Startseite Technik Examination of phase transformations in the system Fe–N–C by means of nitrocarburising reactions and secondary annealing experiments; the α + ∊ two-phase equilibrium
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Examination of phase transformations in the system Fe–N–C by means of nitrocarburising reactions and secondary annealing experiments; the α + ∊ two-phase equilibrium

  • Marc Nikolussi , Andreas Leineweber , Ewald Bischoff und Eric Jan Mittemeijer
Veröffentlicht/Copyright: 23. Mai 2013
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 98 Heft 11

Abstract

The until now controversially discussed existence of the two-phase equilibrium α-Fe + ∊-Fe3(N, C)1+x in the ternary system Fe – N – C was proven by the investigation (optical microscopy, X-ray diffraction, Electron Backscatter Diffraction) of compound-layer microstructures generated by gaseous nitrocarburising of pure iron and subsequent secondary annealing experiments under static inert-gas atmosphere. The invariant transition reaction γ-Fe4N + Fe3C → α-Fe + ∊-Fe3(N, C)1+x could be shown to proceed at a (single) temperature (at constant pressure of 1 atm) between 833 K and 843 K.

Keywords: Iron nitrides; Nitriding; Nitrocarburising; Fe – N – C ternary phase diagram; Electron Backscatter Diffraction (EBSD)
* Correspondence address, Dr. Andreas Leineweber, Max Planck Institute for Metals Research, Heisenbergstraße 3, D-70569 Stuttgart, Germany, Tel.: +49 711 689 3365, Fax: +49 711 689 3312, E-mail:

References

[1] M.A.J.Somers: Heat Treat. Met.27 (2000) 92.Suche in Google Scholar

[2] P.M.Unterweiser, A.G.Gray (Eds.): Source Book on Nitriding, ASM, Metals Park, OH (1977).Suche in Google Scholar

[3] W.Schröter: Wiss. Z. d. Techn. Hochsch. Karl-Marx-Stadt24 (1982) 795.Suche in Google Scholar

[4] E.J.Mittemeijer, J.T.Slycke: Surf. Eng.12 (1996) 152.Suche in Google Scholar

[5] K.H.Jack: Proc. Roy. Soc. A195 (1948) 41.10.1098/rspa.1948.0101Suche in Google Scholar

[6] F.K.Naumann, G.Langenscheid: Arch. Eisenhüttenwesen36 (1965) 583.Suche in Google Scholar

[7] V.Raghavan: Trans. Indian Inst. Met.37 (1984) 293.Suche in Google Scholar

[8] X.Zuyao, L.Lin: Mat. Sci. Tec.3 (1987) 325.Suche in Google Scholar

[9] J.Slycke, L.Sproge, J.Ågren: Scand. J. Metallurgy17 (1988) 122.Suche in Google Scholar

[10] H.Du, M.Hillert: Z. Metallkde.82 (1991) 310.Suche in Google Scholar

[11] U.Huchel, J.Kunze: Härterei-Tech. Mitt.46 (1991) 351.Suche in Google Scholar

[12] H.Du: J. Phase Eq.14 (1993) 682.10.1007/BF02667880Suche in Google Scholar

[13] J.Kunze: Härterei-Tech. Mitt.51 (1996) 348.10.1515/htm-1996-510606Suche in Google Scholar

[14] D.Ge´rardin, H.Michel, J.P.Morniroli, M.Gantois: Mémoires Sci. Rev. Me´t.77 (1977) 457.Suche in Google Scholar

[15] D.Ge´rardin, H.Michel, M.Gantois: Scr. Metall.11 (1977) 557.Suche in Google Scholar

[16] J.Matauschek, H.Trenkler: Härterei-Tech. Mitt.32 (1977) 4.Suche in Google Scholar

[17] M.A.J.Somers, P.F.Colijn, W.G.Sloof, E.J.Mittemeijer: Z. Metallkd.81 (1990) 33.Suche in Google Scholar

[18] E.J.Mittemeijer, W.T.M.Straver, P.F.Colijn, P.J.van der Schaaf, J.A.van der Hoeven: Scr. Metall.14 (1980) 1189.Suche in Google Scholar

[19] M.A.J.Somers, E.J.Mittemeijer: Surf. Eng.3 (1987) 123.Suche in Google Scholar

[20] A.Wells, T.Bell: Heat Treat. Metals (1983) 39.Suche in Google Scholar

[21] A.Wells: Thin Sol. Films128 (1985) L33.10.1016/0040-6090(85)90347-5Suche in Google Scholar

[22] A.Wells: J. Mat. Sci.20 (1985) 2439.10.1007/BF00556072Suche in Google Scholar

[23] A.Leineweber, J.Aufrecht, E.J.Mittemeijer: Int. J. Mat. Res.97 (2006) 753.Suche in Google Scholar

[24] M.A.J.Somers, E.J.Mittemeijer: Härterei.Tech. Mitt.47 (1992) 5.Suche in Google Scholar

[25] H.Du, M.A.J.Somers, J.Ågren: Metall. Mater. Trans. A31 (2000) 195.Suche in Google Scholar

[26] H.C.F.Rozendaal, E.J.Mittemeijer, P.F.Colijn, P.J.van der Schaaf: Met. Trans. A14 (1983) 395.Suche in Google Scholar

[27] E.J.Mittemeijer, M.A.J.Somers: Surf. Eng.13 (1997) 483.Suche in Google Scholar

[28] T.Liapina, A.Leineweber, E.J.Mittemeijer: Scr. Mat.48 (2003) 1643.Suche in Google Scholar

[29] T.Gressmann, M.Nikolussi, A.Leineweber, E.J.Mittemeijer: Scr. Mat.55 (2006) 723.Suche in Google Scholar

