.1151-2916.1985.tb15314.xSuche in Google Scholar

[37] Q.Huang, J.Xu, W.Li: Solid State Ionics32–33 (1989) 244–249. 10.1016/0167-2738(89)90228-2Suche in Google Scholar

[38] J.S.Hwang, K.J.Lin, C.Tien: Review of Scientific Instruments,68 (1997) 94–101. 10.1063/1.1147722Suche in Google Scholar

[39] J.C.Lashley, M.F.Hundley, A.Migliori, J.L.Sarrao, P.G.Pagliuso, T.W.Darling, M.Jaime, J.C.Cooley, W.L.Hults, L.Morales, D.J.Thoma, J.L.Smith, J.Boerio-Goates, B.F.Woodfield, G.R.Stewart, R.A.Fisher, N.E.Phillips: Cryogenics43 (2003) 369–378. 10.1016/S0011-2275(03)00092-4Suche in Google Scholar

[40] Q.Shi, T.J.Park, J.Schliesser, A.Navrotsky, B.F.Woodfield: J. Chem. Thermodyn.72 (2014) 77–84. 10.1016/j.jct.2014.01.021Suche in Google Scholar

[41] M.Okaji: Teion-Kougaku36 (2001) 46–50. 10.2221/jcsj.36.46Suche in Google Scholar

[42] Q.Shi, L.Zhang, M.E.Schlesinger, J.Boerio-Goates, B.F.Woodfield: J. Chem. Thermodyn.62 (2013) 35–42. 10.1016/j.jct.2013.02.017Suche in Google Scholar

[43] J.M.Schliesser, S.J.Smith, G.Li, L.Li, T.F.Walker, T.Parry, J.Boerio-Goates, B.F.Woodfield: J. Chem. Thermodyn.81 (2015) 311–322. 10.1016/j.jct.2014.08.002Suche in Google Scholar

[44] L.Wu, J.Schliesser, B.F.Woodfield, H.Xu, A.Navrotsky: J. Chem. Thermodyn.93 (2016) 1–7. 10.1016/j.jct.2015.09.019Suche in Google Scholar

[45] C.Ma, Q.Shi, B.F.Woodfield, A.Navrotsky: J. Chem. Thermodyn.60 (2013) 191–196. 10.1016/j.jct.2013.01.004Suche in Google Scholar

[46] J.E.Gordon, C.Marcenat, J.P.Franck, I.Isaac, G.Zhang, R.Lortz, C.Meingast, F.Bouquet, R.A.Fisher, N.E.Phillips: Phys. Rev.B 65 (2001). 10.1103/PhysRevB.65.024441Suche in Google Scholar

[47] M.Dixon, F.E.Hoare, T.M.Holden, D.E.Moody: The Low Temperature Specific Heats of Some Pure Metals (Cu, Ag, Pt, Al, Ni Fe Co), Proc. Royal Society of London,Vol. 285, London (1965) 561–580. 10.1098/rspa.1965.0125Suche in Google Scholar

[48] C.Kittel: Elementary Solid State Physics, John Wiley & Sons. Inc., New York (1962) 45–65.Suche in Google Scholar

[49] T.H.K.Barron, G.K.White: Heat Capacity and Thermal Expansion at Low Temperatures, Plenum Publishers, New York (1999) 234. 10.1007/978-1-4615-4695-5Suche in Google Scholar

[50] K.K.Kelley, E.G.King: Contribution to the Data Theoretical Metallurgy, Part 16., Bur. Mines Invest. Bull.592 (1961) 1–149.Suche in Google Scholar

[51] J.M.D.Coey, S.Von Molnar, A.Torressen: J. Less Common Met.151 (1989) 191–194. 10.1016/0022-5088(89)90316-0Suche in Google Scholar

[52] M.Morishita, K.Koyama, T.Shiraga: Microelectronic Engineering81 (2005) 382–388. 10.1016/j.mee.2005.03.037Suche in Google Scholar

[53] K.Niira: Phys. Rev.117 (1960) 129–133. 10.1103/PhysRev.117.129Suche in Google Scholar

[54] R.A.Fisher, F.Bouquet, N.E.Phillips, J.P.Franck, G.Zhang, J.E.Gordon, C.Marcenat: Phys. Rev.B 64 (2001) 134425. 10.1103/PhysRevB.64.134425Suche in Google Scholar

[55] C.L.Snow, Q.Shi, J.Boerio-Goates, B.F.Woodfield: J. Phys. Chem.C 114 (2010) 21100–21108. 10.1021/jp1072704Suche in Google Scholar

[56] F.J.Morin, J.P.Maita: Phys. Rev.129 (1963) 1115–1120. 10.1103/PhysRev.129.1115Suche in Google Scholar

[57] L.M.Khriplovich, I.E.Paukov: J. Chem. Therm.15 (1983) 333–337. 10.1016/0021-9614(83)90062-9Suche in Google Scholar

[58] J.R.Taylor: An Introduction to Error Analysis: The Study of Uncertainty in Physical Measurement. Oxford University Press, Oxford (1982).Suche in Google Scholar

[59] J.M.Lock: Proc. Phys. Soc. London Sect.B 70 (1957) 566–576. 10.1088/0370-1301/70/5/303Suche in Google Scholar

