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High-activity of Pd catalyst supported on antimony tin oxide for hydrogen peroxide electroreduction

  • Limei Sun , Zongrui Liu , Yingrong Bao , Hongxia Li and Wuyunga Bao
Published/Copyright: June 1, 2014
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 105 Issue 6

Abstract

Pd electrocatalysts supported on antimony tin oxide and Vulcan XC-72 were both synthesized via a modified sodium borohydride reduction method. The catalysts were characterized by means of powder X-ray diffraction and cyclic voltammetry. Linear sweep voltammetry, open circuit potential curves and chronoamperometry were employed to evaluate the activities of the catalysts. The results show the particle size of Pd in the Pd electrocatalysts supported on antimony tin oxide catalyst is about 2.5 nm, which is smaller than that of the Pd electrocatalysts supported on Vulcan XC-72 (about 6.3 nm), and the surface area of the Pd electrocatalysts supported on antimony tin oxide electrode is larger than that of the Pd electrocatalysts supported on Vulcan XC-72 electrode. The Pd catalyst supported on antimony tin oxide shows superior performance to the catalyst supported on Vulcan XC-72.

Keywords: Palladium; Antimony tin oxide; Hydrogen peroxide; Electroreduction reaction; Fuel cell
*Correspondence address, Associate Professor Sun Limei, College of Chemistry and Chemical Engineering, Inner Mongolia University for the Nationalities, Tongliao, 028000, P. R. China, Tel: 86-15332970147, E-mail:

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Received: 2013-08-12
Accepted: 2014-01-13
Published Online: 2014-06-01
Published in Print: 2014-06-12

© 2014, Carl Hanser Verlag, München

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https://doi.org/10.3139/146.111066
Keywords for this article
Palladium; Antimony tin oxide; Hydrogen peroxide; Electroreduction reaction; Fuel cell

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Thermodynamic modeling of the In–Pt–Sb system
  5. Classical controlled rolling of low C steels microalloyed with Ti and Mo
  6. Development of carbide intermetallic layer by electric discharge alloying on AISI-D2 tool steel and its wear resistance
  7. Comparison of fatigue crack growth rate of selective laser sintered RapidSteel via computational fracture mechanics
  8. Wear resistance and fracture mechanics of WC–Co composites
  9. Thermal expansion behavior of CNT/Ag nanocomposite
  10. Thermophysical properties of solid phase rhodium measured by the pulse calorimetry technique over a wide temperature range
  11. Influence of Co3O4 addition on the ionic conductivity and microstructural properties of yttria-stabilized zirconia (8YSZ)
  12. High-activity of Pd catalyst supported on antimony tin oxide for hydrogen peroxide electroreduction
  13. Investigation of low k interfacial layer characteristics of LaAlO3 thin films grown on Si (100)
  14. In-situ catalytic growth of MgAl2O4 spinel whiskers in MgO–C refractories
  15. Short Communications
  16. Preparation and characterization of boron nitride/carbon fiber composite with high specific surface area
  17. Crevice corrosion resistance of high alloyed materials in 3.5 % NaCl solution
  18. Effect of grain size on the microstructure and mechanical properties of Mg-4Y-3Nd-0.5Zr alloy
  19. People
  20. Professor Ulrich Martin on his 65th birthday
  21. DGM News
  22. DGM News
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