[30] P.F.Colijn, E.J.Mittemeijer, H.C.F.Rozendaal: Z. Metallkd.74 (1983) 620.Suche in Google Scholar

[31] R.Chatterjee-Fischer: Wärmebehandlung von Eisenwerkstoffen, Expert-Verlag, Renningen-Malmsheim (1995).Suche in Google Scholar

[32] G.Petzow: Metallographic Etching, ASM International, Materials Park, Ohio (1999).Suche in Google Scholar

[33] T.Liapina, A.Leineweber, E.J.Mittemeijer, W.Kockelmann: Acta Mat.52 (2004) 173.Suche in Google Scholar

[34] T.Liapina, A.Leineweber, E.J.Mittemeijer: Metall. Mater. Trans. A37 (2006) 319.Suche in Google Scholar

[35] H.A.Wriedt, N.A.Gokcen, R.H.Nafziger: Bull. Alloy Phase Diagr.8 (1987) 355.Suche in Google Scholar

[36] A.Leineweber, T.Liapina, T.Gressmann, M.Nikolussi, E.J.Mittemeijer: Adv. Sci. Tec.46 (2006) 32.Suche in Google Scholar

[37] B.Predel, M.Hoch, M.Pool: Phase diagrams and heterogeneous equilibria, Springer-VerlagBerlin (2004).10.1007/978-3-662-09276-7Suche in Google Scholar

[38] H.-J.Spies, S.Böhmer: VDI – Ber. Nr.797 (1990) 245.Suche in Google Scholar

[39] T.Bell, in: L.E.Alban (Ed.), Metals Handbook, ASM International, Metals Park, Ohio (1981) 264.Suche in Google Scholar

Received: 2007-3-14
Accepted: 2007-8-20
Published Online: 2013-05-23
Published in Print: 2007-11-01

© 2007, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Professor Dr. phil. Dr. techn. e. h. Hellmut F. Fischmeister
  5. Basic
  6. Compressive deformation of lamellar microstructures – a short review
  7. Influence of external and internal length scale on the flow stress of copper
  8. Spinodal decomposition of cubic Ti1−xAlxN: Comparison between experiments and modeling
  9. Combined ab-initio and N-K, Ti-L2,3, V-L2,3 electron energy-loss near edge structure studies for TiN and VN films
  10. Gold-enhanced oxidation of silicon nanowires
  11. Numerical determination of parameterised failure curves for ductile structural materials
  12. Relaxation of semiconductor nanostructures using molecular dynamics with analytic bond order potentials*
  13. Examination of phase transformations in the system Fe–N–C by means of nitrocarburising reactions and secondary annealing experiments; the α + ∊ two-phase equilibrium
  14. Applied
  15. On the evolution of secondary hardening carbides in a high-speed steel characterised by APFIM and SANS
  16. Silicon nitride tools for hot rolling of high-alloyed steel and superalloy wires – load analysis and first practical tests
  17. Development of the unloading stiffness during cyclic plastic deformation of a high-strength aluminium alloy in different tempers
  18. Enhanced thermal stability of a cobalt–boron carbide nanocomposite by ion-implantation
  19. Experimental studies and thermodynamic simulation of phase transformations in high Nb containing γ-TiAl based alloys
  20. Kinetics of nanoscale structure development during Mg-vapour reduction of tantalum oxide
  21. On the interaction of ductile damage and materials softening of a Ni-base alloy during hot deformation
  22. Adhesive contact between flat punches with finite edge radius and an elastic half-space
  23. Notifications
  24. DGM News
https://doi.org/10.3139/146.101576
Schlagwörter für diesen Artikel
Iron nitrides; Nitriding; Nitrocarburising; Fe – N – C ternary phase diagram; Electron Backscatter Diffraction (EBSD)

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Professor Dr. phil. Dr. techn. e. h. Hellmut F. Fischmeister
  5. Basic
  6. Compressive deformation of lamellar microstructures – a short review
  7. Influence of external and internal length scale on the flow stress of copper
  8. Spinodal decomposition of cubic Ti1−xAlxN: Comparison between experiments and modeling
  9. Combined ab-initio and N-K, Ti-L2,3, V-L2,3 electron energy-loss near edge structure studies for TiN and VN films
  10. Gold-enhanced oxidation of silicon nanowires
  11. Numerical determination of parameterised failure curves for ductile structural materials
  12. Relaxation of semiconductor nanostructures using molecular dynamics with analytic bond order potentials*
  13. Examination of phase transformations in the system Fe–N–C by means of nitrocarburising reactions and secondary annealing experiments; the α + ∊ two-phase equilibrium
  14. Applied
  15. On the evolution of secondary hardening carbides in a high-speed steel characterised by APFIM and SANS
  16. Silicon nitride tools for hot rolling of high-alloyed steel and superalloy wires – load analysis and first practical tests
  17. Development of the unloading stiffness during cyclic plastic deformation of a high-strength aluminium alloy in different tempers
  18. Enhanced thermal stability of a cobalt–boron carbide nanocomposite by ion-implantation
  19. Experimental studies and thermodynamic simulation of phase transformations in high Nb containing γ-TiAl based alloys
  20. Kinetics of nanoscale structure development during Mg-vapour reduction of tantalum oxide
  21. On the interaction of ductile damage and materials softening of a Ni-base alloy during hot deformation
  22. Adhesive contact between flat punches with finite edge radius and an elastic half-space
  23. Notifications
  24. DGM News
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Gewinner des OpenAthens UX Award 2026
Gewinner des OpenAthens UX Award 2026
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2026 De Gruyter Brill
Heruntergeladen am 4.3.2026 von https://www.degruyterbrill.com/document/doi/10.3139/146.101576/html
Button zum nach oben scrollen