Rheology and microstructure of polymer-modified asphalt nanocomposites
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Ali Topal
, Markanday Subramanian Sureshkumar , Burak Sengoz und Giovanni Polacco
Abstract
Asphalt modification with polymers has utilized the advantages of nanotechnology including nanoclays as one of the components in addition to polymers. This led to the metamorphosis of polymer-modified asphalts into a new class of material called polymer-modified asphalt nanocomposites which offer the cumulative characteristic features obtained by the polymer modification of asphalt as well as the innovative properties experienced from polymer nanocomposites. Polymer-modified asphalt nanocomposites including styrene butadiene and ethylene vinyl acetate have revealed additional features which were not available in polymer-modified asphalts. The compositional complexity provides a great challenge in addressing the structure–property relations prevailing in these materials. This paper describes microstructural features as determined by Qwin Plus Software analysis and the rheological properties on compositional changes.
Refrences
[1]H.J.Forbes: Nature135 (1935) 845.10.1038/135845a0Suche in Google Scholar
[2]J.Reed, D.Whiteoak, in: R.Hunter (Ed.) Shell Bitumen Handbook, Thomas Telford, London (2003).Suche in Google Scholar
[3]G.Polacco, J.Statsna, D.Biondi, L.Zanzotto: Curr. Opin. Colloid Interface Sci.11 (2006) 230. 10.1016/j.cocis.2006.09.001Suche in Google Scholar
[4]J.F.Masson, V.Leblond, J.Margeson: J. Microsc.221 (2006) 17. 10.1111/j.1365-2818.2006.01540.xSuche in Google Scholar PubMed
[5]M.B.De Moraes, R.B.Pereira, R.A.Simão, L.F.M.Leite: J. Microsc.239 (2010) 46. Suche in Google Scholar PubMed
[6]R.M.Ho, A.Adedeji, D.W.Giles, D.A.Hajduk, C.W.Macosko, F.S.Bates: J. Polym. Sci. Pol. Phys. B35 (1997) 2857. 10.1002/(SICI)1099-0488(199712)35:17<2857::AID-POLB10>3.0.CO;2-6Suche in Google Scholar
[7]I.A.Uskev: Vyosokomol Soedin, 2 (1960) 926.Suche in Google Scholar
[8]R.A.Vaia, H.Ishi, E.P.Giannelis: Chem. Mater.5 (1993) 1694. 10.1021/cm00036a004Suche in Google Scholar
[9]S.S.Ray, K.Okamoto: Prog. Polym. Sci.28 (2003) 1539. 10.1016/j.progpolymsci.2003.08.002Suche in Google Scholar
[10]M.E.ClaranceJr., L.G.Martin, W.E.Chester, P.G.Dennis: U.S. Pat. No. 5.652.284. (1977) 1.Suche in Google Scholar
[11]D.B.Ghile: Ph D Thesis, Delft University of Technology, Netherlands (2006) 1.Suche in Google Scholar
[12] M.S. Sureshkumar, D. Biondi, S. Fillipi, G. Polacco (Eds.) Proc. Int. Conf. on Nanotechnology and Advanced Materials (ICNAM), University of Bahrain, Bahrain (2009) 138.Suche in Google Scholar
[13]M.Alexander, P.Dubois: Mater. Sci. Eng. R.28 (2000) 1.Suche in Google Scholar
[14]I.J.Chin, T.Thurn-Albrech, H.C.Kim, T.P.Russell, J.Wang: Polymer42 (2001) 5947. 10.1016/S0032-3861(00)00898-3Suche in Google Scholar
[15]C.M.Kim, D.H.Lee, B.Hoffman, J.Kressler, G.Stoppelman: Polymer42 (2001) 1095. 10.1016/S0032-3861(00)00468-7Suche in Google Scholar
[16]C.Ouyang, S.Wang, S.Zhang, Y.Zhang: Polym. Degrad. Stab.87 (2005) 309. 10.1016/j.polymdegradstab.2004.08.014Suche in Google Scholar
[17]G.Polacco, P.Kříž, S.Filippi, J.Stastna, D.Biondi, L.Zanzotto: Eur. Polym. J.44 (2008) 3412. 10.1016/j.eurpolymj.2008.08.032Suche in Google Scholar
[18]B.Brule, Y.Brion, B.Tanguy: J. Assoc. Asphalt Paving. Technol.57 (1988) 41.Suche in Google Scholar
[19]G.Airey: Constr. Build. Mater.16 (2002) 473. 10.1016/S0950-0618(02)00103-4Suche in Google Scholar
