Home Technology Thermophysical properties of solid phase rhodium measured by the pulse calorimetry technique over a wide temperature range
Article
Licensed
Unlicensed Requires Authentication

Thermophysical properties of solid phase rhodium measured by the pulse calorimetry technique over a wide temperature range

  • Nenad Milošević
Published/Copyright: June 1, 2014
Become an author with De Gruyter Brill

Abstract

This paper presents experimental results on four thermophysical properties of pure polycrystalline rhodium samples over a wide temperature range. Specific heat capacity and specific electrical resistivity were measured from 300 to 2 200 K, while hemispherical total and normal spectral emissivities were measured from 1 200 to 2 200 K. All the properties were obtained by means of the electrical pulse calorimetry technique using specimens in the form of a thin rod, of about 2 mm in diameter and 200 mm in length. For necessary corrections, literature data on thermal linear expansion have been used. All the results are compared with available literature data and discussed.


*Correspondence address, Dr. Nenad Milošević, Institute VINČA, P.O. Box 522, 11001 Belgrade, Serbia, Tel.: +381 11 6308 609, Fax: +381 11 6453 670, E-mail:

References

[1] C.Hammond, in: D.Lide (Ed.), CRC Handbook of Chemistry and Physics, Section 4 – Properties of the Elements and Inorganic Compounds, CRC Press, Boca Raton, FL, (2005) 426.Search in Google Scholar

[2] J.Arblaster: Platinum Metals Rev.55 (2011) 124. 10.1595/147106711X555656Search in Google Scholar

[3] N.Milošević, M.Babić: Int. J. Mater. Res.104 (2013) 462. 10.3139/146.110889Search in Google Scholar

[4] A.Cezairliyan, in: K.Maglić, A.Cezairliyan, V.Peletsky (Eds.), Compendium of Thermophysical Property Measurement Methods, Vol. 2 – Recommended Measurement Techniques and Practices, Plenum Press, New York, (1992) 483.Search in Google Scholar

[5] A.Dobrosavljević, K.Maglić: High Temp. High Press.21 (1989) 411.Search in Google Scholar

[6] Y.Touloukian, Y.Kirby, R.Taylor, P.Desai: Thermophysical Properties of Matter, Vol. 12: Thermal expansion-metallic elements and alloys, IFI/Plenum Press, New York (1975) 286.10.1007/978-1-4757-1622-1_6Search in Google Scholar

[7] S.Glazkov: Teplophys. Vys. Temp.26 (1988) 501.10.1111/j.1468-2435.1988.tb00670.xSearch in Google Scholar

[8] F.Jaeger, E.Rosenbohm: Rec. Trav. Chim.51 (1932) 1. 10.1002/recl.19320510102Search in Google Scholar

[9] G.Ramanauskas, V.Chehovskoy, V.Tarasov: Teplofiz. Vys. Temp.26 (1986) 1227.Search in Google Scholar

[10] K.Clusius, C.Losa: Z. Naturforsch.A10 (1955) 545.Search in Google Scholar

[11] L.Filippov: Int. J. Heat Mass Transfer16 (1973) 865. 10.1016/0017-9310(73)90029-XSearch in Google Scholar

[12] Ya.Kraftmakher: Lecture notes on equilibium point defects and thermophysical properties of metals, World Scientific Publishing Co. Pte. Ltd., (2000). 10.1142/4279Search in Google Scholar

[13] P.-F.Paradis, T.Ishikawa, S.Yoda: Int. J. Thermophys.24 (2003) 1121. 10.1023/A:1025065304198Search in Google Scholar

[14] T.Hüpf, C.Cagran, B.Wilthan, G.Pottlacher: J. Phys.: Condens. Matter21 (2009) 125701. 10.1088/0953-8984/21/12/125701Search in Google Scholar PubMed

[15] R.Powel, R.Tye, M.Woodman: Platinum Met. Rev.6 (1962) 138.Search in Google Scholar

[16] W.Landensperger, D.Stark: Z. Physik180 (1964) 178. 10.1007/BF01380688Search in Google Scholar

[17] L.Binkele, M.Brunen: Thermal Conductivity, Electrical Resistivity and Lorentz Function Data for Metallic Elements in the Range 273 to 1500 K, Report Jül-3006, Forschungszentrum Jülich GmbH (1994) 115.Search in Google Scholar

[18] V.Mimeault, R.Hansen: J. Chem. Phys.45 (1966) 2240. 10.1063/1.1727917Search in Google Scholar

[19] E.Yolanda-García, D.Löffler: J. Chem. Eng. Data30 (1985) 304. 10.1021/je00041a020Search in Google Scholar

[20] A.Sorokin, L.Truhanova, L.Filippov: Teplofiz. Vys. Temp.2 (1969) 372.Search in Google Scholar

[21] S.Jain, B.Sharma, B.Reddy: J. Phys. D: Appl. Phys.5 (1972) 155. 10.1088/0022-3727/5/1/320Search in Google Scholar

[22] H.Betz, O.Olson, B.Schurin, J.Morris: WADC-TR-56-222 Pt2 (1957).Search in Google Scholar

[23] L.Whitney: Phys. Rev.48 (1935) 458. 10.1103/PhysRev.48.458Search in Google Scholar

[24] G.Burgess, R.Waltenberg: National Bur. Stds. Bull.11 (1915) 591. 10.6028/bulletin.264Search in Google Scholar

Received: 2013-10-17
Accepted: 2014-01-13
Published Online: 2014-06-01
Published in Print: 2014-06-12

© 2014, Carl Hanser Verlag, München

Downloaded on 6.12.2025 from https://www.degruyterbrill.com/document/doi/10.3139/146.111074/html
Scroll to top button