Startseite Solubilization and Thermodynamic Attributes of Nickel Phenanthroline Complex in Micellar Media of Sodium 2-Ethyl Hexyl Sulfate and Sodium Bis(2-ethyl hexyl) Sulfosuccinate
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Solubilization and Thermodynamic Attributes of Nickel Phenanthroline Complex in Micellar Media of Sodium 2-Ethyl Hexyl Sulfate and Sodium Bis(2-ethyl hexyl) Sulfosuccinate

  • Sadia Noor und Muhammad Abid Rashid
Veröffentlicht/Copyright: 13. November 2019
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 56 Heft 6

Abstract

Micellar solubilization and physicochemical behaviour of [Ni(phen)3]F2 EtOH · MeOH · 8 H2O complex in sodium 2-ethylhexyl sulfate and sodium bis(2-ethyl hexyl) sulfosuccinate is addressed in this paper. The interactions of surfactants in the solution of nickel complex were studied by UV-Vis spectroscopy and electrical conductivity. The extent of solubilization in terms of partitioning and binding parameters was determined by UV-Vis spectroscopy, whereas conductivity data were employed to calculate critical micellar concentration and other thermodynamic parameters of micellization. The value of critical micellar concentration increased in both surfactants due to structure breaking effect of nickel complex. The complex showed significant antioxidant radical scavenging and hemolytic activities, without any substantial cytotoxic activity against 3T3 cell line.

Kurzfassung

Die mizellare Solubilisierung und das physikochemische Verhalten des [Ni(phen)3]F2 EtOH · MeOH · 8 H2O-Komplexes in Natrium-2-ethylhexylsulfat und Natrium-bis-(2-ethylhexyl)sulfosuccinat werden in diesem Paper behandelt. Die Wechselwirkungen von Tensiden in der Nickelkomplexlösung wurden mittels UV-Vis-Spektroskopie und elektrischer Leitfähigkeit untersucht. Das Ausmaß der Solubilisierung hinsichtlich der Verteilungs- und Bindungsparameter wurde durch UV-Vis-Spektroskopie bestimmt, wohingegen Leitfähigkeitsdaten verwendet wurden, um die kritische Mizellenbildungskonzentration und weitere thermodynamische Parameter der Mizellenbildung zu berechnen. Der Wert der kritischen Mizellenbildungskonzentration stieg für beide Tenside aufgrund der strukturaufbrechenden Wirkung des Nickelkomplexes an. Der Komplex zeigte signifikante antioxidative Radikalfänger- und hämolytische Aktivitäten ohne wesentliche zytotoxische Aktivität gegenüber der 3T3-Zelllinie.

Key words: Nickel complex; anionic surfactants; solubilization; electrical conductivity; UV-Vis spectroscopy
Stichwörter: Nickelkomplex; anionische Tenside; Solubilisierung; elektrische Leitfähigkeit; UV-Vis-Spektroskopie
∗Correspondence address, Dr. Muhammad Abid Rashid, University of Agriculture, Department of Chemistry, Faisalabad, Pakistan, E-Mail:

Sadia Noor completed her M.Phil in Chemistry from University of Agriculture Faisalabad, Pakistan in 2013. Currently, she is conducting her research degree with Dr. Rashid on the intramolecular gold cyclized of o-alkyenyl systenes, synthesis of polysulfanes and solubilization of nickel complex. She also worked with Prof. George Baranay at Department of Chemistry university of Minnesota USA and with Prof. Roberto Sanz at Departmento de Química. Área de Química Orgánica. Universidad de Burgos, Burgos, Spain. She has contributed to six research publications. Her research is focused on the synthesis and characterization of gold catalyzed transformations, metal complexes, dyes and other organic complexes.