[60] T.Miyake, H.Akai: J. Phys. Soc. Jpn.87 (2018) 41009. 10.7566/JPSJ.87.041009Suche in Google Scholar

[61] J.F.Herbst, L.G.Hector: J. Alloys Compd.693 (2017) 238–244. 10.1016/j.jallcom.2016.09.138Suche in Google Scholar

[62] W.W.Weller, E.G.King: Bur. Mines Rep. Invest.6147 (1963).Suche in Google Scholar

[63] D.L.Martin: Phys. Rev.B 8 (1973) 5357–5360. 10.1103/PhysRevB.8.5357Suche in Google Scholar

[64] R.Stevens, J.Boerio-Goates: J. Chem. Thermodyn.36 (2004) 857–863. 10.1016/j.jct.2004.06.008Suche in Google Scholar

[65] R.Sabbah, A.Xu-Wu, J.S.Chickos, M.L.P.Leitão, M.V.Roux, L.A.Torres: Thermochim. Acta331 (1999) 93–204. 10.1016/S0040-6031(99)00009-XSuche in Google Scholar

[66] I.Barin: Thermochemical Data of Pure Substance, Part II, VCH Verlag (1989) 1044.Suche in Google Scholar

[67] D.D.Wagman, W.H.Evans, V.B.Parker, R.H.Schumm, I.Halow, S.M.Bailey, K.L.Churney, R.L.Nuttall: J. Phys. Chem. Ref. Data11 (1982) 234.Suche in Google Scholar

[68] A.P.Zhidikowa, S.D.Malinin: Geokhimiya (1972) 28.Suche in Google Scholar

[69] M.E.Essington: Environ. Sci. Technol.24 (1990) 214. 10.1021/es00072a010Suche in Google Scholar

[70] B.Grambow, R.Müller, A.Rother: Radiochim. Acta58–59 (1992). 10.1524/ract.1992.5859.1.71Suche in Google Scholar

[71] A.R.Felmy, D.Rai, M.J.Mason: J. Solution Chem.21 (1992) 525–532. 10.1007/bf00649561Suche in Google Scholar

[72] H.Gamsjäger: Pure Appl. Chem.85 (2013) 2059–2076. 10.1351/pac-con-13-01-04Suche in Google Scholar

[73] A.R.Felmy, D.Rai, M.J.Mason, R.W.Fulton: Radiochim. Acta69 (1995) 177–183. 10.1524/ract.1995.69.3.177Suche in Google Scholar

Received: 2018-11-13
Accepted: 2019-03-05
Published Online: 2019-08-07
Published in Print: 2019-08-12

© 2019, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Dendritic solidification of highly undercooled dilute alloys
  5. Dendritic structure formation of magnesium alloys for the manipulation of corrosion properties: Part 2 – corrosion
  6. Thermodynamic properties of cerium molybdate
  7. A new approach to reduce springback in sheet metal bending using digital image correlation
  8. Effects of minor La and Ce additions on microstructure and mechanical properties of A201 alloy
  9. Strengthening and toughening of laminated TiAl composite sheets by titanium alloy layers and carbide particles
  10. A fractal analysis for the microstructures of β-SiC films
  11. Synthesis of La2(Zr0.7Ce0.3)2O7 nanopowder using a simple chemical precipitation method and heat treatment at high temperature
  12. Optimized microstructure with alumina micropowder and its effects on properties of phosphate-bonded castables
  13. Co-deposition and electrokinetic behavior of TiO2–WO3 nanoparticles under non-uniform AC field
  14. 3D nanoflower-structured TiO2 photoanode for efficient photoelectrochemical water splitting
  15. Short Communications
  16. Investigation of Al2O3/TiB2 ceramic cutting tool materials with the addition of core–shell structured Ni–B coated CaF2
  17. DGM News
  18. DGM News
https://doi.org/10.3139/146.111794
Schlagwörter für diesen Artikel
Thermodynamic properties; Heat capacity; Nuclear fuel waste glass; Fission product; Yellow phase

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Dendritic solidification of highly undercooled dilute alloys
  5. Dendritic structure formation of magnesium alloys for the manipulation of corrosion properties: Part 2 – corrosion
  6. Thermodynamic properties of cerium molybdate
  7. A new approach to reduce springback in sheet metal bending using digital image correlation
  8. Effects of minor La and Ce additions on microstructure and mechanical properties of A201 alloy
  9. Strengthening and toughening of laminated TiAl composite sheets by titanium alloy layers and carbide particles
  10. A fractal analysis for the microstructures of β-SiC films
  11. Synthesis of La2(Zr0.7Ce0.3)2O7 nanopowder using a simple chemical precipitation method and heat treatment at high temperature
  12. Optimized microstructure with alumina micropowder and its effects on properties of phosphate-bonded castables
  13. Co-deposition and electrokinetic behavior of TiO2–WO3 nanoparticles under non-uniform AC field
  14. 3D nanoflower-structured TiO2 photoanode for efficient photoelectrochemical water splitting
  15. Short Communications
  16. Investigation of Al2O3/TiB2 ceramic cutting tool materials with the addition of core–shell structured Ni–B coated CaF2
  17. DGM News
  18. DGM News
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2026 De Gruyter Brill
Heruntergeladen am 12.1.2026 von https://www.degruyterbrill.com/document/doi/10.3139/146.111794/html?lang=de
Button zum nach oben scrollen