Segregation of phosphorus to ferrite grain boundaries during transformation in an Fe–P alloy
-
Jeong In Kim
, Jun Hak Pak , Kyong-Su Park , Jae Hoon Jang , Dong-Woo Suh und Harshad Kumar Dharamshi Hansraj Bhadeshia
Abstract
A binary alloy of iron containing 0.17 wt.% of phosphorus has been heat treated under a variety of conditions in order to see whether the segregation of phosphorus to grain boundaries can be controlled. The alloy transforms fully into ferrite. It is found that the majority of solute found at the ferrite grain boundaries has its origins in the temperature range where phase transformation occurs, in other words, phosphorus that is accumulated and dragged with the growing ferrite–austenite transformation front. As a consequence, it cannot be suppressed using cooling rates as high as 400 K s−1.
References
[1] D.McLean: Grain Boundaries in Metals, Clarendon Press, Oxford (1957).Suche in Google Scholar
[2] M.Guttmann: Surf. Sci.53 (1975) 213. 10.1016/0039-6028(75)90125-9Suche in Google Scholar
[3] E.D.Hondros, M.P.Seah: Int. Met. Rev.22 (1977) 262. 10.1179/095066077791100390Suche in Google Scholar
[4] X.Tingdong, C.Buyuan: Prog. Mater. Sci.49 (2004) 109. 10.1016/S0079-6425(03)00019-7Suche in Google Scholar
[5] M.Vsianska, M.Sob: Prog. Mater. Sci.56 (2011) 817. 10.1016/j.pmatsci.2011.01.008Suche in Google Scholar
[6] H.K.D.H.Bhadeshia: Prog. Mater. Sci.57 (2012) 268. 10.1016/j.pmatsci.2011.06.002Suche in Google Scholar
[7] M.J.Xu, H.Lu, C.Yu, J.J.Xu, J.M.Chen: Sci. Technol. Weld. Joi.18 (2013) 184. 10.1179/1362171812Y.0000000097Suche in Google Scholar
[8] C.J.McMahonJr: Mater. Sci. Eng.25 (1976) 233. 10.1016/0025-5416(76)90075-6Suche in Google Scholar
[9] H.Erhart, H.J.Grabke: Met. Sci.15 (1981) 401. 10.1179/030634581790426877Suche in Google Scholar
[10] A.K.Cianelli, H.C.Feng, A.H.Ucisik, C.J.McMahon: Metall. Trans.A8 (1977) 1059. 10.1007/BF02667390Suche in Google Scholar
[11] G.L.Krasko, G.B.Olson: Solid State Commun.76 (1990) 247. 10.1016/0038-1098(90)90832-VSuche in Google Scholar
[12] A.V.Nikolaeva, Y.A.Nikolaev, Y.R.Kevorkyan: Atom. Energy91 (2001) 534. 10.1023/A:1012482419952Suche in Google Scholar
[13] S.Takayama, T.Ogura, S.C.Fu, C.J.McMahonJr: Metall. Trans.A11 (1980) 1513. 10.1007/BF02654515Suche in Google Scholar
[14] R.M.Horn, R.O.Ritchie: Metall. Trans.A9 (1978) 1039. 10.1007/BF02652208Suche in Google Scholar
[15] H.K.D.H.Bhadeshia, D.V.Edmonds: Met. Sci.13 (1979) 325.Suche in Google Scholar
[16] J.A.Peters, J.V.Bee, B.Kolk, G.G.Garrett: Acta Mater.37 (1995) 675. 10.1016/0001-6160(89)90251-4Suche in Google Scholar
[17] C.L.Li, D.J.Cheng, Z.H.Jin: Scr. Mater.35 (1996) 1147. 10.1016/1359-6462(96)00226-6Suche in Google Scholar
[18] J.L.Song, S.B.Lin, C.L.Yang, C.L.Fan, G.C.Ma: Sci. Technol. Weld. Joi.15 (2010) 213. 10.1179/136217110X12665048207610Suche in Google Scholar
[19] W.S.Ko, J.Y.Park, J.Y.Byun, J.K.Lee, N.J.Kim, B.J.Lee: Scr. Mater.68 (2012) 329. 10.1016/j.scriptamat.2012.11.005Suche in Google Scholar
[20] W.S.Ko, J.B.Jeon, C.H.Lee, J.K.Lee, B.J.Lee: Modell. Simul. Mater. Sci. Eng.21 (2013) 025012. 10.1088/0965-0393/21/2/025012Suche in Google Scholar
[21] L.Cheng, M.Enomoto, D.Hirakami, T.Tarui: ISIJ Int.53 (2013) 131. 10.2355/isijinternational.53.131Suche in Google Scholar
[22] P.Ghosh, C.Ghosh, R.K.Ray: ISIJ Int.49 (2009) 1080. 10.2355/isijinternational.49.1080Suche in Google Scholar
[23] S.Hong, S.Y.Shin, J.Lee, C.H.Lee, S.Lee: Mat. Sci. Eng.A564 (2013) 461. 10.1016/j.msea.2012.11.102Suche in Google Scholar
[24] S.Hong, J.Lee, K.S.Park, S.Lee: Mat. Sci. Eng.A589 (2014) 165. 10.1016/j.msea.2013.09.095Suche in Google Scholar
[25] J.R.Cowan, H.E.Evans, R.B.Jones, P.Bowen: Acta Mater.46 (1998) 6565. 10.1016/S1359-6454(98)00295-XSuche in Google Scholar
[26] R.W.Balluffi, S.M.Allen, W.C.Carter: Kinetics of Materials, John Wiley & Sons, Inc., New Jersey, USA (2005). 10.1002/0471749311Suche in Google Scholar
[27] B.C.De Cooman, J.G.Speer, I.Y.Pyshmintsev, N.Yoshinaga: Materials design: the key to modern steel products, GRIPS media, Harzburg (2007).Suche in Google Scholar
