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Self-assembling behavior and corrosion inhibition properties of TDPA films on differently structured surfaces of 2024 and 1060 aluminum alloys

  • Jun-e Qu , Hai0ren Wang , Qiang Zhang and Li-xia Yang
Published/Copyright: June 11, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 103 Issue 10

Abstract

The adsorption and corrosion inhibition behavior of 1–tetradecylphosphonic acid self-assembled monolayers on the differently structured surfaces of 2024 and 1060 aluminum alloys were investigated by contact-angle measurement, potentiodynamic polarization, electrochemical impedance spectroscopy, and scanning electron microscopy coupled with energy-dispersive spectroscopy. The electrochemical experiments showed that a 4 h modification of 2024 and 1060 alloys resulted in a maximal inhibition efficiency. Independent of assembly time, the desorption of the tetradecylphosphonic acid molecules provoked by anodic polarization to a certain degree resulted in the acceleration of the anodic dissolution reaction. The inhibition of the self-assembled monolayers for the 1060 alloy was more prominent than for the 2024 alloy. This is consistent with the contact-angle values, supporting the conclusion that TDPA formed a more closely packed SAM on the surface of the 1060 alloy than of the 2024 alloy. Scanning electron microscopy/energy dispersive X-ray spectroscopy results directly revealed the inhibition effect of the monolayers on the primary corrosion stage of these two alloys.

Keywords: Aluminum alloys; Self-assembled monolayer; Adsorption; Corrosion
1 Correspondence address: Dr. Jun-e Qu, Faculty of Materials Science and Engineering, Hubei University, 368 Youyi street, 430062 Wuhan, PR China, Tel.: 86-027-88661729, Fax: 86-027-88663043, E-mail:

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Received: 2010-12-3
Accepted: 2012-1-31
Published Online: 2013-06-11
Published in Print: 2012-10-01

© 2012, Carl Hanser Verlag, Munich

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https://doi.org/10.3139/146.110753
Keywords for this article
Aluminum alloys; Self-assembled monolayer; Adsorption; Corrosion

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Phase equilibria in the Gd–Ni binary and Mg–Ni–Gd ternary systems
  5. Thermodynamics of dilute binary solid solutions using the cluster variation method
  6. Thermal stability of coherent Pd/TiAl interfaces studied from first-principles calculations and experiments
  7. Electropulsing-induced phase transformations and their effects on the single point diamond turning of a tempered alloy AZ91
  8. Study of the mechanism of ductile-regime grinding of SiCp/Al composites using finite element simulation
  9. Investigations on laser welding of magnesium alloys
  10. Investigation of the surface of a laser-treated cast iron cylinder bore
  11. Solidification behaviour of an AA5754 Al alloy ingot cast with high impurity content
  12. Study of the structural evolution of crystalline zinc oxide films prepared by PLD
  13. Effects of sintering temperature on pore characterization and strength of porous cordierite–mullite ceramics by a pore-forming in-situ technique
  14. Sol–gel synthesis of Eu3+, Tb3+ co-doped Y2O3 scintillating nanopowders
  15. Morphological study of SiC coating developed on 2D carbon composites using MTS precursor in a hot-wall vertical reactor
  16. Self-assembling behavior and corrosion inhibition properties of TDPA films on differently structured surfaces of 2024 and 1060 aluminum alloys
  17. Photocatalytic activity of MnWO4 powder in highly effective hydrogen generation from H2O and H2O2
  18. Rheology and microstructure of polymer-modified asphalt nanocomposites
  19. Short Communications
  20. Microstructure and phase composition in a die cast Mg–Nd alloy containing Zn and Zr
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