Mass-transfer in pertraction of butyric acid by phosphonium ionic liquids and dodecane
-
Ján Marták
,
Štefan Schlosser
Abstract
Transport of butyric acid (BA) through a supported liquid membrane (SLM) containing phosphonium ionic liquid (IL) Cyphos IL-104 and dodecane occurs by two mechanisms. The first is related to the physical solubility of undissociated acid in dodecane in the form of a monomer or dimer and the second to the reactive extraction of acid by IL. Although the model of pertraction indicates that increasing the mean concentration of acid in the feed, c F,lmv, increases the participation of pertraction based on the physical solubility; in the tested range of c F,lmv from 0 kmol m−3 to 0.45 kmol m−3 it does not play an important role and at the highest c F,lmv value, less than 10 % of the overall BA transport were achieved. The presence of IL in SLM considerably increases the value of the overall mass transfer coefficient in pertraction at low BA concentrations. However, at c F,lmv > 0.4 kmol m−3 its values are similar for SLMs with and without IL. Compared to lactic acid, the pertraction of BA through the same SLM is about five times faster. Reactive transport of BA is connected with the back transport of water via reverse micelles decomposition and formation on the extraction and stripping interfaces.
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© 2011 Institute of Chemistry, Slovak Academy of Sciences
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Artikel in diesem Heft
- 5th conference on membrane science and technology PERMEA 2010
- A procedure for the determination of dichloromethane and tetrachloroethene in water using pervaporation and gas chromatography
- Modeling of diffusive transport of benzoic acid through a liquid membrane
- Comparison of ceramic capillary membrane and ceramic tubular membrane with inserted static mixer
- New approach to regeneration of an ionic liquid containing solvent by molecular distillation
- Mass-transfer in pertraction of butyric acid by phosphonium ionic liquids and dodecane
- Determination of carbon in solidified sodium coolant using new ICP-OES methods
- Interpretation of interactions of halogenated hydrocarbons with modified silica adsorbent coated with 3-benzylketoimine group silane
- Adaptive nonlinear control of a continuous stirred tank reactor
- Anaerobic baffled reactor treatment of biodiesel-processing wastewater with high strength of methanol and glycerol: reactor performance and biogas production
- Analysis of streptolydigin degradation and conversion in cultural supernatants of Streptomyces lydicus AS 4.2501
- Spectroscopic and magnetic evidence of coordination properties of bioactive diethyl (pyridin-4-ylmethyl)phosphate ligand with chloride transition-metal ions
- Microstructure and properties of polyhydroxybutyrate-calcium phosphate cement composites
- Intercalation of basic amino acids into layered zirconium proline-N-methylphosphonate phosphate
- Effect of sol-gel preparation method on particle morphology in pure and nanocomposite PZT thin films
- Synthesis, spectroscopic and configurational study, and ab initio calculations of new diazaphospholanes
- Synthesis and in vitro antimicrobial activity of new 3-(2-morpholinoquinolin-3-yl) substituted acrylonitrile and propanenitrile derivatives
- Silicon-based thiourea-mediated and microwave-assisted thio-Michael addition under solvent-free reaction conditions
- One-pot synthesis of 2-amino-3-cyano-4-arylsubstituted tetrahydrobenzo[b]pyrans catalysed by silica gel-supported polyphosphoric acid (PPA-SiO2) as an efficient and reusable catalyst
- Comparison and optimisation of biodiesel production from Jatropha curcas oil using supercritical methyl acetate and methanol
- Determination of photoredox properties of individual kinetically labile complexes in equilibrium systems
- A halogenated coumarin from Ficus krishnae
- 4β-Isocyanopodophyllotoxins: valuable precursors for the synthesis of new podophyllotoxin analogues
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