[28] J.Svoboda, F.D.Fischer, E.Gamsjäger: Acta Mater.50 (2002) 967. 10.1016/S1359-6454(01)00396-2Suche in Google Scholar
[29] J.W.Cahn: Acta Metall. Mater.10 (1962) 789. 10.1016/0001-6160(62)90092-5Suche in Google Scholar
[30] F.Christien, R.Le Gall: Surf. Sci.605 (2011) 1711. 10.1016/j.susc.2011.06.003Suche in Google Scholar
[31] C.R.Hutchinson, R.E.Hackenberg, G.J.Shiflet: Acta Mater.52 (2004) 3565. 10.1016/j.actamat.2004.04.010Suche in Google Scholar
[32] H.S.Zurob, D.Panahi, C.R.Hutchinson, Y.Bréchet, G.R.Purdy: Metall. Mater. Trans.A44 (2013) 3456. 10.1007/s11661-012-1479-8Suche in Google Scholar
[33] C.W.Sinclair, C.R.Hutchinson, Y.Bréchet: Metall. Mater. Trans.A38 (2007) 821. 10.1007/s11661-007-9106-9Suche in Google Scholar
[34] J.Svoboda, E.Gamsjäger, F.D.Fischer, Y.Liu, E.Kozeschnik: Acta Mater.59 (2011) 4775. 10.1016/j.actamat.2010.09.001Suche in Google Scholar
[35] J.Svoboda, J.Vala, E.Gamsjäger, F.D.Fischer: Acta Mater.54 (2006) 3953. 10.1016/j.actamat.2006.02.041Suche in Google Scholar
[36] H.N.Han, S.J.Kim, M.Kim, G.Kim, D.W.Suh, S.J.Kim: Philos. Mag.88 (2008) 1811. 10.1080/14786430802320119Suche in Google Scholar
[37] M.Hillert, G.Purdy: Acta Metall. Mater.26 (1978) 333. 10.1016/0001-6160(78)90132-3Suche in Google Scholar
[38] K.Smidoda, C.Gottschalk, H.Gleiter: Met. Sci.13 (1979) 146. 10.1179/msc.1979.13.3-4.146Suche in Google Scholar
[39] L.Chongmo, M.Hillert: Acta Metall. Mater.30 (1982) 1133. 10.1016/0001-6160(82)90007-4Suche in Google Scholar
© 2014, Carl Hanser Verlag, München
Artikel in diesem Heft
- Contents
- Contents
- Original Contributions
- On the orientation dependence of grain boundary triple line energy in Cu
- Hydrogen storage kinetics of as-cast and spun (Mg24Ni10Cu2)100–xNdx (x = 0–20) alloys
- Segregation of phosphorus to ferrite grain boundaries during transformation in an Fe–P alloy
- A study on the pseudoelasticity of low temperature aged and thermomechanically treated Ti-51.5 at.% Ni shape memory alloy
- Experimental determination and thermodynamic calculation of the phase equilibria in the Co–Mn–Ta system
- 800°C isothermal section of the Co–Cr–Mo–Si quaternary system
- Phase fraction mapping in the as-cast microstructure of extrudable 6xxx aluminum alloys
- Effect of thixoforming on morphological changes in iron-bearing intermetallics and mechanical properties of Al–Si–Cu alloys
- The superplasticity of friction stir processed Al-5Mg alloy with additions of scandium and zirconium
- Short Communications
- Anti-corrosion behaviour of VE/GF coatings on mild steel
- Intermetallic phase stabilized Al/Pb metallic emulsion
- Synthesis of ultrafine powder (W,Ti)C by microwave heating in a stream of argon
- Fabrication and properties of porous silicon nitride ceramics via microwave sintering
- DGM News
- Personal
Artikel in diesem Heft
- Contents
- Contents
- Original Contributions
- On the orientation dependence of grain boundary triple line energy in Cu
- Hydrogen storage kinetics of as-cast and spun (Mg24Ni10Cu2)100–xNdx (x = 0–20) alloys
- Segregation of phosphorus to ferrite grain boundaries during transformation in an Fe–P alloy
- A study on the pseudoelasticity of low temperature aged and thermomechanically treated Ti-51.5 at.% Ni shape memory alloy
- Experimental determination and thermodynamic calculation of the phase equilibria in the Co–Mn–Ta system
- 800°C isothermal section of the Co–Cr–Mo–Si quaternary system
- Phase fraction mapping in the as-cast microstructure of extrudable 6xxx aluminum alloys
- Effect of thixoforming on morphological changes in iron-bearing intermetallics and mechanical properties of Al–Si–Cu alloys
- The superplasticity of friction stir processed Al-5Mg alloy with additions of scandium and zirconium
- Short Communications
- Anti-corrosion behaviour of VE/GF coatings on mild steel
- Intermetallic phase stabilized Al/Pb metallic emulsion
- Synthesis of ultrafine powder (W,Ti)C by microwave heating in a stream of argon
- Fabrication and properties of porous silicon nitride ceramics via microwave sintering
- DGM News
- Personal