[20]A.Okada, A.Usuki: Mater. Sci. Eng. C3 (1995) 109. 10.1016/0928-4931(95)00110-7Suche in Google Scholar
[21]R.Krishnamoorthi, K.Yurekli: Curr. Opin. Colloid Interface Sci.6 (2001) 464. 10.1016/S1359-0294(01)00121-2Suche in Google Scholar
© 2012, Carl Hanser Verlag, Munich
Artikel in diesem Heft
- Contents
- Contents
- Original Contributions
- Phase equilibria in the Gd–Ni binary and Mg–Ni–Gd ternary systems
- Thermodynamics of dilute binary solid solutions using the cluster variation method
- Thermal stability of coherent Pd/TiAl interfaces studied from first-principles calculations and experiments
- Electropulsing-induced phase transformations and their effects on the single point diamond turning of a tempered alloy AZ91
- Study of the mechanism of ductile-regime grinding of SiCp/Al composites using finite element simulation
- Investigations on laser welding of magnesium alloys
- Investigation of the surface of a laser-treated cast iron cylinder bore
- Solidification behaviour of an AA5754 Al alloy ingot cast with high impurity content
- Study of the structural evolution of crystalline zinc oxide films prepared by PLD
- Effects of sintering temperature on pore characterization and strength of porous cordierite–mullite ceramics by a pore-forming in-situ technique
- Sol–gel synthesis of Eu3+, Tb3+ co-doped Y2O3 scintillating nanopowders
- Morphological study of SiC coating developed on 2D carbon composites using MTS precursor in a hot-wall vertical reactor
- Self-assembling behavior and corrosion inhibition properties of TDPA films on differently structured surfaces of 2024 and 1060 aluminum alloys
- Photocatalytic activity of MnWO4 powder in highly effective hydrogen generation from H2O and H2O2
- Rheology and microstructure of polymer-modified asphalt nanocomposites
- Short Communications
- Microstructure and phase composition in a die cast Mg–Nd alloy containing Zn and Zr
- DGM News
- DGM News
Artikel in diesem Heft
- Contents
- Contents
- Original Contributions
- Phase equilibria in the Gd–Ni binary and Mg–Ni–Gd ternary systems
- Thermodynamics of dilute binary solid solutions using the cluster variation method
- Thermal stability of coherent Pd/TiAl interfaces studied from first-principles calculations and experiments
- Electropulsing-induced phase transformations and their effects on the single point diamond turning of a tempered alloy AZ91
- Study of the mechanism of ductile-regime grinding of SiCp/Al composites using finite element simulation
- Investigations on laser welding of magnesium alloys
- Investigation of the surface of a laser-treated cast iron cylinder bore
- Solidification behaviour of an AA5754 Al alloy ingot cast with high impurity content
- Study of the structural evolution of crystalline zinc oxide films prepared by PLD
- Effects of sintering temperature on pore characterization and strength of porous cordierite–mullite ceramics by a pore-forming in-situ technique
- Sol–gel synthesis of Eu3+, Tb3+ co-doped Y2O3 scintillating nanopowders
- Morphological study of SiC coating developed on 2D carbon composites using MTS precursor in a hot-wall vertical reactor
- Self-assembling behavior and corrosion inhibition properties of TDPA films on differently structured surfaces of 2024 and 1060 aluminum alloys
- Photocatalytic activity of MnWO4 powder in highly effective hydrogen generation from H2O and H2O2
- Rheology and microstructure of polymer-modified asphalt nanocomposites
- Short Communications
- Microstructure and phase composition in a die cast Mg–Nd alloy containing Zn and Zr
- DGM News
- DGM News