Experimental determination and thermodynamic calculation of the phase equilibria in the Co–Mn–Ta system
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Cuiping Wang
, Cancan Zhao , Zhong Lin and Xingjun Liu
Abstract
The phase equilibria in the Co-rich corner of the Co–Mn–Ta system were investigated by means of optical microscopy, electron probe microanalysis and X-ray diffraction. Six isothermal sections in the Co-rich corner of the Co–Mn–Ta ternary system at 1300°C, 1200°C, 1100°C, 1000°C, 900°C, 800°C were experimentally determined. On the basis of previous and present experimental data of the phase equilibria, the thermodynamic assessments of the Mn–Ta binary and Co–Mn–Ta ternary systems were carried out by using CALPHAD. The thermodynamic parameters of the Mn–Ta binary and the Co–Mn–Ta ternary systems have been optimized for reproducing the experimental results in each system. An agreement between the calculated results and experimental data is obtained.
References
[1] S.Iwasaki, K.Ouchi: IEEE Trans. Magn.14 (1978) 849. 10.1109/TMAG.1978.1059928Search in Google Scholar
[2] J.Sato, T.Omori, K.Oikawa, I.Ohnuma, R.Kainuma, K.Ishida: Science21 (2006) 90–91. 10.1126/science.1121738Search in Google Scholar
[3] G.Inden: Calphad5 (1981) 152.Search in Google Scholar
[4] M.Matsui, T.Ido, K.Sato, K.Adachi: J. Phys. Soc. Jpn.28 (1970) 791. 10.1143/JPSJ.28.791Search in Google Scholar
[5] O.Kitakami, N.Kikuchi, S.Okamoto: J. Magn. Magn. Mater.202 (1999) 305–310. 10.1016/S0304-8853(99)00368-6Search in Google Scholar
[6] J.C.Zhao, B.P.Bewlay, M.R.Jackson, L.A.Peluso, in: K.J.Hemker (Ed.), Structural Intermetallics 2001, TMS, Warrendale PA (2001) 483.Search in Google Scholar
[7] X.Q.Zhang, S.Y.Yang, C.C.Zhao, Y.Lu, X.J.Liu, C.P.Wang: Int. J. Mater. Res.104 (2013) 836–842. 10.3139/146.110935Search in Google Scholar
[8] X.Q.Zhang, S.Y.Yang, C.C.Zhao, Y.Lu, X.J.Liu, C.P.Wang: J. Phase. Equilib. Diff.34 (2013) 313–321. 10.1007/s11669-013-0237-ySearch in Google Scholar
[9] C.P.Wang, G.M.Tao, W.W.Xu, S.Y.Yang, C.C.Zhao, H.P.Xiong, X.J.Liu: J. Alloys Compd.574 (2013) 33–44. 10.1016/j.jallcom.2013.03.179Search in Google Scholar
[10] J.J.Ruan, C.C.Zhao, Y.Yu, S.Y.Yang, C.P.Wang, X.J.Liu: J. Alloys Compd.556 (2013) 280–286. 10.1016/j.jallcom.2012.11.140Search in Google Scholar
[11] X.J.Liu, X.Q.Zhang, S.Y.Yang, C.C.Zhao, C.P.Wang: Intermetallics31 (2012) 48–54. 10.1016/j.intermet.2012.06.008Search in Google Scholar
[12] C.C.Zhao, Y.Yu, X.J.Liu, C.P.Wang: J. Phase. Equilib. Diff.33 (2012) 189–194. 10.1007/s11669-012-0030-3Search in Google Scholar
[13] C.P.Wang, X.Q.Deng, W.J.Yu, Y.Yu, X.J.Liu: Intermetallics22 (2012) 129–135. 10.1016/j.intermet.2011.09.014Search in Google Scholar
[14] H.Okamoto: Desk Handbook-Phase Diagrams for Binary Alloys, ASM International, Materials Park (2000).Search in Google Scholar
[15] O.Redlich, A.T.Kister: Ind. Eng. Chem.40 (1948) 345. 10.1021/ie50458a036Search in Google Scholar
[16] A.T.Dinsdale: CALPHAD15 (1991) 317. 10.1016/0364-5916(91)90030-NSearch in Google Scholar
[17] M.Hillert, M.Jarl: CALPHAD2 (1978) 227–238. 10.1016/0364-5916Search in Google Scholar
[18] M.Hillert, B.Jansson, B.Sundman, J.Agren: Metall. Trans.A16 (1985) 261–266. 10.1007/BF02815307Search in Google Scholar
[19] S.Gorsse, G.J.Shiflet: CALPHAD26 (2002) 63–83. 10.1016/S0364-5916(02)00025-1Search in Google Scholar
[20] E.M.Savitskii, C.V.Kopetskii: Zh. Neorg. Khim.5 (1960) 2638–2640.Search in Google Scholar
[21] T.B.Massalski, P.R.Subramanian, H.Okamoto, L.Kacprzak: Binary alloy phase diagrams, 2nd Edition, ASM International, Materials Park (1990).Search in Google Scholar
[22] O.M.Barabash, Yu.N.Koval: Crystal Structures of Metals and Alloys, Naukova Dumka, Kiev (1986) 247–248.Search in Google Scholar
[23] B.Jansson: Thesis, Division of Physical Metallurgy, Royal Institute of Technology, Stockholm, Sweden (1984).Search in Google Scholar
[24] B.Sundman, B.Jansson, J.O.Andersson: CALPHAD9 (1985) 153. 10.1016/0364-5916(85)90021-5Search in Google Scholar
[25] L.Kaufman: CALPHAD15 (1991) 243–259. 10.1016/0364-5916(91)90004-4Search in Google Scholar
[26] W.M.Huang: CLAPHAD13 (1989) 231–242. 10.1016/0364-5916(89)90003-5Search in Google Scholar
[27] Z.K.Liu, Y.A.Chang: CALPHAD23 (1999) 339–356. 10.1016/S0364-5916(00)00005-5Search in Google Scholar
© 2014, Carl Hanser Verlag, München
Articles in the same Issue
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- On the orientation dependence of grain boundary triple line energy in Cu
- Hydrogen storage kinetics of as-cast and spun (Mg24Ni10Cu2)100–xNdx (x = 0–20) alloys
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Articles in the same Issue
- Contents
- Contents
- Original Contributions
- On the orientation dependence of grain boundary triple line energy in Cu
- Hydrogen storage kinetics of as-cast and spun (Mg24Ni10Cu2)100–xNdx (x = 0–20) alloys
- Segregation of phosphorus to ferrite grain boundaries during transformation in an Fe–P alloy
- A study on the pseudoelasticity of low temperature aged and thermomechanically treated Ti-51.5 at.% Ni shape memory alloy
- Experimental determination and thermodynamic calculation of the phase equilibria in the Co–Mn–Ta system
- 800°C isothermal section of the Co–Cr–Mo–Si quaternary system
- Phase fraction mapping in the as-cast microstructure of extrudable 6xxx aluminum alloys
- Effect of thixoforming on morphological changes in iron-bearing intermetallics and mechanical properties of Al–Si–Cu alloys
- The superplasticity of friction stir processed Al-5Mg alloy with additions of scandium and zirconium
- Short Communications
- Anti-corrosion behaviour of VE/GF coatings on mild steel
- Intermetallic phase stabilized Al/Pb metallic emulsion
- Synthesis of ultrafine powder (W,Ti)C by microwave heating in a stream of argon
- Fabrication and properties of porous silicon nitride ceramics via microwave sintering
- DGM News
- Personal