Dr. Muhammad Abid Rashid completed his doctoral degree with Prof. P. Langer in 2008 from “Institut für Chemie, Abteilung Organische Chemie Universität Rostock, Germany”. He also worked as research associate with Prof. Viqar Uddin Ahmad at HEJ Research Institute of Chemistry, University of Karachi, Pakistan since 2002 – 2006. Dr. Rashid was involved with Prof. Armido Studer as postdoctoral fellow at “Organische-Chemisches Institut Westfälische Wilhelms Universität Münster, Germany”. Dr. Rashid also pursued his post doctral studies with Prof. Ilhong Ryu at Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakia, Osaka, Japan and with Prof. Roberto Sanz at “Dpto. de Química. Área de Química Orgánica. Universidad de Burgos, Burgos, Spain”. Currently, he is working as Assistant Professor since 2011 at Department of Chemistry, University of Agriculture Faisalabad, Pakistan. He is author/co-author of 47 publications in reputed journals. His main research is based on the development of new methodologies in Organic synthesis. His group is also involved in solubilization of transition metal complexed/drugs with surfactants. He also successfully completed one project awarded by Higher Education Commission Pakistan. Concurrently, working on 02 more projects related to gold chemistry by Higher Education Commission Pakistan is going on. His main research interests include development of new methodology for the synthesis of pharmacological relevance molecules based on unusual intermediates, formulation of new drug delivery system and isolation and structure elucidation of natural products.

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Received: 2019-04-01
Accepted: 2019-07-04
Published Online: 2019-11-13
Published in Print: 2019-11-15

© 2019, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Dish Washing
  4. Potential of Near-Infrared Spectroscopy to Evaluate the Cleaning Performance of Dishwashing Processes
  5. Socio-demographic Differences in Washing-up Behaviour in Germany
  6. Physical Chemistry
  7. Dynamic Surface Properties of Eco-Friendly Cationic Saccharide Surfactants at the Water/Air Interface
  8. Dependence of Surface Tension on Surface Concentration in Ionic Surfactant Solutions and Influences of Supporting Electrolyte Therein
  9. Solubilization and Thermodynamic Attributes of Nickel Phenanthroline Complex in Micellar Media of Sodium 2-Ethyl Hexyl Sulfate and Sodium Bis(2-ethyl hexyl) Sulfosuccinate
  10. Novel Surfactants
  11. Synthesis and Properties of Novel Catanionic Surfactant Phosphonium Benzene Sulfonate
  12. A Micellar-Enhanced Spectrofluorimetric Method for the Determination of Ciprofloxacin in Pure Form, Pharmaceutical Preparations and Biological Samples
  13. Micellar Catalysis
  14. A Review on Micellar Catalyzed Oxidation Reactions of Organic Functional Groups in Aqueous Medium Using Various Transition Metals
  15. Application
  16. Application of Oxidative Fatty Acid Esters in Amino Acid Surfactants
  17. Environmental Chemistry
  18. Adsorptive Removal of Cetyltrimethyl Ammonium Bromide (CTAB) Surfactant from Aqueous Solution: Crossbreed Pilot Plant Membrane Studies
https://doi.org/10.3139/113.110653
Schlagwörter für diesen Artikel
Nickel complex; anionic surfactants; solubilization; electrical conductivity; UV-Vis spectroscopy

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Dish Washing
  4. Potential of Near-Infrared Spectroscopy to Evaluate the Cleaning Performance of Dishwashing Processes
  5. Socio-demographic Differences in Washing-up Behaviour in Germany
  6. Physical Chemistry
  7. Dynamic Surface Properties of Eco-Friendly Cationic Saccharide Surfactants at the Water/Air Interface
  8. Dependence of Surface Tension on Surface Concentration in Ionic Surfactant Solutions and Influences of Supporting Electrolyte Therein
  9. Solubilization and Thermodynamic Attributes of Nickel Phenanthroline Complex in Micellar Media of Sodium 2-Ethyl Hexyl Sulfate and Sodium Bis(2-ethyl hexyl) Sulfosuccinate
  10. Novel Surfactants
  11. Synthesis and Properties of Novel Catanionic Surfactant Phosphonium Benzene Sulfonate
  12. A Micellar-Enhanced Spectrofluorimetric Method for the Determination of Ciprofloxacin in Pure Form, Pharmaceutical Preparations and Biological Samples
  13. Micellar Catalysis
  14. A Review on Micellar Catalyzed Oxidation Reactions of Organic Functional Groups in Aqueous Medium Using Various Transition Metals
  15. Application
  16. Application of Oxidative Fatty Acid Esters in Amino Acid Surfactants
  17. Environmental Chemistry
  18. Adsorptive Removal of Cetyltrimethyl Ammonium Bromide (CTAB) Surfactant from Aqueous Solution: Crossbreed Pilot Plant Membrane Studies
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